CN105802046A - Wearing-resistant antibacterial rubber plate and preparation method thereof - Google Patents
Wearing-resistant antibacterial rubber plate and preparation method thereof Download PDFInfo
- Publication number
- CN105802046A CN105802046A CN201610309892.2A CN201610309892A CN105802046A CN 105802046 A CN105802046 A CN 105802046A CN 201610309892 A CN201610309892 A CN 201610309892A CN 105802046 A CN105802046 A CN 105802046A
- Authority
- CN
- China
- Prior art keywords
- rubber
- wearing
- powder
- nano
- resistant antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a wearing-resistant antibacterial rubber plate and a preparation method thereof, and relates to the technical field of rubber plates. The wearing-resistant antibacterial rubber plate is mainly prepared from butadiene styrene rubber, waste rubber powder, kaolin, barium sulfate, lead oxide, nano-diamond, nano-carbon sol, pitch-based carbon fiber, silicon nitride micro powder, coco fatty acid diethanol amide, stearic acid, tricresyl phosphate, pentaerythritol oleate, 1,2-benzisothiazolon-3-ketone, rosin, N-(trichloromethyl sulfur) phthalimide, aromatic oil and the like. As the butadiene styrene rubber and the waste rubber powder are taken as main raw materials, the wearing-resistant antibacterial rubber plate is excellent in wearing resistance, thermal resistance and aging resistance, the production cost is lowered, and the solid waste pollution is reduced; due to addition of raw materials such as nano-carbon sol and nano-diamond, the wearing resistance of the rubber plate is improved; due to cooperation of N-(trichloromethyl sulfur) phthalimide and 1,2-benzisothiazolon-3-ketone, good antibacterial mold-proof properties can be achieved, and the produced rubber plate is excellent in comprehensive property and good in adaptability.
Description
Technical field
The present invention relates to rubber slab technical field, more specifically a kind of wear-resistant antibacterial rubber slab and preparation method thereof.
Background technology
(can contain the reinforcing material such as fabric, sheet metal) with rubber as material of main part, prepared through sulfuration have one
Determine the sheet products of thickness and larger area, be called for short offset plate.Rubber slab has higher hardness, and physical and mechanical properties is general, can be
Pressure is little, and temperature is to work in the air of 20 ° ~+140 DEG C.Rubber slab system or is extruded into through calender lamination molding by elastomeric compound
Type, with vulcanizing press sulfuration or makes with drum vulcanizer continuous vulcanization.Color and luster: black, Lycoperdon polymorphum Vitt, green, blue etc..Extensively
General for aspects such as industrial and mining establishment, traffic and transportation sector and house earth surfaces.As O-ring seal, rubber cushion, door and window strip of paper used for sealing and laying
Workbench and floor.
There is wearability in existing rubber slab and antibiotic property is poor, and along with the development of society, the performance of rubber slab is wanted by people
Asking more and more higher, existing rubber slab increasingly can not meet the requirement of people.
Summary of the invention
The invention aims to make up the deficiencies in the prior art, it is provided that a kind of wear-resistant antibacterial rubber slab and preparation side thereof
Method.
It is an object of the invention to be achieved through the following technical solutions:
A kind of wear-resistant antibacterial rubber slab, is made up of following raw material: butadiene-styrene rubber 60-70, waste rubber powder 15-25, height
Ridge soil 6-8, barium sulfate 3-5, lead oxide 1-3, Nano diamond 4-6, nano carbon sol 3-5, asphalt base carbon fiber 2-4, nitridation
Silicon powder 3-5, lauric acid amide of ethanol 0.6-0.8, stearic acid 1-2, tricresyl phosphate 3-5, PETO 1-
3,1,2-benzisothiazole-3-ketone 3-5, Colophonium 3-5, N-(trichloromethyl sulfur) phthalimide 4-6, aromatic naphtha 5-7.
