CN105801895A - PVC hand-touch film and preparing method thereof - Google Patents
PVC hand-touch film and preparing method thereof Download PDFInfo
- Publication number
- CN105801895A CN105801895A CN201610231944.9A CN201610231944A CN105801895A CN 105801895 A CN105801895 A CN 105801895A CN 201610231944 A CN201610231944 A CN 201610231944A CN 105801895 A CN105801895 A CN 105801895A
- Authority
- CN
- China
- Prior art keywords
- pvc
- film
- coating
- parts
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2433/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to the field of preparing functional PVC films and discloses a PVC hand-touch film and a preparing method thereof.A functional coating is printed on the surface of a PCV film body in the PVC hand-touch film in a coating mode, wherein the thickness of the functional coating ranges from 1.5 micrometers to 2 micrometers, and the functional coating is prepared from, by weight, 45-55 parts of polyurethane, 25-35 parts of polymethyl methacrylate, 3-7 parts of aziridine and 15-25 parts of silicon dioxide.The preparing method of the PVC hand-touch film comprises the following steps that firstly, coating paint is blended; secondly, preheating is carried out, wherein a PVC face film is preheated at 50-70 DEG C; thirdly, printing and coating are carried out, the preheated PVC face film is fed into a printing machine to spread the coating; fourthly, drying and cooling are carried out, wherein the film prepared through the third step is dried at 50-55 DEG C, cooled and then rolled into a finished product.The PVC hand-touch film and the preparing method thereof are simple in process, easy to implement, low in cost and good in effect.
Description
Technical field
The present invention relates to the preparation field of functional PVC film, particularly relate to a kind of PVC feel film and preparation method thereof.
Background technology
Along with the development of thin film technique, market occurs the multiple protecting film for being attached to various material surface, for surface protection,
Material aging be can effectively prevent, materials'use quality and service life extended.Polrvinyl chloride (PVC) is as yield in the world
Big general-purpose plastics, also becomes the pioneer of improvement in functionality research.
Having a lot of functional PVC film at present, most preparation method is to join in polyvinyl chloride resin by functional additive,
Prepare film forming after Gong Huning, Chinese patent CN103029311A " a kind of semi-rigid PVC decorative diaphragm " discloses a kind of for pasting
In the formula of the semi-rigid PVC film with high flame retardant and mildew resistance and the preparation method of glass surface, add in polyvinyl chloride resin
Added processing aid at least 7, sequentially pass through stirring, banburying, mill, Screw Extrusion, four rollers prolong pressure, traction, embossing,
Cooling and the technique such as rolling prepare film forming, but this type of method complex process, and formula fixes, and required auxiliary agent kind is more, cost
Higher.
And print coating, because its technique is simple to operation, gradually favored by vast researcher.But, it is used mostly at present
Printing coating, it mostly is at PVC film surface-coated adhesive etc., for fitting with other films or material.Chinese patent
CN1636705A " environment protecting energy-accumulating luminous decoration cloth " discloses one and in substrate surface spraying or prints adhesive, and at glue
Paste release paper in glutinous agent or spray at substrate surface, print or instillation luminescent material gluing layer, and on luminescent material gluing layer
The method of instillation polyester resin.Chinese patent CN102615902A " manufacture method that a kind of PVC composite sand is issued " discloses one
Form ink printing process layer by being printed on PVC film surface-coated cloudy surface agent and bright agent, conveniently enter on PVC film surface
Row intaglio printing, but the character of PVC film is not had any lifting and change.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of technique is simple to operation, low cost, effective PVC feel film and
Its preparation method.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that
PVC feel film of the present invention, including PVC film and functional coat, described PVC film surface printing is coated with functional painting
Layer, functional coat thickness is 1.5-2 μm, and functional coat composition includes following components (parts by weight): polyurethane 45-55
Part, polymethyl methacrylate 25-35 part, aziridine 3-7 part, silica 1 5-25 part.
PVC feel film of the present invention, further, described functional coat composition includes following components (parts by weight): poly-ammonia
Ester 50 parts, polymethyl methacrylate 30 parts, aziridine 5 parts, silicon dioxide 20 parts.
