CN105831854A - Interventional anti-radiation latex gloves and preparation method thereof - Google Patents

Interventional anti-radiation latex gloves and preparation method thereof Download PDF

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Publication number
CN105831854A
CN105831854A CN201610308036.5A CN201610308036A CN105831854A CN 105831854 A CN105831854 A CN 105831854A CN 201610308036 A CN201610308036 A CN 201610308036A CN 105831854 A CN105831854 A CN 105831854A
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China
Prior art keywords
gloves
dry
latex
radiation
cooling
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CN201610308036.5A
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CN105831854B (en
Inventor
张式琦
岳保荣
范瑶华
孟宪有
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    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/0055—Plastic or rubber gloves
    • A41D19/0058—Three-dimensional gloves
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/0006—Gloves made of several layers of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/06—Sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0837—Bismuth
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0887—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Gloves (AREA)

Abstract

The invention provides a pair of interventional anti-radiation latex gloves. The gloves are latex gloves and are prepared from, by weight, natural rubber latex 28-30%, sulfur 0.1-0.5%, zinc oxide 1-3%, an accelerant 0.1-0.5%, an antioxidant 0.3-0.5% and 50-500 nm tungsten and bismuth particles 65.5-70.5%. Compared with the prior art, a rubber material of the pair of interventional anti-radiation latex gloves is moderate in consistence and good in liquidity, air bubbles can automatically float out rightly, the filling material proportion is high, and latex does not produce layering and gelling within a usage period. The pair of interventional anti-radiation latex gloves has a better attenuation effect on X-ray radiation and is environmentally friendly.

