CN105792649A - Herbicidal compositions comprising triazinone herbicide and als inhibitor herbicide and uses thereof - Google Patents
Herbicidal compositions comprising triazinone herbicide and als inhibitor herbicide and uses thereof Download PDFInfo
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- CN105792649A CN105792649A CN201480064748.6A CN201480064748A CN105792649A CN 105792649 A CN105792649 A CN 105792649A CN 201480064748 A CN201480064748 A CN 201480064748A CN 105792649 A CN105792649 A CN 105792649A
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- herbicide
- methyl
- herbicidal composition
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- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 124
- 239000004009 herbicide Substances 0.000 title claims abstract description 78
- 239000000203 mixture Substances 0.000 title claims abstract description 74
- QMNWYGTWTXOQTP-UHFFFAOYSA-N 1h-triazin-6-one Chemical compound O=C1C=CN=NN1 QMNWYGTWTXOQTP-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000003112 inhibitor Substances 0.000 title abstract description 5
- 231100000674 Phytotoxicity Toxicity 0.000 claims abstract description 15
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 claims description 37
- 239000002552 dosage form Substances 0.000 claims description 30
- 239000005584 Metsulfuron-methyl Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 23
- CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 claims description 22
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 claims description 20
- -1 amine piperazine ketone Chemical class 0.000 claims description 17
- 239000004562 water dispersible granule Substances 0.000 claims description 16
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- WMLPCIHUFDKWJU-UHFFFAOYSA-N Cinosulfuron Chemical compound COCCOC1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OC)=NC(OC)=N1 WMLPCIHUFDKWJU-UHFFFAOYSA-N 0.000 claims description 7
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- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 claims description 7
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- ADZSGNDOZREKJK-UHFFFAOYSA-N 4-amino-6-tert-butyl-3-ethylsulfanyl-1,2,4-triazin-5-one Chemical compound CCSC1=NN=C(C(C)(C)C)C(=O)N1N ADZSGNDOZREKJK-UHFFFAOYSA-N 0.000 claims description 4
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- LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 description 1
- BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Disclosed a herbicidal composition comprising an ALS Inhibitor herbicide and a triazinone herbicide, which reduces phytotoxicity of the ALS Inhibitor herbicide to crop plant.
Description
Technical field
The present invention relates to a kind of method preventing and treating undesired plant growth, the method uses a kind of herbicidal composition suppressing dosage form herbicide and triazinone herbicide containing ALS.
Background technology
Undesired plant growth can cause that crop yield is greatly decreased.Therefore, will obtaining crop good harvest, preventing and treating undesired plant growth is extremely important, and to continue the noxious plant preventing and treating in farmland.
ALS suppresses dosage form herbicide to can be used to prevent and treat undesired plant growth.nullSuch as，ALS suppresses dosage form herbicide to include sulfonylurea herbicide，Such as amidosulfuron (amidosulfuron)、Azimsulfuron (azimsulfuron)、Sulfometuron Methyl (bensulfuron)、Chlorine phonetic (chlorimuron)、Ring the third cinosulfuron (cyclosulfamuron)、Ethoxysulfuron (ethoxysulfuron)、Flazasulfuron (flazasulfuron)、Flucetosulfuron (flucetosulfuron)、Fluorine pyridine sulphur grand (flupyrsulfuron)、Foramsulfuron (foramsulfuron)、Halosulfuronmethyl (halosulfuron)、Imazosulfuron (imazosulfuron)、Mesosulfuronmethyl (mesosulfuron)、Piperazine pyrazosulfuron (metazosulfuron)、Sulfonylurea (methiopyrisulfuron)、Monosulfmeturon (monosulfuron)、Nicosulfuron (nicosulfuron)、Orthosulfamuron (orthosulfamuron)、Oxasulfuron (oxasulfuron)、Primisulfuronmethyl (primisulfuron)、Promazine Sulfometuron Methyl (propyrisulfuron)、Pyrazosulfuron (pyrazosulfuron)、Rimsulfuron (rimsulfuron)、Sulfometuron Methyl (sulfometuron)、Sulfosulfuron (sulfosulfuron)、Trifloxysulfuron (trifloxysulfuron)、Azoles Sulfometuron Methyl (zuomihuanglong)、Chlorine sulphur grand (chlorsulfuron)、Cinosulfuron (cinosulfuron)、Ethametsulfuron (ethametsulfuron)、Iodine metsulfuron-methyl (iodosulfuron)、Different Ou Fen sulphur grand (iofensulfuron)、Metsulfuron-methyl (metsulfuron-methyl)、Prosulfuron (prosulfuron)、Thifensulfuronmethyl (thifensulfuron)、Triasulfuron (triasulfuron)、Tribenuron-methyl (tribenuron)、Triflusulfuronmethyl (triflusulfuron)、Tritosulfuron (tritosulfuron)、Metsulfuron-methyl (metasulfuronmethyl)、Chlorimuronethyl (chlorimuron-ethyl)、The grand free acid of sulphur (clopyrasulfuron) and sulfometuronmethyl (sulfometuron-methyl).
