CN105820743A - Wall coating for high definition projection and preparation method thereof - Google Patents

Wall coating for high definition projection and preparation method thereof Download PDF

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Publication number
CN105820743A
CN105820743A CN201610165819.2A CN201610165819A CN105820743A CN 105820743 A CN105820743 A CN 105820743A CN 201610165819 A CN201610165819 A CN 201610165819A CN 105820743 A CN105820743 A CN 105820743A
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coating
polyurethane resin
drier
preparation
carbon black
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CN105820743B (en
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陈照峰
吴操
李艳明
鲍舒婷
李斌斌
王蕾
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Nanjing University of Aeronautics and Astronautics
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Nanjing University of Aeronautics and Astronautics
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

The invention provides a wall coating for high definition projection and a preparation method thereof.The viscosity of the coating is 7000-9000 mPa.s.The coating is characterized by being prepared from 40-55% of acrylate modified polyurethane resin, 10-20% of titanium dioxide, 0.2-0.4% of a dispersing agent, 0.01-0.06% of carbon black, 5-8% of filler, 2-3% of aerogel powder, 1-2% of drier, 0.3-0.6% of a defoaming agent, 6-10% of cosolvent, 0.8-1.3% of neutralizer and 8-20% of deionized water.The preparation method of the coating includes the following steps that 1, crylic acid and polyurethane resin are mixed in proportion and subjected to a reaction; 2, acrylate modified polyurethane resin, titanium dioxide, the dispersing agent, a defoaming agent, the cosolvent, the neutralizer and the deionized water are mixed and then ground; 3, the carbon black, the wear-resistant filler and the drier are added to slurry and mixed uniformly, filtered and packaged.The wall coating has the advantages of being low in cost, convenient, flexible and good in viewing effect.

Description

A kind of high definition projection wall covering and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly to a kind of high definition projection wall covering and preparation method thereof.
Background technology
Projection screen application in life is very extensive, and it is mainly used in large conference room, command and control center, training The occasions such as educational structure, meeting room, exhibition room, exhibition center, airport, show window.As the requisite partner of scialyscope, buy Projection screen is also required to spend a high expense, and is also required to oneself as scialyscope and installs.Application was most in the past Home projector curtain mainly has: picture frame screen, manual curtain and electric screen, but not only need separately installed, maintenance cost is higher, and And also space limits, become projection system and enter the major obstacle of average family, and the appearance projecting paint well solves this One problem.
Projection paint is a kind of cold coating product being mixed with filler and various additive, it is not necessary to special instrument and skill, can So that smooth the surface conversion of japanning high performance projection screen can be become by any.But, the projection screen of a lot of curtain wall forms in reality Curtain is not inside the projection room and movie theatre of specialty, and is under natural light environment appreciating for people more, and projection screen is respectively Planting under light environment, the most in bright ambient light under environment, its surface is projected by high light, it is easy to cause imaging to be drawn Face is unintelligible, uneven, dazzle, white haze shape are serious.If it is known that projection screen imaging picture white haze shape is serious, Can be substantially reduced contrast and the brightness of picture, thus it is unclear to easily lead to user viewing, so lose itself displaying, Demonstration or effect of advertising.Therefore, solving the ambient light impact on imaging picture, design one is effective against ambient light to imaging The scheme of the projection screen paint of the interference of picture either still improves viewing comfortableness and is all for reducing the cost of projection screen Extremely it is necessary.
Number of patent application be 201520313487.9 Chinese patent provide a kind of can strong light environment use Novel Microstructure throw The design of shadow screen, including the base material of absorbable light, is interval with several for absorbing light to reduce on base material The raised line that imaging is disturbed by ambient light, raised line is horizontally set, and is parallel to each other, on the substrate surface between raised line and raised line Being provided with the projection imaging layer for projection imaging, the surface of projection imaging layer, less than the outer surface of raised line, is made so that play interference The raised line that can be made up of light absorbent of ambient light absorb and block, and then can effectively reduce ambient light to imaging picture Impact, makes that imaging picture is apparent, contrast is higher, brightness is higher.Improve the imaging picture of existing projection screen, and its Processing technology is simple, it is easy to implement.
Number of patent application is a kind of high projection system to comparison of United States Patent (USP) of US6529322B1, by optical selective glass Filter layer, AR backing layer and the appropriate design of surface layer so that the light of projector is neutralized by the collection of selectivity and reflects, and natural light Line then is projected by the absorption of selectivity, improves contrast, decreases the ambient light impact on viewing effect.
Although existing reduction ambient light can solve problem to a certain extent to the design of the impact of imaging picture, but logical Crossing the scheme of the screen construction designed selective absorbing and reflection to realize available light and projection ray, screen construction is more multiple Miscellaneous, naturally also cause the defect that projection screen is relatively costly.
Summary of the invention
It is desirable to provide a kind of high definition projection wall covering, by selectivity synthesis acrylic acid modified polyurethane resin system Electronic structure and quantity, and the structure of the internal filler particles of resin system and nano effect, realize the screen selection to light Property absorb and reflection function, and then reduce the natural environment interference to viewing effect, improve viewing comfortableness.
A kind of high definition projection wall covering and preparation method thereof, the viscosity of coating is 7000~9000mPa s, it is characterised in that be coated with The composition of material is: acrylic acid modified polyurethane resin 40~55%, titanium dioxide 10~20%, dispersant 0.2-0.4%, white carbon black 0.01-0.06%, filler 5-8%, aerogel powder 2~3%, drier 1-2%, defoamer 0.3-0.6%, cosolvent 6~10%, Nertralizer 0.8~1.3%, deionized water 8-20%;The preparation method of this coating includes the step of following order:
(1) by acrylic acid and polyurethane resin according to mass ratio 1: the ratio mixing of (10~20), 1~1.5h at 80 DEG C, is reacted, Prepare acrylic acid modified polyurethane resin;
(2) by acrylic acid modified polyurethane resin, titanium dioxide, dispersant, defoamer, cosolvent, nertralizer and deionized water In a reservoir with mixing dispersion 20-30 minute, then put in sand mill and be ground to below fineness 30um;
(3) adding white carbon black, wear resistant filler and drier in above-mentioned slurry, the speed mixed at high speed with 500-700r/min is equal Even, being transferred to viscosity is 7000~9000mPa s, finally with strainer filterings more than 200 mesh, and packaging.
Described cosolvent be butyl glycol ether and propylene glycol monomethyl ether according to mass ratio 1: (1~4) mix;Nertralizer is organic Amine AM-95;Defoamer is polysiloxane emulsion;Dispersant is modified carboxylic acid sodium salt, acrylic resin mean molecule quantity 12000~16000;White carbon black, titanium dioxide particle diameter are 1~20 μm;Drier be zirconium oxide and cobalt oxide according to mass ratio 1: (2~3) Mix;Filler be the ceramic particle of particle diameter 10~25 μm and glass microballoon according to mass ratio 1: (2~4) mix;Gas Gel powder body density is 0.15~0.20g/cm3, porosity is 85~92%, and average pore size is 80nm.
The present invention is had the beneficial effect that 1. low cost, directly by plane base brushing, it is not necessary to extra support material With the installation of specialty, greatly reduce use cost;The most convenient, flexible, the ground such as family's metope, glass, square can be coated in Side, is translates directly into high performance projection screen by surfaces such as family's metope, glass, enclosure walls, is not take up exceptional space;3. see Shadow is effective, by the selective absorbing of projection ray and available light and reflection, greatly reducing the loss of projection ray With the interference of available light, viewing effect significant increase.
Detailed description of the invention
Below in conjunction with specific embodiment, it is further elucidated with the present invention, it should be understood that these embodiments are merely to illustrate the present invention and need not In limiting the scope of the present invention, after having read the present invention, those skilled in the art repair the various equivalent form of values of the present invention Change and all fall within the application claims and limited.
Embodiment 1
A kind of high definition projection wall covering and preparation method thereof, the viscosity of coating is 7000mPa s, it is characterised in that coating Composition is: acrylic acid modified polyurethane resin 40%, titanium dioxide 10%, dispersant 0.2%, white carbon black 0.01%, filler 5%, Aerogel powder 2%, drier 1%, defoamer 0.3%, cosolvent 6%, nertralizer 0.8%, deionized water 8%;Should The preparation method of coating includes the step of following order:
(1) acrylic acid and polyurethane resin are mixed according to the ratio of mass ratio 1: 10, react 1h at 80 DEG C, prepare acrylic acid Modified polyurethane resin;
(2) by acrylic acid modified polyurethane resin, titanium dioxide, dispersant, defoamer, cosolvent, nertralizer and deionized water In a reservoir with mixing dispersion 20 minutes, then put in sand mill and be ground to below fineness 30um;
(3) adding white carbon black, wear resistant filler and drier in above-mentioned slurry, the speed mixed at high speed with 500r/min is uniform, Being transferred to viscosity is 7000mPa s, finally with strainer filterings more than 200 mesh, and packaging.
Described cosolvent is butyl glycol ether and propylene glycol monomethyl ether mixes according to mass ratio 1: 1;Nertralizer is organic amine AM-95;Defoamer is polysiloxane emulsion;Dispersant is modified carboxylic acid sodium salt, acrylic resin mean molecule quantity 12000; White carbon black, titanium dioxide particle diameter are 1 μm;Drier is zirconium oxide and cobalt oxide mixes according to mass ratio 1: 2;Filler is particle diameter Ceramic particle and the glass microballoon of 10 μm mix according to mass ratio 1: 2;Aerogel powder density is 0.15g/cm3, hole Rate is 85%, and average pore size is 80nm.
Embodiment 2
A kind of high definition projection wall covering and preparation method thereof, the viscosity of coating is 9000mPa s, it is characterised in that coating Composition is: acrylic acid modified polyurethane resin 55%, titanium dioxide 20%, dispersant 0.4%, white carbon black 0.06%, filler 8%, Aerogel powder 3%, drier 2%, defoamer 0.6%, cosolvent 10%, nertralizer 1.3%, deionized water 20%;Should The preparation method of coating includes the step of following order:
(1) acrylic acid and polyurethane resin are mixed according to the ratio of mass ratio 1: 20, react 1.5h at 80 DEG C, prepare propylene Acid modified polyurethane resin;
(2) by acrylic acid modified polyurethane resin, titanium dioxide, dispersant, defoamer, cosolvent, nertralizer and deionized water In a reservoir with mixing dispersion 30 minutes, then put in sand mill and be ground to below fineness 30um;
(3) adding white carbon black, wear resistant filler and drier in above-mentioned slurry, the speed mixed at high speed with 700r/min is uniform, Being transferred to viscosity is 9000mPa s, finally with strainer filterings more than 200 mesh, and packaging.
Described cosolvent is butyl glycol ether and propylene glycol monomethyl ether mixes according to mass ratio 1: 4;Nertralizer is organic amine AM-95;Defoamer is polysiloxane emulsion;Dispersant is modified carboxylic acid sodium salt, acrylic resin mean molecule quantity 16000; White carbon black, titanium dioxide particle diameter are 20 μm;Drier is zirconium oxide and cobalt oxide mixes according to mass ratio 1: 3;Filler is grain Ceramic particle and the glass microballoon of footpath 25 μm mix according to mass ratio 1: 4;Aerogel powder density is 0.20g/cm3, hole Gap rate is 92%, and average pore size is 80nm.
Above are only two detailed description of the invention of the present invention, but the design concept of the present invention is not limited thereto, all utilize this structure Think the present invention is carried out the change of unsubstantiality, the behavior invading the scope of protection of the invention all should be belonged to.In every case it is without departing from this The content of inventive technique scheme, any type of simple modification above example made according to the technical spirit of the present invention, etc. With change and remodeling, still fall within the protection domain of technical solution of the present invention.

Claims (2)

1. high definition projection wall covering and preparation method thereof, the viscosity of coating is 7000~9000mPa s, it is characterised in that The composition of coating is: acrylic acid modified polyurethane resin 40~55%, titanium dioxide 10~20%, dispersant 0.2-0.4%, white carbon black 0.01-0.06%, filler 5-8%, aerogel powder 2~3%, drier 1-2%, defoamer 0.3-0.6%, cosolvent 6~10%, Nertralizer 0.8~1.3%, deionized water 8-20%;The preparation method of this coating includes the step of following order:
(1) by acrylic acid and polyurethane resin according to mass ratio 1: the ratio mixing of (10~20), 1~1.5h at 80 DEG C, is reacted, Prepare acrylic acid modified polyurethane resin;
(2) by acrylic acid modified polyurethane resin, titanium dioxide, dispersant, defoamer, cosolvent, nertralizer and deionized water In a reservoir with mixing dispersion 20-30 minute, then put in sand mill and be ground to below fineness 30um;
(3) adding white carbon black, wear resistant filler and drier in above-mentioned slurry, the speed mixed at high speed with 500-700r/min is equal Even, being transferred to viscosity is 7000~9000mPa s, finally with strainer filterings more than 200 mesh, and packaging.
Coating the most according to claim 1, it is characterised in that described cosolvent be butyl glycol ether and propylene glycol monomethyl ether according to Mass ratio 1: (1~4) mix;Nertralizer is organic amine AM-95;Defoamer is polysiloxane emulsion;Dispersant is for changing Property carboxylic acid sodium salt, acrylic resin mean molecule quantity 12000~16000;White carbon black, titanium dioxide particle diameter are 1~20 μm;Drier For zirconium oxide and cobalt oxide according to mass ratio 1: (2~3) mix;Filler is ceramic particle and the glass of particle diameter 10~25 μm Microballon is according to mass ratio 1: (2~4) mix;Aerogel powder density is 0.15~0.20g/cm3, porosity is 85~92%, Average pore size is 80nm.
CN201610165819.2A 2016-03-16 2016-03-16 A kind of high definition projection wall covering and preparation method thereof Active CN105820743B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106189628A (en) * 2016-08-24 2016-12-07 彭晓中 The making of a kind of aqueous projection screen paint and technique for applying thereof
CN106957542A (en) * 2017-03-29 2017-07-18 合肥天沃能源科技有限公司 A kind of projection wall covering and preparation method
CN108546486A (en) * 2018-04-04 2018-09-18 合肥展游软件开发有限公司 A kind of backlight module superelevation diffusing reflection coating and preparation method thereof
CN108559355A (en) * 2018-05-11 2018-09-21 河北晨阳工贸集团有限公司 A kind of orthographic projection curtain wall sealing wax and preparation method thereof
CN109243337A (en) * 2018-10-15 2019-01-18 马鞍山和春文化传媒有限公司 A kind of high-strength ageing projection advertisement curtain
CN109517454A (en) * 2018-11-16 2019-03-26 杭州隅千象科技有限公司 The projection wall finiss and projection curtain wall with environment resistant light interference function
CN109683443A (en) * 2019-01-30 2019-04-26 广州悦荣欣科技有限公司 A kind of NEW TYPE OF COMPOSITE coating
CN109817119A (en) * 2019-01-29 2019-05-28 华芯云数字科技(武汉)有限责任公司 A kind of media advertising system based on Internet of Things
CN113493636A (en) * 2020-04-07 2021-10-12 深圳光峰科技股份有限公司 Projection reflection screen coating and preparation method thereof

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CN101364039A (en) * 2007-08-10 2009-02-11 北京理工大学 Rear-projection display screen with nanometer coatings
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CN104893452A (en) * 2015-05-26 2015-09-09 康圣科 High definition projection fiber paint
CN104945973A (en) * 2015-06-17 2015-09-30 山东香山装饰工程有限公司 Paint for projection and preparation method of paint

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CN104497777A (en) * 2014-12-01 2015-04-08 山西大学 Room temperature self-crosslinking water-based paint as well as preparation method and application thereof
CN104893452A (en) * 2015-05-26 2015-09-09 康圣科 High definition projection fiber paint
CN104945973A (en) * 2015-06-17 2015-09-30 山东香山装饰工程有限公司 Paint for projection and preparation method of paint

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106189628A (en) * 2016-08-24 2016-12-07 彭晓中 The making of a kind of aqueous projection screen paint and technique for applying thereof
CN106957542A (en) * 2017-03-29 2017-07-18 合肥天沃能源科技有限公司 A kind of projection wall covering and preparation method
CN108546486A (en) * 2018-04-04 2018-09-18 合肥展游软件开发有限公司 A kind of backlight module superelevation diffusing reflection coating and preparation method thereof
CN108559355A (en) * 2018-05-11 2018-09-21 河北晨阳工贸集团有限公司 A kind of orthographic projection curtain wall sealing wax and preparation method thereof
CN109243337A (en) * 2018-10-15 2019-01-18 马鞍山和春文化传媒有限公司 A kind of high-strength ageing projection advertisement curtain
CN109517454A (en) * 2018-11-16 2019-03-26 杭州隅千象科技有限公司 The projection wall finiss and projection curtain wall with environment resistant light interference function
CN109817119A (en) * 2019-01-29 2019-05-28 华芯云数字科技(武汉)有限责任公司 A kind of media advertising system based on Internet of Things
CN109683443A (en) * 2019-01-30 2019-04-26 广州悦荣欣科技有限公司 A kind of NEW TYPE OF COMPOSITE coating
CN113493636A (en) * 2020-04-07 2021-10-12 深圳光峰科技股份有限公司 Projection reflection screen coating and preparation method thereof
CN113493636B (en) * 2020-04-07 2023-12-01 深圳光峰科技股份有限公司 Projection reflection screen paint and preparation method thereof

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