CN105802542A - Insect-resistant adhesive for paper products and preparing method of insect-resistant adhesive - Google Patents

Insect-resistant adhesive for paper products and preparing method of insect-resistant adhesive Download PDF

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Publication number
CN105802542A
CN105802542A CN201610340177.5A CN201610340177A CN105802542A CN 105802542 A CN105802542 A CN 105802542A CN 201610340177 A CN201610340177 A CN 201610340177A CN 105802542 A CN105802542 A CN 105802542A
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Prior art keywords
parts
weight
resistant adhesive
pest
corresponding parts
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Pending
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CN201610340177.5A
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Inventor
曹堪洲
范刚华
许米乐
陈伟伟
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JIANGSU JINWO MACHINERY CO Ltd
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JIANGSU JINWO MACHINERY CO Ltd
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Priority to CN201610340177.5A priority Critical patent/CN105802542A/en
Publication of CN105802542A publication Critical patent/CN105802542A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/21Urea; Derivatives thereof, e.g. biuret
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The invention discloses an insect-resistant adhesive for paper products and a preparing method of the insect-resistant adhesive.The insect-resistant adhesive for paper products is prepared from, by weight, 100-150 parts of potato residues, 2-8 parts of an antioxidant, 2-8 parts of urea, 1-4 parts of a thermal initiator, 1-4 parts of an antifoaming agent, 1-4 parts of borax, 10-20 parts of sodium bentonite, 4-20 parts of an antibacterial agent and 0.2-0.4 part of an assistant.According to the insect-resistant adhesive for paper products and the preparing method of the insect-resistant adhesive, waste materials are utilized, energy conservation and environment protection are achieved, pollution to the environment is relieved, the service life of the adhesive is integrally prolonged, high environment friendliness is achieved, safety is high, and significance is remarkable.

