CN105800596A - Charging method of high-yield high-efficiency novel graphitizing furnace - Google Patents

Charging method of high-yield high-efficiency novel graphitizing furnace Download PDF

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CN105800596A
CN105800596A CN201610105645.0A CN201610105645A CN105800596A CN 105800596 A CN105800596 A CN 105800596A CN 201610105645 A CN201610105645 A CN 201610105645A CN 105800596 A CN105800596 A CN 105800596A
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graphitizing
furnace
article
graphitizing furnace
temperature
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CN105800596B (en
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张英丽
谢承启
李双珠
黄王英
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Changzhou University
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Changzhou University
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Abstract

The invention discloses a charging method of a high-yield high-efficiency novel graphitizing furnace. Two graphitizing furnaces are connected in series, and the furnace core size of the graphitizing furnace is properly enlarged to 1800mm*1800mm*1800mm (length*width*height) so as to reduce the graphitizing energy consumption of made-up articles, wherein the energy consumption of each ton of product is reduced to about 4500KWh; and the made-up articles to be fed into the graphitizing furnaces are matched, and the technical problems such as bias caused by the enlargement of the furnace core size are solved; and the two graphitizing furnaces in series connection are synchronized in temperature so as to solve the temperature difference caused by the initial resistance difference of the two graphitizing furnaces.

Description

A kind of shove charge method of the novel graphite stove of high-yield and high-efficiency
Technical field
The present invention relates to the shove charge method of the novel graphite stove of a kind of high-yield and high-efficiency.
Background technology
Graphitizing furnace, has another name called " acheson furnace ", is the key processing equipment of carbon production enterprise acquisition Delanium.Currently, national standard is 8800KWh for producing 1 ton of graphite products power consumption.
Under current market competition environment, for reducing energy consumption, graphitizing furnace develops to string polarization or maximization direction.For producing the enterprise of graphite electrode, it is worthwhile for once producing more graphite electrode.So, acheson furnace just develops into " string pole graphitization " stove.For producing the enterprise of special graphite, due to the molded product that product is " multi-varieties and small-batch ", small-sized extruded product, it is impossible to use " string pole graphitizing furnace ", for reducing production cost, adopt large-scale graphitizing furnace graphitization special graphite made-up article.
And for the carbon element enterprise producing isotropic graphite material, due to the reason of material behavior, it is impossible to use " string pole graphitizing furnace " and " large-scale graphitizing furnace ".Reason is as follows:
1, the graphitization of isotropic graphite made-up article is inadaptable uses " string pole graphitizing furnace "
String pole graphitizing furnace, is after being processed the electrode made-up article end of extrusion, after being well placed successively, compresses burner conductive electrode in burner hydraulic system in stove, makes conductive electrode and product end surface laminating, and promotes product head and the tail successively in stove to be affixed.Afterwards, starting the electric control system of graphitizing furnace, graphitizing furnace power-supply system works, and electric current passes sequentially through made-up article in stove from furnace end electrode, and electric current makes made-up article heating in stove, it is achieved in-furnace temperature, completes the graphitization of graphite electrode made-up article.
String pole graphitizing furnace, is the graphitizing furnace of a kind of efficient fecund, the graphitization energy consumption of the graphitized electrode produced can be made to drop to 4500-5500KWh/ ton, significantly reduce the production cost of graphite electrode.
But string pole graphitizing furnace, owing to current DC is by product, causes that product exists polarity difference in energising direction and non-energized direction.This species diversity, for the graphite electrode state conducted electricity vertically, is advantageous for;But for there being the graphite field of the single crystal growing furnace such as the polycrystalline furnace graphite field of photovoltaic industry, photovoltaic industry and electron trade of specific demand, or the nuclear graphite materials of nuclear reactor core, and incorrect.Because they are required of the isotropism of material.