The preparation method of PVC feel film of the present invention, comprises the following steps:
(1) allotment coated coating: carry out dispensing, polyurethane 45-55 part, polymethyl methacrylate 25-35 according to following parts by weight
Part, aziridine 3-7 part, silica 1 5-25 part；
(2) preheating: PVC facial film is preheated at 50-70 DEG C；
(3) printing coating: the PVC facial film of preheating is sent into printer and carries out coating coating；
(4) Drying and cooling: film step (3) prepared is through 50-55 DEG C of drying, rolling after cooling finished product.
The preparation method of PVC feel film of the present invention, further, step (1) floating coat paint prepare in accordance with the following methods and
Become: polyurethane, polymethyl methacrylate, aziridine are separately added in ethyl ester or butyl ester, stirring and dissolving.
The preparation method of PVC feel film of the present invention, further, the coated coating viscosity that step (1) is allocated is 15-18s/4
# examines grace cup.
The preparation method of PVC feel film of the present invention, further, in step (2), PVC film uses pre-hot-rolling to preheat,
The preheating temperature in summer is 50-53 DEG C, and the preheating temperature in winter is 60-70 DEG C.
The preparation method of PVC feel film of the present invention, further, the scraper angle on step (3) printer is set to 45 °.
The preparation method of PVC feel film of the present invention, further, the pressure of printing compacting rubber roll on printer in step (3)
For 3-6N.
PVC feel film of the present invention and preparation method thereof compared with prior art, has the advantages that
The preparation method of PVC feel film of the present invention is through substantial amounts of experiment and screening, with simplest raw material, and most suitable material,
By the way of printing, functional coating is coated on the surface of PVC film, by regulation process conditions, makes the Function of coating
To at utmost.The consumption of the functional coat coating needed for the inventive method is less, coating used by the PVC film of every square metre
Consumption is only 6.8-7.4g, greatly reduces production cost.The functional coat thickness of PVC feel film of the present invention is 1.5-2 μm,
Its pencil hardness is at more than HB, and hardness has obtained pole and significantly promoted, and the performance such as glossiness and surface matte degree has simultaneously
Bigger lifting, glossiness test is 2.5-3.0GU, and surface matte degree is 0.406-0.448, and the surface that can be effectively improved material is touched
Sense, hands touches soft pro-skin, has stronger hardness simultaneously, improve the glossiness of material, protect material color, extends material
Service life, expand the use environmental field of building material.
Functional coat coating composition composition needed for the PVC feel film that the inventive method prepares is simple, and PVC film to be made reaches
To identical surface effect, the kind of the functional aid added and quantity is needed to be far above this in PVC granule resin raw material
Bright method, and technique very complicated be difficult to operation, relatively costly.The inventive method preparation technology simple and flexible, it is adaptable to advise greatly
Mould produces, and can be used for protecting material itself by plastic uptake technique for imitation wood, the surface of imitative bag building materials, improve making of material
Use the life-span.
Detailed description of the invention
Preparation embodiment
The preparation method of PVC feel film of the present invention comprises the following steps:
(1) allotment coated coating: carry out dispensing according to parts by weight shown in table 1, each component is separately added in ethyl ester or butyl ester, stirs
Mix dissolving；The coated coating viscosity of allotment is that 15-18s/4# examines grace cup；
(2) preheating: being preheated by the PVC facial film pre-hot-rolling of use, the preheating temperature in summer is 50-53 DEG C, the preheating temperature in winter
For 60-70 DEG C；
(3) printing coating: the PVC facial film of preheating being sent into printer and carries out coating coating, the scraper angle on printer is set to
45 °, the pressure of printing compacting rubber roll is 3-6N；
(4) Drying and cooling: film step (3) prepared is through 50-55 DEG C of drying, rolling after cooling finished product.
