CN105833887A - 一种BiOCl/β-FeOOH复合纳米材料及其制备方法 - Google Patents
一种BiOCl/β-FeOOH复合纳米材料及其制备方法 Download PDFInfo
- Publication number
- CN105833887A CN105833887A CN201610207665.9A CN201610207665A CN105833887A CN 105833887 A CN105833887 A CN 105833887A CN 201610207665 A CN201610207665 A CN 201610207665A CN 105833887 A CN105833887 A CN 105833887A
- Authority
- CN
- China
- Prior art keywords
- biocl
- feooh
- beta
- preparation
- composite nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 229910003153 β-FeOOH Inorganic materials 0.000 title claims abstract description 52
- 239000002131 composite material Substances 0.000 title claims abstract description 33
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 10
- 239000008103 glucose Substances 0.000 claims abstract description 10
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 10
- 239000012153 distilled water Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims description 9
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical compound [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 claims description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 230000001699 photocatalysis Effects 0.000 abstract description 7
- 230000003197 catalytic effect Effects 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 239000003054 catalyst Substances 0.000 abstract description 4
- 239000010865 sewage Substances 0.000 abstract description 2
- 239000002073 nanorod Substances 0.000 abstract 2
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 abstract 1
- 239000002135 nanosheet Substances 0.000 abstract 1
- 239000002957 persistent organic pollutant Substances 0.000 abstract 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 43
- 239000000243 solution Substances 0.000 description 28
- 239000000047 product Substances 0.000 description 17
- 238000013019 agitation Methods 0.000 description 6
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 5
- 229940012189 methyl orange Drugs 0.000 description 5
- 238000007146 photocatalysis Methods 0.000 description 5
- 238000002835 absorbance Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000002114 nanocomposite Substances 0.000 description 3
- 239000002055 nanoplate Substances 0.000 description 3
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000002003 electron diffraction Methods 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000010183 spectrum analysis Methods 0.000 description 2
- 229910002588 FeOOH Inorganic materials 0.000 description 1
- 239000012028 Fenton's reagent Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- -1 transition-metal sulphides Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/40—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/026—Fenton's reagent
