CN105837191A - Ceramic tiles improving environment temperature and preparation method thereof - Google Patents
Ceramic tiles improving environment temperature and preparation method thereof Download PDFInfo
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- CN105837191A CN105837191A CN201610181092.7A CN201610181092A CN105837191A CN 105837191 A CN105837191 A CN 105837191A CN 201610181092 A CN201610181092 A CN 201610181092A CN 105837191 A CN105837191 A CN 105837191A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002699 waste material Substances 0.000 claims abstract description 14
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010881 fly ash Substances 0.000 claims abstract description 13
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 13
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052878 cordierite Inorganic materials 0.000 claims abstract description 11
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 11
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003094 microcapsule Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 16
- 239000012153 distilled water Substances 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 238000000498 ball milling Methods 0.000 claims description 10
- 239000012267 brine Substances 0.000 claims description 10
- 239000006071 cream Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 235000013379 molasses Nutrition 0.000 claims description 10
- 239000011863 silicon-based powder Substances 0.000 claims description 10
- 239000010802 sludge Substances 0.000 claims description 10
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 10
- 238000003825 pressing Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract 3
- 239000010432 diamond Substances 0.000 abstract 2
- 229910003460 diamond Inorganic materials 0.000 abstract 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 230000000703 anti-shock Effects 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000013081 microcrystal Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910052596 spinel Inorganic materials 0.000 abstract 1
- 239000011029 spinel Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000006188 syrup Substances 0.000 abstract 1
- 235000020357 syrup Nutrition 0.000 abstract 1
- 235000018553 tannin Nutrition 0.000 abstract 1
- 229920001864 tannin Polymers 0.000 abstract 1
- 239000001648 tannin Substances 0.000 abstract 1
- 239000002383 tung oil Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000009413 insulation Methods 0.000 description 3
- 101100027969 Caenorhabditis elegans old-1 gene Proteins 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/195—Alkaline earth aluminosilicates, e.g. cordierite or anorthite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3804—Borides
- C04B2235/3813—Refractory metal borides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
- C04B2235/427—Diamond
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Treatment Of Sludge (AREA)
Abstract
The invention discloses a ceramic tile improving environment temperature and a preparation method thereof and relates to the technical field of ceramic tiles. The ceramic tile is mainly produced from cordierite, spinel, fly ash, zirconium boride, silicon micro-powder, salt mud, diamond micro-powder, seashell mud, microcrystal kaolin, phase-change microcapsules, waste mortar, waste syrup, tung oil, valex tannin extract, sodium tripolyphosphate and ammonium citrate. The ceramic tile is high in mechanical strength, is low in water absorption, is good in thermal anti-shock property and is good in corrosion resistance. The added fly ash and waste mortar reduces production cost and environment pollution. The zirconium boride and the diamond micro-powder have synergistic effects to improve strength and anti-wear performance of the ceramic tile. The added phase-change microcapsules enable environment to be warm in winter and cool in summer, thereby improving living comfort.
Description
Technical field
The present invention relates to Ceramic Tiles technical field, a kind of Ceramic Tiles improving ambient temperature and system thereof
Preparation Method.
Background technology
Ceramic Tiles is by clay and other inorganic non-metallic raw materials, through tabular or the bulk of the production of the technique such as molding, sintering
Ceramic, for decorating and protect building, the metope of structures and ground.Generally the most at room temperature by dry-pressing, extruding or
Other forming method molding, are then dried, burn till at a certain temperature.
In recent years, developing rapidly along with China's Building Ceramics Industry so that the performance requirement of Ceramic Tiles is also got over by people
Come the highest.The function of Ceramic Tiles is more single in the market, the most only decoration function, can improve ambient temperature, improves people
The Ceramic Tiles of residence comfort do not occur.
Summary of the invention
The invention aims to make up the deficiencies in the prior art, it is provided that a kind of Ceramic Tiles improving ambient temperature and
Its preparation method.
It is an object of the invention to be achieved through the following technical solutions:
A kind of Ceramic Tiles improving ambient temperature, is made up of following raw material: cordierite 18-20, spinelle 16-18,
Flyash 6-8, zirconium boride 3-5, silicon powder 2-4, brine sludge 4-6, diadust 1-3, sea cowry mud 2-4, white cream mud 1-3, phase transformation
Microcapsule 4-6, waste mortar 3-5, molasses 5-7, Oleum Verniciae fordii 2-4, valonea extract 1-3, sodium tripolyphosphate 5-7, ammonium citrate 3-6.
The preparation method of a kind of Ceramic Tiles improving ambient temperature, comprises the following steps:
(1) by cordierite, spinelle mix homogeneously, putting in the hydrochloric acid solution that concentration is 0.6-0.8mol/L, heating in water bath is extremely
It is incubated 3-4 hour after 65-75 DEG C, then filters and be washed with distilled water to neutrality, placing into the hydrogen-oxygen that concentration is 1-2mol/L
Change in sodium solution, heating in water bath to isothermal holding after 80-90 DEG C 1-2 hour, filter and be washed with distilled water to neutrality, after drying
Take out and shrend after calcining 2-3 hour at 1220-1280 DEG C, dry, pulverize, cross 200 mesh sieves, standby；
(2) by molasses, Oleum Verniciae fordii mixing, silicon powder, diadust, sodium tripolyphosphate, ammonium citrate ultrasonic disperse are added
Uniformly, standby；
(3) flyash, zirconium boride, brine sludge, sea cowry mud, waste mortar, white cream mud are added to ball milling in ball mill, batch mixing mistake after ball milling
400 mesh sieves, then by batch mixing, the raw material of step (1), the mixing raw material of step (2) and other residual componentss in batch mixer
Mix 2-3 hour, add the stirring of appropriate distilled water and form hygrometric state compound, old 1-2 days of homogenizing, standby；
(4) by old good material pressurize 4-6 minute under the pressure of 18-24MPa, half dry-pressing is compressing, is then fed into height
Carrying out roasting in temperature resistance furnace, be wherein all incubated 1 hour under 500 ° of C, 700 ° of C, 900 ° of C, 1100 ° of C, 1200 ° of C, roasting is tied
Take out after bundle and get final product.
It is an advantage of the current invention that:
The Ceramic Tiles mechanical strength of the present invention is high, and water absorption rate is low, and hot shock resistance is good, good corrosion resistance, flyash, the adding of waste mortar
Adding, saved production cost, decrease environmental pollution, zirconium boride, diadust interact, and improve the intensity of Ceramic Tiles
And anti-wear performance, the interpolation of phase-change microcapsule, ambient temperature can be made cool in summer and warm in winter, improve residence comfort.
Detailed description of the invention
Embodiment 1, a kind of Ceramic Tiles improving ambient temperature, it is made up of following weight (kg) raw material: cordierite 18, point
Spar 16, flyash 6, zirconium boride 3, silicon powder 2, brine sludge 4, diadust 1, sea cowry mud 2, white cream mud 1, phase-change microcapsule 4,
Waste mortar 3, molasses 5, Oleum Verniciae fordii 2, valonea extract 1, sodium tripolyphosphate 5, ammonium citrate 3.
The preparation method of a kind of Ceramic Tiles improving ambient temperature, comprises the following steps:
(1) by cordierite, spinelle mix homogeneously, put in the hydrochloric acid solution that concentration is 0.6mol/L, heating in water bath to 65 DEG C
Rear insulation 3 hours, then filters and is washed with distilled water to neutrality, places in the sodium hydroxide solution that concentration is 1mol/L,
Heating in water bath, to isothermal holding after 80 DEG C 1 hour, filters and is washed with distilled water to neutrality, calcine 2 after drying at 1220 DEG C
Take out and shrend after hour, dry, pulverize, cross 200 mesh sieves, standby；
(2) by molasses, Oleum Verniciae fordii mixing, silicon powder, diadust, sodium tripolyphosphate, ammonium citrate ultrasonic disperse are added
Uniformly, standby；
(3) flyash, zirconium boride, brine sludge, sea cowry mud, waste mortar, white cream mud are added to ball milling in ball mill, batch mixing mistake after ball milling
400 mesh sieves, then by batch mixing, the raw material of step (1), the mixing raw material of step (2) and other residual componentss in batch mixer
Mix 2 hours, add the stirring of appropriate distilled water and form hygrometric state compound, old 1 day of homogenizing, standby；
(4) by old good material pressurize 4 minutes under the pressure of 18MPa, half dry-pressing is compressing, is then fed into high temperature resistance
Carrying out roasting in stove, be wherein all incubated 1 hour under 500 ° of C, 700 ° of C, 900 ° of C, 1100 ° of C, 1200 ° of C, roasting takes after terminating
Go out and get final product.
Embodiment 2, a kind of Ceramic Tiles improving ambient temperature, it is made up of following weight (kg) raw material: cordierite 19, point
Spar 17, flyash 7, zirconium boride 4, silicon powder 3, brine sludge 5, diadust 2, sea cowry mud 3, white cream mud 2, phase-change microcapsule 5,
Waste mortar 4, molasses 6, Oleum Verniciae fordii 3, valonea extract 2, sodium tripolyphosphate 6, ammonium citrate 5.
The preparation method of a kind of Ceramic Tiles improving ambient temperature, comprises the following steps:
(1) by cordierite, spinelle mix homogeneously, put in the hydrochloric acid solution that concentration is 0.7mol/L, heating in water bath to 70 DEG C
Rear insulation 3.5 hours, then filters and is washed with distilled water to neutrality, places into the sodium hydroxide solution that concentration is 1.5mol/L
In, isothermal holding 1.5 hours after heating in water bath to 85 DEG C, filter and be washed with distilled water to neutrality, after drying at 1250 DEG C
Take out and shrend after calcining 2.5 hours, dry, pulverize, cross 200 mesh sieves, standby；
(2) by molasses, Oleum Verniciae fordii mixing, silicon powder, diadust, sodium tripolyphosphate, ammonium citrate ultrasonic disperse are added
Uniformly, standby；
(3) flyash, zirconium boride, brine sludge, sea cowry mud, waste mortar, white cream mud are added to ball milling in ball mill, batch mixing mistake after ball milling
400 mesh sieves, then by batch mixing, the raw material of step (1), the mixing raw material of step (2) and other residual componentss in batch mixer
Mix 2.5 hours, add the stirring of appropriate distilled water and form hygrometric state compound, old 1 day of homogenizing, standby；
(4) by old good material pressurize 5 minutes under the pressure of 21MPa, half dry-pressing is compressing, is then fed into high temperature resistance
Carrying out roasting in stove, be wherein all incubated 1 hour under 500 ° of C, 700 ° of C, 900 ° of C, 1100 ° of C, 1200 ° of C, roasting takes after terminating
Go out and get final product.
Embodiment 3, a kind of Ceramic Tiles improving ambient temperature, it is made up of following weight (kg) raw material: cordierite 20, point
Spar 18, flyash 8, zirconium boride 5, silicon powder 4, brine sludge 6, diadust 3, sea cowry mud 4, white cream mud 3, phase-change microcapsule 6,
Waste mortar 5, molasses 7, Oleum Verniciae fordii 4, valonea extract 3, sodium tripolyphosphate 7, ammonium citrate 6.
The preparation method of a kind of Ceramic Tiles improving ambient temperature, comprises the following steps:
(1) by cordierite, spinelle mix homogeneously, put in the hydrochloric acid solution that concentration is 0.8mol/L, heating in water bath to 75 DEG C
Rear insulation 4 hours, then filters and is washed with distilled water to neutrality, places in the sodium hydroxide solution that concentration is 2mol/L,
Heating in water bath, to isothermal holding after 90 DEG C 2 hours, filters and is washed with distilled water to neutrality, calcine 3 after drying at 1280 DEG C
Take out and shrend after hour, dry, pulverize, cross 200 mesh sieves, standby；
(2) by molasses, Oleum Verniciae fordii mixing, silicon powder, diadust, sodium tripolyphosphate, ammonium citrate ultrasonic disperse are added
Uniformly, standby；
(3) flyash, zirconium boride, brine sludge, sea cowry mud, waste mortar, white cream mud are added to ball milling in ball mill, batch mixing mistake after ball milling
400 mesh sieves, then by batch mixing, the raw material of step (1), the mixing raw material of step (2) and other residual componentss in batch mixer
Mix 3 hours, add the stirring of appropriate distilled water and form hygrometric state compound, old 2 days of homogenizing, standby；
(4) by old good material pressurize 6 minutes under the pressure of 24MPa, half dry-pressing is compressing, is then fed into high temperature resistance
Carrying out roasting in stove, be wherein all incubated 1 hour under 500 ° of C, 700 ° of C, 900 ° of C, 1100 ° of C, 1200 ° of C, roasting takes after terminating
Go out and get final product.
The main performance testing result of the Ceramic Tiles that above-described embodiment 1-3 prepares is as follows:
The main performance testing result of the Ceramic Tiles that table 1 embodiment 1-3 prepares
| Sequence number | Breakdown strength (N) | Water absorption rate (%) | The modulus of rupture (MPa) | Stain resistance | Angularity (%) |
| Embodiment 1 | 1435 | 0.39 | 36 | 5 grades | ±0.03 |
| Embodiment 2 | 1460 | 0.36 | 38 | 5 grades | ±0.03 |
| Embodiment 3 | 1420 | 0.37 | 36 | 5 grades | ±0.03 |
Claims (2)
1. the Ceramic Tiles that can improve ambient temperature, it is characterised in that: it is made up of following raw material: cordierite 18-20,
Spinelle 16-18, flyash 6-8, zirconium boride 3-5, silicon powder 2-4, brine sludge 4-6, diadust 1-3, sea cowry mud 2-4, white
Cream mud 1-3, phase-change microcapsule 4-6, waste mortar 3-5, molasses 5-7, Oleum Verniciae fordii 2-4, valonea extract 1-3, sodium tripolyphosphate 5-7,
Ammonium citrate 3-6.
The preparation method of a kind of Ceramic Tiles improving ambient temperature the most according to claim 1, it is characterised in that: include
Following steps:
(1) by cordierite, spinelle mix homogeneously, putting in the hydrochloric acid solution that concentration is 0.6-0.8mol/L, heating in water bath is extremely
It is incubated 3-4 hour after 65-75 DEG C, then filters and be washed with distilled water to neutrality, placing into the hydrogen-oxygen that concentration is 1-2mol/L
Change in sodium solution, heating in water bath to isothermal holding after 80-90 DEG C 1-2 hour, filter and be washed with distilled water to neutrality, after drying
Take out and shrend after calcining 2-3 hour at 1220-1280 DEG C, dry, pulverize, cross 200 mesh sieves, standby；
(2) by molasses, Oleum Verniciae fordii mixing, silicon powder, diadust, sodium tripolyphosphate, ammonium citrate ultrasonic disperse are added
Uniformly, standby；
(3) flyash, zirconium boride, brine sludge, sea cowry mud, waste mortar, white cream mud are added to ball milling in ball mill, batch mixing mistake after ball milling
400 mesh sieves, then by batch mixing, the raw material of step (1), the mixing raw material of step (2) and other residual componentss in batch mixer
Mix 2-3 hour, add the stirring of appropriate distilled water and form hygrometric state compound, old 1-2 days of homogenizing, standby；
(4) by old good material pressurize 4-6 minute under the pressure of 18-24MPa, half dry-pressing is compressing, is then fed into height
Carrying out roasting in temperature resistance furnace, be wherein all incubated 1 hour under 500 ° of C, 700 ° of C, 900 ° of C, 1100 ° of C, 1200 ° of C, roasting is tied
Take out after bundle and get final product.
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| CN201610181092.7A CN105837191A (en) | 2016-03-28 | 2016-03-28 | Ceramic tiles improving environment temperature and preparation method thereof |
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| CN201610181092.7A CN105837191A (en) | 2016-03-28 | 2016-03-28 | Ceramic tiles improving environment temperature and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020069590A1 (en) * | 2018-10-05 | 2020-04-09 | Braskem S.A. | Ceramic coating composition, method for obtaining a ceramic coating base mass, use of the ceramic coating composition and ceramic panel |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102503319A (en) * | 2011-10-24 | 2012-06-20 | 沈阳建筑大学 | Phase-change-energy-storage phase change concrete and preparation method |
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