2, the graphitization of isotropic graphite made-up article is inadaptable uses " ultra-large type " graphitizing furnace
For produce the molded product that product be " multi-varieties and small-batch ", small-sized extruded product special graphite factory for, for reduce production cost, employing " ultra-large type " graphitizing furnace.
Large-scale graphitizing furnace, is by the conventional graphitizing furnace that furnace core size is 1500mm × 1500mm × 15000mm, increases to 2400mm × 2400mm × 30000mm, make the batch of graphitizing furnace, from 30mt/ stove, bring up to 180mt/ stove.
For the conventional graphitizing furnace that furnace core size is 1500mm × 1500mm × 15000mm, generally do not have bias current.Under normal circumstances, combustion chamber central high temperature district is about higher than high-temperature edge district temperature 200 DEG C.
For large-scale graphitizing furnace, such as the graphitizing furnace that furnace core size is 2400mm × 2400mm × 30000mm, Biased flow phenomenon easily occurs, the temperature in central high temperature district is about higher than high-temperature edge district temperature 450 DEG C, cause that the temperature in high-temperature edge district is too low, the made-up article degree of graphitization in this region is inadequate, have impact on the quality of production of product and sells the scope used.
Summary of the invention
The technical problem to be solved in the present invention is: in order to overcome isotropic graphite material cannot use " string pole graphitizing furnace " and " ultra-large type graphitizing furnace ", and the deficiency of production cost cannot be reduced, the present invention provides the shove charge method of the novel graphite stove of a kind of high-yield and high-efficiency.
The technical solution adopted for the present invention to solve the technical problems is: the shove charge method of the novel graphite stove of a kind of high-yield and high-efficiency, comprises the following steps:
1) graphitizing furnace of suitable dimension is designed:
Furnace core size length, width and height are 1800mm × 1800mm × 18000mm, and batch is 60mt/ stove;
2) series connection uses graphitizing furnace:
By two steps 1) in graphitizing furnace series connection, and be composed in series loop with same power-supply system;
3) product coupling: to intending loading step 2) in two graphitizing furnaces in made-up article group match, make that the made-up article state of the art in two graphitizing furnaces of loading (referring to front end production process and the production process of made-up article of the formula of made-up article, made-up article) is consistent, quantity and weight is consistent or basically identical;And made-up article is uniformly put in the combustion chamber length areas of graphitizing furnace;
4) coupling of resistance material filler:
The coupling of resistance material, intend insert step 2) in two graphitizing furnaces in resistance material basically identical;Namely the physical and chemical index that the kind of resistance material, granularity, shape, resistivity, ash grade is basically identical.
5) coupling of insulation material filler:
The coupling of insulation material, intend insert step 2) in two graphitizing furnaces in insulation material basically identical;Namely the physical and chemical index that the kind of insulation material, granularity, shape, resistivity, ash grade is basically identical.
6) temperature of the graphitizing furnace of two series connection is synchronized.
Measure the temperature of the graphitizing furnace of two series connection, with higher temperature for monitoring temperature, i.e. fiducial temperature, control the temperature of the graphitizing furnace of lower temperature.
Step 3) product coupling in group match, including the formula of made-up article, production process, shape, specification and consistent in density or basically identical.
Step 3) product coupling in, utilize shove charge figure Secondary Match made-up article so that made-up article is uniformly put in whole combustion chamber length areas.Shove charge figure of the present invention refers to that made-up article puts into the location drawing of stove, uses the term of kiln and silicate industry, and shove charge figure of the present invention embodies the resistors match of made-up article in itself, reduces electric current Biased flow phenomenon in stove;Can analyzing product quality, such as the concordance (uniformity) of in-furnace temperature, the graphite rate of product, the oxidation in product cooling procedure affects and cools down impact etc. simultaneously.Made-up article owing to producing is different, each position all different, different for shove charge figure, and the made-up article placed is different.
Step 4) in, also include the coupling of insulation material, intend inserting step 2) in two graphitizing furnaces in the physical and chemical index of insulation material consistent or basically identical.