The preparation method of a kind of wear-resistant antibacterial rubber slab, comprises the following steps:
(1) lauric acid amide of ethanol is joined in 22-24 times of deionized water, be stirring evenly and then adding into stearic acid, nanometer gold
Hard rock, standby after magnetic agitation 4-6 minute；
(2) grind uniformly after waste rubber powder, Kaolin, asphalt base carbon fiber, silicon nitride powder mixing, add tricresyl phosphate
Toluene ester, aromatic naphtha, in 95-105 DEG C, stir under 1200-1400r/min 6-8 minute, then instill melted Colophonium also rapidly
Stir 12-14 minute under similarity condition, add barium sulfate and preserve 5-7 hour under 75-85, cooling, filter, 105-115
It is ground to 100-200 mesh after DEG C being dried completely, obtains powder body standby；
(3) by butadiene-styrene rubber, N-(trichloromethyl sulfur) phthalimide in 90-100 DEG C mix 1 hour, be subsequently adding season
Penta tetrol oleate, stirs 1-3 hour at 55-65 DEG C, standby；
(4) gained raw material mixing in step (1), step (2) and step (3) is added in reactor mixed prior to 105-115 DEG C
Close 12-14 minute, be subsequently adding remaining raw material, mix 1-2 hour at 80-90 DEG C, finally use double screw extruder 220-240
DEG C extrusion, after last mould machine-shaping and get final product.
It is an advantage of the current invention that:
The rubber slab of the present invention uses butadiene-styrene rubber and waste rubber powder to be primary raw material, has outstanding wearability, thermostability
And resistance to ag(e)ing, and saved production cost, and decreasing solid waste pollution, nano carbon sol, Nano diamond etc. are original
Interpolation, enhance the anti-wear performance of rubber slab, N-(trichloromethyl sulfur) phthalimide, 1,2-benzisothiazole-
Both 3-ketone coordinates, and antibacterial and mouldproof performance is good, and the rubber slab excellent combination property produced, the suitability is strong.
Detailed description of the invention
Embodiment 1, a kind of wear-resistant antibacterial rubber slab, it is made up of following weight portion (kg) raw material: butadiene-styrene rubber 60, waste and old rubber
Rubber powder 15, Kaolin 6, barium sulfate 3, lead oxide 1, Nano diamond 4, nano carbon sol 3, asphalt base carbon fiber 2, silicon nitride are micro-
Powder 3, lauric acid amide of ethanol 0.6, stearic acid 1, tricresyl phosphate 3, PETO 1,1,2-benzisothiazole
Quinoline-3-ketone 3, Colophonium 3, N-(trichloromethyl sulfur) phthalimide 4, aromatic naphtha 5.
The preparation method of a kind of wear-resistant antibacterial rubber slab, comprises the following steps:
(1) lauric acid amide of ethanol is joined in 22 times of deionized waters, be stirring evenly and then adding into stearic acid, nanometer Buddha's warrior attendant
Stone, magnetic agitation is standby after 4 minutes；
(2) grind uniformly after waste rubber powder, Kaolin, asphalt base carbon fiber, silicon nitride powder mixing, add tricresyl phosphate
Toluene ester, aromatic naphtha, in 95 DEG C, stir under 1200r/min 6 minutes, then instill rapidly melted Colophonium and in similarity condition
Lower stirring 12 minutes, adds barium sulfate and preserves 5 hours in 75 times, and cooling is filtered, 105 DEG C be dried completely after be ground to 100
Mesh, obtains powder body standby；
(3) by butadiene-styrene rubber, N-(trichloromethyl sulfur) phthalimide in 90 DEG C mix 1 hour, be subsequently adding Ji Wusi
Alcohol oleate, stirs 1 hour at 55 DEG C, standby；
(4) gained raw material mixing in step (1), step (2) and step (3) is added in reactor prior to 105 DEG C of mixing 12
Minute, it is subsequently adding remaining raw material, mixes at 80 DEG C 1 hour, finally by double screw extruder 220 DEG C extrusion, last mould
After machine-shaping and get final product.