Above-mentioned herbicide, its production procedure, the herbicidal composition containing above-mentioned herbicide and this technical field that is applied in as herbicide thereof belong to known knowledge; such as; (thePesticideManual in Britain crop protection committee 1991 " pesticide handbook " the 9th edition; 9thedition (1991); TheBritishCropprotectionCouncil, London)；Ag chemistry new product summary (AgChemNewProductReview), Ag chemical information service (AgChemInformationServices), Indianapolis (Indianapolis, Ind.) and similar document record.
But, ALS suppresses dosage form herbicide, for instance sulfonylurea herbicide, it is possible to crop is produced phytotoxicity.Helianthi is one of which to ALS suppresses the crop of dosage form herbicide sensitive, it may appear that apical bud development is slow, variable color and the symptom (Alonso-Prados etc., 2002) be completely cured.The phytotoxicity of herbicide can slow down the growth of crop, even results in it dead.Accordingly, it is desirable to a kind of plant-less toxicity or low phytotoxicity and can efficiently prevent and treat the compositions of undesired plant growth.
Surprisingly, have now found that suppressing the Herbicidal combinations of the present invention of dosage form herbicide can reduce ALS containing triazinone herbicide and ALS suppresses dosage form herbicide to crop (such as forage crop, such as Caulis Sacchari sinensis) vegetalitas toxicity, and do not reduce its preventing and treating undesired plant growth drug effect.
Summary of the invention
Therefore the present invention relates to a kind of undesired plant growth that can control and can reduce again the ALS suppression dosage form herbicide phytotoxic method to crop, the method includes using, to crop or its position, the compositions suppressing dosage form herbicide containing triazinone herbicide and ALS.
" phytotoxicity " described in the context of the invention relates to all herbicide impacts hindering crop normal development.The phytotoxicity of herbicide may suppress plant growth, even causes plant death.Therefore to keep crop healthy, then need plant-less toxicity or low phytotoxic herbicide.
The triazinone herbicide suppressing dosage form herbicide containing ALS consecutively or simultaneously can be used by any desired order and combination.Triazinone herbicide can suppress jointly using of dosage form herbicide may be accomplished by with ALS: is obtained and mix (being known as a barrel mixture, pre-mixing agent, fermentation liquid spraying or slurry mode) by independent preparation source, and can be optionally added other pesticide, such as other antibacterial, insecticide and nematicide, or obtained (being known as pre-mixing agent, concentrating agents, built agent (or product)) by monospecies preparation mixture source, and optionally it is mixed into other pesticide, for instance other antibacterial, insecticide and nematicide.
On the one hand, herbicidal composition provided by the present invention comprises following components:
(A) triazinone herbicide；And
(B) ALS suppresses dosage form herbicide；
Wherein, triazinone herbicide can reduce ALS and suppress the dosage form herbicide phytotoxicity to crop.
On the other hand, the present invention provides a kind of ALS that reduces to suppress the dosage form herbicide method to crop plants toxicity, and described method includes:
The herbicidal composition comprising following components is used to crop or its position:
(A) triazinone herbicide；And
(B) ALS suppresses dosage form herbicide.
In some embodiments, triazinone herbicide disclosed herein can be selected from amine piperazine ketone (ametridione), amine metribuzin (amibuzin), ethiozin (ethiozin), hexazinone (hexazinone), isomethiozin (isomethiozin), metamitron (metamitron) and metribuzin (metribuzin).Hexazinone is to can be used to prevent and treat annual and 2 years raw weeds herbicide.
In other detailed description of the invention, broad leaved weed and grassy weed are all had broad-spectrum weed-killing activity by ALS inhibitor disclosed herein.Concrete structure according to compound, has selectivity widely to single crop.
ALS suppresses dosage form herbicide can be sulfonylurea herbicide, as Sulfometuron Methyl, U.S. special sulphur grand (metsulfuron), metsulfuron-methyl, ethametsulfuron, nicosulfuron, triasulfuron, primisulfuronmethyl, Sulfometuron Methyl, chlorine is phonetic, chlorimuronethyl, chlorine sulphur are grand, thifensulfuronmethyl, tribenuron-methyl, triflusulfuronmethyl, sulphur grand free acid (clopyrasulfuron), pyrazosulfuron, Sulfometuron Methyl and sulfometuronmethyl；Sulfonamides herbicide, such as Flumetsulam (flumetsulam)；And imidazolinone herbicide, such as Scepter (imazaquin), miaow grass ester (imazamethabenz), Arsenal (imazapyr), AC 263222 (imazmethapyr) and Imazethapyr (imazethapyr).
Sulfonylurea herbicide is agriculturally for preventing and treating a compounds of noxious plant, is characterized as being and has the active and low person poultry toxicity of high herbicidal.They generally comprise a sulfonylurea chain (-SO2NHCONH-) two aromatic hydrocarbon ring or heteroaromatic are connected.Sulfometuronmethyl is a kind of sulfonylurea herbicide being commercially commercially available, and is used for preventing and treating weeds on industry weeds, roadside and rail, and is used as sugarcane ripeners.Metsulfuron-methyl is a kind of sulfonylurea herbicide, is used for preventing and treating the multiple annual and perennial broadleaf weed of the Tanakas such as Semen Tritici aestivi, Fructus Hordei Vulgaris, Oryza sativa L., Herba bromi japonici.