Step 5) in, also include the coupling of insulation material, intend inserting step 2) in two graphitizing furnaces in the physical and chemical index of insulation material consistent or basically identical.
Described physical and chemical index includes granularity, source and cooking level.
The invention has the beneficial effects as follows, two graphitizing furnace series connection are used, and suitably expand the furnace core size of graphitizing furnace by the shove charge method of the novel graphite stove of a kind of high-yield and high-efficiency of the present invention, thus reducing the graphitization energy consumption of made-up article, the energy consumption of ton product is reduced to about 4500KWh;The made-up article and filler intending loading graphitizing furnace is mated, solves the technical problems such as the bias current after being expanded by furnace core size;The graphitizing furnace of two series connection is carried out temperature synchronization, thus solving the temperature contrast that two graphitizing furnace initial resistance differences cause.
Accompanying drawing explanation
Below in conjunction with drawings and Examples, the present invention is further described.
Fig. 1 is the trendgram of the change of carbon element made-up article graphite rate and graphite block resistance variations.
In Fig. 1, heavy line is graphite block resistance change curves, and fine line is graphite rate change curve.
Fig. 2 is the fundamental diagram of two graphitizing furnace series connection uses of the present invention.
In Fig. 21, First graphitizing furnace, 2, second graphitizing furnace, 3, control system, 4, power-supply system.
Detailed description of the invention
In conjunction with the accompanying drawings, the present invention is further detailed explanation.These accompanying drawings are the schematic diagram of simplification, and the basic structure of the present invention is only described in a schematic way, and therefore it only shows the composition relevant with the present invention.
1, the operation principle of graphitizing furnace
Producing at full capacity product and resistance material filler and insulation material filler etc. when graphitizing furnace is built-in, whole graphitizing furnace just constitutes one " resistance ".After starting power control system, the power-supply system of graphitizing furnace is started working.
Heat Q in stove, is namely the function of product temperature T in stove
Q = I 2 R t U 2 R t Formula 1
T is the time of power-supply system startup work, I be graphitizing furnace stove in electric current, U be graphitizing furnace stove in voltage.
T ∝ Q (product temperature T is directly proportional to the heat Q in stove) formula 2
2, carbon element made-up article change in graphitizing furnace
Along with the prolongation of the power-supply system working time t of graphitizing furnace, the heat Q in stove increases, and in-furnace temperature T raises.Along with the in-furnace temperature of graphitizing furnace rises, in stove, the graphite rate of made-up article rises therewith, and the resistivity of made-up article will decline, and therefore in stove, the resistance of product also declines therewith.Fig. 1 shows the trendgram of the change of carbon element made-up article graphite rate and graphite block resistance variations.
From fig. 1, along with high on in-furnace temperature, in stove, the graphite rate of product improves constantly, and reaches capacity during to 3000 DEG C;In stove, the resistance of product declines with the raising of in-furnace temperature, reaches capacity during to 3000 DEG C.It addition, Fig. 1 shows, graphitizing furnace is respectively arranged with a turning point at 1250 DEG C and 2500 DEG C of regions.
Rt is in the interval of 0 DEG C-1250 DEG C: the change of in-furnace temperature, and the resistance of product and the impact of graphite rate change is little.
Rt is in the interval of 1250 DEG C-2500 DEG C: the change of in-furnace temperature, causes the graphite rate significant change of product in stove, and indefinite form carbon changes into graphite, causes that in stove, the resistance of made-up article sharply changes.
Rt is in the interval of 2500 DEG C-3000 DEG C: the change of in-furnace temperature, causes the micro crystal graphite Stability Analysis of Structures of made-up article in stove, improves the conversion of the graphite rate of made-up article, and in this stage stove, the resistance variations of made-up article significantly reduces.