Embodiment coated coating component prepared by table 1
| Preparation example 1 | Preparation example 2 | Preparation example 3 | Preparation example 4 | Preparation example 5 | |
| Polyurethane | 50 | 55 | 48 | 45 | 53 |
| Polymethyl methacrylate | 30 | 25 | 33 | 27 | 35 |
| Aziridine | 5 | 4 | 3 | 7 | 6 |
| Silicon dioxide | 20 | 25 | 15 | 17 | 23 |
The functional coat thickness of the PVC feel film that above-mentioned preparation embodiment prepares is 1.5-2 μm, and it is carried out pencil hardness survey
Examination, test result display pencil hardness is at more than HB, and the pencil hardness of general PVC film is at below 2B, and the present invention is resistance to
The hardness drawing PVC film has obtained pole and has significantly promoted, and the performance such as glossiness and surface matte degree has had bigger lifting simultaneously,
Substantially improve the surface tactile sensation of film, and preparation technology simple and flexible, it is adaptable to large-scale production, can be used for by plastic uptake technique
Imitation wood, the surface of imitative bag building materials, be used for protecting material itself, improve the service life of material.
Testing example
Use the glossiness of vancometer test PVC feel film, in accordance with method in GB/T8807-1988, it is stipulated that incident angle is
20.0 ± 0.1 °, testing the glossiness of all kinds of PVC film, measurement result is as shown in table 2.
According to Chinese patent CN102779770B " detection method of solar cell surface suede structure ", use described in it
Measuring method, α takes 90 °, and β takes 45 °, under d 65 illuminant, replaces solar panel with the PVC film that need to measure,
Measuring and be calculated the R value of all kinds of PVC film, R value is the surface matte degree of this product, through as shown in table 2.
Embodiment performance test results prepared by table 2
| Preparation example 1 | Preparation example 2 | Preparation example 3 | Preparation example 4 | Preparation example 5 | |
| Glossiness (GU) | 3.0 | 2.8 | 2.9 | 2.7 | 2.5 |
| R | 0.406 | 0.429 | 0.412 | 0.435 | 0.448 |
Visible, the surface gloss of the PVC feel film that the present invention prepares is between 2.5-3.0, and R value is at 0.406-0.448
Between.Measure according to existing film product accounting that the inventive method is prepared, the film product average R value prepared up to
0.400, therefore the calibration value of the R value being film product with 0.400, the R value measured when the PVC feel film produced is higher than 0.400
Time, it is believed that meet factory calibration.
Comparative example
With above-mentioned preparation embodiment 1 as experimental group, arranging 3 groups of matched groups, comparison 1 is according in above-mentioned preparation embodiment 1
The formula of functional coat coating, adds in 100 parts of (parts by weight) polyvinyl chloride resin pellets, according to PVC by each component
The film that the production technology of facial film raw material prepares, comparison 2 is for randomly selecting what commercially available Ningbo Ke Qida plastic cement Science and Technology Ltd. produced
The soft PVC film of EN71 environmental protection, comparison 3 is the PVC facial film raw material coated without any coating, often 5 Duplicate Samples of group
Product, according to method described in above-mentioned testing example, detect, and the contrast of gained test result is as shown in table 3.
Table 3 comparative example's test result contrasts
| Preparation example 1 | Comparison 1 | Comparison 2 | Comparison 3 | |
| Glossiness (GU) | 3.0 | 6.8 | 4.2 | 7.6 |
| R | 0.406 | 0.291 | 0.354 | 0.274 |
As shown in Table 3, the glossiness of PVC feel film of the present invention is and the 2.5 of the PVC facial film raw material coated without any coating
Times, and the functional additive of coating shown in the present invention is joined in polyvinyl chloride resin granule, carry out traditional functional PVC
Film preparation, the film product glossiness obtained is more or less the same with PVC facial film raw material, and the light of the commercially available soft feel film randomly selected
Pool degree is 4.2, and PVC feel film the most of the present invention differs about 1.2GU.The PVC feel film that the present invention prepares has preferable gloss
Degree.
Measuring the film of matched group according to said method, the R value obtained is as shown in table 3, the PVC coated without any coating
Facial film is with that functional additive is directly added into the film R value prepared in polyvinyl chloride resin is close, and the most relatively present invention prepares embodiment
The R value of 1 gained PVC feel film is low by about 30%, and the R value of the PVC feel film that the present invention prepares exceeds commercially available common softness
Feel film about 13%.Fusion that film wants to reach excellent, coordination and functional is prepared with the preparation method of conventional functionality film,
Must be added to more functional additive and regulator, increase cost, formula is complicated, and loaded down with trivial details being difficult to of technical process operates.
The PVC feel film that the present invention prepares has preferable surface matte degree, substantially increases the sense of touch of film so that it is softer, close
Skin.
Functional coat coating, with simplest raw material, most suitable material, is coated to PVC with the method for printing by the inventive method
Facial film surface, by regulation process conditions, makes the Function of coating at utmost, reduces production cost, simplify and produce work
Skill, improves the glossiness of PVC film, reduces surface matte degree.
Embodiment described above is only to be described the preferred embodiment of the present invention, not carries out the scope of the present invention
Limiting, on the premise of designing spirit without departing from the present invention, technical scheme is made by those of ordinary skill in the art
Various deformation and improvement, all should fall in the protection domain that claims of the present invention determines.
Claims (8)
1.PVC feel film, it is characterised in that: include that PVC film and functional coat, described PVC film surface printing are coated with
Functional coat, functional coat thickness is 1.5-2 μm, and functional coat composition includes following components (parts by weight): poly-ammonia
Ester 45-55 part, polymethyl methacrylate 25-35 part, aziridine 3-7 part, silica 1 5-25 part.
PVC feel film the most according to claim 1, it is characterised in that: described functional coat composition includes following group
Divide (parts by weight): polyurethane 50 parts, polymethyl methacrylate 30 parts, aziridine 5 parts, silicon dioxide 20 parts.
3. the method for preparation PVC feel film described in claim 1, it is characterised in that: comprise the following steps:
(1) allotment coated coating: carry out dispensing, polyurethane 45-55 part, polymethyl methacrylate 25-35 according to following parts by weight
Part, aziridine 3-7 part, silica 1 5-25 part；
(2) preheating: PVC facial film is preheated at 50-70 DEG C；
(3) printing coating: the PVC facial film of preheating is sent into printer and carries out coating coating；
(4) Drying and cooling: film step (3) prepared is through 50-55 DEG C of drying, rolling after cooling finished product.
The preparation method of PVC feel film the most according to claim 3, it is characterised in that: step (1) floating coat paint
It is prepared from accordance with the following methods: polyurethane, polymethyl methacrylate, aziridine are separately added in ethyl ester or butyl ester, stir
Mix dissolving.
The preparation method of PVC feel film the most according to claim 3, it is characterised in that: the coating that step (1) is allocated
Dope viscosity is that 15-18s/4# examines grace cup.
The preparation method of PVC feel film the most according to claim 3, it is characterised in that: PVC film in step (2)
Using pre-hot-rolling to preheat, the preheating temperature in summer is 50-53 DEG C, and the preheating temperature in winter is 60-70 DEG C.
The preparation method of PVC feel film the most according to claim 3, it is characterised in that: on step (3) printer
Scraper angle is set to 45 °.
The preparation method of PVC feel film the most according to claim 3, it is characterised in that: in step (3) on printer
The pressure of printing compacting rubber roll is 3-6N.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610231944.9A CN105801895A (en) | 2016-04-14 | 2016-04-14 | PVC hand-touch film and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610231944.9A CN105801895A (en) | 2016-04-14 | 2016-04-14 | PVC hand-touch film and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105801895A true CN105801895A (en) | 2016-07-27 |
Family
ID=56460176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610231944.9A Pending CN105801895A (en) | 2016-04-14 | 2016-04-14 | PVC hand-touch film and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105801895A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106978055A (en) * | 2017-05-12 | 2017-07-25 | 佛山市天进塑胶有限公司 | A kind of surface conditioning agent for lifting PVC decorative Film wearability |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101074343A (en) * | 2006-05-15 | 2007-11-21 | 北京高盟化工有限公司 | Finishing agent of PVC gloves |
| CN102702953A (en) * | 2012-07-03 | 2012-10-03 | 佛山市天进塑胶有限公司 | PVC (polyvinyl chloride) decorative film surface treating agent, PVC decorative film treated with same and preparation method thereof |
| CN103103790A (en) * | 2013-01-24 | 2013-05-15 | 陕西科技大学 | Aqueous treating agent applied to surface treatment of PVC (Polyvinyl Chloride) artificial leather, and preparation method of aqueous treating agent |
| CN103194105A (en) * | 2013-03-27 | 2013-07-10 | 佛山市天进塑胶有限公司 | UV (Ultraviolet) gloss oil, high-gloss scrap-resisting decorative film prepared from same and preparation method of decorative film |
| CN104231901A (en) * | 2014-10-11 | 2014-12-24 | 江苏华夏制漆科技有限公司 | Water-based elastic rubber paint and preparation method thereof |
| CN104479530A (en) * | 2014-12-05 | 2015-04-01 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Back paint for lightweight PVC and preparation method thereof |
-
2016
- 2016-04-14 CN CN201610231944.9A patent/CN105801895A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101074343A (en) * | 2006-05-15 | 2007-11-21 | 北京高盟化工有限公司 | Finishing agent of PVC gloves |
| CN102702953A (en) * | 2012-07-03 | 2012-10-03 | 佛山市天进塑胶有限公司 | PVC (polyvinyl chloride) decorative film surface treating agent, PVC decorative film treated with same and preparation method thereof |
| CN103103790A (en) * | 2013-01-24 | 2013-05-15 | 陕西科技大学 | Aqueous treating agent applied to surface treatment of PVC (Polyvinyl Chloride) artificial leather, and preparation method of aqueous treating agent |
| CN103194105A (en) * | 2013-03-27 | 2013-07-10 | 佛山市天进塑胶有限公司 | UV (Ultraviolet) gloss oil, high-gloss scrap-resisting decorative film prepared from same and preparation method of decorative film |
| CN104231901A (en) * | 2014-10-11 | 2014-12-24 | 江苏华夏制漆科技有限公司 | Water-based elastic rubber paint and preparation method thereof |
| CN104479530A (en) * | 2014-12-05 | 2015-04-01 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Back paint for lightweight PVC and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 方少明，冯钠主编: "《高分子材料成型工程》", 30 June 2014 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106978055A (en) * | 2017-05-12 | 2017-07-25 | 佛山市天进塑胶有限公司 | A kind of surface conditioning agent for lifting PVC decorative Film wearability |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104968499B (en) | graphic article | |
| CN103717396B (en) | Graphic article | |
| CN110104960B (en) | Environment-friendly decorative glass and preparation method thereof | |
| EP2739484A2 (en) | Graphic article | |
| CN110408250B (en) | Preparation method of polymer composite film | |
| CN103732417A (en) | Graphic article | |
| CN105799282B (en) | A kind of part imitates the preparation method of mirror metal laminated film | |
| CN110408249B (en) | Preparation method of polymer composite film | |
| CN104530930A (en) | Orange-peel coating | |
| CN106479262A (en) | IMR dumb light ink and its preparation and application | |
| CN103316830A (en) | Coating process on impregnated and presseure-adheriing laminate flooring | |
| CN104908380A (en) | Transfer decoration film | |
| CN107151516A (en) | A kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity | |
| CN108908544A (en) | A kind of ultra-wide high abrasion can plastic uptake, coat environmentally friendly wood skin preparation method | |
| CN105801895A (en) | PVC hand-touch film and preparing method thereof | |
| CN105970735A (en) | Varnishing process of specially shaped paper printed matter | |
| KR100968698B1 (en) | Superior Scratchproof and Pollutionproof Surface Treatment and PVC Decoration Sheet Coated with Thereof | |
| CN105820727A (en) | Scratch-resistant PVC film and preparation method thereof | |
| CN105694083A (en) | Weather-resistant PVC(polyvinyl chloride) film and manufacturing method thereof | |
| CN103305098A (en) | Water boiling-resistant UV (ultraviolet) high-adhesion primer on impregnated laminate flooring | |
| JP5915307B2 (en) | Decorative sheet and decorative resin molded product | |
| JP5915306B2 (en) | Decorative sheet and decorative resin molded product | |
| CN110157250B (en) | Water-based low-temperature hot mounting coating and preparation method thereof | |
| CN1274741C (en) | Method for preparing plastic decorative plates | |
| KR101056908B1 (en) | FBC decorative sheet using surface treatment agent with excellent stain and scratch resistance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160727 |