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Compounds Of Iron (AREA)
Abstract
一种BiOCl/β‑FeOOH复合纳米材料及其制备方法，涉及复合纳米材料技术领域。先将FeCl3·6H2O溶解于蒸馏水中，再依次加入Bi(NO3)3·5H2O、葡萄糖后混合均匀，调节pH值至3～6，然后经水热合成反应得到BiOCl/β‑FeOOH复合纳米材料。采用低温水热法合成，通过葡萄糖生物大分子来控制β‑FeOOH纳米棒在BiOCl纳米片上的附着生长，在BiOCl/β‑FeOOH纳米复合材料的结构中，呈纺锤形的β‑FeOOH纳米棒分布在呈片状的BiOCl上，这种纳米复合材料具有较高的比表面积、优异的光催化和类芬顿催化活性等优点，可望用作脱除污水中各类有机污染物的有效催化剂。
Description
技术领域
本发明涉及复合纳米材料技术领域，具体是涉及一种BiOCl/β-FeOOH复合纳米材料及其制备方法。
背景技术
羟基氧化铁(β-FeOOH)是一种性能优良的功能材料，可用作颜料、催化剂、磁记录介质的前驱体、磁性涂料和气体传感器等。具有成本低廉和较高的比表面积，可用作吸附剂和类芬顿试剂，在催化、医药和生物领域有着重要的应用价值。
氯氧化铋(BiOCl)作为过渡族金属硫化物，纳米BiOCl具有比表面积大，可作为光催化剂来去除有机污染物。然而，纳米BiOCl光催化剂对可见光响应范围狭小的，因而，其可见光催化效应不明显。已研究表明，β-FeOOH和BiOCl都为层状结构，这为两者的复合提供可能的依据。目前，关于利用β-FeOOH来调控BiOCl光催化性能方面的研究报道较少。
发明内容
为了克服现有技术中存在的上述缺陷，本发明的目的在于提供了一种BiOCl/β-FeOOH复合纳米材料及其制备方法，获得的复合材料具有优异的可见光和类芬顿双重催化功能。
为实现该目的，本发明采用了以下技术方案：
一种BiOCl/β-FeOOH复合纳米材料，呈纺锤形的β-FeOOH纳米棒分布在呈片状的BiOCl上。
一种BiOCl/β-FeOOH复合纳米材料的制备方法，先将FeCl3·6H2O溶解于蒸馏水中，再依次加入Bi(NO3)3·5H2O、葡萄糖后混合均匀，调节pH值至3～6，然后经水热合成反应得到BiOCl/β-FeOOH复合纳米材料。
作为上述制备方法的进一步改进，反应体系中FeCl3·6H2O、Bi(NO3)3·5H2O和葡萄糖的质量浓度依次为0.27～1.35g/mL、0.485～7.276g/mL、3.5～8.5g/L。水热合成反应的时间为24～48h，反应温度为80～100℃。水热合成反应产物经固液分离、洗涤、烘干得到复合纳米材料，烘干温度为60～80℃，烘干时间为2～6h。
与现有技术相比，本发明的有益效果表现在：
1、本发明采用低温水热法合成，通过葡萄糖生物大分子来控制β-FeOOH纳米棒在BiOCl纳米片上的附着生长，在BiOCl/β-FeOOH纳米复合材料的结构中，呈纺锤形的β-FeOOH纳米棒分布在呈片状的BiOCl上，这种纳米复合材料具有较高的比表面积、优异的光催化和类芬顿催化活性等优点，可望用作脱除污水中各类有机污染物的有效催化剂。另外，在颜料和磁性元件等方面上也有潜在的应用价值。
2、本发明制备方法工艺简单，整个制备体系容易构建、操作简便、条件易控、成本低廉、产物组成可控、适合于大规模工业生产。采用常规可溶性铁盐作为反应物，在制备过程中产生的副产物少，对环境污染较小，是一种环保型合成工艺。
附图说明
图1是实施例1所得产物的XRD谱图
图2a是实施例1所得产物的扫描电镜图像。
图2b是对单个BiOCl/β-FeOOH复合片的面扫描能谱分析图。
图3a是实施例1所得产物的低倍率TEM投射照片。
图3b是BiOCl和β-FeOOH的电子衍射分析结果。
图4是β-FeOOH、BiOCl和β-FeOOH/BiOCl三者的紫外-可见吸收光谱图。
图5是β-FeOOH、BiOCl和β-FeOOH/BiOCl复合材料光催化降解甲基橙的动力学曲线。
具体实施方式
以下结合实施例以及附图对本发明作进一步详细描述。
实施例1
(1)、将27g的FeCl3·6H2O溶解在100mL蒸馏水中，室温下磁力搅拌2分钟使之充分溶解得到溶液a。
(2)、称取48.5g的Bi(NO3)3·5H2O加入到上述溶液a中，继续磁力搅拌1分钟得到溶液b。
(3)、称0.35g的葡萄糖加入到溶液b中，用HCl溶液调节溶液pH为3，得到溶液c。
(4)、将溶液c装入反应釜中进行水热合成反应，反应时间为24h，反应温度为100℃。
(5)、反应结束后取出产物，经过洗涤、离心和干燥，得到目标产物，烘干温度为70℃，烘干时间为4h。
图1为实施例1所得产物的XRD谱图。将产物的XRD所有衍射峰与标准BiOCl(PDF#34-1266)与β-FeOOH(PDF#06-0249)的XRD谱图进行对比分析，可以看出，所得产物中出现了BiOCl和β-FeOOH的特征衍射峰，可以初步确定所得的产物为BiOCl/β-FeOOH复合物，且两者的结晶度较高。
图2a是实施例1所得产物的扫描电镜图像，从图中可以看出在片状的BiOCl上分布着纺锤形的β-FeOOH纳米棒，片状BiOCl的尺寸约为几个微米。图2b是对单个BiOCl/β-FeOOH复合片进行了面扫描能谱分析图，从分析结果中可以看出，Bi和Cl元素的分布均匀，且形状基本一致，而Fe和O元素分布区域基本一致。结合图1的XRD和图2b的能谱分析结果，可初步认为得到的产物为BiOCl/β-FeOOH复合片。
为了进一步确认复合纳米片中的BiOCl和β-FeOOH两者的结合关系，对产物进行了TEM和HRTEM分析，其结果如图3所示。图3a为产物的低倍投射照片，由图3a可以清晰看出，复合纳米片是由片状的BiOCl和纺锤形的β-FeOOH构成。图3b为两者的电子衍射分析结果，从图3b中标注的结果进一步可以证明，复合纳米片中BiOCl和β-FeOOH位向关系，两者依附生长在一起，结晶程度高。
图4是β-FeOOH、BiOCl和β-FeOOH/BiOCl三者的紫外-可见吸收光谱图。从图4中可以看出，纯的BiOCl和β-FeOOH的吸收峰均在360nm左右，说明两者在可见光范围内(＞420nm)内吸收不明显。而BiOCl/β-FeOOH复合纳米片最大吸收峰为480nm左右，说明获得的BiOCl/β-FeOOH复合纳米材料具有良好的可见光吸收性能。
实施例2
(1)、将135g的FeCl3·6H2O溶解在100mL蒸馏水中，室温下磁力搅拌3分钟使之充分溶解得到溶液a。
