CN105831148A - Fungicide for water-based glue, preparation method and application thereof - Google Patents
Fungicide for water-based glue, preparation method and application thereof Download PDFInfo
- Publication number
- CN105831148A CN105831148A CN201610184793.6A CN201610184793A CN105831148A CN 105831148 A CN105831148 A CN 105831148A CN 201610184793 A CN201610184793 A CN 201610184793A CN 105831148 A CN105831148 A CN 105831148A
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- CN
- China
- Prior art keywords
- water
- based glue
- antifungus agent
- glue
- fungicide
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides fungicide for water-based glue, a preparation method and application thereof. The fungicide for water-based glue includes 2-40wt% of pyrithione salt, 2-20wt% of silicone quaternary ammonium salt, 2-20wt% of isothiazolinone, and the balance of a solvent. The preparation method is by weighing pyridinethione salt, organosilicon quaternary ammonium salt, isothiazolone and solvent, and then mixing evenly. For mold proofing of the water-based glue, the fungicide is added to the water-based glue and evenly mixed; the fungicide and the glue are in the weight ratio of 1-2:100. REACH environmental test proves the fungicide reaches the standard, has mildewproof grade 0, and good antiseptic effect.
Description
Technical field
The invention belongs to antifungus agent technical field, be specifically related to the antifungus agent of a kind of water-based glue, preparation side
Method and application thereof.
Background technology
In recent years, along with the requirement of environmental protection improves, the water-based glue of environmental protection uses widely, as packed,
Product glue is fitted.Water-based glue contains the utilizable Organic substance of mycete, and the easy humidity increasing product,
Therefore a principal element of the easy mildew of product is become.It is carried out mildew-resistant process, it can be avoided to cause
The risk that product is mouldy, thus the mouldy risk of reduction product of high degree.Maybe can experience for long term storage
Transport by sea equiprobable severe environmental conditions, use the product of environment-friendly water-based glue, occur mouldy be one non-
The quality problem of Chang Yanchong, therefore avoids glue to cause product mouldy most important.
So far, for preventing glue from causing mouldy method less, wherein adding antifungus agent in glue is
One of effective and maneuverable method.Similar products on market are of a great variety, most owing to being added with one
The most poisonous or chemical substance not environmentally, although have preferable effect, but can be to people, animal, environment etc.
Bring impact in various degree or injury；Some antifungus agents, preparation complexity, expensive, it is unfavorable for wide
General utilization.The antifungus agent of some relative environmental protection, does not reaches anti-mold effect.Current improvement direction be environmental protection,
High performance-price ratio, efficiently.Therefore develop a kind of environmental protection, the glue antifungus agent of high-efficiency broad spectrum is necessary.
Summary of the invention
For solving anti-mold effect difference and problem not environmentally, the present invention that existing water-based glue antifungus agent exists
Proposing the antifungus agent of a kind of water-based glue, this antifungus agent is through REACH environmental protection test conformance with standard, mildew-resistant etc.
Level is 0 grade, and anti-mold effect is good.
The technical scheme is that and be achieved in that:
The antifungus agent of a kind of water-based glue, including pyrithione 2-40wt%, organosilicon quaternary ammonium salt
2-20wt%, isothiazolone 2-20wt%, surplus is solvent.
Further, described organosilicon quaternary ammonium salt is octadecyldimethyl (3-methoxy silane base propyl group) chlorination
Ammonium.
Further, described pyrithione is selected from sodium pyrithione or Zinc Pyrithione, preferably pyrithione
Sodium.
Further, owing to the water solublity of Zinc Pyrithione is poor with alcohol-soluble, preferably Zinc Pyrithione and surface
Aqueous suspensions made by activating agent.
Further, described isothiazolone is selected from MIT or the different thiophene of 2-n-octyl-4-
Oxazoline-3-ketone.
Further, described solvent is selected from the mixed solvent of water or alcohol and water, preferably water.
Further, described alcohol is selected from ethanol, propanol or benzylalcohol.
It is a further object to provide the preparation method of the antifungus agent of a kind of water-based glue, weigh pyrrole
Pyridine thioketone salt, organosilicon quaternary ammonium salt, isothiazolone and solvent, then mixing and stirring.
