CN105838093A - SBS (styrene-butadiene-styrene) modified asphalt and preparation method thereof - Google Patents
SBS (styrene-butadiene-styrene) modified asphalt and preparation method thereof Download PDFInfo
- Publication number
- CN105838093A CN105838093A CN201610253003.5A CN201610253003A CN105838093A CN 105838093 A CN105838093 A CN 105838093A CN 201610253003 A CN201610253003 A CN 201610253003A CN 105838093 A CN105838093 A CN 105838093A
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- sbs
- stabilizer
- pitch
- colophonium
- sbs modified
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses asphalt and in particular relates to SBS (styrene-butadiene-styrene) modified asphalt and a preparation method thereof. The SBS modified asphalt comprises 88.6-94.9% of matrix asphalt, 4-6% of SBS modifier, 0.1-0.4% of stabilizer and 1-5% of aromatic hydrocarbon oil, wherein the stabilizer is prepared from an accelerant TMTD and sulfur powder. The asphalt has good high and low temperature resistance in regions with larger temperature difference, better rut resistance and good elasticity and toughness, has the effect of improving the fatigue resistance of the pavement, has good strain capacity especially on severely overloaded high flow highways and can conduce to reducing permanent deformation of the pavement.
Description
Technical field
The present invention relates to a kind of Colophonium, be specifically related to a kind of SBS modified pitch and preparation method thereof.
Background technology
In civil engineering, Colophonium is widely used waterproof material and anti-corrosion material, be mainly used in roofing, ground, underground structure waterproof, timber, the anticorrosion of steel.Widely used pavement structure cementing material in Colophonium or road engineering, it can build up the bituminous paving of different structure from the mineral nitrogen material of different compositions after proportioning, application in highways is relatively broad.
Existing Colophonium processing technology is relatively simple, there is poor-performing, easily feels like jelly summer, the defects such as winter is the most dry and cracked.
The Colophonium that matrix pitch i.e. extract from oil or coal.Existing matrix pitch material temperature poor stability, easily isolates in transportation, the road surface easy embrittlement in winter laid with it, easily softens summer;The mixture gap rate of compacting is big, and poor water resistance is easily generated Water Damage;Matrix pitch is macromolecular material, and resistance to ag(e)ing is poor, and durability is difficult to ensure;The retentivity of flatness is poor, and not only sedimentation makes flatness deteriorate, and material softening is easily formed rut.
Summary of the invention
It is an object of the invention to provide a kind of SBS modified pitch and preparation method thereof, solve existing manufacture method and make and go out Colophonium, there is poor-performing, easily feel like jelly summer, the problem that winter is the most dry and cracked.
A kind of SBS modified pitch, the stabilizer of the SBS modifier of matrix pitch, 4~6%, 0.1~0.4% including 88.6%~94.9% and the aromatic naphtha of 1%~5%, wherein said stabilizer is to be configured by TMTD accelerator and Cosan to form.
More detailed proportioning, can be the described SBS modified pitch matrix pitch, the SBS modifier of 5%, the stabilizer of 0.2% and the aromatic naphtha of 3% that include 91.8%.
Further, described matrix pitch is 70#A type Colophonium.
Further, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan.
The manufacture method of a kind of SBS modified pitch, comprises the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 88.6%~94.9% and heats, and is heated to 175 DEG C~185 DEG C;
Step 2, adds the matrix pitch being in 175 DEG C~185 DEG C temperature and produces tank, be simultaneously introduced the SBS modifier of 4~6%, is stirred mixing, and stirring incorporation time was at 1~2 hour;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loads finished pot, and adds 0.1~the stabilizer of 0.4% and the aromatic naphtha of 1%~5% in finished pot, is again stirring for mixing and breeds 1~2 hour, it is thus achieved that SBS modified pitch.