2 one kinds of wear-resistant antibacterial rubber slabs of embodiment, are made up of following weight portion (kg) raw material: butadiene-styrene rubber 65, waste and old rubber
Rubber powder 20, Kaolin 7, barium sulfate 4, lead oxide 2, Nano diamond 5, nano carbon sol 4, asphalt base carbon fiber 3, silicon nitride are micro-
Powder 4, lauric acid amide of ethanol 0.7, stearic acid 1, tricresyl phosphate 4, PETO 2,1,2-benzisothiazole
Quinoline-3-ketone 4, Colophonium 4, N-(trichloromethyl sulfur) phthalimide 5, aromatic naphtha 6.
The preparation method of a kind of wear-resistant antibacterial rubber slab, comprises the following steps:
(1) lauric acid amide of ethanol is joined in 23 times of deionized waters, be stirring evenly and then adding into stearic acid, nanometer Buddha's warrior attendant
Stone, magnetic agitation is standby after 5 minutes；
(2) grind uniformly after waste rubber powder, Kaolin, asphalt base carbon fiber, silicon nitride powder mixing, add tricresyl phosphate
Toluene ester, aromatic naphtha, in 100 DEG C, stir under 1300r/min 7 minutes, then instill rapidly melted Colophonium and in similarity condition
Lower stirring 13 minutes, adds barium sulfate and preserves 6 hours in 80 times, and cooling is filtered, 110 DEG C be dried completely after be ground to 100
Mesh, obtains powder body standby；
(3) by butadiene-styrene rubber, N-(trichloromethyl sulfur) phthalimide in 95 DEG C mix 1 hour, be subsequently adding Ji Wusi
Alcohol oleate, stirs 2 hours at 60 DEG C, standby；
(4) gained raw material mixing in step (1), step (2) and step (3) is added in reactor prior to 110 DEG C of mixing 13
Minute, it is subsequently adding remaining raw material, mixes at 85 DEG C 1.5 hours, finally by double screw extruder 230 DEG C extrusion, rear mold
Tool machine-shaping after and get final product.
Embodiment 3, a kind of wear-resistant antibacterial rubber slab, it is made up of following weight portion (kg) raw material: butadiene-styrene rubber 70, waste and old rubber
Rubber powder 25, Kaolin 8, barium sulfate 5, lead oxide 3, Nano diamond 6, nano carbon sol 5, asphalt base carbon fiber 4, silicon nitride are micro-
Powder 5, lauric acid amide of ethanol 0.8, stearic acid 2, tricresyl phosphate 5, PETO 3,1,2-benzisothiazole
Quinoline-3-ketone 5, Colophonium 5, N-(trichloromethyl sulfur) phthalimide 6, aromatic naphtha 7.
The preparation method of a kind of wear-resistant antibacterial rubber slab, comprises the following steps:
(1) lauric acid amide of ethanol is joined in 24 times of deionized waters, be stirring evenly and then adding into stearic acid, nanometer Buddha's warrior attendant
Stone, magnetic agitation is standby after 6 minutes；
(2) grind uniformly after waste rubber powder, Kaolin, asphalt base carbon fiber, silicon nitride powder mixing, add tricresyl phosphate
Toluene ester, aromatic naphtha, in 105 DEG C, stir under 1400r/min 8 minutes, then instill rapidly melted Colophonium and in similarity condition
Lower stirring 14 minutes, adds barium sulfate and preserves 7 hours in 85 times, and cooling is filtered, 115 DEG C be dried completely after be ground to 200
Mesh, obtains powder body standby；
(3) by butadiene-styrene rubber, N-(trichloromethyl sulfur) phthalimide in 100 DEG C mix 1 hour, be subsequently adding Ji Wusi
Alcohol oleate, stirs 3 hours at 65 DEG C, standby；
(4) gained raw material mixing in step (1), step (2) and step (3) is added in reactor prior to 115 DEG C of mixing 14
Minute, it is subsequently adding remaining raw material, mixes at 90 DEG C 2 hours, finally by double screw extruder 240 DEG C extrusion, last mould
After machine-shaping and get final product.