The preferred metsulfuron-methyl of ALS inhibitor, Sulfometuron Methyl and sulfometuronmethyl in the present invention.The preferred hexazinone of triazinone herbicide in the present invention.Therefore particularly preferred it is combined as hexazinone and metsulfuron-methyl；Hexazinone and Sulfometuron Methyl；And hexazinone and sulfometuronmethyl.
Generally, the rate of application of herbicidal composition is determined according to the concrete active component in compositions, weeds kind, crop species, soil types, season, weather, soil ecology and other factors various.Compositions rate of application under certain condition can easily pass through test and determine.
Comprise component (A) triazinone herbicide；And the rate of application of the herbicidal composition of (B) ALS suppression dosage form herbicide can be about 50 to 6000g/ha, 50 to 3000g/ha, 100 to 2000g/ha, 100 to 1000g/ha, 200 to 1000g/ha, 300 to 1000g/ha, 400 to 800g/ha, 400 to 600g/ha or 450g/ha.In certain specific embodiments of the invention, the rate of application of the herbicidal composition comprising hexazinone and metsulfuron-methyl, Sulfometuron Methyl or sulfometuronmethyl ranges for 300 to 1000g/ha, 400 to 800g/ha, 400 to 600g/ha or 450g/ha.
Generally, for jointly using, the rate of application of triazinone herbicide is 250 to 6000g/ha, or 250 to 3000g/ha, or especially 300 to 2000g/ha, or 300 to 1000g/ha, or 300 to 600g/ha；ALS suppresses the rate of application of dosage form herbicide to be 5 to 630g/ha, especially 30 to 150g/ha.In other detailed description of the invention of the present invention, for jointly using, the rate of application of hexazinone is the rate of application of 300 to 600g/ha and metsulfuron-methyl, Sulfometuron Methyl or sulfometuronmethyl is 30 to 150g/ha.In certain specific embodiments of the invention, for jointly using, the rate of application of hexazinone is 300 to 500g/ha, and the rate of application of metsulfuron-methyl, Sulfometuron Methyl or sulfometuronmethyl is 30 to 80g/ha.
Generally, triazinone herbicide and ALS suppress the weight ratio of dosage form herbicide to be 25:1 to 1:25,10:1 to 1:10,7:1 to 1:7 or 3:1 to 1:3.In certain specific embodiments of the invention, triazinone herbicide and ALS suppress the weight ratio of dosage form herbicide to be 25:1,10:1,7:1,3:1,2:1 or 1:1.In other detailed description of the invention of the present invention, triazinone herbicide and ALS suppress the weight ratio of dosage form herbicide to be 1:25,1:10,1:7,1:3,1:2 or 1:1.In certain specific embodiments of the invention, the weight ratio of triazinone herbicide and ALS suppressive herbicide can be 10:1.In other detailed description of the invention of the present invention, the weight ratio of hexazinone and metsulfuron-methyl, Sulfometuron Methyl or sulfometuronmethyl is 25:1 to 1:25,10:1 to 1:10,7:1 to 1:7 or 3:1 to 1:3.In certain specific embodiments of the invention, the weight ratio of hexazinone and metsulfuron-methyl, Sulfometuron Methyl or sulfometuronmethyl is 10:1.
In certain specific embodiments of the invention, the total amount of component (A) and component (B) accounts for 5 weight % to the 99 weight % of herbicidal composition, it is preferable that 50 weight % to 99 weight %, 70 weight % to 99 weight %, 80 weight % to 99 weight % or 80 weight % to 90 weight %.
This herbicidal composition can also include one or more auxiliary agents agriculturally allowed.Pharmacy type and/or the method for application of medicament that the auxiliary agent used in compositions and consumption thereof adopt according to end user and determine.The auxiliary agent being suitable for is common medicine agent aid or composition, such as dispersant, wetting agent, extender, carrier, solvent, surfactant, stabilizer, defoamer, antifreezing agent, preservative, antioxidant, coloring agent, thickening agent, solid binder and inert filler.This auxiliary agent is known in this field and commercially.Person skilled in art is familiar with how using these auxiliary agents in present composition medicament.
Herbicidal composition of the present invention can comprise one or more dispersants.The known applicable dispersant in this field can in commercial acquirement.The example of the dispersant being suitable for includes, but not limited to1494, sodium lignin sulfonate, sulfonated aromatic polymers, sodium salt and fatty alcohol polyglycol ether.
Herbicidal composition of the present invention can comprise one or more wetting agents.The known applicable wetting agent in this field can in commercial acquirement.The example of the wetting agent being suitable for includes; but it is not limited to, N-methyl N-oleoyl taurate, octylphenoxy polyethoxy ethanol, nonylphenoxy polyethoxy ethanol, dioctyl sodium sulphosuccinate, dodecyl base sodium sulfonate, dodecyl sodium sulfate, Negel, sulfonated alkyl carboxylic acid sodium and Negel.
