CN105821316A - Casting method for Ni-B-Si alloy surface modified composite valve body - Google Patents
Casting method for Ni-B-Si alloy surface modified composite valve body Download PDFInfo
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- CN105821316A CN105821316A CN201610343112.6A CN201610343112A CN105821316A CN 105821316 A CN105821316 A CN 105821316A CN 201610343112 A CN201610343112 A CN 201610343112A CN 105821316 A CN105821316 A CN 105821316A
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- casting
- valve body
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- oozed
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/08—Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
The invention discloses a casting method for a Ni-B-Si alloy surface modified composite valve body. The casting method comprises the following steps: (1) preparing a pouring solution which comprises the following chemical components in percentage by weight: 0.22-0.26% of C, 0.25-0.45% of Si, 0.60-0.80% of Mn, 0.03-0.05% of Y, 0.05-0.10% of Pr, 0.10-0.15% of La, 0.15-0.25% of Cu, no more than 0.03% of P, no more than 0.02% of S and the balance of Fe; (2) preparing casting-infiltration coating; (3) pouring the valve body; and (4) performing heat treatment and finishing. A uniform and stable casting-filtration composite layer is formed on the surface of the valve body obtained through the casting method, and the valve body has the advantages of being high in anti-impact toughness, excellent in corrosion-resistant and high-temperature-resistant performance, high in finished product ratio, stable in quality, high in appearance quality and usability, and long in service life.
Description
Technical field
The present invention relates to valve casting technology field, particularly relate to a kind of nickel borosilicate alloy surface modifying and be combined the casting method of valve body.
Background technology
Valve is flowable materials conveying and the vitals controlled, and in use, in addition to the requirement of the technical specifications such as temperature to be met, pressure, is also adapted to the different needs of heterogeneity material, such as corrosion, wear, adhesion etc..Meanwhile, sealing property and the service life of valve is also highly important technical specification.
Casting infiltration is at mo(U)ld face by raw material furnishing coating application such as alloyed powders, parent metal immersion antireflective coating material capillary porosity during cast, rely on molten metal heat to make alloy powder melt, melt, combine together with parent metal, thus form the surface composite layer with superperformance at cast(ing) surface.Infiltration technology is promoting while cast properties, has and need not the advantage that special equipment, technique are simple, with short production cycle, with low cost.But, it is susceptible to the problems such as pore, slag inclusion and surface composite layer uneven thickness due to Infiltration technology, causes casting flaw when being applied to valve body production, affect presentation quality and the service life of valve body.Document " research of casting infiltration raising cast steel valve wearability " uses technology of infiltration casting to prepare the valve that flushing resistance is good, improves the service life of valve, but it also indicates that simultaneously, and the problem of casting quality layer poor stability yet suffers from, and need to improve further.Therefore, selecting suitable processing temperature, suitable base material and casting to ooze coating, optimize casting method, improving technology of infiltration casting, to be combined the quality stability of valve body moulding most important.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of steady quality, presentation quality and serviceability are good, the nickel borosilicate alloy surface modifying of length in service life is combined the casting method of valve body.
The present invention is achieved by the following technical solutions:
A kind of nickel borosilicate alloy surface modifying is combined the casting method of valve body, comprises the following steps:
(1) preparation potting syrup, the chemical component weight percentage ratio of described potting syrup is as follows: C:0.22%-0.26%, Si:0.25%-0.45%, Mn:0.60%-0.80%, Y:0.03%-0.05%, Pr:0.05%-0.10%, La:0.10%-0.15%, Cu:0.15%-0.25%, P≤0.03%, S≤0.02%, surplus is Fe, each raw material is i.e. obtained potting syrup in medium-frequency induction furnace after 1580-1620 DEG C of melting, adjustment chemical composition;
(2) coating is oozed in preparation casting, and described casting is oozed coating and is prepared by the raw materials in: 200-300 mesh nickel borosilicate alloyed powder 30-40,200-300 mesh silicon nitride 15-25, Nano diamond micropowder 0.3-0.5, polyvinyl alcohol 0.5-1, acrylic acid 0.1-0.2, glyceryl monostearate 0.5-1, Ammonium persulfate. 0.01-0.015, Lithium metasilicate 2-4, sodium fluoride 1-2, CNT 1-2, silane resin acceptor kh-550 0.5-1, dimethicone 0.1-0.2;It is first by uniform for dispersed with stirring in CNT, Nano diamond micropowder and silane resin acceptor kh-550 addition ethanol in proper amount that the preparation method of coating is oozed in described casting, it is subsequently adding nickel borosilicate alloyed powder, silicon nitride stirring 1-2h, it is dried and removes 100-120 DEG C of process 0.5-1h after ethanol, obtain component A;Polyvinyl alcohol first adds 85-95 DEG C of dissolving in suitable quantity of water completely, be subsequently adding acrylic acid and Ammonium persulfate. 60-70 DEG C stirring 2-4h, after cooling, obtain B component;Component A, B component is uniform with remaining raw material mixed grinding, obtain casting and ooze coating;
(3) cast valve body, first by core in 220-240 DEG C of drying and processing 4-6h, then casting is oozed coating and is coated uniformly on core surface, coating thickness is 1.5-2.5mm, process 1-2h, then mould assembling then at 160-180 DEG C, then potting syrup is poured into a mould under the conditions of 1520-1560 DEG C, it is cooled to room temperature with 20-30 DEG C/h, then carries out finishing;
(4) heat treatment, valve body after step (3) being processed is in 200-300 DEG C of isothermal holding 2-4h, then it is to slowly warm up to 800-850 DEG C of isothermal holding 6-8h with 60-80 DEG C/h, again with 30-50 DEG C/h of slow cooling to 600-650 DEG C of isothermal holding 4-6h, finally it is slowly dropped to room temperature with 50-60 DEG C/h, again obtains finished product after finishing.
The invention have the advantage that
The present invention utilizes CNT, Nano diamond micropowder and silane resin acceptor kh-550 that nickel borosilicate alloyed powder, silicon nitride are carried out surface coating modification as casting infiltration layer material; alloy powder is had good surface protection effect; improve the wettability with molten metal, strengthen metallurgical interface bond strength;Using acrylic acid modified polyvinyl alcohol as binding agent, bond strength is high, and can form stable capillary gap, improves molten metal and wettability that casting is oozed between coating, advantageously forms uniform, stable casting infiltration layer;Being processed by the mixed grinding of remaining raw material, the casting obtained is oozed coating and is fused with metallic matrix through cast, and the compound valve body matrix obtained, through the subsequent processing steps such as Overheating Treatment, finishing, finally gives finished product again.The valve body obtained by casting method of the present invention, surface forms uniform, stable casting and oozes composite bed, and there is high rigidity, high impact-resistant toughness and excellent erosion resistant, resistance to elevated temperatures, yield rate is high, and steady quality, presentation quality and serviceability are good, service life is long.
Detailed description of the invention
A kind of nickel borosilicate alloy surface modifying is combined the casting method of valve body, comprises the following steps:
(1) preparation potting syrup, wherein the chemical component weight percentage ratio of potting syrup is as follows: C:0.22%, Si:0.25%, Mn:0.60%, Y:0.03%, Pr:0.05%, La:0.10%, Cu:0.15%, P:0.03%, S:0.02%, surplus is Fe, each raw material is i.e. obtained potting syrup in medium-frequency induction furnace after 1580 DEG C of meltings, adjustment chemical composition;
(2) coating is oozed in preparation casting, and wherein casting is oozed coating and is made up of the raw material of following weight (kg): 200 mesh nickel borosilicate alloyed powder 30,200 mesh silicon nitrides 15, Nano diamond micropowder 0.3, polyvinyl alcohol 0.5, acrylic acid 0.1, glyceryl monostearate 0.5, Ammonium persulfate. 0.01, Lithium metasilicate 2, sodium fluoride 1, CNT 1, silane resin acceptor kh-550 0.5, dimethicone 0.1;It is first by uniform for dispersed with stirring in CNT, Nano diamond micropowder and silane resin acceptor kh-550 addition ethanol in proper amount that the preparation method of coating is oozed in described casting, it is subsequently adding nickel borosilicate alloyed powder, silicon nitride stirring 1h, it is dried and removes 100 DEG C of process 0.5h after ethanol, obtain component A;Polyvinyl alcohol first adds 85 DEG C of dissolvings in suitable quantity of water completely, be subsequently adding acrylic acid and Ammonium persulfate. 60 DEG C stirring 2h, after cooling, obtain B component;Component A, B component is uniform with remaining raw material mixed grinding, obtain casting and ooze coating;
(3) cast valve body, first by core in 220 DEG C of drying and processing 4h, then oozes casting coating and is coated uniformly on core surface, coating thickness is 1.5mm, processes 1h, then mould assembling then at 160 DEG C, again potting syrup is poured into a mould under the conditions of 1520 DEG C, be cooled to room temperature with 20 DEG C/h, then carry out finishing;
(4) heat treatment, valve body after step (3) being processed, in 200 DEG C of isothermal holding 2h, is then to slowly warm up to 800 DEG C of isothermal holding 6h with 60 DEG C/h, then with 30 DEG C/h of slow coolings to 600 DEG C of isothermal holding 4h, finally it is slowly dropped to room temperature with 50 DEG C/h, again obtains finished product after finishing.
Wherein the model of nickel borosilicate alloyed powder selects Ni60AA.
The performance test results of the said goods is as follows:
Casting infiltration layer intensity is 61.8HRC, and service life is 6 times of common WCB valve body, and during actual condition uses, composite bed will not peel off, ftracture, and operation conditions is good.
Claims (1)
1. a nickel borosilicate alloy surface modifying is combined the casting method of valve body, it is characterised in that comprise the following steps:
(1) preparation potting syrup, the chemical component weight percentage ratio of described potting syrup is as follows: C:0.22%-0.26%, Si:0.25%-0.45%, Mn:0.60%-0.80%, Y:0.03%-0.05%, Pr:0.05%-0.10%, La:0.10%-0.15%, Cu:0.15%-0.25%, P≤0.03%, S≤0.02%, surplus is Fe, each raw material is i.e. obtained potting syrup in medium-frequency induction furnace after 1580-1620 DEG C of melting, adjustment chemical composition;
(2) coating is oozed in preparation casting, and described casting is oozed coating and is prepared by the raw materials in: 200-300 mesh nickel borosilicate alloyed powder 30-40,200-300 mesh silicon nitride 15-25, Nano diamond micropowder 0.3-0.5, polyvinyl alcohol 0.5-1, acrylic acid 0.1-0.2, glyceryl monostearate 0.5-1, Ammonium persulfate. 0.01-0.015, Lithium metasilicate 2-4, sodium fluoride 1-2, CNT 1-2, silane resin acceptor kh-550 0.5-1, dimethicone 0.1-0.2;It is first by uniform for dispersed with stirring in CNT, Nano diamond micropowder and silane resin acceptor kh-550 addition ethanol in proper amount that the preparation method of coating is oozed in described casting, it is subsequently adding nickel borosilicate alloyed powder, silicon nitride stirring 1-2h, it is dried and removes 100-120 DEG C of process 0.5-1h after ethanol, obtain component A;Polyvinyl alcohol first adds 85-95 DEG C of dissolving in suitable quantity of water completely, be subsequently adding acrylic acid and Ammonium persulfate. 60-70 DEG C stirring 2-4h, after cooling, obtain B component;Component A, B component is uniform with remaining raw material mixed grinding, obtain casting and ooze coating;
(3) cast valve body, first by core in 220-240 DEG C of drying and processing 4-6h, then casting is oozed coating and is coated uniformly on core surface, coating thickness is 1.5-2.5mm, process 1-2h, then mould assembling then at 160-180 DEG C, then potting syrup is poured into a mould under the conditions of 1520-1560 DEG C, it is cooled to room temperature with 20-30 DEG C/h, then carries out finishing;
(4) heat treatment, valve body after step (3) being processed is in 200-300 DEG C of isothermal holding 2-4h, then it is to slowly warm up to 800-850 DEG C of isothermal holding 6-8h with 60-80 DEG C/h, again with 30-50 DEG C/h of slow cooling to 600-650 DEG C of isothermal holding 4-6h, finally it is slowly dropped to room temperature with 50-60 DEG C/h, again obtains finished product after finishing.
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CN201610343112.6A CN105821316A (en) | 2016-05-23 | 2016-05-23 | Casting method for Ni-B-Si alloy surface modified composite valve body |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113563659A (en) * | 2021-08-24 | 2021-10-29 | 胜利油田胜机石油装备有限公司 | Polyethylene composite material and application thereof in preparation of high-temperature-resistant lining oil pipe |
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CN103314063A (en) * | 2011-02-21 | 2013-09-18 | 旭化成化学株式会社 | Coating material containing organic/inorganic composite, organic/inorganic composite film and antireflection member |
CN104480461A (en) * | 2014-12-12 | 2015-04-01 | 广西科技大学 | Laser cladding method for Cr12MoV steel through multiple overlapping of Ni60/SiC composite powder |
CN104508166A (en) * | 2012-07-30 | 2015-04-08 | 杰富意钢铁株式会社 | Abrasion-resistant steel plate and manufacturing process therefor |
JP2015193874A (en) * | 2014-03-31 | 2015-11-05 | Jfeスチール株式会社 | Thick steel plate excellent in abrasion resistance and manufacturing method therefor |
CN105176347A (en) * | 2015-09-08 | 2015-12-23 | 天长市银狐漆业有限公司 | Weather-resistant shock-resistant anticorrosive coating |
CN105268909A (en) * | 2015-10-21 | 2016-01-27 | 南京润屹电子科技有限公司 | Graphene enhanced type valve casting-penetration composition and application method thereof |
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2016
- 2016-05-23 CN CN201610343112.6A patent/CN105821316A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103314063A (en) * | 2011-02-21 | 2013-09-18 | 旭化成化学株式会社 | Coating material containing organic/inorganic composite, organic/inorganic composite film and antireflection member |
CN104508166A (en) * | 2012-07-30 | 2015-04-08 | 杰富意钢铁株式会社 | Abrasion-resistant steel plate and manufacturing process therefor |
JP2015193874A (en) * | 2014-03-31 | 2015-11-05 | Jfeスチール株式会社 | Thick steel plate excellent in abrasion resistance and manufacturing method therefor |
CN104480461A (en) * | 2014-12-12 | 2015-04-01 | 广西科技大学 | Laser cladding method for Cr12MoV steel through multiple overlapping of Ni60/SiC composite powder |
CN105176347A (en) * | 2015-09-08 | 2015-12-23 | 天长市银狐漆业有限公司 | Weather-resistant shock-resistant anticorrosive coating |
CN105268909A (en) * | 2015-10-21 | 2016-01-27 | 南京润屹电子科技有限公司 | Graphene enhanced type valve casting-penetration composition and application method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113563659A (en) * | 2021-08-24 | 2021-10-29 | 胜利油田胜机石油装备有限公司 | Polyethylene composite material and application thereof in preparation of high-temperature-resistant lining oil pipe |
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Application publication date: 20160803 |