CN105820495A - Thermoplastic elastomer rubber material capable of releasing anions and preparation method thereof - Google Patents
Thermoplastic elastomer rubber material capable of releasing anions and preparation method thereof Download PDFInfo
- Publication number
- CN105820495A CN105820495A CN201610250739.7A CN201610250739A CN105820495A CN 105820495 A CN105820495 A CN 105820495A CN 201610250739 A CN201610250739 A CN 201610250739A CN 105820495 A CN105820495 A CN 105820495A
- Authority
- CN
- China
- Prior art keywords
- thermoplastic elastomer
- tpe
- sizing material
- parts
- anion releasing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Abstract
The invention discloses a thermoplastic elastomer rubber material capable of releasing anions. The thermoplastic elastomer rubber material comprises the following components in parts by weight: 15-40 parts of styrene thermoplastic elastomer, 5-25 parts of polyolefin resin, 1-40 parts of phosphorus-nitrogen flame retardant, 1-60 parts of inorganic flame retardant, 10-50 parts of extender oil, 1-5 parts of tourmaline and 0.1-3 parts of aid. The invention also discloses a preparation method of the thermoplastic elastomer rubber material. The thermoplastic elastomer rubber material capable of releasing anions has favorable processibility, and the hardness is adjustable within the Shaw hardness range of 55-95A according to requirements. The pulverized tourmaline is added into the raw material components. The added tourmaline does not influence the overall performance and tactile sensation of the rubber material, but can release anions, thereby improving the quality of air around the human body; and thus, people can breathe smoothly and be in good mood.
Description
Technical field
The invention belongs to technical field of polymer materials, thermoplastic elastomer (TPE) sizing material being specifically related to a kind of anion releasing and preparation method thereof.
Background technology
Thermoplastic elastomer (TPE) sizing material is that one has rubber and plastic properties concurrently, has excellent processability and the material of good human body sense of touch, is widely used in life, particularly dresses field in intelligence.Such as Intelligent bracelet, intelligent watch, intelligent glasses, intelligence running shoe etc..Intelligent worn device changes the life style of modern greatly, become office, entertain, move, the movable indispensable equipment such as healthy.
Anion can improve environmental quality, purifies air, makes people be in a cheerful frame of mind.The thermoplastic elastomer (TPE) sizing material of a kind of anion releasing is used for Intelligent worn device, can make people while enjoying smart machine, and the air of breath freshening, body and mind is loosened.
Summary of the invention
It is an object of the invention to provide the thermoplastic elastomer (TPE) sizing material of a kind of anion releasing.
For achieving the above object, the thermoplastic elastomer (TPE) sizing material of anion releasing provided by the present invention, by weight, including following composition by weight:
Styrene analog thermoplastic elastomer 15-40 part；
Polyolefin resin 5-25 part；
Phosphor nitrogen combustion inhibitor 1-40 part；
Inorganic combustion inhibitor 1-60 part；
Fill oil 10-50 part；
Tourmaline 1-5 part；
Auxiliary agent 0.1-3 part.
Preferably, described styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene block copolymer, and styrene-content is 10-35%.
Preferably, described polyolefin resin is the one in polyethylene, polypropylene and copolymer thereof or several, described polyolefin resin melt index 2-30g/10min, 2.16kg/190 DEG C.
Preferably, one or more combinations during described phosphor nitrogen combustion inhibitor is inorganic hypo-aluminum orthophosphate, divinyl hypo-aluminum orthophosphate, melamine cyanurate, APP.
Preferably, described inorganic combustion inhibitor is one or more combinations of aluminium hydroxide, magnesium hydroxide, montmorillonite, calcium carbonate.
Preferably, described filling oil is one or more combinations of white oil, naphthenic oil, aromatic naphtha.
Preferably, described tourmaline is powder, and granularity is 1-5 micron.
Preferably, described auxiliary agent include copper ion inhibitor, UV absorbers and aromatic amine, Hinered phenols one or more.Wherein, copper ion inhibitor is preferably N-salicyloyl amino phthalimide；UV absorbers is preferably salicylic acid esters, triazines and one or more combinations in Hinered phenols..
The present invention also provides for the preparation method of the thermoplastic elastomer (TPE) sizing material of a kind of anion releasing, it is characterised in that comprise the steps:
Weigh by weight, first 15-40 part styrene analog thermoplastic elastomer and 10-50 part are filled oil stirring and stands, allow the abundant oil suction of styrene analog thermoplastic elastomer；
Weigh by weight, 5-25 part polyolefin resin, 1-40 part phosphor nitrogen combustion inhibitor, 1-60 part inorganic combustion inhibitor, 1-5 part tourmaline, 0.1-3 part auxiliary agent are mixed with oil-filled styrene analog thermoplastic elastomer, it is sufficiently stirred for, the twin screw using draw ratio 40-48 carries out taking out grain, twin screw temperature, at 160 DEG C-220 DEG C, i.e. obtains the thermoplastic elastomer (TPE) sizing material of anion releasing after taking out grain.
As mentioned above, the invention provides a kind of thermoplastic elastomer (TPE) sizing material that can be used for manufacturing intelligence equipment, this sizing material has good processability, can regulate in shore 55A-95A as requested, add the tourmaline (granularity 1-5 micron) through pulverization process in raw material forms, the addition of tourmaline does not affect sizing material overall performance and sense of touch, but it is capable of releasing negative ion, this can improve human peripheral's air quality, makes people breathe smooth and easy, is in a cheerful frame of mind.
Detailed description of the invention
By describing the technology contents of the present invention, formula proportion in detail, being realized purpose and effect, it is explained in detail below in conjunction with embodiment.
In following example, all numbers are by weight:
Embodiment
1
The component of embodiment 1 is: styrene-ethylene-butylene-styrene block copolymer 25 parts, wherein styrene-content is 28wt%, polypropylene 15 parts, inorganic hypo-aluminum orthophosphate 10 parts, melamine cyanurate 20 parts, calcium carbonate 5 parts, white oil 25 parts, 1 part of tourmaline, antioxidant 1010 0.2 part, N-salicyloyl amino phthalimide 0.1 part, oxybenzoic acid phenyl ester 0.1 part.
Weigh by quality, first 25 parts of styrene-ethylene-butylene-styrene block copolymers and the stirring of 25 parts of white oils are stood 4 hours, allow the abundant oil suction of styrene-ethylene-butylene-styrene block copolymer；
Weigh by quality, rest materials is mixed with oil-filled styrene-ethylene-butylene-styrene block copolymer, is sufficiently stirred for, use the twin screw of draw ratio 44 to carry out taking out grain, twin screw temperature 170 DEG C.
Embodiment
2
The component of embodiment 2 is: styrene-ethylene-butylene-styrene block copolymer 28 parts, wherein styrene-content is 30wt%, polypropylene 15 parts, inorganic hypo-aluminum orthophosphate 10 parts, melamine cyanurate 30 parts, montmorillonite 5 parts, naphthenic oil 12 parts, 1.5 parts of tourmaline, antioxidant 1010 0.2 part, N-salicyloyl amino phthalimide 0.1 part, oxybenzoic acid phenyl ester 0.1 part.
Weigh by quality, first 28 parts of styrene-ethylene-butylene-styrene block copolymers and the stirring of 12 parts of naphthenic oils are stood 3 hours, allow the abundant oil suction of styrene-ethylene-butylene-styrene block copolymer；
Weigh by quality, rest materials is mixed with oil-filled styrene-ethylene-butylene-styrene block copolymer, is sufficiently stirred for, use the twin screw of draw ratio 44 to carry out taking out grain, twin screw temperature 210 DEG C.
Embodiment
3
The component of embodiment 3 is: styrene-ethylene-butylene-styrene block copolymer 33 parts, wherein styrene-content is 28wt%, polypropylene 10 parts, APP 8 parts, melamine cyanurate 26 parts, calcium carbonate 8 parts, white oil 16 parts, 3 parts of tourmaline, irgasfos 168 0.2 part, N-salicyloyl amino phthalimide 0.1 part, oxybenzoic acid phenyl ester 0.1 part.
Weigh by quality, first 33 parts of ethylene-vinyls of benzene-butylene-styrene block copolymer and the stirring of 16 parts of white oils are stood 3 hours, allow the abundant oil suction of styrene-ethylene-butylene-styrene block copolymer；
Weigh by quality, rest materials is mixed with oil-filled styrene-ethylene-butylene-styrene block copolymer, is sufficiently stirred for, use the twin screw of draw ratio 46 to carry out taking out grain, twin screw temperature 200 DEG C.
Embodiment
4
The component of embodiment 4 is: styrene-ethylene-butylene-styrene block copolymer 37 parts, wherein styrene-content is 33wt%, polypropylene 14 parts, APP 11 parts, melamine cyanurate 10 parts, 8 parts of magnesium hydroxide, white oil 20 parts, 4 parts of tourmaline, antioxidant 1076 0.2 part, N-salicyloyl amino phthalimide 0.1 part, oxybenzoic acid phenyl ester 0.1 part.