Description

A kind of paper product pest-resistant adhesive and preparation method thereof
Technical field
The present invention relates to a kind of adhesive, be specifically related to a kind of paper product adhesive.
Background technology
Adhesive is material bi-material or two kinds of materials separated linked together by adhesion and the cohesive strength at interface, the structure of material to be bonded is not had significant change, and gives cement plane with enough intensity.The bonding at interface uses adhesive to overcome stress concentration phenomenon, and bonding has good vibration resistance, fatigue durability, the characteristics such as stress distribution is uniform, good airproof performance.At light sheet material, the field adhesive such as weaving, timber processing, the articles for daily use, paper product and adhesive technology are widely used.
Adhesive has a natural and synthetic, of a great variety, different properties, of many uses, easy to use.
Wherein paper article packaging industry is the bigger market of adhesive, is broadly divided into packaging material and packaging applications two parts;The production of packaging material, uses amylum adhesive, acetate emulsion and PUR in a large number, and packaging applications has the bonding of Commercial goods labels etc. to use amylan, adhesive sticker etc..
But a lot of adhesive is because raw material adopts natural organic to be prepared from, the paper product being prepared from time in processing in particular for paper product is easy to be eaten into erosion, or easily recruits fly worm or bacterium of easily mildewing, and therefore needs to develop adhesive numerous in variety to solve this problem.
Summary of the invention
Goal of the invention: for prior art Problems existing, the technical problem to be solved is to provide a kind of pest-resistant adhesive of paper product.The preparation method that second technical problem to be solved by this invention is to provide the pest-resistant adhesive of this paper product a kind of.
Technical scheme: for solving above-mentioned technical problem, the invention provides a kind of pest-resistant adhesive of paper product, includes following components according to parts by weight and make: potato residues 100~150 parts;Oxidant 2~8 parts;2~8 parts of carbamide;Thermal initiator 1~4 part;Defoamer 1~4 part;Borax 1~4 part;Sodium bentonite 10~20 parts;Antibacterial 4~20 parts;Auxiliary agent 0.2~0.4 part.
Preferably, described auxiliary agent includes following components according to parts by weight and makes: thickening agent 0.1~0.2 part;Toughener 0.1~0.2 part.
Preferably, described auxiliary agent includes following components according to parts by weight and makes: medical stone powder 0.1~0.2 part;Toughener 0.1~0.2 part.
Preferred as another kind, described auxiliary agent includes following components according to parts by weight and makes: medical stone powder 0.1~0.2 part;Thickening agent 0.05~0.1 part;Toughener 0.05~0.1 part.
Preferably, described antibacterial includes following components according to parts by weight and makes: Parmelia tinctorum Despr. extract 1~6 part;Radix Buddlejae Butterflybush extract 1~4 part;Nano-silver ionic 1~6 part, Luan Shu extract 1~4 part.
Present invention simultaneously provides a kind of preparation method for above-mentioned paper product with pest-resistant adhesive, comprise the steps:
1) by the potato residues of corresponding parts by weight, adding suitable quantity of water, pH value controls 7.5~9.5, carries out micronizing after stirring;
2) thermal initiator of the potato residues processed through micronizing and corresponding parts by weight is loaded reactor, carry out autoclaving 45~60min;
3) by through step 2) material that processed of high compressed steam add after the sodium bentonite of corresponding parts by weight stirs 5~10 minutes, add the defoamer of corresponding parts by weight, oxidant and auxiliary agent, pH value controls 7~9, heating mixing high-speed stirred reaction 1~2h, temperature controls at 40~50 DEG C;
4) in the reactor, the antibacterial of corresponding parts by weight that will process through atomization, mixing adds the step 3 being in high-speed stirred) in gains;
5) carbamide and the Borax of corresponding parts by weight are then added, ultra violet lamp 0.5~1 hour while stirring;
6) stir, cooling, prepare target product.
Beneficial effect: provided by the invention be primary raw material with potato residues paper product pest-resistant adhesive and preparation method thereof, twice laid energy-conserving and environment-protective, decrease the pollution to environment;And initial viscosity is moderate, and reach relatively high viscosity within a certain period of time, it is easy to operation is implemented;It is while having higher bond strength and good bacteriostasis efficacy, can effectively suppress the breeding of worm's ovum, has good pest-resistant bacteriostasis efficacy;Other component synergism such as Parmelia tinctorum Despr. extract in its antibacterial, Luan Shu extract and potato residues, while having pest-resistant bacteriostasis property, have antioxidation, significantly improve this paper product antioxygenic property of pest-resistant adhesive, bactericidal performance;Especially