3, the shove charge method of the novel graphite stove of the high-yield and high-efficiency of the present invention
For the carbon element enterprise producing isotropic graphite material, equally need to reduce the production cost of graphitization process, equally need to improve the production efficiency of graphitization process.According to this, it is necessary to suitably expanding furnace core size, series connection uses graphitizing furnace, solves the technical problems such as bias current.Specific as follows:
1) graphitizing furnace of suitable dimension is designed:
Furnace core size length, width and height are 1800mm × 1800mm × 18000mm, namely from the furnace core size 1500mm × 1500mm × 15000mm of length, suitably expand so that batch brings up to 60mt/ stove from 30mt/ stove.
Usually, the burner stove tail of each graphitizing furnace is respectively arranged with 9 square graphite electrodes, the Commonly Used Size specification of these 9 square graphite electrodes is that 250mm, 300mm, 350mm, 400mm are several, consider the locus that the attended operation etc. of electrode needs, the centre-to-centre spacing of general conductive electrode is 400-600mm, it is so the conductive electrode of 250mm for square graphite electrode size, conductive area is maximum can reach 1500mm × 1500mm, being the conductive electrode of 400mm for square graphite electrode size, conductive area is up to 1800mm × 1800mm.The centre-to-centre spacing of conductive electrode can also be expanded again, but excessive conduction wall deviates easily caused by the electric current in combustion chamber too big, causes that the combustion chamber temperature difference reaches more than 500 DEG C, affects the concordance of product in stove and the machinery of graphitization product and electric property.The roasting base of conventional small dimension graphitization in large-sized graphitizing furnace arises a problem that.
2) series connection uses graphitizing furnace:
By two steps 1) in graphitizing furnace series connection, and be composed in series loop with same power-supply system.The principle that series connection uses is as shown in Figure 2.
Two graphitizing furnaces that series connection uses, total batch G is
G=G1+G1=60mt+60mt=120mt, G1 are the batch of First graphitizing furnace, and G2 is the batch of second graphitizing furnace.
So, the graphitization of 120 tons of products (made-up article) can once be completed, it is possible to decrease the graphitization cost of made-up article.Namely the energy consumption of ton product is reduced to about 4500KWh from 8800KWh.
The bias current problem of so-called graphitizing furnace, it is after the furnace core size expanding graphitizing furnace, owing to graphitization made-up article is " multi items small dimension ", the product of these small dimension sizes, what easily lead in loading furnace process is unbalanced, thus cause the electric current bias current in stove, the series technique problem such as hot-zone displacement and hot-zone deformation, and the made-up article graphitization program differentiation thus caused is big or even some quality problems such as crack due to thermal stress occurs in made-up article.
For producing isotropic special graphite manufacturing enterprise, the specification of every stove graphitization made-up article is limited, and (such as cylindrical product size has φ 700 × 850, φ 750 × 850, φ 900 × 850 equal-specification;Square product includes 1200 × 900 × 300,800 × 800 × 500,850 × 850 × 600 equal-specifications), the specification of these made-up articles is limited, and the method for " product coupling " and " filler coupling " can be adopted to solve bias current problem.
1) product coupling: plan is loaded the made-up article group match in two graphitizing furnaces and made-up article is uniformly put in the combustion chamber length areas of graphitizing furnace.
Made-up article for intending loading in two graphitizing furnaces is grouped, and makes the made-up article state of the art in two graphitizing furnaces of loading (referring to front end production process and the production process of made-up article of the formula of made-up article, made-up article), quantity and weight consistent or basically identical.Plan is made to load the formula of made-up article of 2 stoves, production process, shape, specification and consistent in density or basically identical.Such as: the weight loading the made-up article in two graphitizing furnaces is about about 60 tons, and quantity is also roughly the same;The quantity of the circular quantity of made-up article and the quantity of square made-up article and shaped blank is also basically identical;The dimensions of made-up article is also substantially uniform;For difform made-up article, such as circular, square, shaped blank, respective formula is consistent, and preceding working procedure process is consistent.