Weigh by quality, first 37 parts of styrene-ethylene-butylene-styrene block copolymers and the stirring of 20 parts of white oils are stood 4 hours, allow the abundant oil suction of styrene-ethylene-butylene-styrene block copolymer；
Weigh by quality, rest materials is mixed with oil-filled styrene-ethylene-butylene-styrene block copolymer, is sufficiently stirred for, use the twin screw of draw ratio 46 to carry out taking out grain, twin screw temperature 180 DEG C.
Taken out for above-described embodiment particle vulcanizing press is carried out tabletting, test performance such as following table:
In sum, the thermoplastic elastomer (TPE) sizing material of anion releasing of the present invention can be used for manufacturing the thermoplastic elastomer (TPE) sizing material of intelligence equipment, this sizing material has good processability, can regulate in shore 55A-95A as requested, add the tourmaline (granularity 1-5 micron) through pulverization process in raw material forms, the addition of tourmaline does not affect sizing material overall performance and sense of touch, but it is capable of releasing negative ion, this can improve human peripheral's air quality, makes people breathe smooth and easy, is in a cheerful frame of mind.
The invention is not limited in above-mentioned detailed description of the invention, those skilled in the art also can make multiple change accordingly, but any is equal to the present invention or similar change all should be contained within the scope of the claims.
Claims (11)
1. the thermoplastic elastomer (TPE) sizing material of an anion releasing, it is characterised in that the thermoplastic elastomer (TPE) sizing material of described anion releasing includes following composition by weight:
Styrene analog thermoplastic elastomer 15-40 part；
Polyolefin resin 5-25 part；
Phosphor nitrogen combustion inhibitor 1-40 part；
Inorganic combustion inhibitor 1-60 part；
Fill oil 10-50 part；
Tourmaline 1-5 part；
Auxiliary agent 0.1-3 part.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 1, it is characterised in that described styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene block copolymer, styrene-content is 10-35%.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 1, it is characterized in that, described polyolefin resin is the one in polyethylene, polypropylene and copolymer thereof or several, described polyolefin resin melt index 2-30g/10min, 2.16kg/190 DEG C.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 1, it is characterised in that described phosphor nitrogen combustion inhibitor is one or more combinations in inorganic hypo-aluminum orthophosphate, divinyl hypo-aluminum orthophosphate, melamine cyanurate, APP.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 1, it is characterised in that described inorganic combustion inhibitor is one or more combinations of aluminium hydroxide, magnesium hydroxide, montmorillonite, calcium carbonate.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 1, it is characterised in that described filling oil is one or more combinations of white oil, naphthenic oil, aromatic naphtha.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 1, it is characterised in that described tourmaline is powder, granularity is 1-5 micron.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 1, it is characterised in that described auxiliary agent include copper ion inhibitor, UV absorbers and aromatic amine, Hinered phenols one or more.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 8, it is characterised in that described copper ion inhibitor is N-salicyloyl amino phthalimide.
The thermoplastic elastomer (TPE) sizing material of anion releasing the most according to claim 8, it is characterised in that described UV absorbers is salicylic acid esters, triazines and one or more combinations in Hinered phenols.
11. 1 kinds of preparation methoies according to the thermoplastic elastomer (TPE) sizing material of the anion releasing described in any one of claim 1 to 10, it is characterised in that comprise the steps:
Weigh by weight, first 15-40 part styrene analog thermoplastic elastomer and 10-50 part are filled oil stirring and stands, allow the abundant oil suction of styrene analog thermoplastic elastomer；
Weigh by weight, 5-25 part polyolefin resin, 1-40 part phosphor nitrogen combustion inhibitor, 1-60 part inorganic combustion inhibitor, 1-5 part tourmaline, 0.1-3 part auxiliary agent are mixed with oil-filled styrene analog thermoplastic elastomer, it is sufficiently stirred for, the twin screw using draw ratio 40-48 carries out taking out grain, twin screw temperature, at 160 DEG C-220 DEG C, i.e. obtains the thermoplastic elastomer (TPE) sizing material of anion releasing after taking out grain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610250739.7A CN105820495A (en) | 2016-04-21 | 2016-04-21 | Thermoplastic elastomer rubber material capable of releasing anions and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610250739.7A CN105820495A (en) | 2016-04-21 | 2016-04-21 | Thermoplastic elastomer rubber material capable of releasing anions and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105820495A true CN105820495A (en) | 2016-08-03 |
Family
ID=56527178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610250739.7A Pending CN105820495A (en) | 2016-04-21 | 2016-04-21 | Thermoplastic elastomer rubber material capable of releasing anions and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105820495A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250657A (en) * | 2018-01-11 | 2018-07-06 | 湖南盛亚体育实业有限公司 | The thermoplastic elastic material of anion and its application and preparation method can be discharged |
| CN114456475A (en) * | 2022-01-14 | 2022-05-10 | 中国核电工程有限公司 | Low-smoke halogen-free material for nuclear power station cable and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002249612A (en) * | 2001-02-23 | 2002-09-06 | Sanwa Kako Co Ltd | Resin foam having vibration-camping property and containing tourmaline ore, and method for producing the same |
| WO2009102387A1 (en) * | 2008-02-15 | 2009-08-20 | Exxonmobil Chemical Patents Inc. | Blends of low crystallinity, low molecular weight propylene copolymers and styrenic block copolymers |
| CN101747579A (en) * | 2008-12-22 | 2010-06-23 | 上海日之升新技术发展有限公司 | Low-smoke halogen-free flame-retardant thermoplastic elastomer and preparation method thereof |
| CN105176029A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Composite automotive upholstery material capable of releasing negative ions and preparing method of composite automotive upholstery material |
-
2016
- 2016-04-21 CN CN201610250739.7A patent/CN105820495A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002249612A (en) * | 2001-02-23 | 2002-09-06 | Sanwa Kako Co Ltd | Resin foam having vibration-camping property and containing tourmaline ore, and method for producing the same |
| WO2009102387A1 (en) * | 2008-02-15 | 2009-08-20 | Exxonmobil Chemical Patents Inc. | Blends of low crystallinity, low molecular weight propylene copolymers and styrenic block copolymers |
| CN101747579A (en) * | 2008-12-22 | 2010-06-23 | 上海日之升新技术发展有限公司 | Low-smoke halogen-free flame-retardant thermoplastic elastomer and preparation method thereof |
| CN105176029A (en) * | 2015-09-23 | 2015-12-23 | 芜湖环瑞汽车内饰件有限公司 | Composite automotive upholstery material capable of releasing negative ions and preparing method of composite automotive upholstery material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250657A (en) * | 2018-01-11 | 2018-07-06 | 湖南盛亚体育实业有限公司 | The thermoplastic elastic material of anion and its application and preparation method can be discharged |
| CN114456475A (en) * | 2022-01-14 | 2022-05-10 | 中国核电工程有限公司 | Low-smoke halogen-free material for nuclear power station cable and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102660129A (en) | EVA (ethylene-vinyl acetate copolymer) foamed composite and preparation method thereof | |
| CN103910996A (en) | Antibacterial masterbatch, nano antibacterial super-tough plastic added with antibacterial masterbatch and preparation and application of plastic | |
| CN103724789A (en) | Thermoplastic elastomer toy material and preparation method thereof | |
| CN103524942B (en) | A kind of flexible polrvinyl chloride flexible cable material | |
| CN105820495A (en) | Thermoplastic elastomer rubber material capable of releasing anions and preparation method thereof | |
| TW200626670A (en) | Process for the preparation of particles based on a thermoplastic polymer and powder thus obtained | |
| CN107759898B (en) | High-shading-degree polypropylene composite material and preparation method thereof | |
| MY144167A (en) | Demolding aids for silicone hydrogels and related methods | |
| CN103834099A (en) | Special medical irradiation-resistant polypropylene material | |
| CN104530623B (en) | HIPS materials with rubber sense of touch and preparation method thereof | |
| CN103571125A (en) | Elastomer nylon coating material as well as preparation method thereof | |
| SG11201809320RA (en) | Hydrogenated block copolymer, polypropylene resin composition, and molded body | |
| CN101798434B (en) | Furniture ABS resin sealing strip | |
| CN104046019A (en) | High-strength polyamide resin alloy material for processing safety toe cap | |
| US7790253B2 (en) | Wear-resistive housing for a portable electronic device | |
| CN110938275A (en) | High-weather-resistance high-flame-retardant thermoplastic elastomer material and preparation method thereof | |
| CN104592624A (en) | Modified polypropylene material and use thereof | |
| CN103525073A (en) | Polyphenylene ether cable material | |
| CN104403253A (en) | Anti-aging TPE plastic formula | |
| CN109810456B (en) | Thermoplastic elastomer sucker material | |
| KR20010076929A (en) | Thermoplastic elastomer compounds for footwear | |
| CN104371245A (en) | Formula of ultraviolet-resistant TPE (Thermoplastic Elastomer) plastics | |
| CN106146919A (en) | A kind of antibacterial sole material and preparation method thereof | |
| CN109810459A (en) | A kind of table tennis ABS/SAN composite material and preparation method and application | |
| CN110894334B (en) | Thermoplastic elastomer capable of coating PC/ABS material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160803 |
|
| RJ01 | Rejection of invention patent application after publication |