Description

A kind of intervention uses radiation proof emgloves and preparation method thereof
Technical field
The present invention relates to a kind of intervention radiation proof emgloves, particularly relate to a kind of brand-new, lead-free, Environmental protection, meet healthy and safe, unleaded and protective capacities is more than lead, and other physical and chemical index is better than the spoke of lead Penetrate the emgloves that protective materials is made.It is applied to X, γ, β, alpha radiation guard technology field.
Background technology
Along with the progress of medical technology, radiology diagnostics and treatment technology are promoted and popularize, especially exist The status of big-and-middle-sized Chemical Examination Material in Hospital diagnosis and treatment application is indispensable.The development of adjoint kernel medical career, irradiation makes radiation The application of protector and equipment is the most extensive.A kind of intervention radiation proof emgloves that we develop, It is exactly a adaptation various big hospital nuclear medicine, intervention, whole bone, radiation protection articles for use time particle is inserted.
X-ray has the strongest radiativity, for from the point of view of doctor and patient, it is simply that utilize this characteristic, enter Row disease treatment and diagnosis, but, radiation has certain injury to healthy colony the most simultaneously.Especially It is the medical personnel of those long campaigns diagnosis and treatment, when every day carries out diagnosis and treatment to patient, the irradiation agent of contact radiation Measuring higher, the radiation injury being subject to is relatively big, especially stochastic effect it may happen that.
Summary of the invention
It is an object of the invention to provide one can effectively protect medical personnel, from or weaken direct projection or scattering X-ray radiation injury, nuclear medicine can be widely used in, intervention, whole bone, particle insert in latex protection Gloves.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of get involved that to use radiation proof emgloves, described gloves be emgloves, described latex contain 65.5%～ 50～the 500nm tungsten of 70.5%, bismuth particle.
Preferably, described latex includes following component by weight percentage:
Natural rubber latex 28～30%
Sulphur 0.1～0.5%
Zinc oxide 1～3%
Accelerator 0.1～0.5%
Antioxidant 0.3～0.5%
50～500nm tungsten, bismuth particle 65.5～70.5%
The percentage by weight sum of above-mentioned each composition is 100%.
The two of the purpose of the present invention are to provide a kind of latex protective gloves as described in one of the object of the invention Preparation method, comprises the following specific steps that:
1) natural rubber latex of formula ratio, sulphur, zinc oxide, accelerator, antioxidant and 50～500nm are pressed Tungsten, bismuth particle mix, and prepare heavy metal protection Composite rubber material；
2) the glue bucket top layer bubble filter paper containing sizing material is exhausted；
3) glove mould is used running water washes clean, then with distilled water drip washing once, dry；
4) dip in a coagulator after cooling, dry；
5) dip in a white glue after slightly cooling down, dry；
6) dip in heavy metal protection Composite rubber material after cooling, dry, repeat 3～6 times；
7) dip in last white glue after cooling, dry；
8) crimping after cooling, is dried 30～40 minutes in 60～80 DEG C in placing into bakery；
9) taking out the demoulding, the gloves taken off are put in tank, are not folded, and allow water total flooding, logical steam add Heat is to boiling sulfuration sizing in 30 minutes；
10), after taking-up gloves dry naturally, surfaces externally and internally smears proper amount of gypsum powder；
11) gloves are carried out performance detection；
12) by qualified gloves product through disinfecting, paper using is packed good, it is impossible to folds, finally seals paper bag Mouthful.
Compared with prior art, beneficial effects of the present invention is as follows:
The sizing material denseness that the present invention provides is moderate, flows, and bubble just can emersion, inserts ratio automatically Higher, latex is not stratified in validity period, not gel；The radiation proof emgloves that the present invention provides is for X Ray radiation has more preferable attenuation, and environmental friendliness.
Detailed description of the invention
For the present invention is better described, it is simple to understand technical scheme, the typical case of the present invention but unrestricted The embodiment of property is as follows:
It is emgloves that radiation proof emgloves, described gloves are used in a kind of intervention, and described latex is by weight percentage Including following component:
Natural rubber latex 29%
Sulphur 0.2%
Zinc oxide 2%
Accelerator 0.3%
Antioxidant 0.4%
50～500nm tungsten, bismuth particle 68.1%.
The preparation method of described intervention radiation proof emgloves, comprises the following specific steps that:
1) natural rubber latex of formula ratio, sulphur, zinc oxide, accelerator, antioxidant and 50～500nm are pressed Tungsten, bismuth particle mix, and prepare heavy metal protection Composite rubber material；
2) the glue bucket top layer bubble filter paper containing sizing material is exhausted；
3) glove mould is used running water washes clean, then with distilled water drip washing once, dry；
4) dip in a coagulator after cooling, dry；
5) dip in a white glue after slightly cooling down, dry；
6) dip in heavy metal protection Composite rubber material after cooling, dry, be repeated 5 times；
7) dip in last white glue after cooling, dry；
8) crimping after cooling, is dried 35 minutes in 70 DEG C in placing into bakery；
9) taking out the demoulding, the gloves taken off are put in tank, are not folded, and allow water total flooding, logical steam add Heat is to boiling sulfuration sizing in 30 minutes；
10), after taking-up gloves dry naturally, surfaces externally and internally smears proper amount of gypsum powder；
11) gloves are carried out performance detection；
12) by qualified gloves product through disinfecting, paper using is packed good, it is impossible to folds, finally seals paper bag Mouthful.
The present invention illustrates method detailed and the system of unleaded high radiation proof material of the present invention by above-described embodiment Standby and application, but the invention is not limited in above-mentioned method detailed, i.e. do not mean that the present invention has to rely on State method detailed could implement.Person of ordinary skill in the field is it will be clearly understood that change any of the present invention Entering, the equivalence of raw material each to product of the present invention is replaced and the interpolation of auxiliary element, concrete way choice etc., Within the scope of all falling within protection scope of the present invention and disclosure.

Claims (3)