Through five aspects such as the formula of made-up article, production process, shape, specification, density are carried out group match, make made-up article in the stove of two graphitizing furnaces of loading basically identical.
Meanwhile, utilize shove charge figure that made-up article is carried out Secondary Match so that the made-up article in each graphitizing furnace is uniformly put in whole combustion chamber length areas, it is to avoid local hot spots suddenlys change, and causes hot-zone Biased flow phenomenon in stove.
Specifically, shove charge figure can obtain by the following method:
Condition: treat the made-up article measurement of shove charge, measure the size of each made-up article, weight and resistance (each made-up article is all numbered, according to number record).
Implement step:
1. the made-up article of shove charge is grouped, is divided into two groups according to overall dimensions size, weight and resistance data, make two groups of data basically identical.
2. the combustion chamber subregion to two graphitizing furnaces, is divided into 6 hot-zones, respectively here
Two set products intending putting into A stove or B stove are carried out second time packet, are put together respectively by the product intending putting into certain hot-zone, be divided into 6 groups by 3. profile and weight-matched.And these data are recorded, their resistivity is filled out respectively in corresponding position, forms the resistance value matrix of each hot-zone.Such as, A1 hot-zone, product three layers, every layer 2 row, often row 3, i.e. 6 every layer, uniformly put totally by 18;Corresponding B1 hot-zone, product is also three layers, and every layer is also 2 rows, and often row 3, i.e. 6 every layer, uniformly put totally by 18.
Their resistor matrix is respectively
R A 1 = R 11 R 12 R 13 R 14 R 15 R 16 R 21 R 22 R 23 R 24 R 25 R 26 R 31 R 32 R 33 R 34 R 35 R 36
R B 1 = R 11 ′ R 12 ′ R 13 ′ R 14 ′ R 15 ′ R 16 ′ R 21 ′ R 22 ′ R 23 ′ R 24 ′ R 25 ′ R 26 ′ R 31 ′ R 32 ′ R 33 ′ R 34 ′ R 35 ′ R 36 ′
Wherein, Rmn and Rmn', m=1~3, n=1~6, represent the resistance value of each product in A1 hot-zone and B1 hot-zone in A stove and B stove respectively.
Respectively obtain R according to thisB2, RB3, RB4, RB5, RB6;RA2, RA3, RA4, RA5, RA6Resistor matrix.
4. calculate the eigenvalue treating shove charge product of each hot-zone, obtain
RA1, RA2, RA3, RA4, RA5, RA6
RB1, RB2, RB3, RB4, RB5, RB6
It is respectively compared RA1With RB1, RA2With RB2, RA3With RB3, RA4With RB4, RA5With RB5, RA6With RB6
If their difference is less than 0.5%, then can shove charge produce according to this.
5. adjust: if their difference is more than 0.5% in 4., then needing to finely tune, each hot-zone data making the product of loading A stove and B stove are basically identical, the error scope less than 0.5%.Such as, RA1With RB1Difference reach 1%, then exchange part intend load A stove, B stove product, it is thus achieved that new resistor matrix.
As R A 1 = R 11 R 12 ′ R 13 R 14 R 15 R 16 R 21 R 22 ′ R 23 R 24 R 25 R 26 R 31 R 32 ′ R 33 R 34 R 35 R 36
R B 1 = R 11 ′ R 12 R 13 ′ R 14 ′ R 15 ′ R 16 ′ R 21 ′ R 22 R 23 ′ R 24 ′ R 25 ′ R 26 ′ R 31 ′ R 32 R 33 ′ R 34 ′ R 35 ′ R 36 ′
Calculate RA1、RB1Eigenvalue, until be fine-tuning to RA1≈RB1Till.
Above RAnAnd RBn, n=1~6, the respectively resistance value of 6 hot-zones in A stove and B stove.
2) filler coupling: graphitizing furnace filler includes resistance material and insulation material two kinds, is wherein mainly the coupling of resistance material.
The coupling of resistance material, refer to that plan inserts step 2) in two graphitizing furnaces in the physical and chemical index of resistance material consistent or basically identical, as basically identical in its granularity, source (manufacturer), cooking level etc. so that their resistance is basically identical.
As for insulation material, also make a strong impact.For stopping its impact on made-up article graphitizing process, also need to mate.The coupling of insulation material requires just the same with the made-up article of resistance material, namely intend inserting step 2) in two graphitizing furnaces in the physical and chemical index of insulation material consistent or basically identical, as basically identical in its granularity, source (manufacturer), cooking level etc..
By to product coupling and filler coupling, solving the bias current technical problem of the graphitizing furnace expanding furnace core size.
3) temperature of the graphitizing furnace of two series connection is synchronized.
As in figure 2 it is shown, two graphitizing furnace series connection, then the caloric value of whole system is
Q=I2Rt,R1For the resistance of First graphitizing furnace, R2Being the resistance of second graphitizing furnace, t is the time of power-supply system startup work, I be graphitizing furnace stove in electric current, U be graphitizing furnace stove in voltage.
Q=Q1+Q2, Q1For the heat of First graphitizing furnace, Q2It it is the heat of second graphitizing furnace.
Q 1 = I 2 R 1 T = ( U R 1 + R 2 ) 2 R 1 t ,
Q 2 = I 2 R 2 T = ( U R 1 + R 2 ) 2 R 2 t
Due to R1≈R2, then Q1≈Q2
Due to the resistance of made-up article in the stove of two graphitizing furnaces, change with the variations in temperature in stove, see Fig. 1.For this, different phase adopt diverse ways be controlled:
Rt in the interval of 0 DEG C-1250 DEG C, the change of in-furnace temperature, the resistance of made-up article and the impact of graphite rate is little.So now being controlled according to the furnace temperature of the graphitizing furnace of lower temperature in two measured graphitizing furnaces, the temperature of an other graphitizing furnace is as monitoring data.
Rt is in the interval of 1250 DEG C-2500 DEG C, and the change of in-furnace temperature, graphite rate and Resistance Influence to made-up article are huge.Now need dynamically to observe control.In principle according to the temperature of the graphitizing furnace of lower temperature for controlling temperature, the temperature of another one graphitizing furnace is for monitoring temperature.Such as: interval at this, the resistance of original state First graphitizing furnace is less than the resistance of second graphitizing furnace, i.e. R1< R2, Q occurs1< Q2, namely the temperature of First graphitizing furnace is lower than the temperature of second graphitizing furnace.
In the stove of second graphitizing furnace, made-up article graphite rate improves, and resistance declines, and causes the resistance resistance less than First graphitizing furnace of second graphitizing furnace, i.e. R1> R2.So slowly occur in that Q1> Q2Phenomenon, cause in the stove of First graphitizing furnace made-up article degree of graphitization to improve, cause the resistance phenomenon lower than the resistance of First graphitizing furnace of second graphitizing furnace.
On the whole, for the graphitizing furnace of series connection, it may appear that First graphitizing furnace and second graphitizing furnace are in the phenomenon of the furnace temperature alternate in this interval.No matter how furnace temperature changes, all using the temperature of the graphitizing furnace of relatively low temperature as controlling temperature, the temperature of another one graphitizing furnace is as monitoring temperature.
Rt in the interval of 2500 DEG C-3000 DEG C, the change of in-furnace temperature, the impact of the graphite rate of made-up article in stove and the impact of resistance variations is little.Now still with the temperature of the relatively low graphitizing furnace of temperature for controlling temperature, the temperature of an other graphitizing furnace is for monitoring temperature, to guarantee that in the stove of two graphitizing furnaces, product is attained by the temperature of 2850 DEG C or even 3000 DEG C.
Two graphitizing furnace series connection are used, and suitably expand the furnace core size of graphitizing furnace, thus reduce the graphitization energy consumption of made-up article by the shove charge method of the novel graphite stove of the high-yield and high-efficiency of the present invention, and the energy consumption of ton product is reduced to about 4500KWh;The made-up article and filler intending loading graphitizing furnace is mated, solves the technical problems such as the bias current after being expanded by furnace core size;The graphitizing furnace of two series connection is carried out temperature synchronization, thus solving the temperature contrast that two graphitizing furnace initial resistance differences cause.
With the above-mentioned desirable embodiment according to the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not necessarily departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content in description, it is necessary to determine its technical scope according to right.

Claims (7)

1. the shove charge method of the novel graphite stove of a high-yield and high-efficiency, it is characterised in that comprise the following steps:
1) graphitizing furnace of suitable dimension is designed:
Furnace core size length, width and height are 1800mm × 1800mm × 18000mm, and batch is 60mt/ stove;
2) series connection uses graphitizing furnace:
By two steps 1) in graphitizing furnace series connection, and be composed in series loop with same power-supply system;
3) product coupling: to intend load step 2) in two graphitizing furnaces in made-up article group match, make the state of the art of made-up article in two graphitizing furnaces of loading, quantity and weight consistent or basically identical;Made-up article is made uniformly to put in the combustion chamber length areas of graphitizing furnace;And by shove charge figure record shove charge made-up article position in graphitizing furnace and state.
4) coupling of resistance material filler:
The coupling of resistance material, intend insert step 2) in two graphitizing furnaces in the material of resistance material, granularity and physical and chemical index basically identical;
5) coupling of insulation material filler:
The coupling of insulation material, intends inserting step 2) in two graphitizing furnaces in insulation material material, granularity and physical and chemical index basically identical;
6) temperature of the graphitizing furnace of two series connection is synchronized.
2. the shove charge method of the novel graphite stove of high-yield and high-efficiency as claimed in claim 1, it is characterised in that: measure the temperature of the graphitizing furnace of two series connection, with higher temperature for monitoring temperature, i.e. fiducial temperature, control the temperature of the graphitizing furnace of lower temperature.
3. the shove charge method of the novel graphite stove of high-yield and high-efficiency as claimed in claim 1, it is characterized in that: step 3) product coupling in group match, including the formula of made-up article, production process, shape, specification and consistent in density or basically identical.
4. the shove charge method of the novel graphite stove of the high-yield and high-efficiency as described in claim 1 or 3, it is characterised in that: step 3) product coupling in, utilize shove charge figure Secondary Match made-up article so that made-up article is uniformly put in whole combustion chamber length areas.
5. the shove charge method of the novel graphite stove of high-yield and high-efficiency as claimed in claim 1, it is characterized in that: step 4) in, also include the coupling of resistance material, intend inserting step 2) in two graphitizing furnaces in the physical and chemical index of resistance material consistent or basically identical.
6. the shove charge method of the novel graphite stove of high-yield and high-efficiency as claimed in claim 5, it is characterized in that: step 5) in, also include the coupling of insulation material, intend inserting step 2) in two graphitizing furnaces in the physical and chemical index of insulation material consistent or basically identical.
7. the shove charge method of the novel graphite stove of the high-yield and high-efficiency as described in claim 5 or 6, it is characterised in that: described physical and chemical index includes granularity, source and cooking level.
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CN101857223A (en) * 2010-06-08 2010-10-13 郴州市三晶科贸有限公司 Inner string graphitization process technology of isostatic pressing and mould pressing carbonaceous roasting product
CN102557016A (en) * 2011-11-19 2012-07-11 宜宾天原集团股份有限公司 Anthracite graphitization process

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CN109060175A (en) * 2018-06-04 2018-12-21 中钢集团新型材料(浙江)有限公司 It is a kind of for detecting the test method of graphitization temperature
CN109060175B (en) * 2018-06-04 2020-06-05 中钢集团新型材料(浙江)有限公司 Test method for detecting graphitization temperature

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