when in auxiliary agent containing medical stone powder, its with antibacterial, potato residues, sodium bentonite and other component synergism, greatly reduce regain;Simultaneously provided by the invention be primary raw material with potato residues the paper product preparation method of pest-resistant adhesive, control by correlation step pH value, in the process of high-speed stirred, atomization adds antibacterial, and under ultra violet lamp, addition carbamide and Borax cool down after being stirred, and improve the pest-resistant bacteriostasis efficacy of the pest-resistant adhesive of obtained paper product, stability and non-oxidizability further;Entirety extends service life, possesses excellent environment friendly, it is provided that a kind of adhesive new varieties select as required for user, and safety is high, and meaning is notable.
Detailed description of the invention
Embodiment 1: a kind of pest-resistant adhesive of paper product, includes following components according to parts by weight and makes: potato residues 100 parts;Oxidant 2 parts;2 parts of carbamide;Thermal initiator 1 part;Defoamer 1 part;Borax 1 part;Sodium bentonite 10 parts;Antibacterial 4 parts;Auxiliary agent 0.2 part.
Wherein auxiliary agent includes following components according to parts by weight and makes: thickening agent 0.1 part;Toughener 0.1 part.
Described antibacterial includes following components according to parts by weight and makes: Parmelia tinctorum Despr. extract 1 part;Radix Buddlejae Butterflybush extract 1 part;Nano-silver ionic 1 part, Luan Shu extract 1 part.
Preparation method comprises the steps: 1) by the potato residues of corresponding parts by weight, add suitable quantity of water, pH value controls 7.5, carries out micronizing after stirring;2) thermal initiator of the potato residues processed through micronizing and corresponding parts by weight is loaded reactor, carry out autoclaving 45min;3) by through step 2) material that processed of high compressed steam add after the sodium bentonite of corresponding parts by weight stirs 5 minutes, add the defoamer of corresponding parts by weight, oxidant and auxiliary agent, pH value controls 7, and heating mixing high-speed stirred react 1h, and temperature controls at 40 DEG C;4) in the reactor, the antibacterial of corresponding parts by weight that will process through atomization, mixing adds the step 3 being in high-speed stirred) in gains;5) carbamide and the Borax of corresponding parts by weight are then added, ultra violet lamp 0.5 hour while stirring;6) stir, cooling, prepare target product.Target product outward appearance is milky thick liquid, and after testing, this product initial viscosity is 0.05Pa.s, reaches 4Pa.s, regain 12% after 30s.
Embodiment 2: a kind of pest-resistant adhesive of paper product, includes following components according to parts by weight and makes: potato residues 150 parts;Oxidant 8 parts;8 parts of carbamide;Thermal initiator 4 parts;Defoamer 4 parts;Borax 4 parts;Sodium bentonite 20 parts;Antibacterial 20 parts;Auxiliary agent 0.4 part.
Wherein auxiliary agent includes following components according to parts by weight and makes: thickening agent 0.2 part;Toughener 0.2 part.
Described antibacterial includes following components according to parts by weight and makes: Parmelia tinctorum Despr. extract 6 parts;Radix Buddlejae Butterflybush extract 4 parts;Nano-silver ionic 6 parts, Luan Shu extract 4 parts.
Preparation method comprises the steps: 1) by the potato residues of corresponding parts by weight, add suitable quantity of water, pH value controls 9.5, carries out micronizing after stirring;2) thermal initiator of the potato residues processed through micronizing and corresponding parts by weight is loaded reactor, carry out autoclaving 60min;3) by through step 2) material that processed of high compressed steam add after the sodium bentonite of corresponding parts by weight stirs 10 minutes, add the defoamer of corresponding parts by weight, oxidant and auxiliary agent, pH value controls 9, and heating mixing high-speed stirred react 2h, and temperature controls at 50 DEG C;4) in the reactor, the antibacterial of corresponding parts by weight that will process through atomization, mixing adds the step 3 being in high-speed stirred) in gains;5) carbamide and the Borax of corresponding parts by weight are then added, ultra violet lamp 1 hour while stirring;6) stir, cooling, prepare target product.Target product outward appearance is milky thick liquid, and after testing, this product initial viscosity is 0.15Pa.s, reaches 5Pa.s, regain 11% after 30s.
Embodiment 3: a kind of pest-resistant adhesive of paper product, includes following components according to parts by weight and makes: potato residues 125 parts;Oxidant 5 parts;5 parts of carbamide;Thermal initiator 2 parts;Defoamer 2 parts;Borax 2 parts;Sodium bentonite 15 parts;Antibacterial 12 parts;Auxiliary agent 0.3 part.
Wherein auxiliary agent includes following components according to parts by weight and makes: medical stone powder 0.15 part;Thickening agent 0.075 part;Toughener 0.075 part.
Described antibacterial includes following components according to parts by weight and makes: Parmelia tinctorum Despr. extract 4 parts;Radix Buddlejae Butterflybush extract 2 parts;Nano-silver ionic 4 parts, Luan Shu extract 2 parts.