In the manufacture method of this SBS modified pitch, more detailed step is as follows:
Step one, is delivered to high-temperature tank by the matrix pitch of 93% and heats, and is heated to 180 DEG C;
Step 2, adds the matrix pitch being in 180 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 4.5%, is stirred mixing, and stirring incorporation time was at 1~2 hour;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loading finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 2.2% of 0.3%, it is again stirring for mixing and breeds 1~2 hour, it is thus achieved that SBS modified pitch.
Further, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan.
Compared with prior art, the invention has the beneficial effects as follows: on original base, add aromatic naphtha.High temperature resistant, antiinflammatory is trembled with fear, and improves service life, compares environmental protection.
On this SBS modified pitch original base, add aromatic naphtha, can have the most high temperature resistant in the region that the temperature difference is bigger, anti-seismic design;There is preferable rutting resistance, its elastic and good toughness;Improve the anti-fatigue ability on road surface, particularly on big flow, the serious highway that overloads, there is good adaptability to changes, the permanent deformation on road surface can be reduced.
Additionally being thoroughly mixed by modifying agent and matrix pitch in the manufacture method of SBS modified pitch, not only make Colophonium obtain homogenizing process with modified, and make the mutual tractive of strand of modifying agent, net distribution, improve the intensity of compound, enhance anti-fatigue ability.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
Embodiment 1:
A kind of SBS modified pitch, matrix pitch, the SBS modifier of 6%, the stabilizer of 0.4% and the aromatic naphtha of 5% including 88.6%%, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan, and described SBS modifier is can be thermoplastic styrene butadiene rubber.
Its manufacture method is to comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 88.6% and heats, and is heated to 185 DEG C;
Step 2, adds the matrix pitch being in 185 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 6%, is stirred mixing, and stirring incorporation time was at 2 hours;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loading finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 5% of 0.4%, it is again stirring for mixing and breeds 1~2 hour, it is thus achieved that SBS modified pitch.
Embodiment 2:
A kind of SBS modified pitch, the stabilizer of the SBS modifier of matrix pitch, 4~6%, 0.1~0.4% including 94.9% and the aromatic naphtha of 1%~5%, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan, and described SBS modifier is can be thermoplastic styrene butadiene rubber.
Its manufacture method is to comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 94.9% and heats, and is heated to 178 DEG C;
Step 2, adds the matrix pitch being in 178 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 4%, is stirred mixing, and stirring incorporation time was at 2 hours;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loading finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 1% of 0.1%, it is again stirring for mixing and breeds 2 hours, it is thus achieved that SBS modified pitch.
Embodiment 3:
A kind of SBS modified pitch, matrix pitch, the SBS modifier of 5%, the stabilizer of 0.2% and the aromatic naphtha of 3% including 91.8%, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan, and described SBS modifier is can be thermoplastic styrene butadiene rubber.
Its manufacture method is to comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 91.8%% and heats, and is heated to 180 DEG C;
Step 2, adds the matrix pitch being in 180 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 5%, is stirred mixing, and stirring incorporation time was at 1.5 hours;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loading finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 3% of 0.2%, it is again stirring for mixing and breeds 1.5 hours, it is thus achieved that SBS modified pitch.
Embodiment 4:
A kind of SBS modified pitch, matrix pitch, the SBS modifier of 3%, the stabilizer of 0.3 and the aromatic naphtha of 2% including 94.7%, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan, and described SBS modifier is can be thermoplastic styrene butadiene rubber.
Its manufacture method is to comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 94.7% and heats, and is heated to 182 DEG C;
Step 2, adds the matrix pitch being in 182 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 3%, is stirred mixing, and stirring incorporation time was at 2 hours;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loading finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 2% of 0.3%, it is again stirring for mixing and breeds 2 hours, it is thus achieved that SBS modified pitch.
Embodiment 5:
A kind of SBS modified pitch, matrix pitch, the SBS modifier of 4%, the stabilizer of 0.2% and the aromatic naphtha of 5% including 90.8%, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan, and described SBS modifier is can be thermoplastic styrene butadiene rubber.