(2)、称取48.5g的Bi(NO3)3·5H2O加入到上述溶液a中，继续磁力搅拌1分钟得到溶液b。
(3)、称0.55g的葡萄糖加入到溶液b中，用HCl溶液调节溶液pH为4，得到溶液c。
(4)、将溶液c装入反应釜中进行水热合成反应，反应时间为48h，反应温度为80℃。
(5)、反应结束后取出产物，经过洗涤、离心和干燥，得到目标产物，烘干温度为80℃，烘干时间为2h。
实施例3
(1)、将27g的FeCl3·6H2O溶解在100mL蒸馏水中，室温下磁力搅拌1分钟使之充分溶解得到溶液a。
(2)、称取727.6g的Bi(NO3)3·5H2O加入到上述溶液a中，继续磁力搅拌3分钟得到溶液b。
(3)、称0.85g的葡萄糖加入到溶液b中，用HCl溶液调节溶液pH为6，得到溶液c。
(4)、将溶液c装入反应釜中进行水热合成反应，反应时间为36h，反应温度为90℃。
(5)、反应结束后取出产物，经过洗涤、离心和干燥，得到目标产物，烘干温度为60℃，烘干时间为6h。
实施例4(BiOCl/β-FeOOH纳米复合材料光催化降解污染物)
(1)、以甲基橙为目标污染物，在100mL甲基橙初始浓度为20mg/L的溶液中加入0.1g所制备的BiOCl/β-FeOOH复合材料，快速均匀分散后得到混合液a，然后放入光催化装置中进行光催化实验。
(2)、光照t1分钟后，从a溶液中取出10mL进行离心分离，得到上清液b。
(3)、用紫外-可见光谱仪测试溶液b的吸光度A1，测试完毕后，倒回试管并连同剩余的溶液和催化剂摇匀后倒回到溶液a中，继续进行光催化实验。
(4)、光照t2分钟、t3分钟和t4分钟、t5分钟和t6分钟后的取样和测试过程与(2)和(3)两步完全相同，测得的系列吸光度分别标记为A2、A3、A4、A5和A6。
(5)、作时间ti和吸光度Ai(i＝0,1,2,3,4,5,6)曲线。再依据吸光度A和浓度C关系(朗伯比尔定律)计算得到吸附时间t和浓度Ct的关系曲线。
图5是β-FeOOH、BiOCl和β-FeOOH/BiOCl复合材料光催化降解甲基橙的动力学曲线。对比三者的可见光催化动力学曲线后可以看出，BiOCl和β-FeOOH可见光催化效果不明显，而BiOCl/β-FeOOH复合材料能有效光催化降解甲基橙。
Claims (5)
1.一种BiOCl/β-FeOOH复合纳米材料，其特征在于：呈纺锤形的β-FeOOH纳米棒分布在呈片状的BiOCl上。
2.一种BiOCl/β-FeOOH复合纳米材料的制备方法，其特征在于先将FeCl3·6H2O溶解于蒸馏水中，再依次加入Bi(NO3)3·5H2O、葡萄糖后混合均匀，调节pH值至3～6，然后经水热合成反应得到BiOCl/β-FeOOH复合纳米材料。
3.如权利要求1所述的BiOCl/β-FeOOH复合纳米材料的制备方法，其特征在于反应体系中FeCl3·6H2O、Bi(NO3)3·5H2O和葡萄糖的质量浓度依次为0.27～1.35g/mL、0.485～7.276g/mL、3.5～8.5g/L。
4.如权利要求1所述的BiOCl/β-FeOOH复合纳米材料的制备方法，其特征在于水热合成反应的时间为24～48h，反应温度为80～100℃。
5.如权利要求1所述的BiOCl/β-FeOOH复合纳米材料的制备方法，其特征在于水热合成反应产物经固液分离、洗涤、烘干得到复合纳米材料，烘干温度为60～80℃，烘干时间为2～6h。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610207665.9A CN105833887B (zh) | 2016-04-01 | 2016-04-01 | 一种BiOCl/β‑FeOOH复合纳米材料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610207665.9A CN105833887B (zh) | 2016-04-01 | 2016-04-01 | 一种BiOCl/β‑FeOOH复合纳米材料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105833887A true CN105833887A (zh) | 2016-08-10 |
| CN105833887B CN105833887B (zh) | 2018-03-23 |
Family
ID=56597997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610207665.9A Active CN105833887B (zh) | 2016-04-01 | 2016-04-01 | 一种BiOCl/β‑FeOOH复合纳米材料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105833887B (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107961785A (zh) * | 2017-12-07 | 2018-04-27 | 清华大学 | 一种高活性铬酸铋纳米光催化剂的制备方法及其应用 |
| CN109225291A (zh) * | 2018-09-10 | 2019-01-18 | 河海大学 | 一种Ti3C2-FeOOH复合型过渡金属催化剂及其制备方法和应用 |
| CN109692970A (zh) * | 2018-11-26 | 2019-04-30 | 合肥学院 | 一种快速制备Fe/Ag复合纳米粉体的方法 |
| CN110773206A (zh) * | 2019-11-27 | 2020-02-11 | 中国科学院青岛生物能源与过程研究所 | 一种具有高催化降解活性的Fe2O3/BiOCl复合光催化剂及其制备方法与应用 |
| CN116651474A (zh) * | 2023-06-16 | 2023-08-29 | 西北师范大学 | 一种羟基氧化铁量子点修饰的BiOX光催化材料的制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012066545A2 (en) * | 2010-11-16 | 2012-05-24 | Yissum Research Development Company Of The Hebrew University Of Jerusalem Ltd. | Bismuth oxyhalide compounds useful as photocatalysts |