Herbicidal composition of the present invention can comprise one or more solvents.Solvent can be organic or inorganic.The solvent being suitable for can be the common solvent in this field, and this solvent can be completely dissolved the agrochemical active substance of use.The solvent being suitable for is known solvent in this field, and can in commercial acquirement.The example of the solvent being suitable for includes water, aromatic solvent, if dimethylbenzene is (as with SolvessoTMSell solvent product), mineral oil, animal oil, vegetable oil；Alcohols, such as methanol, butanol, amylalcohol and alcohol；Ketone, such as Ketohexamethylene and gamma-butyrolacton；Ketopyrrolidine, such as NMP and NOP；Acetate esters, such as ethylene acetate；Glycols；Fatty acid dimethylamides class；Fatty acid and fatty acid ester.
Herbicidal composition can also comprise one or more surfactants.nullThe surfactant being suitable for known in this field includes，But it is not limited to lignosulphonic acid、LOMAR PWA EINECS 246-676-2、Phenolsulfonic acid、The alkali metal salt of dibutyl naphthalenesulfonic acid、Alkali salt and ammonium salt、Alkylaryl sulfonates、Alkyl sulfate、Alkylsulfonate、Arylsulphonate、Aliphatic alcohol sulfate、Fatty acid and sulphated fatty alcohol glycol ether，Condensation substance in addition with sulfonated naphthalene and naphthalene derivatives and formaldehyde、Naphthalene or LOMAR PWA EINECS 246-676-2 and phenol、Octyl phenol、Nonyl phenol、Alkyl phenyl polyglycol ether、Tributyl phenyl polyglycol ether、The condensation substance of three stearyl phenyl polyglycol ethers、Alkyl aryl polyether alcohol、Alcohol and fatty alcohol/ethylene oxide condensate、Ethoxylated castor oil、Polyoxyethylene alkyl ether、Ethoxylation polyoxypropylene、Lauryl alcohol polyglycol ether acetal、Sorbitol ester、Lignin sulfite waste liquor and methylcellulose and ethylene oxide/propylene oxide block copolymer.The surfactant being suitable for can be bought in market.
Herbicidal composition of the present invention can also comprise one or more polymer stabilizers.In the present invention, operable applicable polymer stabilizer includes, but are not limited to the copolymer of polypropylene, polyisobutylene, polyisoprene, monoolefine and alkadienes, polyacrylate, polystyrene, polyvinyl acetate, polyurethane or polyamide.The stabilizer being suitable for known in this field can in commercial acquirement.
Herbicidal composition of the present invention can also comprise one or more defoamer.The defoamer being suitable for includes the froth breaking material that is generally used for this purpose in agrochemical composition, and is the material be familiar with of the professional in this field.The defoamer being suitable for is known pharmaceutical agents and can in commercial acquirement in this field.Defoamer is particularly preferably polydimethylsiloxane and the mixture of perfluoroalkyl phosphonic acids, such as organic silicon defoamer (as purchased from GE or Compton).Such as, another kind of defoamer is fatty acid, Adeps Bovis seu Bubali, sodium salt.
Herbicidal composition of the present invention can also comprise one or more preservative.The preservative being suitable for includes the preservative substance being generally used for this purpose in the type agrochemical composition, and is also the known pharmaceutical agents in this field.The preservative that can be suitable for referred in this includes(as purchased from BayerAG) and(as purchased from BayerAG).
Herbicidal composition of the present invention can also comprise one or more antioxidants.The antioxidant being suitable for is the antioxidant being generally used for this purpose in agrochemical composition, and is the known pharmaceutical agents in this field.For example, it is preferable to be butylated hydroxytoluene.
Herbicidal composition of the present invention can also comprise one or more solid binder.This binding agent is the known pharmaceutical agents in this field, and can in commercial acquirement.They include organic bond, including viscosifier, as powdery, graininess or lenticular be substituted, natural and synthetic polymeric fibers is plain, and inorganic bond, such as Gypsum Fibrosum, Silicon stone or cement.
Herbicidal composition of the present invention can also comprise one or more inert fillers.These inert fillers are the medicament that this field is known, and can in commercial acquirement.The filler being suitable for includes, such as natural levigate mineral, such as the levigate mineral of Kaolin, aluminium oxide, Talcum, Chalk, quartz, Attagel, montmorillonite, kieselguhr or synthesis, such as the hydrophosphate of the phosphate of high dispersive silicic acid, aluminium oxide, silicate and calcium and calcium.The granule of the inert filler being suitable for includes, as pulverized and the natural mineral matter of classification, such as calcite, marble, Pumex, meerschaum, dolomite, or the synthesis granule of inorganic and organic levigate mineral, and organic material particles, such as sawdust, Exocarpium cocois (Cocos nucifera L), corncob and tobacco stem.The example of inert filler also includes sodium tripolyphosphate and sucrose.
Herbicidal combinations of the present invention can also comprise one or more thickening agents.The thickening agent being suitable for includes the thickening material being generally used for this purpose in agrochemical composition.The example of the thickening agent being suitable for includes glue, such as xanthan gum, polyvinyl alcohol, cellulose and its derivates, hydrated clay silicate, zeopan or their mixture.Equally, the medicament that these thickening agents are known in the art, and can in commercial acquirement.
Herbicidal composition of the present invention can be several formulations form, such as soluble concentrate (SL), cream (EC), aqueous emulsion (EW), microemulsion (ME), suspending agent (SC), oil-suspending agent (OD), seed treatment is with aqueous suspension (FS), water-dispersible granules (WG), water-soluble granule (SG), wettable powder (WP), water solube powder (SP), granule (GR), microcapsulated granule (CG), granula subtilis (FG), big granule (GG), suspension emulsion (SE), microcapsule suspending agent (CS) and microgranule (MG).In certain specific embodiments of the invention, the pharmacy type of herbicidal composition is water-dispersible granules (WG).According to pharmacy type, the present composition can also comprise water.
Suppress the herbicidal composition of dosage form herbicide containing component (A) triazinone herbicide and (B) ALS, can be applied on crop with controlling weeds, and triazinone herbicide can reduce ALS and suppress the phytotoxicity of dosage form herbicide.Herbicidal composition containing hexazinone and metsulfuron-methyl, Sulfometuron Methyl or sulfometuronmethyl can be applied on crop to control weeds, and hexazinone can reduce the phytotoxicity of metsulfuron-methyl, Sulfometuron Methyl or sulfometuronmethyl.
Described crop includes corn, such as Semen Tritici aestivi, Fructus Hordei Vulgaris, rye (Secale cereale L.), Herba bromi japonici, rice, Semen Maydis, Sorghum vulgare Pers., Semen setariae and Maninot esculenta crantz.；Radix Betae, such as sugar beet and fodder beet；Fruit, such as melonidum, drupe and mushy fruit, such as Fructus Mali pumilae, pears, Fructus Pruni salicinae, Fructus Persicae, Semen Armeniacae Amarum, Fructus Pruni pseudocerasi or berry, such as Fructus Fragariae Ananssae, Fructus Rubi and blackberry；Leguminous plant, such as Kidney bean, Radix Crotalariae szemoensis, Semen Pisi sativi and Semen sojae atricolor；Oilseed plant, such as Brassica campestris L, Caulis et Folium Brassicae junceae, Semen Papaveris, Fructus Canarii albi, Helianthi, Cortex cocois radicis, Semen Ricini, cacao bean and Semen arachidis hypogaeae；Cucurbitaceous plant, such as calabash, Fructus Cucumidis sativi and Fructus Melo；Fibre plant, such as Cotton Gossypii, Caulis et Folium Lini, Fructus Cannabis, Corchorus olitorius L. etc.；Citrus fruit, such as Fructus Citri junoris, Fructus Citri Limoniae, grapefruit and Citrus；Vegetable, such as Herba Spinaciae, Caulis et Folium Lactucae Sativae, Germinatus Phragmitis, Brassica oleracea L.var.capitata L., Radix Dauci Sativae, Bulbus Allii Cepae, Fructus Lycopersici esculenti, Rhizoma Solani tuber osi and Fructus Capsici；Lauraceae, such as American Avocado Tree, Cortex Cinnamomi, Camphora；And Nicotiana tabacum L., nut, coffee, Fructus Solani melongenae, Caulis Sacchari sinensis, tea, Fructus Piperis, Fructus Vitis viniferae, Flos lupuli (Flos Humuli Lupuli), Fructus Musae, natural rubber plant, Eucalyptus and ornamental plant.Particularly preferred plant is corn, leguminous plant and fibre plant.Particularly preferred crop plants is Caulis Sacchari sinensis.
Herbicidal composition in the present invention can effectively prevent and treat undesired plant growth, for instance (but not limited to):
Herba stellariae mediae (Chickweed), Herba Digitariae (Crabgrass), silk leaf Herba Lycopi (Dogfennel), fescue grass (Fescue), weeds (willow herb (willowweed)), Hemerocallis citrina Baroni (Goldenrod), Herba Erigerontis Canadensis (Horseweed), English grass (Kentuckybluegrass), dried tuber (Nutsedge) (yellow), Panicum (broad-leaved, autumn, narrow row), Radix Phytolaccae (Pokeweed), artemisiifolia (Ragweed), Herba Capsellae (Shepherd ' spurse), white Herba ophiorrhizae japonicae (Whitesnakeroot) and Cladrastis kentukea Rudd sweet-scented osmanthus (Yellowsweetclover).
Following examples set forth the practical application of the present invention.
Embodiment 1 Developing restraint
Prepare test mixture 1-9 in the following manner: the fine grinding component (A) of different components and (B) are closely mixed with auxiliary agent, grind with ultrafine crusher, more paste-extruded pelletize obtains water-dispersible granules.This auxiliary agent include polyvinyl alcohol (2%w/w),1494 (sodium salt of cresol/formaldehyde condensation) (5%w/w) and Kaolin.Then, water dispersible granules dilute is become any desired concn.
By cane planting on the seedling bed of the special peat composed of rotten mosses growth substrate of High quality agricultural products, cultivate in greenhouse.When crop germinates and grows to about 4 cun, one of which test mixture is sprayed on the crop seedling bed separated according to default medication rate.