Its manufacture method is to comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 90.8% and heats, and is heated to 175 DEG C;
Step 2, adds the matrix pitch being in 175 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 4%, is stirred mixing, and stirring incorporation time was at 1~2 hour;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loads finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 5% of 0.2%, it is again stirring for mixing and breeds 1 hour, obtain SBS modified pitch, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan, and described SBS modifier is can be thermoplastic styrene butadiene rubber.
Embodiment 6:
A kind of SBS modified pitch, matrix pitch, the SBS modifier of 4.5 %, the stabilizer of 0.3% and the aromatic naphtha of 2.2% including 93%, described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan, and described SBS modifier is can be thermoplastic styrene butadiene rubber.
Its manufacture method is to comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 93% and heats, and is heated to 180 DEG C;
Step 2, adds the matrix pitch being in 180 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 4.5%, is stirred mixing, and stirring incorporation time was at 1~2 hour;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loading finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 2.2% of 0.3%, it is again stirring for mixing and breeds 1~2 hour, it is thus achieved that SBS modified pitch.
Although reference be made herein to invention has been described for the multiple explanatory embodiment of the present invention, but, it should be understood that those skilled in the art can be designed that a lot of other amendments and embodiment, these amendments and embodiment will fall within spirit disclosed in the present application and spirit.More specifically, in the range of disclosure and claim, the building block of theme composite configuration and/or layout can be carried out multiple modification and improvement.In addition to the deformation carrying out building block and/or layout and improving, to those skilled in the art, other purposes also will be apparent from.
Claims (7)
1. a SBS modified pitch, it is characterised in that: including stabilizer and the aromatic naphtha of 1%~5% of the SBS modifier of matrix pitch, 4~6%, 0.1~0.4% of 88.6%~94.9%, wherein said stabilizer is to be configured by TMTD accelerator and Cosan to form.
A kind of SBS modified pitch the most according to claim 1, it is characterised in that include matrix pitch, the SBS modifier of 5%, the stabilizer of 0.2% and the aromatic naphtha of 3% of 91.8% described in:.
A kind of SBS modified pitch the most according to claim 1, it is characterised in that: described matrix pitch is 70#A type Colophonium.
4. according to a kind of SBS modified pitch described in claim 1-3 any one, it is characterised in that: described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan.
5. the manufacture method of a SBS modified pitch, it is characterised in that comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 88.6%~94.9% and heats, and is heated to 175 DEG C~185 DEG C;
Step 2, adds the matrix pitch being in 175 DEG C~185 DEG C temperature and produces tank, be simultaneously introduced the SBS modifier of 4~6%, is stirred mixing, and stirring incorporation time was at 1~2 hour;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loads finished pot, and adds 0.1~the stabilizer of 0.4% and the aromatic naphtha of 1%~5% in finished pot, is again stirring for mixing and breeds 1~2 hour, it is thus achieved that SBS modified pitch.
The manufacture method of a kind of SBS modified pitch the most according to claim 5, it is characterised in that comprise the following steps:
Step one, is delivered to high-temperature tank by the matrix pitch of 93% and heats, and is heated to 180 DEG C;
Step 2, adds the matrix pitch being in 180 DEG C of temperature and produces tank, be simultaneously introduced the SBS modifier of 4.5%, is stirred mixing, and stirring incorporation time was at 1~2 hour;
Step 3, makes it fully dissolve by grinding machine the Colophonium being stirred;
Step 4, the Colophonium fully dissolved loading finished pot, and in finished pot, add stabilizer and the aromatic naphtha of 2.2% of 0.3%, it is again stirring for mixing and breeds 1~2 hour, it is thus achieved that SBS modified pitch.
7. according to the manufacture method of a kind of SBS modified pitch described in claim 5 or 6, it is characterised in that: described stabilizer is to be formed with the proportional arrangement of 2:1 by TMTD accelerator and Cosan.
