CN105818476A - Surface-modification three-dimensional-network-carbon-fiber-reinforced composite material and preparing method - Google Patents
Surface-modification three-dimensional-network-carbon-fiber-reinforced composite material and preparing method Download PDFInfo
- Publication number
- CN105818476A CN105818476A CN201610162453.3A CN201610162453A CN105818476A CN 105818476 A CN105818476 A CN 105818476A CN 201610162453 A CN201610162453 A CN 201610162453A CN 105818476 A CN105818476 A CN 105818476A
- Authority
- CN
- China
- Prior art keywords
- carbon fiber
- diamond
- dimensional
- graphene
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012986 modification Methods 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 42
- 239000000463 material Substances 0.000 title claims abstract description 9
- 239000003733 fiber-reinforced composite Substances 0.000 title abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 130
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 109
- 239000004917 carbon fiber Substances 0.000 claims abstract description 109
- 239000002131 composite material Substances 0.000 claims abstract description 87
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 86
- 229910003460 diamond Inorganic materials 0.000 claims abstract description 73
- 239000010432 diamond Substances 0.000 claims abstract description 73
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 54
- 239000011159 matrix material Substances 0.000 claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 claims abstract description 28
- 239000002184 metal Substances 0.000 claims abstract description 28
- 230000002787 reinforcement Effects 0.000 claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract description 3
- 238000000151 deposition Methods 0.000 claims description 61
- 230000004048 modification Effects 0.000 claims description 59
- 230000008021 deposition Effects 0.000 claims description 50
- 239000007789 gas Substances 0.000 claims description 33
- 239000010949 copper Substances 0.000 claims description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- -1 polyethylene Polymers 0.000 claims description 21
- 239000002041 carbon nanotube Substances 0.000 claims description 15
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 238000005516 engineering process Methods 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 238000005240 physical vapour deposition Methods 0.000 claims description 10
- 238000007747 plating Methods 0.000 claims description 10
- 238000005245 sintering Methods 0.000 claims description 10
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 8
- 238000001704 evaporation Methods 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 8
- 239000007792 gaseous phase Substances 0.000 claims description 8
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 8
- 239000004005 microsphere Substances 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 230000008595 infiltration Effects 0.000 claims description 7
- 238000001764 infiltration Methods 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 229920002379 silicone rubber Polymers 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- LLYXJBROWQDVMI-UHFFFAOYSA-N 2-chloro-4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1Cl LLYXJBROWQDVMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910000906 Bronze Inorganic materials 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 4
- 238000005253 cladding Methods 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 238000005065 mining Methods 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000004663 powder metallurgy Methods 0.000 claims description 4
- 239000004945 silicone rubber Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000004634 thermosetting polymer Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- 229910017083 AlN Inorganic materials 0.000 claims description 2
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052580 B4C Inorganic materials 0.000 claims description 2
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920003180 amino resin Polymers 0.000 claims description 2
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004794 expanded polystyrene Substances 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 239000007769 metal material Substances 0.000 claims description 2
- 239000002113 nanodiamond Substances 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229950000845 politef Drugs 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 5
- 238000009826 distribution Methods 0.000 abstract description 3
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 238000009941 weaving Methods 0.000 description 38
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 16
- 238000005452 bending Methods 0.000 description 11
- 239000000758 substrate Substances 0.000 description 8
- 238000004506 ultrasonic cleaning Methods 0.000 description 8
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000005137 deposition process Methods 0.000 description 6
- 229910000838 Al alloy Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920013657 polymer matrix composite Polymers 0.000 description 3
- 239000011160 polymer matrix composite Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011156 metal matrix composite Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 229910021364 Al-Si alloy Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013036 cure process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
- B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0008—Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/162—Cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/041—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/048—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of particles
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/02—Pretreatment of the fibres or filaments
- C22C47/04—Pretreatment of the fibres or filaments by coating, e.g. with a protective or activated covering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/02—Pretreatment of the fibres or filaments
- C22C47/06—Pretreatment of the fibres or filaments by forming the fibres or filaments into a preformed structure, e.g. using a temporary binder to form a mat-like element
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/08—Making alloys containing metallic or non-metallic fibres or filaments by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/14—Making alloys containing metallic or non-metallic fibres or filaments by powder metallurgy, i.e. by processing mixtures of metal powder and fibres or filaments
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0272—Deposition of sub-layers, e.g. to promote the adhesion of the main coating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
- C23C16/27—Diamond only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
- C23C16/27—Diamond only
- C23C16/271—Diamond only using hot filaments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
- C23C16/27—Diamond only
- C23C16/272—Diamond only using DC, AC or RF discharges
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
- C23C16/27—Diamond only
- C23C16/274—Diamond only using microwave discharges
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
- C23C16/27—Diamond only
- C23C16/275—Diamond only using combustion torches
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
- C23C16/27—Diamond only
- C23C16/276—Diamond only using plasma jets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/302—Conductive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Combustion & Propulsion (AREA)
- Fluid Mechanics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Carbon And Carbon Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a surface-modification three-dimensional-network-carbon-fiber-reinforced composite material and a preparing method.Three-dimensional carbon fiber frameworks with different bore diameters are prepared as required, and after surface pretreatment, diamond, carbon nanometer tubes and graphene are subjected to chemical vapor deposition; then the mixture and matrix materials are compounded, wherein the matrix materials are metal or polymers; the carbon-fiber-reinforced metal-based or polymer-based composite material with the three-dimensional net-shaped framework structure is obtained.A three-dimensional continuous heat conduction channel is formed in the composite material through the surface-modification three-dimensional net-shaped carbon fibers, and therefore the heat conduction performance of the composite material is greatly improved; meanwhile, according to space distribution of carbon fibers in the matrix material, the mechanical performance of the composite material can also be improved, and the density and the thermal expansion coefficient can be decreased; the thermal expansion coefficient, the mechanical performance and the thermal performance can be further regulated and controlled by adding zero-dimensional particle reinforcement.
Description
Technical field
The invention discloses a kind of surface modification three-dimensional network carbon fibre reinforced composite and preparation method, belong to technical field of composite preparation.
Background technology
The intensification of international competition develops, and constantly expedites the emergence of the fast development of science and technology, and microelectric technique and guidance technology become the inter-State most important thing falling over each other development naturally.Each class of electronic devices degree of integration is more and more higher, and energy density is increasing, and the heat of generation gets more and more, and for guaranteeing equipment steady operation, needs it is carried out effective heat management.High intensity to material simultaneously, low-density is had higher requirement.Asphalt base carbon fiber is little with its density, light weight, high-tensile, highly thermally conductive, electric conductivity and extremely low thermal coefficient of expansion cause the attention of researcher.
CN105110809A provides the preparation method of a kind of Graphene modification high heat conductance three-dimensional carbon/carbon composite, with graphene oxide and PAN charcoal cloth as raw material, forms graphene oxide membrane by the method for dipping at carbon fiber surface；In high temperature, hydrogen atmosphere, graphene oxide membrane is reduced into Graphene; carry out CVI densification and graphitization processing subsequently; obtain the high heat conductance three-dimensional carbon/carbon composite that Graphene is modified; thermal conductivity and the bending strength of three-dimensional carbon/carbon composite can be improved, it is achieved prepared by the large scale of three-dimensional high heat conduction carbon/carbon composite, scale.But prepare graphene film due to infusion process and there is the characteristics such as uniformity is poor, be easily peeled, overlay capacity is less so that the range of application of this material is restricted.
Metal-base composites, with metal or alloy as matrix, with high heat conductance or low-expansion second as reinforcement, gives full play to the premium properties of respective constituent element, and metal-base composites, because of its good combination property, becomes the study hotspot of electronic package material.Carbon Fibre Reinforced Metal Matrix Composites can improve specific strength and the specific modulus of metal, reduces the thermal coefficient of expansion of metal.For metal lighter for the metal Chang Xuan of composite, alloy or intermetallic compound, mainly aluminum, copper, titanium, magnesium, their alloy and intermetallic compound.CN101713056A proposes a kind of metal matrix three-dimensional netlike carbon fiber composite material and manufacture method thereof, in this composite, carbon fiber is three-dimensional netlike carbon fiber structure, this three-dimensional netlike carbon fiber structure is to be made up of multilayer carbon nanotube, by three-dimensional network shape carbon fiber structure, binding agent and dispersant are mixed in proportion and stir, it is dried, compression forming, cure process, high temperature sintering, form the preform containing carbon fiber structure, sintering metal (silicon by fusing, magnesium, aluminium alloy in the combination such as copper and nickel) it is immersed in the preform containing carbon fiber structure, solidification i.e. forms machinery, heat conduction, the metal-based carbon fiber composite material that hot expansibility is all excellent.But owing to easily there is electrochemical reaction between carbon fiber and metallic matrix, and carbon fiber is relatively big with the electrode potential difference of metallic matrix, is easily generated galvanic corrosion, thus material easily lost efficacy in the environment of high humidity.