After crop processes with test mixture, seedling bed is placed about one week under greenhouse, promotes plant growth.After one week, the height of crop in detection seedling bed, it is determined that the growth inhibition ratio of Caulis Sacchari sinensis.Testing result is provided in the table below in 1.
Table 1 growth inhibited
Embodiment 2 is fallen leaves
Prepare test mixture 10-19 in the following manner: the fine grinding component (A) of different deals and (B) are closely mixed with auxiliary agent, grind with ultrafine crusher, more paste-extruded pelletize obtains water-dispersible granules.Auxiliary agent include polyvinyl alcohol (2%w/w),1494 (5%w/w) and Kaolin.Then, water dispersible granules dilute is become any desired concn.
By cane planting on the seedling bed of the special peat composed of rotten mosses growth substrate of High quality agricultural products, cultivate in greenhouse.When crop germinates and grows to about 4 cun, a kind of test mixture in test mixture 10-19 is sprayed on the crop seedling bed separated according to default medication rate (calculating (gai/ha) by the grams of per hectare active component).
After crop processes with test mixture, seedling bed is placed about surrounding under greenhouse, promotes plant growth.After surrounding, detect seedling bed, calculate residue blade quantity, it is determined that sugarcane crop fallen leaves ratio.Control experiment group drops a piece of leaf.Testing result is provided in the table below in 2.
Table 2 is fallen leaves
Embodiment 3 phytotoxicity is graded
Prepare test mixture 20-29 in the following manner: the fine grinding component (A) of different deals and (B) are closely mixed with auxiliary agent, grind with ultrafine crusher, more paste-extruded pelletize obtains water-dispersible granules.Auxiliary agent include polyvinyl alcohol (2%w/w),1494 (5%w/w) and Kaolin.Then, water dispersible granules dilute is become any desired concn.
By cane planting on the seedling bed of the special peat composed of rotten mosses growth substrate of High quality agricultural products, cultivate in greenhouse.When crop germinates and grows to about 4 cun, a kind of test mixture in test mixture 20-29 is sprayed on the crop seedling bed separated according to default medication rate (calculating (gai/ha) by the grams of every mu of active component).
After crop applying test mixture, seedling bed is placed about one week under greenhouse, promotes plant growth.After one week, visual phytotoxicity.Phytotoxicity rank is divided into 0 to 5.(the serious phytotoxicity of 5=, namely leaf and stem present buff, coke yellow or withered speckle；0=plant-less toxicity).Testing result is provided in the table below in three.
Table 3 phytotoxicity is graded
The effectiveness of embodiment 4 test mixture
Prepare the subject composition 30-33 in table 4 in the following manner: the fine grinding component (A) of different deals and (B) are closely mixed with auxiliary agent, grind with ultrafine crusher, more paste-extruded pelletize obtains water-dispersible granules.Auxiliary agent include polyvinyl alcohol (2%w/w),1494 (5%w/w) and Kaolin.Then, water dispersible granules dilute is become any desired concn.
By cane planting on the seedling bed of the special peat composed of rotten mosses growth substrate of High quality agricultural products.Record weed species and correlation density thereof and be provided in the table below in 5.After planting 40 days, use test mixture according to default medication rate (calculating (gai/ha) by the grams of per hectare active component).
After crop processes with test mixture, seedling bed is placed about two weeks.After two weeks, detect seedling bed, it is determined that the effectiveness of test mixture.Testing result is provided in the table below in 6.
Table 4 test mixture
Table 5 weed species
| Weed species | Relative density (%) |
| Herba stellariae mediae | 30 |
| Herba Digitariae | 20 |
| Rhizoma Cyperi | 25 |
| Panicum | 25 |
Table 6 effectiveness (%)
All publications that present specification is quoted, patents and patent applications are made as a whole to be respectively designated independent document with them when quoting at this and have identical effect.Although for clear understanding, aforementioned invention is described in detail with embodiment already by illustrating, but it easily can be made some according to the teachings of the present invention and change and amendment by those of ordinary skill in the art, without departing from the spirit and scope of described claim.
Claims (22)
1. a herbicidal composition, described compositions comprises:
(A) triazinone herbicide；And
(B) ALS suppresses dosage form herbicide；
Wherein, described triazinone herbicide can reduce ALS and suppress the dosage form herbicide phytotoxicity to crop.
2. herbicidal composition according to claim 1, it is characterised in that described triazinone herbicide is selected from amine piperazine ketone, amine metribuzin, ethiozin, hexazinone, isomethiozin, metamitron and metribuzin.
null3. herbicidal composition according to claim 1 and 2，It is characterized in that，Described ALS suppresses dosage form herbicide selected from lower group of sulfonylurea herbicide: amidosulfuron、Azimsulfuron、Sulfometuron Methyl、Chlorine is phonetic、Ring the third cinosulfuron、Ethoxysulfuron、Flazasulfuron、Flucetosulfuron、Fluorine pyridine sulphur is grand、Foramsulfuron、Halosulfuronmethyl、Imazosulfuron、Mesosulfuronmethyl、Piperazine pyrazosulfuron、Sulfonylurea、Monosulfmeturon、Nicosulfuron、Orthosulfamuron、Oxasulfuron、Primisulfuronmethyl、Promazine Sulfometuron Methyl、Pyrazosulfuron、Rimsulfuron、Sulfometuron Methyl、Sulfosulfuron、Trifloxysulfuron、Azoles Sulfometuron Methyl、Chlorine sulphur is grand、Cinosulfuron、Ethametsulfuron、Iodine metsulfuron-methyl、Different Ou Fen sulphur is grand、Metsulfuron-methyl、Prosulfuron、Thifensulfuronmethyl、Triasulfuron、Tribenuron-methyl、Triflusulfuronmethyl、Tritosulfuron、Metsulfuron-methyl、Chlorimuronethyl、The grand free acid of sulphur and sulfometuronmethyl.