The main performance testing result of the wear-resistant antibacterial rubber slab that above-described embodiment 1-3 prepares is as shown in the table:
The main performance testing result of the wear-resistant antibacterial rubber slab that table 1 embodiment 1-3 prepares
| Tearing strength N/mm >= | Tensile strength MPa >= | Heat-resisting quantity DEG C | Acid resistance | Wear volume (cm3) | Bacteriostasis rate (%) | |
| Embodiment 1 | 53 | 18 | 265 | By force | 0.24 | 98.8 |
| Embodiment 2 | 53 | 21 | 268 | By force | 0.27 | 99.4 |
| Embodiment 3 | 53 | 20 | 266 | By force | 0.25 | 99.1 |
Claims (2)
1. a wear-resistant antibacterial rubber slab, it is characterised in that: it is made up of following raw material: butadiene-styrene rubber 60-70, waste and old rubber
Rubber powder 15-25, Kaolin 6-8, barium sulfate 3-5, lead oxide 1-3, Nano diamond 4-6, nano carbon sol 3-5, pitch base carbon
Fiber 2-4, silicon nitride powder 3-5, lauric acid amide of ethanol 0.6-0.8, stearic acid 1-2, tricresyl phosphate 3-5, season penta
Tetrol oleate 1-3,1,2-benzisothiazole-3-ketone 3-5, Colophonium 3-5, N-(trichloromethyl sulfur) phthalimide 4-
6, aromatic naphtha 5-7.
A kind of wear-resistant antibacterial rubber slab the most according to claim 1 and preparation method thereof, it is characterised in that: include following step
Rapid:
(1) lauric acid amide of ethanol is joined in 22-24 times of deionized water, be stirring evenly and then adding into stearic acid, nanometer gold
Hard rock, standby after magnetic agitation 4-6 minute；
(2) grind uniformly after waste rubber powder, Kaolin, asphalt base carbon fiber, silicon nitride powder mixing, add tricresyl phosphate
Toluene ester, aromatic naphtha, in 95-105 DEG C, stir under 1200-1400r/min 6-8 minute, then instill melted Colophonium also rapidly
Stir 12-14 minute under similarity condition, add barium sulfate and preserve 5-7 hour under 75-85, cooling, filter, 105-115
It is ground to 100-200 mesh after DEG C being dried completely, obtains powder body standby；
(3) by butadiene-styrene rubber, N-(trichloromethyl sulfur) phthalimide in 90-100 DEG C mix 1 hour, be subsequently adding season
Penta tetrol oleate, stirs 1-3 hour at 55-65 DEG C, standby；
(4) gained raw material mixing in step (1), step (2) and step (3) is added in reactor mixed prior to 105-115 DEG C
Close 12-14 minute, be subsequently adding remaining raw material, mix 1-2 hour at 80-90 DEG C, finally use double screw extruder 220-240
DEG C extrusion, after last mould machine-shaping and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610309892.2A CN105802046A (en) | 2016-05-11 | 2016-05-11 | Wearing-resistant antibacterial rubber plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610309892.2A CN105802046A (en) | 2016-05-11 | 2016-05-11 | Wearing-resistant antibacterial rubber plate and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105802046A true CN105802046A (en) | 2016-07-27 |
Family
ID=56456833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610309892.2A Pending CN105802046A (en) | 2016-05-11 | 2016-05-11 | Wearing-resistant antibacterial rubber plate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105802046A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106496701A (en) * | 2016-12-20 | 2017-03-15 | 佛山市高明区塑料行业协会 | A kind of modified abrasion resistant high impact-resistant butadiene-styrene rubber |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509210A (en) * | 2013-07-17 | 2014-01-15 | 铜陵市肆得科技有限责任公司 | Wear-resistant drilling pump valve sealing gasket and its preparation method |
| CN104530586A (en) * | 2014-11-11 | 2015-04-22 | 合肥不老传奇保健科技有限公司 | High-wear-resistant antistatic plastic-steel section for doors and windows and preparation method thereof |
| CN104829892A (en) * | 2015-05-22 | 2015-08-12 | 罗满清 | High-wear-resistance rubber material for shoe soles and preparation method thereof |
| CN104961943A (en) * | 2015-07-14 | 2015-10-07 | 常州市盈顺电子有限公司 | High-strength wear-resistance rubber plate and preparation method thereof |
-
2016
- 2016-05-11 CN CN201610309892.2A patent/CN105802046A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509210A (en) * | 2013-07-17 | 2014-01-15 | 铜陵市肆得科技有限责任公司 | Wear-resistant drilling pump valve sealing gasket and its preparation method |
| CN104530586A (en) * | 2014-11-11 | 2015-04-22 | 合肥不老传奇保健科技有限公司 | High-wear-resistant antistatic plastic-steel section for doors and windows and preparation method thereof |
| CN104829892A (en) * | 2015-05-22 | 2015-08-12 | 罗满清 | High-wear-resistance rubber material for shoe soles and preparation method thereof |
| CN104961943A (en) * | 2015-07-14 | 2015-10-07 | 常州市盈顺电子有限公司 | High-strength wear-resistance rubber plate and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 安秋凤 等: "《橡塑加工助剂》", 30 September 2004, 化学工业出版社 化学与应用化学出版中心 * |
| 张锡秋 等: "《高岭土》", 31 October 1988, 轻工业出版社 * |
| 欧育湘 等: "《塑料助剂性能与选用速查手册》", 31 January 2012, 国防工业出版社 * |
| 范仁德 编: "《废橡胶的综合利用技术》", 31 December 1989, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106496701A (en) * | 2016-12-20 | 2017-03-15 | 佛山市高明区塑料行业协会 | A kind of modified abrasion resistant high impact-resistant butadiene-styrene rubber |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104194079B (en) | A kind of Composite Material Seal Ring and manufacture craft thereof | |
| CN100348656C (en) | Super strong acid resistant rubber material and its preparation method | |
| CN107311505B (en) | A kind of composite material of modified industry inorganic powder and the inorganic powder containing modified industry | |
| CN105646959B (en) | A kind of rubber composition, preparation method and its application in 3D printing air core tyre | |
| KR100764917B1 (en) | An aspalt modifier comprising polyethylene and waste polypropylene and method for preparing the same | |
| CN102585390B (en) | Formula and preparation technology of CPE (Chlorinated Polyethylene) rubber waterstop | |
| CN103467861A (en) | Preparation method of automobile corner window sealing material | |
| CN107298865B (en) | Composite pyrolytic carbon black modifier and composite modified asphalt mixture | |
| CN103938513A (en) | Construction process of colored pavement epoxy non-slip wearing layer structure | |
| US20100308495A1 (en) | Process for the manufacture of reactive rubber process aids | |
| CN107880329A (en) | A kind of automobile rubber diaphragm material and preparation method thereof | |
| ZA200906475B (en) | Rubber | |
| CN105802046A (en) | Wearing-resistant antibacterial rubber plate and preparation method thereof | |
| CN111040322A (en) | Airtight layer adhesive and preparation method thereof | |
| CN104194087A (en) | Fraction lining for mine hoist and preparation method of fraction lining | |
| CN103467801B (en) | One is haled and is stretched wear-resistant conveyor belt rubber cover and preparation method thereof | |
| CN103450568B (en) | A kind of REPDM/RIIR elastomerics and preparation method thereof | |
| RU2353603C1 (en) | Raw material mixture for light concrete production | |
| CN104927121A (en) | Sizing material for super-wearproof semisteel car tyres and preparation method of sizing material | |
| KR101717707B1 (en) | A Manufacturing method of recycled ascon comprising high molecular polymer | |
| CN105885129B (en) | Wear-resistant sand-blasting sizing material | |
| CN108102182A (en) | A kind of rubber slab and preparation method thereof | |
| CN107057133A (en) | A kind of fiber reinforced graphite rubber plate and its preparation technology | |
| CN106147233A (en) | A kind of antibacterial rubber plate and preparation method thereof | |
| CN103171065A (en) | Mould releasing glue for mould and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160727 |