Summary of the invention
It is an object of the invention to overcome the deficiency of prior art and provide that a kind of thermal conductivity is high, thermal coefficient of expansion is low, the composite of lightweight and preparation method.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, and described composite includes matrix material, three-dimensional netlike carbon fiber reinforcement, and wherein said matrix material includes metal material or polymeric material.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, the one in the described metal matrix material a kind of or acid bronze alloy, acieral in metallic copper, aluminum；In described acid bronze alloy, acieral, the content of copper or aluminum is more than or equal to 50%；Polymeric matrix is thermoplastic polymer or thermosetting polymer；Described thermoplastic polymer one in polyethylene, polypropylene, polystyrene, polrvinyl chloride, politef, nylon, Merlon, polymethyl methacrylate, glycol ester, poly terephthalic acid, polyformaldehyde, polyamide, polysulfones；Described thermosetting polymer one in epoxy resin, phenolic resin, Lauxite, amino resins, melmac, unsaturated polyester resin, organic siliconresin, silicone rubber, expanded polystyrene (EPS), polyurethane.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, and the aperture 20 μm-5mm of three-dimensional netlike carbon fiber reinforcement, porosity is 20-95%, and carbon fiber diameter is 3-500 μm.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, deposits high thermal conductivity layer after three-dimensional netlike carbon fiber reinforcement surface Direct precipitation high thermal conductivity layer or surface modification.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, three-dimensional netlike carbon fiber reinforcement surface modification is to deposit layer of metal layer at carbon fiber surface, described metal level one or compound in nickel, copper, tungsten, molybdenum, titanium, silver, chromium, described metal level uses a kind of method in plating, chemical plating, evaporation, magnetron sputtering, chemical gaseous phase deposition, physical vapour deposition (PVD) to deposit.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, the high thermal conductivity layer of deposition one in diamond, Graphene, CNT, Graphene/diamond, CNT/diamond, graphene/carbon nano-tube, diamond/graphene/carbon nano-tube, high thermal conductivity layer thickness is 5-200 μm.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, using CVD technology deposition high thermal conductivity layer, the heated filament auxiliary law being chosen in particular from CVD technology, microwave plasma strengthen at least one in method, DC arc plasma jet, electron cyclotron resonace method, flame combustion process, direct-current discharge method, low pressure radio frequency method, normal-pressure radio-frequency method.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, also comprises high heat conduction particle in the matrix material of composite.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, at least one in diamond, Graphene, CNT, graphene coated diamond microspheres, CNT cladding diamond microsphere, carborundum, boron carbide, aluminium nitride, boron nitride of described high heat conduction particle, described graphene coated diamond microspheres and CNT cladding diamond microsphere all use chemical gaseous phase deposition to obtain.
One surface modification three-dimensional netlike carbon fiber of the present invention strengthens composite, described composite includes following component, and by volume percentage composition forms: matrix material 20-80%, three-dimensional netlike carbon fiber reinforcement 10-70%, high heat conduction particle 0%-30%, each volume components percent and be 100%.
The present invention a kind of surface modification three-dimensional netlike carbon fiber strengthens the preparation method of composite, comprises the steps:
The first step: woven by carbon fiber three-dimensional netted, cleans, dries；
Second step: use the one in carbon fiber surface deposits nickel, copper, tungsten, molybdenum, titanium, silver, chromium of a kind of method in plating, chemical plating, evaporation, magnetron sputtering, chemical gaseous phase deposition, physical vapour deposition (PVD) or complex metal layer；
3rd step: three-dimensional netlike carbon fiber is soaked in nano-diamond powder or Graphene powder or carbon nanotube suspension and carries out ultrasonic vibration plantation seed crystal pretreatment；
4th step: use the high thermal conductivity layer that one or more in three-dimensional netlike carbon fiber surface depositing diamond, Graphene, CNT of chemical vapour deposition technique are compound, obtain three-dimensional network carbon fiber reinforcement；
5th step: three-dimensional network carbon fiber reinforcement, high heat conduction particle are combined with metallic matrix, the Combined Mining a kind of method in powder metallurgy sintered technology or pressureless infiltration, gas infiltration, casting；Described powder metallurgy sintered technology one in cold-rolled sintered, hot pressed sintering, SPS sintering, vacuum-sintering, atmosphere sintering；Or
Three-dimensional network carbon fiber reinforcement, high heat conduction particle are combined with polymeric matrix, a kind of method in Combined Mining dipping curing molding, injection moulding, compressing, injection mo(u)lding, rotation molding, extrusion moulding, laminated into type, flow casting molding.
The present invention a kind of surface modification three-dimensional netlike carbon fiber strengthens the preparation method of composite, when matrix material is metal, is combined with matrix after high thermal conductivity layer surface configuration Modified Membrane again, and Modified Membrane thickness is 5nm-2 μm；At least one in tungsten film, molybdenum film, titanium film, nickel film, chromium film of Modified Membrane, or selected from TiC, WC, Cr7C3, NiC, Mo2At least one in C.
The present invention a kind of surface modification three-dimensional netlike carbon fiber strengthens the preparation method of composite, and in the 4th step, Graphene, CNT, diamond CVD deposition parameter be:
Graphene CVD deposition parameter is: it is 0.5-80% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1200 DEG C, grows air pressure 5-105Pa；
CNT CVD deposition parameter is: it is 5-50% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1300 DEG C, grows air pressure 103-105Pa；
Diamond CVD deposition parameter is: it is 0.5-10% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 600-1000 DEG C, grows air pressure 103-104Pa；
By to applying plasma and induced by magnetic field in CVD deposition stove, and regulate carbon throughput, growth temperature, growth air pressure in real time, realizing Graphene/diamond, CNT/diamond, graphene/carbon nano-tube, the CVD deposition of diamond/graphene/carbon nano-tube, deposition parameter is:
Graphene CVD deposition parameter is: it is 0.5-80% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1200 DEG C, grows air pressure 5-105Pa；Plasma electric current density 0-50mA/cm2；In deposition region, magnetic field intensity is that 100 Gausses are to 30 teslas.
CNT CVD deposition parameter is: it is 5-50% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1300 DEG C, grows air pressure 103-105Pa；Plasma electric current density 0-30mA/cm2；In deposition region, magnetic field intensity is that 100 Gausses are to 30 teslas.
Diamond CVD deposition parameter is: it is 0.5-10% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 600-1000 DEG C, grows air pressure 103-104Pa。
One surface modification three-dimensional network carbon fiber reinforced metal base of the present invention or polymer matrix composite, also rare earth element can be added in metallic matrix, as one or more in the rare earth elements such as Sc, Y, Ce strengthen metal and three-dimensional network carbon fiber reinforcement, the binding ability of high heat conduction particle；Also coupling agent can be added in polymer to change hydrophilic or the organophilic of polymer so that polymer is connected by coupling agent with reinforcement, to improve binding ability.
The present invention is by working out the three-dimensional carbon fiber reinforcement of different pore size, by diamond, CNT or graphene film chemical gaseous phase depositing homogeneous, fine and close after surface preparation, it is combined with matrix material after CVD surface modification, it is thus achieved that with the Carbon Fibre Reinforced Metal Matrix Composites of three dimensional skeletal structure.Through surface modification, reduce potential difference between metal and carbon fiber, effectively alleviate the electrochemical corrosion of material, improve the adaptive faculty of material, the most surface-modified three-dimensional carbon fiber defines three-dimensional passage of heat continuously in the composite, drastically increases the heat conductivility of composite, meanwhile, carbon fiber spatial distribution in matrix material also can play the mechanical property improving composite, reduces the function of its density and thermal coefficient of expansion.Regulate and control its thermal coefficient of expansion and mechanics, thermal property also by addition zero dimension reinforced particulate simultaneously.
Detailed description of the invention
Technical scheme is further described below by specific embodiment.
The embodiment of the present invention is carried out by following technique or step:
The composite of preparation uses laser conductometer to carry out thermal conductivity measurement.
Embodiment one: diamond modification weaving carbon fiber reinforced aluminum matrix composites
Comprise the following steps:
(1) 3 D weaving carbon fiber (aperture is 500 μm, and porosity is 90%) is placed in ultrasonic cleaning in acetone soln；
(2) using magnetically controlled sputter method to sputter W film layer on 3 D weaving carbon fiber surface, wherein W film thickness is 150nm；Use HF CVD depositing diamond film, deposition process parameters: heated filament distance 6mm, substrate temperature 800 DEG C, hot-wire temperature 2200 DEG C, deposition pressure 3KPa, CH4/H2Volume flow ratio 1:99, obtains diamond film thickness 120 μm；Use magnetically controlled sputter method belt carcass diamond three-dimensional network skeleton surface sputter Mo/Cu composite film, wherein Mo film thickness be 50nm, Cu film thickness be 100nm；
(3) weaving carbon fiber of the surface modification obtained in (2) is put in mould, fine aluminium is heated in crucible simultaneously and be melted to 730 DEG C, melt is poured in mould, uses the pressure of hydraulic press pressure 60Mpa, force aluminum or aluminum alloy melt to be infiltrated into the gap location of diamond wire in skeleton, keep pressure 15 seconds, cooling and demolding, takes out composite, and the thermal conductivity of composite is 552W/mK, tensile strength 561MPa, bending strength is 53MPa.
Embodiment two: diamond/Graphene modification weaving carbon fiber reinforced PMMA composite
Comprise the following steps:
(1) 3 D weaving carbon fiber (aperture is 300 μm, and porosity is 80%) is placed in ultrasonic cleaning in acetone soln；
(2) HF CVD depositing diamond film, deposition process parameters: heated filament distance 6mm, substrate temperature 800 DEG C, hot-wire temperature 2200 DEG C, deposition pressure 3KPa, CH are used4/H2Volume flow ratio 1:99, obtains diamond film thickness 200 μm；Use plasma-assisted chemical vapour deposition method at diamond surface growth in situ graphene film layer, deposition parameter: H2/CH4Atmosphere, CH4Gas mass flow percentage ratio is 10%, and growth temperature is 900 DEG C, grows air pressure 5 × 105Pa, plasma electric current density 20mA/cm2, in deposition region, magnetic field intensity is 200 Gausses, and the time is 20min；Then using vacuum evaporation to be plated in its surface one layer of W film of deposition, W film thickness is 100nm；
(3) dipping solidification is used to be combined: a) to prepare PMMA (poly-methyl methacrylate vinegar) precursor liquid: weigh 20gPMMA, it is mixed with organic solvents, chloroform, it is stirred vigorously 2h to PMMA to be completely dissolved, forms the chloroformic solution that PMMA mass percent is 10%；B) mixing: put in mould by diamond/Graphene modification weaving carbon fiber, then according to volume ratio 1:5 instills the chloroformic solution of PMMA so that it is infiltration also fully infiltrates diamond/Graphene modification weaving carbon fiber, obtains mixture；C) heat, solidify: above-mentioned mixture is placed in vacuum drying oven and steams chloroform solvent in 60 DEG C of vacuum drying 24h, it is then heated to 110 DEG C, after insulation 1h, it is down to room temperature, finally give the diamond/Graphene modification weaving carbon fiber/PMMA composite with three-dimensional network framing structure, the thermal conductivity of composite is 252W/mK, tensile strength 274MPa, and bending strength is 35MPa.
Embodiment three: diamond modification weaving carbon fiber strengthens aluminium alloy based composites
Comprise the following steps:
(1) 3 D weaving carbon fiber (aperture is 150 μm, and porosity is 60%) is placed in ultrasonic cleaning in acetone soln；
(2) using evaporation coating technology to sputter Mo film layer on belt carcass diamond three-dimensional network skeleton surface, wherein Mo film thickness is 50nm；Use HF CVD depositing diamond film, deposition process parameters: heated filament distance 6mm, substrate temperature 750 DEG C, hot-wire temperature 2200 DEG C, deposition pressure 3KPa, CH4/H2Volume flow ratio 1:99, obtains diamond film thickness 80 μm；Use magnetically controlled sputter method belt carcass diamond three-dimensional network skeleton surface sputter Mo/Ni/Cu composite film, wherein Mo film thickness be 50nm, Ni film thickness be 50nm, Cu film thickness be 20nm；
(3) weaving carbon fiber of the surface modification obtained in (2) is put in mould; 2 times of Al-Si alloys of weaving carbon fiber skeleton volume are placed on above skeleton; wherein the mass content of Si is 15%; it is then placed in heating furnace; 900 DEG C of insulation 30min under high pure nitrogen is protected, obtain diamond modification weaving carbon fiber and strengthen aluminium alloy based composites, and the thermal conductivity of composite is 572W/mK; tensile strength 587MPa, bending strength is 56MPa.
Embodiment four: diamond/carbon nanotube modification weaving carbon fiber strengthens Cu-base composites
Comprise the following steps:
(1) 3 D weaving carbon fiber (aperture is 250 μm, and porosity is 70%) is placed in ultrasonic cleaning in acetone soln；
(2) using evaporation coating technology to sputter Mo film layer on belt carcass diamond three-dimensional network skeleton surface, wherein Mo film thickness is 50nm；Use HF CVD depositing diamond film, deposition process parameters: heated filament distance 6mm, substrate temperature 750 DEG C, hot-wire temperature 2200 DEG C, deposition pressure 3KPa, CH4/H2Volume flow ratio 1:99, obtains diamond film thickness 500 μm；Use magnetron sputtering technique to deposit the thick nickel film of 5nm on diamond film surface, then use HF CVD to be deposited on diamond film surface catalysis growth CNT woods, depositing operation: CH4/H2Carbonaceous gas mass flow percentage ratio is 10.0%, and growth temperature is 800 DEG C, grows air pressure 104Pa, plasma electric current density 10mA/cm2, in deposition region, magnetic field intensity is 30 teslas, sedimentation time 40min.Using electro-plating method to electroplate Cu film CNT woods again, wherein Cu film thickness is 300nm；
(3) weaving carbon fiber of the surface modification obtained in (2) is put in mould; 2 times of pure Cu blocks of weaving carbon fiber skeleton volume are placed on above skeleton; it is then placed in heating furnace; 1250 DEG C of insulation 30min under high pure nitrogen is protected; obtain diamond/carbon nanotube modification weaving carbon fiber and strengthen Cu-base composites; the thermal conductivity of composite is 1052W/mK, tensile strength 679MPa, and bending strength is 78MPa.
Embodiment five: diamond/graphene/carbon nano-tube modification weaving carbon fiber reinforced epoxy based composites comprises the following steps:
(1) 3 D weaving carbon fiber (aperture is 350 μm, and porosity is 50%) is placed in ultrasonic cleaning in acetone soln；
(2) using evaporation coating techniques to deposit one layer of Mo film on belt carcass diamond three-dimensional network skeleton surface, wherein Mo film thickness is 50nm；Use HF CVD depositing diamond film, deposition process parameters: heated filament distance 6mm, substrate temperature 750 DEG C, hot-wire temperature 2200 DEG C, deposition pressure 3KPa, CH4/H2Volume flow ratio 1:99, obtains diamond film thickness 80 μm；Use magnetron sputtering technique to deposit the thick cobalt film of 5nm on diamond film surface, then use HF CVD to be deposited on diamond film surface carbon nanotube woods, depositing operation: CH4/H2Carbonaceous gas mass flow percentage ratio is 10.0%；Growth temperature is 800 DEG C, grows air pressure 104Pa；Plasma electric current density 10mA/cm2；In deposition region, magnetic field intensity is 200 Gausses, sedimentation time 1h.Using electro-plating method to electroplate Cu film CNT woods again, wherein Cu film thickness is 300nm；
(3) segment by mass parts: epoxy resin 40 parts, diamond/Graphene composite heat-conducting granule 20 parts, coupling agent 0.8 part, antioxidant 0.6 part, the ratio batch mixing of processing aid 3 parts；The weaving carbon fiber of the surface modification obtained in (2) is put in mould, the batch mixings such as mixed epoxy resin is placed in above modified weaving carbon fiber, closes die cavity with the vacuum bag sealing location.Then use a baking oven for heating, melt resin.Solidifying after resin permeable fiber layer under vacuum, curing process is 130 DEG C/1h+150 DEG C/1h+180 DEG C/2h+200 DEG C/2h+220 DEG C/6h.Room temperature is naturally cooled to after having solidified.Being removed from the molds composite sample, the thermal conductivity of composite is 282W/mK.Tensile strength 261MPa, bending strength is 30MPa.
Embodiment six: diamond modification weaving carbon fiber strengthens Cu-base composites
Comprise the following steps:
(1) 3 D weaving carbon fiber (aperture is 300 μm, and porosity is 70%) is placed in ultrasonic cleaning in acetone soln；
(2) using magnetically controlled sputter method to sputter W film layer on 3 D weaving carbon fiber surface, wherein W film thickness is 250nm；Use HF CVD depositing diamond film, deposition process parameters: heated filament distance 6mm, substrate temperature 800 DEG C, hot-wire temperature 2200 DEG C, deposition pressure 3KPa, CH4/H2Volume flow ratio 1:99, obtains diamond film thickness 520 μm；Use magnetically controlled sputter method diamond modification weaving carbon fiber skeleton surface sputter Mo/Cu composite film, wherein Mo film thickness be 50nm, Cu film thickness be 100nm；
(3) weaving carbon fiber of the surface modification obtained in (2) is put in mould, fine copper is heated in crucible simultaneously and be melted to 1140 DEG C, by in fine copper melt cast to mould, use the pressure of hydraulic press pressure 60Mpa, copper melts is forced to be infiltrated into the gap location of diamond modification weaving carbon fiber skeleton, keep pressure 15 seconds, cooling and demolding, take out composite diamond modification weaving carbon fiber and strengthen Cu-base composites, thermal conductivity is 552W/mK, tensile strength 940MPa, bending strength is 49MPa.
Embodiment seven: Graphene modification weaving carbon fiber reinforced aluminum matrix composites
Comprise the following steps:
(1) 3 D weaving carbon fiber (aperture is 400 μm, and porosity is 75%) is placed in ultrasonic cleaning in acetone soln；
(2) using magnetically controlled sputter method to sputter W film layer on 3 D weaving carbon fiber surface, wherein W film thickness is 150nm；Use hot-wall cvd deposited graphite alkene film, particularly as follows: be heated to 950 DEG C (in heating process, H2 and Ar flow velocity is respectively 200 and 500mL/min, and programming rate is 33 DEG C/min) in the atmosphere of H2 and Ar, treat that furnace temperature rises to 950 DEG C of after-baking 10min；Heat treatment is passed through the mixed gas (gas flow rate is respectively methane 5mL/min, hydrogen 200mL/min and argon 500mL/min) of CH4, H2 and Ar after completing, start to grow Graphene, 100 DEG C/min of rate of cooling, obtaining graphene film average thickness is 1.7nm, i.e. obtains graphene coated carbon fiber skeleton；
(3) weaving carbon fiber that the Graphene obtained in (2) is modified is put in mould, fine aluminium is heated in crucible simultaneously and be melted to 730 DEG C, melt is poured in mould, uses the pressure of hydraulic press pressure 60Mpa, force aluminum or aluminum alloy melt to be infiltrated into the gap location of diamond wire in skeleton, keep pressure 15 seconds, cooling and demolding, takes out composite, and the thermal conductivity of composite is 637W/mK, tensile strength 594MPa, bending strength is 60MPa.
Embodiment eight: CNT coated graphite alkene modification weaving carbon fiber strengthens silicon rubber composite material
Comprise the following steps:
(1) 3 D weaving carbon fiber (aperture is 400 μm, and porosity is 75%) is placed in ultrasonic cleaning in acetone soln；
(2) using magnetically controlled sputter method to sputter W film layer on 3 D weaving carbon fiber surface, wherein W film thickness is 150nm；Use hot-wall cvd deposited graphite alkene film, particularly as follows: at H2With the atmosphere of Ar is heated to 950 DEG C of (H in heating process2Being respectively 200 and 500mL/min with Ar flow velocity, programming rate is 33 DEG C/min), treat that furnace temperature rises to 950 DEG C of after-baking 10min；Heat treatment is passed through CH after completing4、H2Mixed gas (gas flow rate is respectively methane 5mL/min, hydrogen 200mL/min and argon 500mL/min) with Ar, start to grow Graphene, 100 DEG C/min of rate of cooling, obtaining graphene film average thickness is 1.7nm, i.e. obtains graphene coated carbon fiber skeleton；Magnetron sputtering deposits one layer of nickel at graphenic surface again, then utilize plasma-assisted chemical vapour deposition at graphenic surface catalytic growth CNT, the lower orientation of growth controlling CNT of effect under extra electric field simultaneously, make them vertical and graphenic surface forms CNT woods, obtaining the strengthening layer of CNT coated graphite alkene film, deposition parameter is: methane, hydrogen mass flow percentage ratio is 10%；Growth temperature is 600 DEG C, grows air pressure 3000Pa；Plasma electric current density 5mA/cm2；In deposition region, magnetic field intensity is 500 Gausses, obtains CNT coated graphite olefinic carbon fiber reinforcement；
(3) instill silicone rubber precursor solution according to volume ratio 1:2 so that it is infiltration fully infiltration CNT coated graphite olefinic carbon fiber reinforcement, obtain mixture；Above-mentioned mixture is carried out application of vacuum 2h, remove solvent therein and bubble, silicone rubber precursor liquid is made preferably to be filled in the hole of carbon fiber skeleton, it is heated to 80 DEG C, and heat preservation solidification 4h, obtaining CNT coated graphite alkene modification weaving carbon fiber and strengthen silicon rubber composite material, heat conductivity is respectively 193W/ (m K), tensile strength 278MPa, bending strength is 28MPa.
Knowable to the thermal conductivity obtained from above example and mechanical performance data, surface modification three-dimensional netlike carbon fiber prepared by the present invention strengthens Metal Substrate or the thermal conductivity of polymer matrix composite, tensile strength, bending strength all obtains tremendous increase, thermal conductivity is up to 1052W/mK, tensile strength is up to 679MPa, bending strength is up to 78MPa, composite prepared by the present invention makes surface reinforced three-dimensional netlike carbon fiber define three-dimensional skeleton continuously in the composite, drastically increase the heat conductivility of composite, meanwhile, carbon fiber spatial distribution in matrix material also can play the mechanical property improving composite, reduce the function of its density and thermal coefficient of expansion.Simultaneously by adding zero dimension reinforced particulate its thermal coefficient of expansion of energy Effective Regulation and mechanics, thermal property.This composite has the most excellent combination property relative to traditional Metal Substrate or polymer matrix composite at aspects such as mechanics, calorifics, electricity, calorifics and high-strength lights.
Claims (13)
1. a surface modification three-dimensional netlike carbon fiber strengthens composite, it is characterised in that: described composite includes matrix material, three-dimensional netlike carbon fiber reinforcement, and wherein said matrix material includes metal material or polymeric material.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 1 strengthens composite, it is characterised in that: the one in the described metal matrix material a kind of or acid bronze alloy, acieral in metallic copper, aluminum；In described acid bronze alloy, acieral, the content of copper or aluminum is more than or equal to 50%；Polymeric matrix is thermoplastic polymer or thermosetting polymer；Described thermoplastic polymer one in polyethylene, polypropylene, polystyrene, polrvinyl chloride, politef, nylon, Merlon, polymethyl methacrylate, glycol ester, poly terephthalic acid, polyformaldehyde, polyamide, polysulfones；Described thermosetting polymer one in epoxy resin, phenolic resin, Lauxite, amino resins, melmac, unsaturated polyester resin, organic siliconresin, silicone rubber, expanded polystyrene (EPS), polyurethane.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 2 strengthens composite, it is characterised in that: the aperture 20 μm-5mm of three-dimensional netlike carbon fiber reinforcement, porosity is 20-95%, and carbon fiber diameter is 3-500 μm.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 3 strengthens composite, it is characterised in that: after three-dimensional netlike carbon fiber reinforcement surface Direct precipitation high thermal conductivity layer or surface modification, deposit high thermal conductivity layer.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 4 strengthens composite, it is characterized in that: three-dimensional netlike carbon fiber reinforcement surface modification is to deposit layer of metal layer at carbon fiber surface, described metal level is selected from the one in nickel, copper, tungsten, molybdenum, titanium, silver, chromium or complex metal layer, and described metal level uses a kind of method in plating, chemical plating, evaporation, magnetron sputtering, chemical gaseous phase deposition, physical vapour deposition (PVD) to deposit.
6. strengthen composite according to a kind of surface modification three-dimensional netlike carbon fiber described in claim 4 or 5, it is characterized in that: the high thermal conductivity layer of deposition one in diamond, Graphene, CNT, Graphene/diamond, CNT/diamond, graphene/carbon nano-tube, diamond/graphene/carbon nano-tube, high thermal conductivity layer thickness is 5-200 μm.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 6 strengthens composite, it is characterized in that: using CVD technology deposition high thermal conductivity layer, the heated filament auxiliary law being chosen in particular from CVD technology, microwave plasma strengthen at least one in method, DC arc plasma jet, electron cyclotron resonace method, flame combustion process, direct-current discharge method, low pressure radio frequency method, normal-pressure radio-frequency method.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 7 strengthens composite, it is characterised in that: the matrix material of composite also includes high heat conduction particle.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 8 strengthens composite, it is characterized in that: at least one in diamond, Graphene, CNT, graphene coated diamond microspheres, CNT cladding diamond microsphere, carborundum, boron carbide, aluminium nitride, boron nitride of described high heat conduction particle, described graphene coated diamond microspheres and CNT cladding diamond microsphere all use chemical gaseous phase deposition to obtain.
A kind of surface modification three-dimensional netlike carbon fiber the most according to claim 9 strengthens composite, it is characterized in that: described composite includes following component, by volume percentage composition composition: matrix material 20-80%, three-dimensional netlike carbon fiber reinforcement 10-70%, high heat conduction particle 0-30%, each volume components percent and be 100%.
11. a kind of surface modification three-dimensional netlike carbon fibers according to claim 10 strengthen the preparation method of composite, comprise the steps:
The first step: woven by carbon fiber three-dimensional netted, cleans, dries；
Second step: use the one in carbon fiber surface deposits nickel, copper, tungsten, molybdenum, titanium, silver, chromium of a kind of method in plating, chemical plating, evaporation, magnetron sputtering, chemical gaseous phase deposition, physical vapour deposition (PVD) or complex metal layer；
3rd step: three-dimensional netlike carbon fiber is soaked in nano-diamond powder or Graphene powder or carbon nanotube suspension and carries out ultrasonic vibration plantation seed crystal pretreatment；
4th step: use the high thermal conductivity layer that one or more in three-dimensional netlike carbon fiber surface depositing diamond, Graphene, CNT of chemical vapour deposition technique are compound, obtain three-dimensional network carbon fiber reinforcement；
5th step: three-dimensional network carbon fiber reinforcement, high heat conduction particle are combined with metallic matrix, the Combined Mining a kind of method in powder metallurgy sintered technology or pressureless infiltration, gas infiltration, casting；Described powder metallurgy sintered technology one in cold-rolled sintered, hot pressed sintering, SPS sintering, vacuum-sintering, atmosphere sintering；Or
Three-dimensional network carbon fiber reinforcement, high heat conduction particle are combined with polymeric matrix, a kind of method in Combined Mining dipping curing molding, injection moulding, compressing, injection mo(u)lding, rotation molding, extrusion moulding, laminated into type, flow casting molding.
12. a kind of surface modification three-dimensional netlike carbon fibers according to claim 11 strengthen the preparation method of composite, it is characterised in that: when matrix material is metal, it is combined with matrix again after high thermal conductivity layer surface configuration Modified Membrane；At least one in tungsten film, molybdenum film, titanium film, nickel film, chromium film of Modified Membrane, or selected from TiC, WC, Cr7C3, NiC, Mo2At least one in C.
13. a kind of surface modification three-dimensional netlike carbon fibers according to claim 11 strengthen the preparation method of composites, and in the 4th step, Graphene, CNT, diamond CVD deposition parameter be:
Graphene CVD deposition parameter is: it is 0.5-80% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1200 DEG C, grows air pressure 5-105Pa；
CNT CVD deposition parameter is: it is 5-50% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1300 DEG C, grows air pressure 103-105Pa；Before CNT CVD deposition, a kind of method in plating, chemical plating, evaporation, magnetron sputtering, chemical gaseous phase deposition, physical vapour deposition (PVD) is used to deposit nickel, copper, the one of cobalt or composite catalytic layer at deposition surface；
Diamond CVD deposition parameter is: it is 0.5-10% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 600-1000 DEG C, grows air pressure 103-104Pa；
By to applying plasma and induced by magnetic field in CVD deposition stove, and regulate carbon throughput, growth temperature, growth air pressure in real time, realizing Graphene/diamond, CNT/diamond, graphene/carbon nano-tube, the CVD deposition of diamond/graphene/carbon nano-tube, deposition parameter is:
Graphene CVD deposition parameter is: it is 0.5-80% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1200 DEG C, grows air pressure 5-105Pa；Plasma electric current density 0-50mA/cm2；In deposition region, magnetic field intensity is that 100 Gausses are to 30 teslas；
CNT CVD deposition parameter is: it is 5-50% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 400-1300 DEG C, grows air pressure 103-105Pa；Plasma electric current density 0-30mA/cm2；In deposition region, magnetic field intensity is that 100 Gausses are to 30 teslas；
Diamond CVD deposition parameter is: it is 0.5-10% that carbonaceous gas accounts for all gas mass flow percentage ratio in stove；Growth temperature is 600-1000 DEG C, grows air pressure 103-104Pa。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610162453.3A CN105818476B (en) | 2016-03-21 | 2016-03-21 | A kind of surface modified 3 D network carbon fibre reinforced composite and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610162453.3A CN105818476B (en) | 2016-03-21 | 2016-03-21 | A kind of surface modified 3 D network carbon fibre reinforced composite and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105818476A true CN105818476A (en) | 2016-08-03 |
| CN105818476B CN105818476B (en) | 2018-08-31 |
Family
ID=56523526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610162453.3A Active CN105818476B (en) | 2016-03-21 | 2016-03-21 | A kind of surface modified 3 D network carbon fibre reinforced composite and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105818476B (en) |
Cited By (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106636992A (en) * | 2016-10-11 | 2017-05-10 | 西南交通大学 | Carbon nanotube and carbon nanofiber synergetic enhanced copper base composite material and preparation method |
| CN106868432A (en) * | 2016-12-05 | 2017-06-20 | 上海阿莱德实业股份有限公司 | It is provided with the gallium alloy heat sink material and its production technology of fiber reinforcement |
| CN107387339A (en) * | 2017-07-19 | 2017-11-24 | 江苏澳盛复合材料科技有限公司 | A kind of composite plate and the wind turbine blade comprising this composite plate |
| CN107675108A (en) * | 2017-09-05 | 2018-02-09 | 巩义市泛锐熠辉复合材料有限公司 | A kind of preparation method of composite carbon-copper material |
| CN108048712A (en) * | 2017-12-14 | 2018-05-18 | 郑州四维特种材料有限责任公司 | A kind of carbon fibre composite boring bar and preparation method thereof |
| CN108058456A (en) * | 2018-01-22 | 2018-05-22 | 山东大学 | A kind of intelligent AUV shell structures and preparation method thereof |
| CN108118269A (en) * | 2016-11-30 | 2018-06-05 | 比亚迪股份有限公司 | A kind of Metal Substrate composite material of silicon carbide and preparation method thereof |
| CN108251063A (en) * | 2016-12-28 | 2018-07-06 | 北京有色金属研究总院 | A kind of high-performance composite phase-change material and preparation method thereof |
| CN108465815A (en) * | 2018-02-13 | 2018-08-31 | 东莞市联洲知识产权运营管理有限公司 | A kind of porous carbon-based transition metal porous material and preparation method thereof of three-dimensional co-continuous |
| CN108796399A (en) * | 2018-07-02 | 2018-11-13 | 黄河科技学院 | A kind of metal alloy and preparation method thereof with high impact resistance |
| CN109037165A (en) * | 2018-07-18 | 2018-12-18 | 上海电机学院 | A kind of aluminium base electronic package material and its processing method |
| CN109338255A (en) * | 2018-11-02 | 2019-02-15 | 罗源县白塔乡企业服务中心 | A method of being used to prepare tungsten nickel bimetal composite material |
| CN109468549A (en) * | 2018-12-10 | 2019-03-15 | 南昌航空大学 | A kind of near-net-shape method of 3D braided fiber enhancing metal-base composites |
| CN109535509A (en) * | 2018-11-20 | 2019-03-29 | 中广核高新核材科技（苏州）有限公司 | A kind of radiation resistant rubber diaphragm and preparation method thereof |
| CN109536935A (en) * | 2018-12-03 | 2019-03-29 | 中南大学 | A kind of preparation method of complex metal layer plating Buckie paper composites |
| CN109722644A (en) * | 2018-12-29 | 2019-05-07 | 赛福纳米科技(徐州)有限公司 | The surface modifying method of carbon nano-hybrid material |
| CN109749637A (en) * | 2018-12-20 | 2019-05-14 | 武汉理工大学 | A kind of method of carbon fibre composite and aluminium alloy interface processing |
| CN109852831A (en) * | 2019-01-15 | 2019-06-07 | 中南大学 | A kind of preparation method of metal material or metallic composite |
| TWI663124B (en) * | 2016-11-23 | 2019-06-21 | 永虹先進材料股份有限公司 | Carbon fiber manufacturing method |
| CN110004384A (en) * | 2019-05-09 | 2019-07-12 | 重庆文理学院 | A kind of preparation method of carbon fiber powder enhancing tungsten-based composite material |
| CN110112005A (en) * | 2019-05-15 | 2019-08-09 | 宁波石墨烯创新中心有限公司 | A kind of combination electrode and preparation method thereof and application |
| CN110165229A (en) * | 2019-05-28 | 2019-08-23 | 东旭光电科技股份有限公司 | A kind of compound carbon fiber paper of graphene and its preparation method and application |
| CN110423959A (en) * | 2019-08-01 | 2019-11-08 | 安徽科蓝特铝业有限公司 | A kind of aluminium base high-ductility composite material and preparation method thereof |
| CN110904356A (en) * | 2019-10-29 | 2020-03-24 | 北京碳垣新材料科技有限公司 | Preparation method of network interpenetrating graphene-copper composite material |
| CN110983210A (en) * | 2019-09-12 | 2020-04-10 | 全球能源互联网研究院有限公司 | Carbon fiber composite copper-tungsten alloy material and preparation method and application thereof |
| CN111500023A (en) * | 2020-05-23 | 2020-08-07 | 湖南东映碳材料科技有限公司 | High-thermal-conductivity composite material and preparation method thereof |
| CN111519115A (en) * | 2020-03-25 | 2020-08-11 | 成都美奢锐新材料有限公司 | High-toughness high-wear-resistance titanium carbonitride based cermet material and preparation method thereof |
| CN111584151A (en) * | 2020-05-26 | 2020-08-25 | 杭州幄肯新材料科技有限公司 | Carbon fiber/carbon/graphite composite carbon felt and method for enhancing heat conduction and electric conduction performance of polymer composite material |
| CN111572114A (en) * | 2020-05-13 | 2020-08-25 | 湖南东映碳材料科技有限公司 | Carbon net composite membrane and preparation method thereof |
| CN111893405A (en) * | 2020-06-23 | 2020-11-06 | 西安理工大学 | Titanium fiber toughening cold heading die and preparation method thereof |
| CN111945123A (en) * | 2020-08-12 | 2020-11-17 | 西部金属材料股份有限公司 | Flexible metal composite fiber porous material and preparation method and application thereof |
| CN112159231A (en) * | 2020-10-09 | 2021-01-01 | 武汉理工大学 | Rapid preparation method of super-hard light diamond-B4C-SiC ternary composite ceramic |
| CN112358315A (en) * | 2020-11-27 | 2021-02-12 | 西北工业大学 | Preparation method of ceramic matrix composite material containing cooling pore channel |
| CN112388881A (en) * | 2020-10-22 | 2021-02-23 | 吴江创源玩具有限公司 | Rotational molding part, fabric framework, rotational molding part production method and fabric framework production method |
| CN112553547A (en) * | 2020-12-07 | 2021-03-26 | 深圳市博迪科技开发有限公司 | Preparation method of high-thermal-conductivity metal-based carbon fiber heating body material |
| CN112831186A (en) * | 2021-01-11 | 2021-05-25 | 华东理工大学 | Fiber-reinforced rubber elastomer composite material and preparation method thereof |
| CN112910379A (en) * | 2021-02-01 | 2021-06-04 | 南京理工大学 | Photo-thermal-pyroelectric heterojunction photovoltaic energy collector and preparation method thereof |
| CN112941596A (en) * | 2021-01-28 | 2021-06-11 | 华侨大学 | Preparation method of fine-grained plated diamond carbon nanotube fiber composite material |
| CN112962035A (en) * | 2021-02-02 | 2021-06-15 | 哈尔滨工业大学 | Method for improving corrosion resistance of carbon fiber reinforced aluminum matrix composite |
| CN113150498A (en) * | 2021-04-19 | 2021-07-23 | 泉州师范学院 | High-strength, heat-conducting and insulating epoxy resin composite material and preparation method thereof |
| CN113275031A (en) * | 2021-05-14 | 2021-08-20 | 金陵科技学院 | Metal particle loaded graphite phase carbon nitride (M/g-C)3N4) Three-dimensional scaffold and preparation method and application thereof |
| CN113308650A (en) * | 2021-05-26 | 2021-08-27 | 苏州融睿电子科技有限公司 | Packaging shell composite material and preparation method and application thereof |
| CN113463246A (en) * | 2021-06-15 | 2021-10-01 | 上海大学绍兴研究院 | Carbon fiber preform, preparation method thereof and densification method of carbon fiber preform |
| CN113480833A (en) * | 2021-07-30 | 2021-10-08 | 宁波石墨烯创新中心有限公司 | Preparation method of graphene/spiral carbon fiber/epoxy resin composite material |
| CN114045114A (en) * | 2021-12-16 | 2022-02-15 | 南京林业大学 | Use method and preparation method of silicon carbide-based core-shell structure microwave absorbing material |
| CN114272852A (en) * | 2021-12-30 | 2022-04-05 | 郑立 | Carbon fiber reinforced high-temperature high-pressure reaction container and processing method thereof |
| CN114407227A (en) * | 2022-01-12 | 2022-04-29 | 江南大学 | High-layer dense flat carbon fiber gradient suture preform and preparation method thereof |
| CN114457294A (en) * | 2022-01-14 | 2022-05-10 | 西安工业大学 | Preparation method of high-strength high-resistance multi-scale cooperative reinforced aluminum matrix composite |
| CN114771042A (en) * | 2022-04-28 | 2022-07-22 | 太原理工大学 | Diamond carbon fiber composite material and preparation method thereof |
| CN114771041A (en) * | 2022-04-28 | 2022-07-22 | 太原理工大学 | Preparation method of diamond carbon fiber multilayer woven composite material |
| CN114771043A (en) * | 2022-04-28 | 2022-07-22 | 太原理工大学 | High-bonding-strength diamond carbon fiber composite material and preparation method thereof |
| CN114935349A (en) * | 2022-05-31 | 2022-08-23 | 江苏大学 | Carbon powder modified multi-electrode CFRP intelligent sensing structure and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080254296A1 (en) * | 2005-03-22 | 2008-10-16 | Bussan Nanotech Research Institute Inc. | Carbon Fibrous Conjunct and Composite Material Using Thereof |
| CN101531804A (en) * | 2009-04-13 | 2009-09-16 | 天津大学 | Electromagnetic shielding compound material made from three-dimensional braided nickel-plated carbon fiber and epoxy resin and method for preparing same |
| CN103144356A (en) * | 2013-03-12 | 2013-06-12 | 南京航空航天大学 | High-conductivity composite carbon fiber and preparation method thereof |
-
2016
- 2016-03-21 CN CN201610162453.3A patent/CN105818476B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080254296A1 (en) * | 2005-03-22 | 2008-10-16 | Bussan Nanotech Research Institute Inc. | Carbon Fibrous Conjunct and Composite Material Using Thereof |
| CN101531804A (en) * | 2009-04-13 | 2009-09-16 | 天津大学 | Electromagnetic shielding compound material made from three-dimensional braided nickel-plated carbon fiber and epoxy resin and method for preparing same |
| CN103144356A (en) * | 2013-03-12 | 2013-06-12 | 南京航空航天大学 | High-conductivity composite carbon fiber and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 高波: "碳纤维织物增强铝基复合材料的制备与性能研究", 《中国优秀硕士学位论文全文数据库》 * |
Cited By (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106636992B (en) * | 2016-10-11 | 2018-06-12 | 西南交通大学 | A kind of CNTs and CNFs collaborations enhancing Cu-base composites and preparation method |
| CN106636992A (en) * | 2016-10-11 | 2017-05-10 | 西南交通大学 | Carbon nanotube and carbon nanofiber synergetic enhanced copper base composite material and preparation method |
| TWI663124B (en) * | 2016-11-23 | 2019-06-21 | 永虹先進材料股份有限公司 | Carbon fiber manufacturing method |
| CN108118269B (en) * | 2016-11-30 | 2020-06-19 | 比亚迪股份有限公司 | Metal-based silicon carbide composite material and preparation method thereof |
| CN108118269A (en) * | 2016-11-30 | 2018-06-05 | 比亚迪股份有限公司 | A kind of Metal Substrate composite material of silicon carbide and preparation method thereof |
| CN106868432A (en) * | 2016-12-05 | 2017-06-20 | 上海阿莱德实业股份有限公司 | It is provided with the gallium alloy heat sink material and its production technology of fiber reinforcement |
| CN108251063B (en) * | 2016-12-28 | 2021-05-11 | 有研工程技术研究院有限公司 | High-performance composite phase-change material and preparation method thereof |
| CN108251063A (en) * | 2016-12-28 | 2018-07-06 | 北京有色金属研究总院 | A kind of high-performance composite phase-change material and preparation method thereof |
| CN107387339A (en) * | 2017-07-19 | 2017-11-24 | 江苏澳盛复合材料科技有限公司 | A kind of composite plate and the wind turbine blade comprising this composite plate |
| CN107675108A (en) * | 2017-09-05 | 2018-02-09 | 巩义市泛锐熠辉复合材料有限公司 | A kind of preparation method of composite carbon-copper material |
| CN108048712A (en) * | 2017-12-14 | 2018-05-18 | 郑州四维特种材料有限责任公司 | A kind of carbon fibre composite boring bar and preparation method thereof |
| CN108058456B (en) * | 2018-01-22 | 2023-12-19 | 山东大学 | Intelligent AUV shell structure and preparation method thereof |
| CN108058456A (en) * | 2018-01-22 | 2018-05-22 | 山东大学 | A kind of intelligent AUV shell structures and preparation method thereof |
| CN108465815A (en) * | 2018-02-13 | 2018-08-31 | 东莞市联洲知识产权运营管理有限公司 | A kind of porous carbon-based transition metal porous material and preparation method thereof of three-dimensional co-continuous |
| CN108796399B (en) * | 2018-07-02 | 2020-07-03 | 黄河科技学院 | Metal alloy with high impact resistance and preparation method thereof |
| CN108796399A (en) * | 2018-07-02 | 2018-11-13 | 黄河科技学院 | A kind of metal alloy and preparation method thereof with high impact resistance |
| CN109037165A (en) * | 2018-07-18 | 2018-12-18 | 上海电机学院 | A kind of aluminium base electronic package material and its processing method |
| CN109338255A (en) * | 2018-11-02 | 2019-02-15 | 罗源县白塔乡企业服务中心 | A method of being used to prepare tungsten nickel bimetal composite material |
| CN109338255B (en) * | 2018-11-02 | 2019-12-27 | 罗源县白塔乡企业服务中心 | Method for preparing tungsten-nickel bimetal composite material |
| CN109535509A (en) * | 2018-11-20 | 2019-03-29 | 中广核高新核材科技（苏州）有限公司 | A kind of radiation resistant rubber diaphragm and preparation method thereof |
| CN109536935A (en) * | 2018-12-03 | 2019-03-29 | 中南大学 | A kind of preparation method of complex metal layer plating Buckie paper composites |
| CN109468549A (en) * | 2018-12-10 | 2019-03-15 | 南昌航空大学 | A kind of near-net-shape method of 3D braided fiber enhancing metal-base composites |
| CN109749637A (en) * | 2018-12-20 | 2019-05-14 | 武汉理工大学 | A kind of method of carbon fibre composite and aluminium alloy interface processing |
| CN109722644A (en) * | 2018-12-29 | 2019-05-07 | 赛福纳米科技(徐州)有限公司 | The surface modifying method of carbon nano-hybrid material |
| CN109722644B (en) * | 2018-12-29 | 2020-09-18 | 赛福纳米科技(徐州)有限公司 | Surface modification method of carbon nano hybrid material |
| CN109852831A (en) * | 2019-01-15 | 2019-06-07 | 中南大学 | A kind of preparation method of metal material or metallic composite |
| CN109852831B (en) * | 2019-01-15 | 2020-09-25 | 中南大学 | Preparation method of metal material or metal composite material |
| CN110004384A (en) * | 2019-05-09 | 2019-07-12 | 重庆文理学院 | A kind of preparation method of carbon fiber powder enhancing tungsten-based composite material |
| CN110004384B (en) * | 2019-05-09 | 2020-02-07 | 重庆文理学院 | Preparation method of carbon fiber powder reinforced tungsten-based composite material |
| CN110112005A (en) * | 2019-05-15 | 2019-08-09 | 宁波石墨烯创新中心有限公司 | A kind of combination electrode and preparation method thereof and application |
| CN110112005B (en) * | 2019-05-15 | 2021-02-09 | 宁波石墨烯创新中心有限公司 | Composite electrode and manufacturing method and application thereof |
| CN110165229A (en) * | 2019-05-28 | 2019-08-23 | 东旭光电科技股份有限公司 | A kind of compound carbon fiber paper of graphene and its preparation method and application |
| CN110165229B (en) * | 2019-05-28 | 2022-06-28 | 东旭光电科技股份有限公司 | Graphene composite carbon fiber paper and preparation method and application thereof |
| CN110423959A (en) * | 2019-08-01 | 2019-11-08 | 安徽科蓝特铝业有限公司 | A kind of aluminium base high-ductility composite material and preparation method thereof |
| CN110983210B (en) * | 2019-09-12 | 2021-05-28 | 全球能源互联网研究院有限公司 | Carbon fiber composite copper-tungsten alloy material and preparation method and application thereof |
| CN110983210A (en) * | 2019-09-12 | 2020-04-10 | 全球能源互联网研究院有限公司 | Carbon fiber composite copper-tungsten alloy material and preparation method and application thereof |
| CN110904356A (en) * | 2019-10-29 | 2020-03-24 | 北京碳垣新材料科技有限公司 | Preparation method of network interpenetrating graphene-copper composite material |
| CN110904356B (en) * | 2019-10-29 | 2021-05-14 | 北京碳垣新材料科技有限公司 | Preparation method of network interpenetrating graphene-copper composite material |
| CN111519115B (en) * | 2020-03-25 | 2021-12-28 | 成都美奢锐新材料有限公司 | High-toughness high-wear-resistance titanium carbonitride based cermet material and preparation method thereof |
| CN111519115A (en) * | 2020-03-25 | 2020-08-11 | 成都美奢锐新材料有限公司 | High-toughness high-wear-resistance titanium carbonitride based cermet material and preparation method thereof |
| CN111572114A (en) * | 2020-05-13 | 2020-08-25 | 湖南东映碳材料科技有限公司 | Carbon net composite membrane and preparation method thereof |
| CN111500023A (en) * | 2020-05-23 | 2020-08-07 | 湖南东映碳材料科技有限公司 | High-thermal-conductivity composite material and preparation method thereof |
| CN111584151A (en) * | 2020-05-26 | 2020-08-25 | 杭州幄肯新材料科技有限公司 | Carbon fiber/carbon/graphite composite carbon felt and method for enhancing heat conduction and electric conduction performance of polymer composite material |
| CN111584151B (en) * | 2020-05-26 | 2021-10-01 | 杭州幄肯新材料科技有限公司 | Carbon fiber/carbon/graphite composite carbon felt and method for enhancing heat conduction and electric conduction performance of polymer composite material |
| CN111893405A (en) * | 2020-06-23 | 2020-11-06 | 西安理工大学 | Titanium fiber toughening cold heading die and preparation method thereof |
| CN111945123A (en) * | 2020-08-12 | 2020-11-17 | 西部金属材料股份有限公司 | Flexible metal composite fiber porous material and preparation method and application thereof |
| CN112159231A (en) * | 2020-10-09 | 2021-01-01 | 武汉理工大学 | Rapid preparation method of super-hard light diamond-B4C-SiC ternary composite ceramic |
| CN112388881A (en) * | 2020-10-22 | 2021-02-23 | 吴江创源玩具有限公司 | Rotational molding part, fabric framework, rotational molding part production method and fabric framework production method |
| CN112358315A (en) * | 2020-11-27 | 2021-02-12 | 西北工业大学 | Preparation method of ceramic matrix composite material containing cooling pore channel |
| CN112553547A (en) * | 2020-12-07 | 2021-03-26 | 深圳市博迪科技开发有限公司 | Preparation method of high-thermal-conductivity metal-based carbon fiber heating body material |
| CN112831186A (en) * | 2021-01-11 | 2021-05-25 | 华东理工大学 | Fiber-reinforced rubber elastomer composite material and preparation method thereof |
| CN112831186B (en) * | 2021-01-11 | 2021-12-03 | 华东理工大学 | Fiber-reinforced rubber elastomer composite material and preparation method thereof |
| CN112941596A (en) * | 2021-01-28 | 2021-06-11 | 华侨大学 | Preparation method of fine-grained plated diamond carbon nanotube fiber composite material |
| CN112910379A (en) * | 2021-02-01 | 2021-06-04 | 南京理工大学 | Photo-thermal-pyroelectric heterojunction photovoltaic energy collector and preparation method thereof |
| CN112910379B (en) * | 2021-02-01 | 2022-07-29 | 南京理工大学 | Preparation method of photo-thermal-pyroelectric heterojunction photovoltaic energy collector |
| CN112962035A (en) * | 2021-02-02 | 2021-06-15 | 哈尔滨工业大学 | Method for improving corrosion resistance of carbon fiber reinforced aluminum matrix composite |
| CN113150498A (en) * | 2021-04-19 | 2021-07-23 | 泉州师范学院 | High-strength, heat-conducting and insulating epoxy resin composite material and preparation method thereof |
| CN113275031A (en) * | 2021-05-14 | 2021-08-20 | 金陵科技学院 | Metal particle loaded graphite phase carbon nitride (M/g-C)3N4) Three-dimensional scaffold and preparation method and application thereof |
| CN113275031B (en) * | 2021-05-14 | 2022-12-23 | 金陵科技学院 | Graphite phase carbon nitride (M/g-C) loaded with metal particles 3 N 4 ) Three-dimensional scaffold and preparation method and application thereof |
| CN113308650A (en) * | 2021-05-26 | 2021-08-27 | 苏州融睿电子科技有限公司 | Packaging shell composite material and preparation method and application thereof |
| CN113463246A (en) * | 2021-06-15 | 2021-10-01 | 上海大学绍兴研究院 | Carbon fiber preform, preparation method thereof and densification method of carbon fiber preform |
| CN113480833A (en) * | 2021-07-30 | 2021-10-08 | 宁波石墨烯创新中心有限公司 | Preparation method of graphene/spiral carbon fiber/epoxy resin composite material |
| CN113480833B (en) * | 2021-07-30 | 2023-08-22 | 宁波石墨烯创新中心有限公司 | Preparation method of graphene/spiral carbon fiber/epoxy resin composite material |
| CN114045114A (en) * | 2021-12-16 | 2022-02-15 | 南京林业大学 | Use method and preparation method of silicon carbide-based core-shell structure microwave absorbing material |
| CN114272852A (en) * | 2021-12-30 | 2022-04-05 | 郑立 | Carbon fiber reinforced high-temperature high-pressure reaction container and processing method thereof |
| CN114272852B (en) * | 2021-12-30 | 2024-06-04 | 郑立 | Carbon fiber reinforced high-temperature high-pressure reaction vessel and processing method thereof |
| CN114407227A (en) * | 2022-01-12 | 2022-04-29 | 江南大学 | High-layer dense flat carbon fiber gradient suture preform and preparation method thereof |
| CN114457294B (en) * | 2022-01-14 | 2022-09-23 | 西安工业大学 | Preparation method of high-strength high-resistance multi-scale cooperative reinforced aluminum matrix composite |
| CN114457294A (en) * | 2022-01-14 | 2022-05-10 | 西安工业大学 | Preparation method of high-strength high-resistance multi-scale cooperative reinforced aluminum matrix composite |
| CN114771043A (en) * | 2022-04-28 | 2022-07-22 | 太原理工大学 | High-bonding-strength diamond carbon fiber composite material and preparation method thereof |
| CN114771041A (en) * | 2022-04-28 | 2022-07-22 | 太原理工大学 | Preparation method of diamond carbon fiber multilayer woven composite material |
| CN114771042A (en) * | 2022-04-28 | 2022-07-22 | 太原理工大学 | Diamond carbon fiber composite material and preparation method thereof |
| CN114771041B (en) * | 2022-04-28 | 2024-01-16 | 太原理工大学 | Preparation method of diamond carbon fiber multi-layer woven composite material |
| CN114771042B (en) * | 2022-04-28 | 2024-01-16 | 太原理工大学 | Diamond carbon fiber composite material and preparation method thereof |
| CN114771043B (en) * | 2022-04-28 | 2024-01-16 | 太原理工大学 | High-bonding-strength diamond carbon fiber composite material and preparation method thereof |
| CN114935349A (en) * | 2022-05-31 | 2022-08-23 | 江苏大学 | Carbon powder modified multi-electrode CFRP intelligent sensing structure and preparation method thereof |
| CN114935349B (en) * | 2022-05-31 | 2024-06-04 | 江苏大学 | Carbon powder modified multi-electrode CFRP intelligent sensing structure and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105818476B (en) | 2018-08-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105818476B (en) | A kind of surface modified 3 D network carbon fibre reinforced composite and preparation method | |
| CN105755307A (en) | Reinforced composite adopting honeycomb structure and preparation method | |
| US10995192B2 (en) | Composite material reinforced by foamed skeleton and preparation method and uses thereof | |
| CN105733192B (en) | A kind of foam framework enhancing polymer matrix composite and preparation method thereof | |
| CN105733191A (en) | Different-dimensionality high-heat-conductivity material enhanced and polymer based composite and preparation method thereof | |
| CN105603248B (en) | A kind of foamy graphite alkene skeleton enhancing Cu-base composites and preparation method | |
| CN105603265B (en) | Foamy graphite alkene skeleton reinforced aluminum matrix composites and preparation method thereof | |
| CN105779804B (en) | A kind of foam framework structure enhancing metal-base composites and preparation method | |
| CN105671354B (en) | A kind of foam diamond framework reinforced aluminum matrix composites and preparation method thereof | |
| CN105779805B (en) | Foam diamond framework strengthens Cu-base composites and preparation method | |
| CN105112754B (en) | Three-dimensional network diamond framework strengthens metal-base composites and preparation method | |
| CN105695831B (en) | A kind of continuous diamond framework enhancing composite of super-high heat-conductive and preparation method | |
| CN105803241B (en) | A kind of conveyor screw enhancing Metal Substrate or polymer matrix composite and preparation method | |
| CN105803242A (en) | Composite enhanced through coupling of flaky and linear thermal conductive materials and preparation method | |
| CN107381555A (en) | A kind of three-dimensional grapheme of structure-controllable and its preparation method of composite | |
| US20180056435A1 (en) | Multi-scale manufacturing of carbon nanotube composites | |
| CN110372390A (en) | Continuous fiber reinforced SiC part preparation method and product based on increasing material manufacturing | |
| JP3673436B2 (en) | Carbon-based metal composite material and manufacturing method thereof | |
| US7063815B2 (en) | Production of composite materials by powder injection molding and infiltration | |
| CN110438457B (en) | Modified diamond particles, modification method, application of modified diamond particles as reinforcing phase and obtained metal-based composite material | |
| CN103724046A (en) | SiC foam and preparation method thereof | |
| Jiang et al. | Enhanced thermal conductivity and bending strength of graphite flakes/aluminum composites via graphite surface modification | |
| Wang et al. | Effects of carbon matrix on microstructure and properties of 3-DC/ZrC composites prepared by reactive melt infiltration | |
| EP3796767B1 (en) | Composite material | |
| CN113996782A (en) | Composite material of graphene coated copper powder and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |