CN105820723A - Wearproof photocuring lens - Google Patents
Wearproof photocuring lens Download PDFInfo
- Publication number
- CN105820723A CN105820723A CN201610369254.XA CN201610369254A CN105820723A CN 105820723 A CN105820723 A CN 105820723A CN 201610369254 A CN201610369254 A CN 201610369254A CN 105820723 A CN105820723 A CN 105820723A
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- CN
- China
- Prior art keywords
- parts
- photocuring
- eyeglass
- wear
- resisting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/378—Thiols containing heterocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the field of photocuring, in particular to a wearproof photocuring lens .The lens is prepared from, by weight, 10-20 parts of lauryl methlacrylate, 70-90 parts of bisphenol A dimethacrylate, 10-20 parts of rosinyl hyperbranched polyester acrylate resin, 1-3 parts of graphene, 3-8 parts of photoinitiator and 3-10 parts of an auxiliary .The lens is low in cost, environmentally friendly and high in light transmittance performance, wear resistance and ageing resistance.
Description
Technical field
The present invention relates to curing field, a kind of wear-resisting photocuring eyeglass.
Background technology
The optical frames used from the eyeglass of public use to high-accuracy CD-ROM drive read head or camera is first-class, all needs to use eyeglass.Traditional glass lens processing procedure is all with optical grinding or make precision cutting with diamond cutter and prepare, and not only production difficulty is high, yield is low, time-consumingly take a lot of work and with high costs, and when as lens wear, glass lens is easily damaged and brings injury.Therefore, optics dealer develops the process technology production resin lens of model optics, with in response to huge market demand.
Eyeglass in use, is easily scratched, and once will be affected with light transmission by the precision scratching rear lens, thus affect the service life of eyeglass.
Summary of the invention
The present invention is directed to the problems referred to above and propose a kind of wear-resisting photocuring eyeglass, it is possible to strengthen the anti-wear performance of eyeglass, promote the service life of eyeglass.
To achieve these goals, the technical solution adopted in the present invention is, a kind of wear-resisting photocuring eyeglass, its raw material is calculated as by weight: lauryl methacrylate 10～20 parts, bisphenol a dimethacrylate 70～90 parts, abietyl hyperbranched polyester acrylic ester resin 10～20 parts, Graphene 1～3 parts, light initiator 3～8 parts, auxiliary agent 3～10 parts.
As preferably, a kind of wear-resisting photocuring eyeglass, its raw material is calculated as by weight: lauryl methacrylate 15 parts, bisphenol a dimethacrylate 80 parts, abietyl hyperbranched polyester acrylic ester resin 15 parts, Graphene 2 parts, light initiator 5 parts, auxiliary agent 5 parts.
Described auxiliary agent is antioxidant, one or more combinations in levelling agent, defoamer, stabilizer.
Described light initiator is: one or more combinations in 2-isopropyl thioxanthone, benzoin dimethylether, 1-hydroxycyclohexyl phenyl ketone, 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone.
As preferably, described light initiator selects 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone.
Wear-resisting photocuring eyeglass of the present invention is with low cost, environmental protection, and the eyeglass light transmission made is good, and the material therefor of eyeglass own is intensity compared with the material big, anti-wear performance is good；Particularly with the addition of Graphene, further enhancing the intensity of eyeglass, make eyeglass more tough, anti-wear performance is superior, use 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone as light initiator, it is possible to the permanent serviceability of effective guarantee eyeglass, to avoid eyeglass to turn to be yellow.
Detailed description of the invention
By predetermined purpose and technological means and effect that the present invention reached is expanded on further, below in conjunction with embodiment, specific embodiments of the present invention are described in detail.
Embodiment 1:, a kind of wear-resisting photocuring eyeglass, its raw material is calculated as by weight: lauryl methacrylate 15 parts, bisphenol a dimethacrylate 80 parts, abietyl hyperbranched polyester acrylic ester resin 15 parts, Graphene 2 parts, 2-methyl isophthalic acid-5 parts of (4-methyl mercapto phenyl)-2-morpholinyl-1-acetone, antioxidant 1.5 parts, levelling agent 1 part, defoamer 1.5 parts, stabilizer 1 part.
Embodiment 2: a kind of wear-resisting photocuring eyeglass, its raw material is calculated as by weight: lauryl methacrylate 10 parts, bisphenol a dimethacrylate 70 parts, abietyl hyperbranched polyester acrylic ester resin 10 parts, Graphene 1 part, 2-isopropyl thioxanthone 1 part, benzoin dimethylether 2 parts, antioxidant 1.5 parts, defoamer 1.5 parts.
Embodiment 3: a kind of wear-resisting photocuring eyeglass, its raw material is calculated as by weight: lauryl methacrylate 20 parts, bisphenol a dimethacrylate 90 parts, abietyl hyperbranched polyester acrylic ester resin 20 parts, Graphene 3 parts, 21-hydroxycyclohexyl phenyl ketone 8 parts, antioxidant 3 parts, defoamer 3 parts, stabilizer 4 parts.
Embodiment 4: similar to Example 1, its difference is: described auxiliary agent is antioxidant 5 parts.
As it has been described above, only present pre-ferred embodiments, therefore appoint all without departing from this programme technology contents, according to the technical spirit of the present invention, above example is made any simple change, equivalent variations and modification, all still fall within the scope of technical solution of the present invention.
Claims (4)
1. a wear-resisting photocuring eyeglass, it is characterised in that: its raw material is calculated as by weight: lauryl methacrylate 10～20 parts, bisphenol a dimethacrylate 70～90 parts, abietyl hyperbranched polyester acrylic ester resin 10～20 parts, Graphene 1～3 parts, light initiator 3～8 parts, auxiliary agent 3～10 parts.
One the most according to claim 1 wear-resisting photocuring eyeglass, it is characterized in that, its raw material is calculated as by weight: lauryl methacrylate 15 parts, bisphenol a dimethacrylate 80 parts, abietyl hyperbranched polyester acrylic ester resin 15 parts, Graphene 2 parts, light initiator 5 parts, auxiliary agent 5 parts.
One the most according to claim 1 and 2 wear-resisting photocuring eyeglass, it is characterised in that: described auxiliary agent is antioxidant, one or more combinations in levelling agent, defoamer, stabilizer.
One the most according to claim 1 and 2 wear-resisting photocuring eyeglass, it is characterised in that: described light initiator is: one or more combinations in 2-isopropyl thioxanthone, benzoin dimethylether, 1-hydroxycyclohexyl phenyl ketone, 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610369254.XA CN105820723A (en) | 2016-05-30 | 2016-05-30 | Wearproof photocuring lens |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610369254.XA CN105820723A (en) | 2016-05-30 | 2016-05-30 | Wearproof photocuring lens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105820723A true CN105820723A (en) | 2016-08-03 |
Family
ID=56532391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610369254.XA Pending CN105820723A (en) | 2016-05-30 | 2016-05-30 | Wearproof photocuring lens |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105820723A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115109195A (en) * | 2022-04-07 | 2022-09-27 | 瑞洲树脂（东莞）有限公司 | Bio-based light and heat dual-curing lens, lens filling adhesive and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5778466A (en) * | 1980-10-31 | 1982-05-17 | Dainippon Toryo Co Ltd | Corrosionproof paint composition |
| EP0142921A1 (en) * | 1983-09-24 | 1985-05-29 | Kureha Kagaku Kogyo Kabushiki Kaisha | Halogen-containing resin lens material |
| CN104761679A (en) * | 2015-03-31 | 2015-07-08 | 长兴（广州）精细涂料有限公司 | Light-cured lens and manufacturing method thereof |
| CN104877530A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-curing antimicrobial wear-resistant paint for PC (polycarbonate) plastic boards |
| CN104877528A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-curing antimicrobial antistatic paint for PCB (printed circuit board) plastic boards |
| CN105415555A (en) * | 2015-10-20 | 2016-03-23 | 蔡征宇 | Photocuring molding equipment for resin lenses |
-
2016
- 2016-05-30 CN CN201610369254.XA patent/CN105820723A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5778466A (en) * | 1980-10-31 | 1982-05-17 | Dainippon Toryo Co Ltd | Corrosionproof paint composition |
| EP0142921A1 (en) * | 1983-09-24 | 1985-05-29 | Kureha Kagaku Kogyo Kabushiki Kaisha | Halogen-containing resin lens material |
| CN104761679A (en) * | 2015-03-31 | 2015-07-08 | 长兴（广州）精细涂料有限公司 | Light-cured lens and manufacturing method thereof |
| CN104877530A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-curing antimicrobial wear-resistant paint for PC (polycarbonate) plastic boards |
| CN104877528A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-curing antimicrobial antistatic paint for PCB (printed circuit board) plastic boards |
| CN105415555A (en) * | 2015-10-20 | 2016-03-23 | 蔡征宇 | Photocuring molding equipment for resin lenses |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115109195A (en) * | 2022-04-07 | 2022-09-27 | 瑞洲树脂（东莞）有限公司 | Bio-based light and heat dual-curing lens, lens filling adhesive and application thereof |
| CN115109195B (en) * | 2022-04-07 | 2024-02-09 | 瑞洲树脂（东莞）有限公司 | Bio-based light and heat dual-curing lens, lens filling adhesive and application thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160803 |
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| RJ01 | Rejection of invention patent application after publication |