Preparation method comprises the steps: 1) by the potato residues of corresponding parts by weight, add suitable quantity of water, pH value controls 8.5, carries out micronizing after stirring;2) thermal initiator of the potato residues processed through micronizing and corresponding parts by weight is loaded reactor, carry out autoclaving 50min;3) by through step 2) material that processed of high compressed steam add after the sodium bentonite of corresponding parts by weight stirs 8 minutes, add the defoamer of corresponding parts by weight, oxidant and auxiliary agent, pH value controls 8, and heating mixing high-speed stirred react 1.5h, and temperature controls at 45 DEG C;4) in the reactor, the antibacterial of corresponding parts by weight that will process through atomization, mixing adds the step 3 being in high-speed stirred) in gains;5) carbamide and the Borax of corresponding parts by weight, ultra violet lamp 45min while stirring are then added;6) stir, cooling, prepare target product.Target product outward appearance is milky thick liquid, and after testing, this product initial viscosity is 0.1Pa.s, reaches 8Pa.s, regain 7% after 30s.
Embodiment 4: a kind of pest-resistant adhesive of paper product, includes following components according to parts by weight and makes: potato residues 120 parts;Oxidant 4 parts;4 parts of carbamide;Thermal initiator 2 parts;Defoamer 2 parts;Borax 2 parts;Sodium bentonite 12 parts;Antibacterial 8 parts;Auxiliary agent 0.2 part.
Wherein auxiliary agent includes following components according to parts by weight and makes: medical stone powder 0.1 part;Toughener 0.1 part.
Described antibacterial includes following components according to parts by weight and makes: Parmelia tinctorum Despr. extract 3 parts;Radix Buddlejae Butterflybush extract 2 parts;Nano-silver ionic 2 parts, Luan Shu extract 1 part.
Preparation method comprises the steps: 1) by the potato residues of corresponding parts by weight, add suitable quantity of water, pH value controls 8, carries out micronizing after stirring;2) thermal initiator of the potato residues processed through micronizing and corresponding parts by weight is loaded reactor, carry out autoclaving 50min;3) by through step 2) material that processed of high compressed steam add after the sodium bentonite of corresponding parts by weight stirs 5 minutes, add the defoamer of corresponding parts by weight, oxidant and auxiliary agent, pH value controls 7.5, and heating mixing high-speed stirred react 1h, and temperature controls at 42 DEG C;4) in the reactor, the antibacterial of corresponding parts by weight that will process through atomization, mixing adds the step 3 being in high-speed stirred) in gains;5) carbamide and the Borax of corresponding parts by weight, ultra violet lamp 40min while stirring are then added;6) stir, cooling, prepare target product.Target product outward appearance is milky thick liquid, and after testing, this product initial viscosity is 0.08Pa.s, reaches 6Pa.s, regain 8% after 30s.
Embodiment 5: a kind of pest-resistant adhesive of paper product, includes following components according to parts by weight and makes: potato residues 140 parts;Oxidant 6 parts;6 parts of carbamide;Thermal initiator 3 parts;Defoamer 3 parts;Borax 3 parts;Sodium bentonite 18 parts;Antibacterial 16 parts;Auxiliary agent 0.4 part.
Wherein auxiliary agent includes following components according to parts by weight and makes: medical stone powder 0.2 part;Thickening agent 0.1 part;Toughener 0.1 part.
Described antibacterial includes following components according to parts by weight and makes: Parmelia tinctorum Despr. extract 5 parts;Radix Buddlejae Butterflybush extract 3 parts;Nano-silver ionic 5 parts, Luan Shu extract 3 parts.
Preparation method comprises the steps: 1) by the potato residues of corresponding parts by weight, add suitable quantity of water, pH value controls 9, carries out micronizing after stirring;2) thermal initiator of the potato residues processed through micronizing and corresponding parts by weight is loaded reactor, carry out autoclaving 55min;3) by through step 2) material that processed of high compressed steam add after the sodium bentonite of corresponding parts by weight stirs 8 minutes, add the defoamer of corresponding parts by weight, oxidant and auxiliary agent, pH value controls 8.5, and heating mixing high-speed stirred react 2h, and temperature controls at 48 DEG C;4) in the reactor, the antibacterial of corresponding parts by weight that will process through atomization, mixing adds the step 3 being in high-speed stirred) in gains;5) carbamide and the Borax of corresponding parts by weight, ultra violet lamp 50min while stirring are then added;6) stir, cooling, prepare target product.Target product outward appearance is milky thick liquid, and after testing, this product initial viscosity is 0.12Pa.s, reaches 6Pa.s, regain 8% after 30s.
More than implementing row and the present invention does not constitute restriction, relevant staff is in the scope not necessarily departing from the technology of the present invention thought, and what carry out various changes and modifications, and all falls within protection scope of the present invention.

Claims (6)

1. the pest-resistant adhesive of paper product, it is characterised in that include following components according to parts by weight and make: potato residues 100~150 parts;Oxidant 2~8 parts;2~8 parts of carbamide;Thermal initiator 1~4 part;Defoamer 1~4 part;Borax 1~4 part;Sodium bentonite 10~20 parts;Antibacterial 4~20 parts;Auxiliary agent 0.2~0.4 part.
2. the pest-resistant adhesive of paper product according to claim 1, it is characterised in that described auxiliary agent includes following components according to parts by weight and makes: thickening agent 0.1~0.2 part;Toughener 0.1~0.2 part.
3. the pest-resistant adhesive of paper product according to claim 1, it is characterised in that described auxiliary agent includes following components according to parts by weight and makes: medical stone powder 0.1~0.2 part;Toughener 0.1~0.2 part.
4. the pest-resistant adhesive of paper product according to claim 1, it is characterised in that described auxiliary agent includes following components according to parts by weight and makes: medical stone powder 0.1~0.2 part;Thickening agent 0.05~0.1 part;Toughener 0.05~0.1 part.
5. the pest-resistant adhesive of paper product according to claim 1, it is characterised in that described antibacterial includes following components according to parts by weight and makes: Parmelia tinctorum Despr. extract 1~6 part;Radix Buddlejae Butterflybush extract 1~4 part;Nano-silver ionic 1~6 part, Luan Shu extract 1~4 part.
6. the preparation method of pest-resistant adhesive of the paper product as described in Claims 1 to 5, it is characterised in that comprise the steps:
1) by the potato residues of corresponding parts by weight, adding suitable quantity of water, pH value controls 7.5~9.5, carries out micronizing after stirring;
2) thermal initiator of the potato residues processed through micronizing and corresponding parts by weight is loaded reactor, carry out autoclaving 45~60min;
3) by through step 2) material that processed of high compressed steam add after the sodium bentonite of corresponding parts by weight stirs 5~10 minutes, add the defoamer of corresponding parts by weight, oxidant and auxiliary agent, pH value controls 7~9, heating mixing high-speed stirred reaction 1~2h, temperature controls at 40~50 DEG C;
4) in the reactor, the antibacterial of corresponding parts by weight that will process through atomization, mixing adds the step 3 being in high-speed stirred) in gains;
5) carbamide and the Borax of corresponding parts by weight are then added, ultra violet lamp 0.5~1 hour while stirring;
6) stir, cooling, prepare target product.
CN201610340177.5A 2016-05-20 2016-05-20 Insect-resistant adhesive for paper products and preparing method of insect-resistant adhesive Pending CN105802542A (en)

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CN201610340177.5A CN105802542A (en) 2016-05-20 2016-05-20 Insect-resistant adhesive for paper products and preparing method of insect-resistant adhesive

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107217521A (en) * 2017-06-16 2017-09-29 江苏金沃机械有限公司 A kind of low ink paper sludge and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101643633A (en) * 2009-08-26 2010-02-10 江南大学 Method for preparing bond for corrugated board by using potato residue as raw material
CN102898966A (en) * 2011-07-25 2013-01-30 日东电工株式会社 Glue sheet and use thereof
CN103147544A (en) * 2012-12-02 2013-06-12 上海馨来建筑装饰设计有限公司 Environment-friendly sticking method of brick wall paper
CN104804669A (en) * 2015-05-18 2015-07-29 金凤善 Corrugated board mineral adhesive as well as preparation method and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101643633A (en) * 2009-08-26 2010-02-10 江南大学 Method for preparing bond for corrugated board by using potato residue as raw material
CN102898966A (en) * 2011-07-25 2013-01-30 日东电工株式会社 Glue sheet and use thereof
CN103147544A (en) * 2012-12-02 2013-06-12 上海馨来建筑装饰设计有限公司 Environment-friendly sticking method of brick wall paper
CN104804669A (en) * 2015-05-18 2015-07-29 金凤善 Corrugated board mineral adhesive as well as preparation method and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107217521A (en) * 2017-06-16 2017-09-29 江苏金沃机械有限公司 A kind of low ink paper sludge and preparation method thereof
CN107217521B (en) * 2017-06-16 2019-01-01 南京陶特思软件科技有限公司 A kind of low ink paper sludge and preparation method thereof

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Application publication date: 20160727