| CN103908973A (zh) * | 2014-03-21 | 2014-07-09 | 合肥工业大学 | Bi/BiOCl复合光催化剂、原位还原制备方法及其应用 |
| CN104069876A (zh) * | 2014-06-24 | 2014-10-01 | 华中师范大学 | BiOCl纳米片{001}晶面沉积纳米银制备的Ag-BiOCl复合光催化剂及方法 |
| CN104689838A (zh) * | 2015-02-13 | 2015-06-10 | 湘潭大学 | 一种形貌及晶面可控的BiOCl光催化剂的制备方法 |
-
2016
- 2016-04-01 CN CN201610207665.9A patent/CN105833887B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012066545A2 (en) * | 2010-11-16 | 2012-05-24 | Yissum Research Development Company Of The Hebrew University Of Jerusalem Ltd. | Bismuth oxyhalide compounds useful as photocatalysts |
| CN103908973A (zh) * | 2014-03-21 | 2014-07-09 | 合肥工业大学 | Bi/BiOCl复合光催化剂、原位还原制备方法及其应用 |
| CN104069876A (zh) * | 2014-06-24 | 2014-10-01 | 华中师范大学 | BiOCl纳米片{001}晶面沉积纳米银制备的Ag-BiOCl复合光催化剂及方法 |
| CN104689838A (zh) * | 2015-02-13 | 2015-06-10 | 湘潭大学 | 一种形貌及晶面可控的BiOCl光催化剂的制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| ZHAO ZHANG ET AL: "Ag-BiOCl nanocomposites prepared by the oxygen vacancy induced photodeposition method with improved visible light photocatalytic activity", 《MATERIALS LETTERS》 * |
| ZHIHUI XU ET AL: "Visible light-degradation of azo dye methyl orange using TiO2/β-FeOOH as a heterogeneous photo-Fenton-like catalyst", 《WATER SCIENCE & TECHNOLOGY》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107961785A (zh) * | 2017-12-07 | 2018-04-27 | 清华大学 | 一种高活性铬酸铋纳米光催化剂的制备方法及其应用 |
| CN107961785B (zh) * | 2017-12-07 | 2020-08-14 | 清华大学 | 一种高活性铬酸铋纳米光催化剂的制备方法及其应用 |
| CN109225291A (zh) * | 2018-09-10 | 2019-01-18 | 河海大学 | 一种Ti3C2-FeOOH复合型过渡金属催化剂及其制备方法和应用 |
| CN109692970A (zh) * | 2018-11-26 | 2019-04-30 | 合肥学院 | 一种快速制备Fe/Ag复合纳米粉体的方法 |
| CN110773206A (zh) * | 2019-11-27 | 2020-02-11 | 中国科学院青岛生物能源与过程研究所 | 一种具有高催化降解活性的Fe2O3/BiOCl复合光催化剂及其制备方法与应用 |
| CN116651474A (zh) * | 2023-06-16 | 2023-08-29 | 西北师范大学 | 一种羟基氧化铁量子点修饰的BiOX光催化材料的制备方法 |
| CN116651474B (zh) * | 2023-06-16 | 2023-11-10 | 西北师范大学 | 一种羟基氧化铁量子点修饰的BiOX光催化材料的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105833887B (zh) | 2018-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Guo et al. | A novel α-Fe2O3@ g-C3N4 catalyst: synthesis derived from Fe-based MOF and its superior photo-Fenton performance | |
| Lu et al. | Hydrothermal synthesis of type II ZnIn2S4/BiPO4 heterojunction photocatalyst with dandelion-like microflower structure for enhanced photocatalytic degradation of tetracycline under simulated solar light | |
| Kumar et al. | Noble metal-free metal-organic framework-derived onion slice-type hollow cobalt sulfide nanostructures: Enhanced activity of CdS for improving photocatalytic hydrogen production | |
| Kim et al. | Synthesis of magnetically separable core@ shell structured NiFe2O4@ TiO2 nanomaterial and its use for photocatalytic hydrogen production by methanol/water splitting | |
| Liu et al. | ZnCr-LDH/N-doped graphitic carbon-incorporated g-C3N4 2D/2D nanosheet heterojunction with enhanced charge transfer for photocatalysis | |
| Liu et al. | A facile solvothermal approach of novel Bi2S3/TiO2/RGO composites with excellent visible light degradation activity for methylene blue | |
| Shang et al. | Effect of acetic acid on morphology of Bi2WO6 with enhanced photocatalytic activity | |
| CN105833887A (zh) | 一种BiOCl/β-FeOOH复合纳米材料及其制备方法 | |
| Mu et al. | 2D/3D S-scheme heterojunction of carbon nitride/iodine-deficient bismuth oxyiodide for photocatalytic hydrogen production and bisphenol A degradation | |
| Li et al. | Enhanced photocatalytic activity in ZnFe2O4–ZnO–Ag3PO4 hollow nanospheres through the cascadal electron transfer with magnetical separation | |
| Gao et al. | One-pot synthesis of biomorphic Mg-Al mixed metal oxides with enhanced methyl orange adsorption properties | |
| CN109908915B (zh) | 一种处理六价铬废水的磁性可见光催化剂及其制备方法 | |
| Shu et al. | Nanoporous g-C3N4 nanosheets: facile synthesis and excellent visible-light photocatalytic H2 evolution performance | |
| Lu et al. | Highly Efficient visible-light-induced photoactivity of magnetically retrievable Fe3O4@ SiO2@ Bi2WO6@ g-C3N4 hierarchical microspheres for the degradation of organic pollutant and production of hydrogen | |
| Ma et al. | Z-scheme g-C3N4/ZnS heterojunction photocatalyst: One-pot synthesis, interfacial structure regulation, and improved photocatalysis activity for bisphenol A | |
| CN111790412A (zh) | 还原二氧化碳产制碳化合物的方法 | |
| Esania et al. | Characterization and assessment of the photocatalytic activity of ZnO-Fe3O4/TiO2 nanocomposite based on MIL-125 (Ti) synthesized by mixed solvo-hydrothermal and sol-gel methods | |
| Zhi et al. | Hierarchically porous BiOCl@ NiCo 2 O 4 nanoplates as low-cost and highly efficient catalysts for the discoloration of organic contaminants in aqueous media | |
| Bi et al. | In-situ upcycling of cadmium from wastewater into core–shell ZnS@ Zn0. 58Cd0. 42S heterojunction photocatalyst for environmental purification and H2 evolution | |
| CN109336161A (zh) | 一种CeO2纳米管的制备方法、CeO2纳米管及应用 | |
| CN106517130B (zh) | 一种以富磷生物质制备羟基磷酸铁微纳米粉体材料的方法 | |
| CN105858733A (zh) | 多孔分级结构四氧化三钴纳米花及其制备方法 | |
| Li et al. | Construction of a Bi 2 WO 6/TiO 2 heterojunction and its photocatalytic degradation performance | |
| Zhang et al. | Photo-Fenton degradation of tetracycline hydrochloride with Fe2O3-on-ZrO2 polypods derived from MIL-88B-on-UiO-66-NH2 within full pH range: Kinetics, degradation pathway and mechanism insight | |
| Pan et al. | Hydrochar-Supported NiFe2O4Nanosheets with a Tailored Microstructure for Enhanced CO2Photoreduction to Syngas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |