CN105838138A - Anti-scraping corrosion-resistant ink and preparation method thereof - Google Patents
Anti-scraping corrosion-resistant ink and preparation method thereof Download PDFInfo
- Publication number
- CN105838138A CN105838138A CN201610387494.2A CN201610387494A CN105838138A CN 105838138 A CN105838138 A CN 105838138A CN 201610387494 A CN201610387494 A CN 201610387494A CN 105838138 A CN105838138 A CN 105838138A
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- resistant ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides anti-scraping corrosion-resistant ink which comprises, by weight parts, 55-68 parts of polyurethane modified epoxy-acrylate resin, 14-21 parts of gum dammar, 7-12 parts of polyterpene phenolic resin, 3-8 parts of butyl methacrylate, 4-9 parts of calcium lignosulfonate, 3-7 parts of nano silica, 1.8-3.4 parts of mica iron oxide, 3-6 parts of short carbon fiber, 2-5 parts of difenoconazole, 1-3.2 parts of coupling agent, 1.5-2.7 parts of flatting agent and 125-150 parts of solvent. After being dried, the prepared anti-scraping corrosion-resistant ink is high in hardness and adhesion and resistant to scraping. The anti-scraping corrosion-resistant ink is excellent in acid and alkali corrosion resistance testing performance, can meet the application requirements in the severe environment and is good in market prospect.
Description
Technical field
The invention belongs to ink material technical field, be specifically related to a kind of scratch resistant corrosion-resistant ink and preparation method thereof.
Background technology
Electrically conductive ink, is dispersed in, with conductive material (gold, silver, copper and carbon), the paste-like ink made in link stuff, is commonly called as paste ink.There is to a certain degree conduction property, can be used as printing conductiving point or conducting wire.Gold system conductive ink, silver system conductive ink, copper system conductive ink, carbon series conductive ink etc. has reached practical, for materials such as printed circuit, electrode, plating bottom, keyboard contact, printed resistors.The dried hardness of existing electrically conductive ink is relatively low, not scratch resistance, and the corrosive nature of its acid and alkali resistance and salt is the best, it is impossible to adapt to the application demand of severe rugged environment.
Summary of the invention
For solving the deficiencies in the prior art, it is an object of the invention to overcome the defect of prior art, it is provided that a kind of scratch resistant corrosion-resistant ink.
In order to realize above-mentioned target, the present invention is achieved by the following technical solutions:
A kind of scratch resistant corrosion-resistant ink, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 55-68 part, gum dammar 14-21 part, terpene phenolic resin 7-12 part, butyl methacrylate 3-8 part, calcium lignosulfonate 4-9 part, nano silicon 3-7 part, micaceous iron oxide 1.8-3.4 part, short carbon fiber 3-6 part, Difenoconazole 2-5 part, coupling agent 1-3.2 part, levelling agent 1.5-2.7 part, solvent 125-150 part.
Preferably, described scratch resistant corrosion-resistant ink, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 62 parts, gum dammar 17 parts, terpene phenolic resin 9 parts, butyl methacrylate 4 parts, calcium lignosulfonate 5 parts, nano silicon 5 parts, micaceous iron oxide 2.3 parts, short carbon fiber 3.5 parts, Difenoconazole 3 parts, coupling agent 1.9 parts, levelling agent 1.7 parts, solvent 140 parts.
Preferably, described coupling agent is γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane or γ-methacryloxypropyl trimethoxy silane.
Preferably, described levelling agent is carboxymethylcellulose calcium.
Preferably, the mixing of one or more during described solvent is ethanol, isopropanol, isophorone, dipropylene glycol methyl ether, butanone and cyclohexanone.
Preferably, a length of 50-150um of described short carbon fiber.
The invention have the benefit that
The dried hardness of scratch resistant corrosion-resistant ink prepared by the present invention is high, and adhesive force is strong, scratch resistance；And acid-alkali-corrosive-resisting performance test excellent performance, the application demand of severe rugged environment can be met, market prospects are good.
Detailed description of the invention
Embodiment 1
A kind of scratch resistant corrosion-resistant ink, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 62 parts, gum dammar 17 parts, terpene phenolic resin 9 parts, butyl methacrylate 4 parts, calcium lignosulfonate 5 parts, nano silicon 5 parts, micaceous iron oxide 2.3 parts, short carbon fiber 3.5 parts, Difenoconazole 3 parts, coupling agent 1.9 parts, levelling agent 1.7 parts, solvent 140 parts.
Described coupling agent is γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.Described levelling agent is carboxymethylcellulose calcium.Described solvent is that ethanol, isopropanol and butanone are by weight the mixing for 1:2:2.The a length of 50-150um of described short carbon fiber.
Embodiment 2
A kind of scratch resistant corrosion-resistant ink, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 55 parts, gum dammar 14 parts, terpene phenolic resin 7 parts, butyl methacrylate 3 parts, calcium lignosulfonate 4 parts, nano silicon 3 parts, micaceous iron oxide 1.8 parts, short carbon fiber 3 parts, Difenoconazole 2 parts, coupling agent 1 part, levelling agent 1.5 parts, solvent 125 parts.
Described coupling agent is γ-methacryloxypropyl trimethoxy silane.Described levelling agent is carboxymethylcellulose calcium.Described solvent is that isophorone, dipropylene glycol methyl ether, cyclohexanone are by weight the mixing for 4:1:2.The a length of 50-150um of described short carbon fiber.
Embodiment 3
A kind of scratch resistant corrosion-resistant ink, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 62 parts, gum dammar 18 parts, terpene phenolic resin 10 parts, butyl methacrylate 5 parts, calcium lignosulfonate 4-9 part, nano silicon 5 parts, micaceous iron oxide 2.6 parts, short carbon fiber 5 parts, Difenoconazole 3.5 parts, coupling agent 2.1 parts, levelling agent 2.1 parts, solvent 132 parts.
Described coupling agent is γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.Described levelling agent is carboxymethylcellulose calcium.Described solvent is that isopropanol, isophorone, butanone are by weight the mixing for 2:3:1.The a length of 50-150um of described short carbon fiber.
Embodiment 4
A kind of scratch resistant corrosion-resistant ink, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 68 parts, gum dammar 21 parts, terpene phenolic resin 12 parts, butyl methacrylate 8 parts, calcium lignosulfonate 9 parts, nano silicon 7 parts, micaceous iron oxide 3.4 parts, short carbon fiber 6 parts, Difenoconazole 5 parts, coupling agent 3.2 parts, levelling agent 2.7 parts, solvent 150 parts.
Described coupling agent is γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.Described levelling agent is carboxymethylcellulose calcium.Described solvent is that isopropanol, isophorone, dipropylene glycol methyl ether are by weight the mixing for 1:2:3.The a length of 50-150um of described short carbon fiber.
The dried hardness of above-mentioned scratch resistant corrosion-resistant ink prepared by the present invention is high, and adhesive force is strong, scratch resistance；And acid-alkali-corrosive-resisting performance test excellent performance, the application demand of severe rugged environment can be met, market prospects are good.
The general principle of the present invention, principal character and advantage have more than been shown and described.Skilled person will appreciate that of the industry, above-described embodiment limits the present invention, the technical scheme that the mode of all employing equivalents or equivalent transformation is obtained the most in any form, all falls within protection scope of the present invention.
Claims (6)
1. a scratch resistant corrosion-resistant ink, it is characterized in that, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 55-68 part, gum dammar 14-21 part, terpene phenolic resin 7-12 part, butyl methacrylate 3-8 part, calcium lignosulfonate 4-9 part, nano silicon 3-7 part, micaceous iron oxide 1.8-3.4 part, short carbon fiber 3-6 part, Difenoconazole 2-5 part, coupling agent 1-3.2 part, levelling agent 1.5-2.7 part, solvent 125-150 part.
Scratch resistant corrosion-resistant ink the most according to claim 1, it is characterised in that described coupling agent is γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane or γ-methacryloxypropyl trimethoxy silane.
Scratch resistant corrosion-resistant ink the most according to claim 1, it is characterised in that described levelling agent is carboxymethylcellulose calcium.
Scratch resistant corrosion-resistant ink the most according to claim 1, it is characterised in that described solvent is the mixing of one or more in ethanol, isopropanol, isophorone, dipropylene glycol methyl ether, butanone and cyclohexanone.
Scratch resistant corrosion-resistant ink the most according to claim 1, it is characterised in that a length of 50-150um of described short carbon fiber.
Scratch resistant corrosion-resistant ink the most according to claim 1, it is characterized in that, including the component of following parts by weight: polyurethane modified epoxy-acrylate resin 62 parts, gum dammar 17 parts, terpene phenolic resin 9 parts, butyl methacrylate 4 parts, calcium lignosulfonate 5 parts, nano silicon 5 parts, micaceous iron oxide 2.3 parts, short carbon fiber 3.5 parts, Difenoconazole 3 parts, coupling agent 1.9 parts, levelling agent 1.7 parts, solvent 140 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610387494.2A CN105838138A (en) | 2016-06-03 | 2016-06-03 | Anti-scraping corrosion-resistant ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610387494.2A CN105838138A (en) | 2016-06-03 | 2016-06-03 | Anti-scraping corrosion-resistant ink and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105838138A true CN105838138A (en) | 2016-08-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610387494.2A Pending CN105838138A (en) | 2016-06-03 | 2016-06-03 | Anti-scraping corrosion-resistant ink and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107962884A (en) * | 2017-11-02 | 2018-04-27 | 苏州太平洋印务有限公司 | A kind of typography of stone paper |
| CN109135414A (en) * | 2018-08-01 | 2019-01-04 | 遵义群建塑胶制品有限公司 | A kind of printing ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101397363A (en) * | 2008-08-19 | 2009-04-01 | 东莞市佳景印刷材料有限公司 | Water ultraviolet light curing epoxy acrylic ester grafted polyurethane and preparation method thereof |
| CN102212304A (en) * | 2011-03-25 | 2011-10-12 | 北京化工大学 | Flexible circuit conductive composition, preparation method and using method thereof |
| CN104151937A (en) * | 2014-07-07 | 2014-11-19 | 杭州海维特化工科技有限公司 | Special ink jet printing machine ink for PE optical cables and cables and preparation method of special ink jet printing machine ink for PE optical cables and cables |
| CN105368270A (en) * | 2015-11-27 | 2016-03-02 | 沈阳顺风新城建筑材料有限公司 | Anticorrosive primer |
-
2016
- 2016-06-03 CN CN201610387494.2A patent/CN105838138A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101397363A (en) * | 2008-08-19 | 2009-04-01 | 东莞市佳景印刷材料有限公司 | Water ultraviolet light curing epoxy acrylic ester grafted polyurethane and preparation method thereof |
| CN102212304A (en) * | 2011-03-25 | 2011-10-12 | 北京化工大学 | Flexible circuit conductive composition, preparation method and using method thereof |
| CN104151937A (en) * | 2014-07-07 | 2014-11-19 | 杭州海维特化工科技有限公司 | Special ink jet printing machine ink for PE optical cables and cables and preparation method of special ink jet printing machine ink for PE optical cables and cables |
| CN105368270A (en) * | 2015-11-27 | 2016-03-02 | 沈阳顺风新城建筑材料有限公司 | Anticorrosive primer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107962884A (en) * | 2017-11-02 | 2018-04-27 | 苏州太平洋印务有限公司 | A kind of typography of stone paper |
| CN109135414A (en) * | 2018-08-01 | 2019-01-04 | 遵义群建塑胶制品有限公司 | A kind of printing ink and preparation method thereof |
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Application publication date: 20160810 |
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| RJ01 | Rejection of invention patent application after publication |