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CN201610253003.5A CN105838093A (en) | 2016-04-22 | 2016-04-22 | SBS (styrene-butadiene-styrene) modified asphalt and preparation method thereof |
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CN201610253003.5A CN105838093A (en) | 2016-04-22 | 2016-04-22 | SBS (styrene-butadiene-styrene) modified asphalt and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108948753A (en) * | 2017-05-17 | 2018-12-07 | 中路高科(北京)公路技术有限公司 | A kind of warm mix high adhered modification pitch and its preparation and application |
CN109897393A (en) * | 2019-04-03 | 2019-06-18 | 浙江鑫长胜材料科技有限公司 | A kind of SBS modified pitch and preparation method thereof |
CN113861708A (en) * | 2021-10-19 | 2021-12-31 | 广州鸿绵合成材料有限公司 | High-viscosity high-elasticity modified asphalt and preparation method thereof |
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CN102898851A (en) * | 2012-11-12 | 2013-01-30 | 天津市恒悦化工有限公司 | Styrene butadiene styrene (SBS) high-performance modified asphalt and preparation method thereof |
CN103194072A (en) * | 2013-04-25 | 2013-07-10 | 交通运输部公路科学研究所 | Complex modified asphalt composition and preparation method thereof |
CN103613942A (en) * | 2013-12-12 | 2014-03-05 | 辽宁瑞德公路科技有限公司 | High-viscosity thermo-stability asphalt and preparation method thereof |
CN103980724A (en) * | 2014-05-30 | 2014-08-13 | 福建省燕宁顺通科技发展有限责任公司 | Preparation method of rubber modified asphalt |
CN104312173A (en) * | 2014-10-21 | 2015-01-28 | 吉林省嘉瑞沥青科技有限公司 | Rubber composite modified asphalt and preparation method thereof |
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2016
- 2016-04-22 CN CN201610253003.5A patent/CN105838093A/en active Pending
Patent Citations (6)
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CN102585525A (en) * | 2012-01-12 | 2012-07-18 | 山东华瑞道路材料技术有限公司 | SBS (styrene-butadiene-styrene) modified asphalt with stable thermal storage and preparation process thereof |
CN102898851A (en) * | 2012-11-12 | 2013-01-30 | 天津市恒悦化工有限公司 | Styrene butadiene styrene (SBS) high-performance modified asphalt and preparation method thereof |
CN103194072A (en) * | 2013-04-25 | 2013-07-10 | 交通运输部公路科学研究所 | Complex modified asphalt composition and preparation method thereof |
CN103613942A (en) * | 2013-12-12 | 2014-03-05 | 辽宁瑞德公路科技有限公司 | High-viscosity thermo-stability asphalt and preparation method thereof |
CN103980724A (en) * | 2014-05-30 | 2014-08-13 | 福建省燕宁顺通科技发展有限责任公司 | Preparation method of rubber modified asphalt |
CN104312173A (en) * | 2014-10-21 | 2015-01-28 | 吉林省嘉瑞沥青科技有限公司 | Rubber composite modified asphalt and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108948753A (en) * | 2017-05-17 | 2018-12-07 | 中路高科(北京)公路技术有限公司 | A kind of warm mix high adhered modification pitch and its preparation and application |
CN108948753B (en) * | 2017-05-17 | 2021-03-16 | 中路高科(北京)公路技术有限公司 | Warm-mixed high-viscosity modified asphalt and preparation and application thereof |
CN109897393A (en) * | 2019-04-03 | 2019-06-18 | 浙江鑫长胜材料科技有限公司 | A kind of SBS modified pitch and preparation method thereof |
CN113861708A (en) * | 2021-10-19 | 2021-12-31 | 广州鸿绵合成材料有限公司 | High-viscosity high-elasticity modified asphalt and preparation method thereof |
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Application publication date: 20160810 |