It is also another object of the present invention to provide antifungus agent the answering in water-based glue of a kind of water-based glue
With, it is added to antifungus agent in water-based glue stir, described antifungus agent and the weight of described glue
Ratio is 1-2:100.
Beneficial effects of the present invention:
1, the antifungus agent of the present invention has and belongs to long-acting, the antifungus agent of wide spectrum, adds in glue according to 1%,
Fit, temperature be 28 DEG C, humidity more than 90%RH in the environment of, reference standard ASTM
D4576-2008 (2013) carries out mildew-resistant level estimate: through test in 14 days, surface was not detected by test
Thalline or the growth of other funguses, mildew-resistant grade is 0 grade；This antifungus agent to chaetomium globosum, Mucor, penicillium sp,
The mycete such as aspergillus terreus, aspergillus niger has significantly to press down and kills anti-effect.
2, through REACH environmental protection test, all will not be to environmental danger during producing and using.
3, in the glue used, only need to add the 1-2% of glue weight, consumption is few.
Detailed description of the invention
Embodiment 1
The antifungus agent of a kind of water-based glue, including sodium pyrithione 40wt%, octadecyldimethyl (3-
Methoxy silane base propyl group) ammonium chloride 10wt%, MIT 2wt%, surplus is water.
Preparation method is:
Weigh the octadecyldimethyl (3-methoxy silane base propyl group) of the sodium pyrithione of 40kg, 10kg
Ammonium chloride, the MIT of 2kg and the water of 48kg, then mixing and stirring.
Embodiment 2
The antifungus agent of a kind of water-based glue, including Zinc Pyrithione aqueous suspensions 10wt%, octadecane
Base dimethyl (3-methoxy silane base propyl group) ammonium chloride 20wt%, Kathon
20wt%, surplus is ethanol water.
Preparation method is:
Weigh the Zinc Pyrithione aqueous suspensions of 10kg, 20kg octadecyldimethyl (3-methoxyl group silicon
Alkyl propyl group) ammonium chloride, the ethanol water of Kathon and 50kg of 20kg,
Then mixing and stirring.
Embodiment 3
The antifungus agent of a kind of water-based glue, including Zinc Pyrithione aqueous suspensions 2wt%, octadecyl
Dimethyl (3-methoxy silane base propyl group) ammonium chloride 18wt%, MIT 20wt%,
Surplus is aqueous propanol solution.
Preparation method is:
Weigh the Zinc Pyrithione of 2kg, 18kg octadecyldimethyl (3-methoxy silane base propyl group) chlorine
Changing ammonium, the MIT of 20kg and the aqueous propanol solution of 60kg, then mix and blend is equal
Even.
Embodiment 4
The antifungus agent of a kind of water-based glue, including sodium pyrithione 35wt%, octadecyldimethyl (3-
Methoxy silane base propyl group) ammonium chloride 2wt%, MIT 20wt%, surplus is benzylalcohol
Aqueous solution.
Weigh the sodium pyrithione of 35kg, 2kg octadecyldimethyl (3-methoxy silane base propyl group) chlorine
Changing ammonium, the MIT of 20kg and the benzylalcohol aqueous solution of 43kg, then mix and blend is equal
Even.
Embodiment 5
Antifungus agent embodiment 1-2 prepared adds according to the ratio of mass percent 1% and carries out water-based glue
In, fit, temperature be 28 DEG C, humidity more than 90%RH in the environment of, reference standard ASTM
D4576-2008 (2013) carries out mildew-resistant level estimate: through test in 14 days, surface was not detected by test
Thalline or the growth of other funguses, mildew-resistant grade is 0 grade.
Antifungus agent embodiment 3-4 prepared adds according to the ratio of mass percent 2% and carries out water-based glue
In, fit, temperature be 28 DEG C, humidity more than 90%RH in the environment of, reference standard ASTM
D4576-2008 (2013) carries out mildew-resistant level estimate: through test in 14 days, surface was not detected by test
Thalline or the growth of other funguses, mildew-resistant grade is 0 grade.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all at this
Within bright spirit and principle, any modification, equivalent substitution and improvement etc. made, should be included in this
Within bright protection domain.
Claims (8)
1. the antifungus agent of a water-based glue, it is characterised in that include pyrithione 2-40wt%, have
Machine silicon quaternary ammonium salt 2-20wt%, isothiazolone 2-20wt%, surplus is solvent.
The antifungus agent of water-based glue the most according to claim 1, it is characterised in that described organosilicon
Quaternary ammonium salt is octadecyldimethyl (3-methoxy silane base propyl group) ammonium chloride.
The antifungus agent of water-based glue the most according to claim 1, it is characterised in that described pyridine sulfur
Ketone salt is selected from sodium pyrithione or Zinc Pyrithione.
The antifungus agent of water-based glue the most according to claim 1, it is characterised in that described isothiazole
Quinoline ketone is selected from MIT or Kathon.
5. according to the antifungus agent of the water-based glue described in Claims 1-4 any one, it is characterised in that
Described solvent is selected from the mixed solvent of water or alcohol and water.
The antifungus agent of water-based glue the most according to claim 5, it is characterised in that described alcohol is selected from
Ethanol, propanol or benzylalcohol.
7. a preparation method for the antifungus agent of the water-based glue as described in claim 1 to 6 any one,
It is characterized in that, weigh pyrithione, organosilicon quaternary ammonium salt, isothiazolone and solvent, then mix
Stir.
8. the antifungus agent of the water-based glue as described in any one of claim 1 to 6 is in water-based glue
Application, it is characterised in that be added to antifungus agent in water-based glue stir, described antifungus agent
It is 1-2:100 with the weight ratio of described glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610184793.6A CN105831148A (en) | 2016-03-26 | 2016-03-26 | Fungicide for water-based glue, preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610184793.6A CN105831148A (en) | 2016-03-26 | 2016-03-26 | Fungicide for water-based glue, preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105831148A true CN105831148A (en) | 2016-08-10 |
Family
ID=56583726
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610184793.6A Pending CN105831148A (en) | 2016-03-26 | 2016-03-26 | Fungicide for water-based glue, preparation method and application thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN105831148A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936659A (en) * | 2017-10-31 | 2018-04-20 | 广州广微包装科技有限公司 | A kind of Coating Antifungal Agents and preparation method thereof |
| CN113736297A (en) * | 2021-09-02 | 2021-12-03 | 亚士创能科技(上海)股份有限公司 | Mildew-proof auxiliary agent and preparation method and application thereof |
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| CN101044853A (en) * | 2005-03-30 | 2007-10-03 | 栗田工业株式会社 | Industrial antibiotic composition and antibacterial method |
| CN102258064A (en) * | 2011-05-12 | 2011-11-30 | 赵正坤 | Antibacterial composition and application thereof |
| CN102293213A (en) * | 2011-07-01 | 2011-12-28 | 苏州市永安微生物控制有限公司 | Alkaline antibacterial preservative for chemical fiber finishes and preparation method thereof |
| CN102783492A (en) * | 2011-05-19 | 2012-11-21 | 大连百傲化学有限公司 | Isothiazolinone composition |
| CN103918709A (en) * | 2014-04-24 | 2014-07-16 | 南雄鼎成化工有限公司 | Preparation method of high-efficiency composite antibacterial and mildew-proof organic-silicon quaternary ammonium salt reagent |
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| CN102258064A (en) * | 2011-05-12 | 2011-11-30 | 赵正坤 | Antibacterial composition and application thereof |
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| CN102293213A (en) * | 2011-07-01 | 2011-12-28 | 苏州市永安微生物控制有限公司 | Alkaline antibacterial preservative for chemical fiber finishes and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936659A (en) * | 2017-10-31 | 2018-04-20 | 广州广微包装科技有限公司 | A kind of Coating Antifungal Agents and preparation method thereof |
| CN113736297A (en) * | 2021-09-02 | 2021-12-03 | 亚士创能科技(上海)股份有限公司 | Mildew-proof auxiliary agent and preparation method and application thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160810 |
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| RJ01 | Rejection of invention patent application after publication |