1. getting involved and using a radiation proof emgloves, described gloves is emgloves, and described latex contains 50～the 500nm tungsten of 65.5%～70.5%, bismuth particle.
Radiation proof emgloves the most according to claim 1, it is characterised in that described latex is by weight Percentage includes following component:
Natural rubber latex 28～30%；
Sulphur 0.1～0.5%；
Zinc oxide 1～3%；
Accelerator 0.1～0.5%；
Antioxidant 0.3～0.5%；
50～500nm tungsten, bismuth particle 65.5～70.5%；
The percentage by weight sum of above-mentioned each composition is 100%.
3. a preparation method for the radiation proof emgloves that one of claim 1～2 is described, its feature exists In, described method comprises the following specific steps that:
1) natural rubber latex of formula ratio, sulphur, zinc oxide, accelerator, antioxidant and 50～500nm are pressed Tungsten, bismuth particle mix, and prepare heavy metal protection Composite rubber material；
2) the glue bucket top layer bubble filter paper containing sizing material is exhausted；
3) glove mould is used running water washes clean, then with distilled water drip washing once, dry；
4) dip in a coagulator after cooling, dry；
5) dip in a white glue after slightly cooling down, dry；
6) dip in heavy metal protection Composite rubber material after cooling, dry, repeat 3～6 times；
7) dip in last white glue after cooling, dry；
8) crimping after cooling, is dried 30～40 minutes in 60～80 DEG C in placing into bakery；
9) taking out the demoulding, the gloves taken off are put in tank, are not folded, and allow water total flooding, logical steam add Heat is to boiling sulfuration sizing in 30 minutes；
10), after taking-up gloves dry naturally, surfaces externally and internally smears land plaster；
11) gloves are carried out performance detection；
12) by qualified gloves product through disinfecting, paper using is packed good, it is impossible to folds, finally seals paper bag Mouthful.
CN201610308036.5A 2016-05-10 2016-05-10 One kind intervention radiation proof emgloves and preparation method thereof Active CN105831854B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111391207A (en) * 2020-03-12 2020-07-10 南通金斯顿防护用品有限公司 Dipped glove and manufacturing process thereof
CN112662020A (en) * 2020-12-23 2021-04-16 成都盛帮核盾新材料有限公司 Lead-free nuclear radiation protection glove and preparation method thereof
CN113223740A (en) * 2021-03-31 2021-08-06 山东双鹰医疗器械有限公司 Lead-free radiation protection gloves and preparation method thereof
CN113270218A (en) * 2021-05-06 2021-08-17 南京润京乳胶制品有限公司 Medical X-ray-proof gloves and preparation method thereof
CN114369271A (en) * 2021-06-09 2022-04-19 桂林恒保健康防护有限公司 Easy-to-wear latex glove with good radiation resistance and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040262546A1 (en) * 2003-06-25 2004-12-30 Axel Thiess Radiation protection material, especially for use as radiation protection gloves
EP1950765A1 (en) * 2007-01-25 2008-07-30 Hutchinson Multi-layer elastomer material charged with radiation attenuator compounds, preparation method and uses of same
CN102922538A (en) * 2012-10-30 2013-02-13 四川材料与工艺研究所 Method for producing tritium-proof gloves
CN104419042A (en) * 2013-09-05 2015-03-18 无锡新亚安全用品有限公司 Latex gloves and preparation method thereof
CN105513660A (en) * 2015-12-22 2016-04-20 苏州大学 Novel anti-radiation material and gloves made from novel anti-radiation material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040262546A1 (en) * 2003-06-25 2004-12-30 Axel Thiess Radiation protection material, especially for use as radiation protection gloves
EP1950765A1 (en) * 2007-01-25 2008-07-30 Hutchinson Multi-layer elastomer material charged with radiation attenuator compounds, preparation method and uses of same
CN102922538A (en) * 2012-10-30 2013-02-13 四川材料与工艺研究所 Method for producing tritium-proof gloves
CN104419042A (en) * 2013-09-05 2015-03-18 无锡新亚安全用品有限公司 Latex gloves and preparation method thereof
CN105513660A (en) * 2015-12-22 2016-04-20 苏州大学 Novel anti-radiation material and gloves made from novel anti-radiation material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111391207A (en) * 2020-03-12 2020-07-10 南通金斯顿防护用品有限公司 Dipped glove and manufacturing process thereof
CN112662020A (en) * 2020-12-23 2021-04-16 成都盛帮核盾新材料有限公司 Lead-free nuclear radiation protection glove and preparation method thereof
CN113223740A (en) * 2021-03-31 2021-08-06 山东双鹰医疗器械有限公司 Lead-free radiation protection gloves and preparation method thereof
CN113270218A (en) * 2021-05-06 2021-08-17 南京润京乳胶制品有限公司 Medical X-ray-proof gloves and preparation method thereof
CN114369271A (en) * 2021-06-09 2022-04-19 桂林恒保健康防护有限公司 Easy-to-wear latex glove with good radiation resistance and preparation method thereof

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