4. according to herbicidal composition in any one of the preceding claims wherein, it is characterised in that the weight ratio of described component (A) and component (B) is 25:1 to 1:25,10:1 to 1:10,7:1 to 1:7 or 3:1 to 1:3.
5. according to herbicidal composition in any one of the preceding claims wherein, it is characterized in that, the total amount of described component (A) and component (B) accounts for 5 weight % to the 99 weight % of described herbicidal composition, preferably 50 weight % to 99 weight %, 70 weight % to 99 weight %, 80 weight % to 99 weight %, or 80 weight % to 90 weight %.
6., according to herbicidal composition in any one of the preceding claims wherein, it is characterised in that the rate of application of component (A) is 50 to 6000g/ha, the rate of application of component (B) is 5 to 630g/ha.
7. according to herbicidal composition in any one of the preceding claims wherein, it is characterized in that, described herbicidal composition is soluble concentrate (SL), cream (EC), aqueous emulsion (EW), suspending agent (SC), oil-suspending agent (OD), seed treatment is with aqueous suspension (FS), water-dispersible granules (WG), water-soluble granule (SG), wettable powder (WP), water solube powder (SP), granule (GR), microcapsulated granule (CG), granula subtilis (FG), big granule (GG), microgranule (MG), microemulsion (ME), suspension emulsion (SE), microcapsule suspending agent (CS) form.
8. the herbicidal composition according to claim 2-7, it is characterised in that described component (A) is hexazinone；And described component (B) is metsulfuron-methyl.
9. the herbicidal composition according to claim 2-7, it is characterised in that described component (A) is hexazinone；And described component (B) is sulfometuronmethyl.
10. the herbicidal composition according to claim 2-7, it is characterised in that described component (A) is hexazinone；And described component (B) is Sulfometuron Methyl.
11. according to herbicidal composition in any one of the preceding claims wherein, wherein said crop is Caulis Sacchari sinensis.
12. reduce ALS to suppress a dosage form herbicide phytotoxic method to crop, described method includes:
Crop or its position are used the herbicidal composition comprising following components:
(A) triazinone herbicide；And
(B) ALS suppresses dosage form herbicide.
13. method according to claim 12, it is characterised in that described triazinone herbicide is selected from amine piperazine ketone, amine metribuzin, ethiozin, hexazinone, isomethiozin, metamitron and metribuzin.
null14. the method according to claim 12 or 13，It is characterized in that，Described ALS suppresses dosage form herbicide selected from lower group of sulfonylurea herbicide: amidosulfuron、Azimsulfuron、Sulfometuron Methyl、Chlorine is phonetic、Ring the third cinosulfuron、Ethoxysulfuron、Flazasulfuron、Flucetosulfuron、Fluorine pyridine sulphur is grand、Foramsulfuron、Halosulfuronmethyl、Imazosulfuron、Mesosulfuronmethyl、Piperazine pyrazosulfuron、Sulfonylurea、Monosulfmeturon、Nicosulfuron、Orthosulfamuron、Oxasulfuron、Primisulfuronmethyl、Promazine Sulfometuron Methyl、Pyrazosulfuron、Rimsulfuron、Sulfometuron Methyl、Sulfosulfuron、Trifloxysulfuron、Azoles Sulfometuron Methyl、Chlorine sulphur is grand、Cinosulfuron、Ethametsulfuron、Iodine metsulfuron-methyl、Different Ou Fen sulphur is grand、Metsulfuron-methyl、Prosulfuron、Thifensulfuronmethyl、Triasulfuron、Tribenuron-methyl、Triflusulfuronmethyl、Tritosulfuron、Metsulfuron-methyl、Chlorimuronethyl、The grand free acid of sulphur and sulfometuronmethyl.
15. the method according to any one of claim 12-14, it is characterised in that the weight ratio of described component (A) and component (B) is 25:1 to 1:25,10:1 to 1:10,7:1 to 1:7, or 3:1 to 1:3.
16. the method according to any one of claim 12-15, it is characterized in that, the total amount of described component (A) and component (B) accounts for 5 weight % to the 99 weight % of described herbicidal composition, preferably 50 weight % to 99 weight %, 70 weight % to 99 weight %, 80 weight % to 99 weight %, or 80 weight % to 90 weight %.
17. the method according to any one of claim 12-16, it is characterised in that the rate of application of described component (A) is 50 to 6000g/ha, and the rate of application of described component (B) is 5 to 630g/ha.
18. the method according to any one of claim 12-17, it is characterized in that, described herbicidal composition is soluble concentrate (SL), cream (EC), aqueous emulsion (EW), suspending agent (SC), oil-suspending agent (OD), seed treatment is with aqueous suspension (FS), water-dispersible granules (WG), water-soluble granule (SG), wettable powder (WP), water solube powder (SP), granule (GR), microcapsulated granule (CG), granula subtilis (FG), big granule (GG), microgranule (MG), microemulsion (ME), suspension emulsion (SE), microcapsule suspending agent (CS) form.
19. the method according to claim 13-18, it is characterised in that described component (A) is hexazinone；And described component (B) is metsulfuron-methyl.
20. the method according to claim 13-19, it is characterised in that described component (A) is hexazinone；And described component (B) is sulfometuronmethyl.
21. the method according to claim 13-20, it is characterised in that described component (A) is hexazinone；And described component (B) is Sulfometuron Methyl.
22. the method according to claim 12-21, it is characterised in that described crop is Caulis Sacchari sinensis.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BR102013030594-4A BR102013030594B1 (en) | 2013-11-28 | 2013-11-28 | HERBICIDAL COMPOSITIONS COMPRISING A HERBICIDE OF TRIAZINONE AND A HERBICIDE INHIBITOR OF ALS AND USES THEREOF |
| BR1020130305944 | 2013-11-28 | ||
| PCT/CN2014/088702 WO2015078243A1 (en) | 2013-11-28 | 2014-10-16 | Herbicidal compositions comprising triazinone herbicide and als inhibitor herbicide and uses thereof |
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| Publication Number | Publication Date |
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| CN105792649A true CN105792649A (en) | 2016-07-20 |
| CN105792649B CN105792649B (en) | 2021-05-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201480064748.6A Expired - Fee Related CN105792649B (en) | 2013-11-28 | 2014-10-16 | Herbicidal composition containing triazinone herbicide and ALS inhibitor herbicide and use thereof |
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| Country | Link |
|---|---|
| CN (1) | CN105792649B (en) |
| AR (1) | AR098405A1 (en) |
| BR (1) | BR102013030594B1 (en) |
| TW (1) | TWI655903B (en) |
| WO (1) | WO2015078243A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107249328A (en) * | 2015-04-28 | 2017-10-13 | 龙灯农业化工国际有限公司 | Control the Herbicidal combinations and method of plant growth |
| CN110214788A (en) * | 2018-03-02 | 2019-09-10 | 柯磊浦（北京）国际贸易有限公司 | Oil tea forest land herbicides special |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112015020018B1 (en) | 2013-02-22 | 2021-02-02 | Ishihara Sangyo Kaisha, Ltd | herbicidal composition and process for controlling unwanted plants or inhibiting their growth |
| GB2545732B (en) * | 2015-12-23 | 2019-11-13 | Rotam Agrochem Int Co Ltd | Herbicidal composition and use thereof |
| GB2545726B (en) * | 2015-12-23 | 2020-06-17 | Rotam Agrochem Int Co Ltd | Herbicidal composition and method for controlling plant growth |
| PL3183966T3 (en) * | 2015-12-23 | 2021-11-29 | Rotam Agrochem International Co., Ltd | Method of controlling growth of als-tolerant plants |
| CN105746551A (en) * | 2016-03-14 | 2016-07-13 | 南京华洲药业有限公司 | Weeding composition containing trifloxysulfuron and metribuzin and application of weeding composition containing trifloxysulfuron and metribuzin |
| AR111415A1 (en) * | 2017-04-26 | 2019-07-10 | Adama Australia Pty Ltd | HERBICIDE FORMULATION |
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- 2013-11-28 BR BR102013030594-4A patent/BR102013030594B1/en not_active IP Right Cessation
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2014
- 2014-10-16 WO PCT/CN2014/088702 patent/WO2015078243A1/en active Application Filing
- 2014-10-16 CN CN201480064748.6A patent/CN105792649B/en not_active Expired - Fee Related
- 2014-11-13 AR ARP140104267A patent/AR098405A1/en active IP Right Grant
- 2014-11-26 TW TW103140911A patent/TWI655903B/en not_active IP Right Cessation
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| CN1181184A (en) * | 1997-11-12 | 1998-05-13 | 江苏省激素研究所 | Efficient weeding composition for non-cultivated land |
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| CN107249328A (en) * | 2015-04-28 | 2017-10-13 | 龙灯农业化工国际有限公司 | Control the Herbicidal combinations and method of plant growth |
| CN110214788A (en) * | 2018-03-02 | 2019-09-10 | 柯磊浦（北京）国际贸易有限公司 | Oil tea forest land herbicides special |
Also Published As
| Publication number | Publication date |
|---|---|
| BR102013030594A2 (en) | 2015-09-22 |
| CN105792649B (en) | 2021-05-07 |
| TWI655903B (en) | 2019-04-11 |
| TW201519768A (en) | 2015-06-01 |
| WO2015078243A1 (en) | 2015-06-04 |
| AR098405A1 (en) | 2016-05-26 |
| BR102013030594B1 (en) | 2019-06-25 |
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