CN105778759A - Asphalt paint for ship anchor chains and preparation method of asphalt paint - Google Patents

Asphalt paint for ship anchor chains and preparation method of asphalt paint Download PDF

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Publication number
CN105778759A
CN105778759A CN201610285080.9A CN201610285080A CN105778759A CN 105778759 A CN105778759 A CN 105778759A CN 201610285080 A CN201610285080 A CN 201610285080A CN 105778759 A CN105778759 A CN 105778759A
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CN
China
Prior art keywords
parts
paint
anchor chains
sufficiently mixed
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610285080.9A
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Chinese (zh)
Inventor
王和山
王和东
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Anhui Kailin New Material Co Ltd
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Anhui Kailin New Material Co Ltd
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Publication date
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Priority to CN201610285080.9A priority Critical patent/CN105778759A/en
Publication of CN105778759A publication Critical patent/CN105778759A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
    • C09D195/005—Aqueous compositions, e.g. emulsions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C09D5/103—Anti-corrosive paints containing metal dust containing Al
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses asphalt paint for ship anchor chains and a preparation method of the asphalt paint, and relates to the technical field of marine paint. The asphalt paint comprises, by weight, 40-50 parts of epoxy coal pitch, 10-14 parts of fluorocarbon resin, 10-15 parts of tephra, 8-11 parts of low-density polyethylene, 6-10 parts of disproportionated rosin, 6-10 parts of polyethylene glycol 6000 double-stearate, 5-8 parts of cetanol, 4-6 parts of Portland cement, 4-6 parts of adhesion promoter, 3-5 parts of carbomer resin, 3-5 parts of polyoxyethylene lauryl ether, 2-3 parts of urea, 1-2 parts of glass fiber powder, 1-2 parts of nano aluminum powder, 1-2 parts of sodium hexametaphosphate, 12-17 parts of paraffinic oil and 150-200 parts of water. The asphalt paint has the advantages that paint films with high adhesion force and strength can be formed quickly after the asphalt paint is sprayed onto the ship anchor chains; the paint films have excellent resistance to seawater corrosion, weather and water, and corrosion and damage of seawater and outdoor environment to the anchor chains can be reduced; preparation cost is low, and accordingly, investment is reduced.

Description

A kind of ship anchor chains asphalt caulk and preparation method thereof
Technical field:
The present invention relates to marine paint technical field, be specifically related to a kind of ship anchor chains asphalt caulk and preparation thereof Method.
Background technology:
Anchor chain is to connect the chain between anchor and hull, is used for transmitting and buffer the external force suffered by boats and ships, also The frictional force of a part can be produced.Owing to boats and ships are chronically in marine environment, the sea water corrosion to anchor chain Very serious, on anchor chain, rust staining layer by layer occurs after using a period of time.In order to protect anchor chain structure and prolongation Its service life, it will usually spray a coating on anchor chain.Although but the anchor chain coating used at present Anchor chain can be played certain corrosion-resisting function, but force limited, coating easily comes off, thus will be de- Outside the anchor chain of the part that falls is exposed to.
Summary of the invention:
The technical problem to be solved is to provide one to have excellent resistance to corrosion seawater, weather-proof Property and resistance to water and the low ship anchor chains asphalt caulk of preparation cost and preparation method thereof.
The technical problem to be solved uses following technical scheme to realize:
A kind of ship anchor chains asphalt caulk, is made up of the raw material of following parts by weight:
Epoxide coal bituminous 40-50 part, fluorocarbon resin 10-15 part, volcanic ash 10-15 part, low density polyethylene Alkene 8-11 part, disproportionated rosin 6-10 part, polyethylene glycol 6000 double stearate 6-10 part, spermol 5-8 Part, portland cement 4-6 part, adhesion promoter 4-6 part, carbomer 3-5 part, lauryl alcohol polyoxy Vinyl Ether 3-5 part, carbamide 2-3 part, glass powder 1-2 part, nanometer aluminium powder 1-2 part, sodium hexameta phosphate 1-2 Part, paraffin oil 12-17 part, water 150-200 part.
Described adhesion promoter is made up of the raw material of following parts by weight: terpene resin 10-15 part, activity Hargil 8-12 part, polyvinyl alcohol 8-12 part, microcrystalline Cellulose 6-10 part, hydroxypropyl guar gum 4-7 part, Petroleum coke 4-7 part, nanometer titanium dioxide 3-5 part, Oleum Ricini 2-4 part, PEG400 2-4 part, soap Powder 1-2 part, bone black 1-2 part, ethanol 50-60 part, its preparation method is: first add terpenes in ethanol Resin, petroleum coke and bone black, after being uniformly dispersed under microwave frequency 2450MHz, power 700W microwave Process 5min, add polyvinyl alcohol, hydroxypropyl guar gum and PEG400, continue after being sufficiently mixed Microwave treatment 10min, then sends into spray dryer by mixture, and powder made by the size-reduced machine of gained granule, It is eventually adding active hargil, microcrystalline Cellulose, nanometer titanium dioxide, Oleum Ricini and soap powder, is sufficiently mixed Uniformly.
The addition of this adhesion promoter can be effectively improved the paint film adhesive force in metal surface, reduces paint In use there is the probability of efflorescence and peeling phenomenon in film, and can strengthen paint film as filler Mechanical performance.
The preparation method of a kind of ship anchor chains asphalt caulk, comprises the steps:
(1) fluorocarbon resin and Low Density Polyethylene are sufficiently mixed, are first heated to 130-140 and are incubated mixing 10 Min, adds disproportionated rosin, adhesion promoter and paraffin oil, continues insulation mixing 10min, to obtain final product Material I；
(2) in water, the epoxide coal bituminous and double stearate of polyethylene glycol 6000 is added, in micro-after being sufficiently mixed Microwave treatment 5min under wave frequency 2450MHz, power 700W, is subsequently adding portland cement and Ka Bo Resin, continues microwave treatment 10min, obtains material II；
(3) in material II add material I, volcanic ash, spermol, polyoxyethylene lauryl ether, carbamide, Glass powder, nanometer aluminium powder and sodium hexameta phosphate, send in ball mill after being sufficiently mixed, be milled to fineness little In 50 μm.
The invention has the beneficial effects as follows: the present invention, with epoxide coal bituminous as primary raw material, is aided with fluorocarbon resin And multiple auxiliary agent prepares ship anchor chains asphalt caulk, this asphalt caulk is sprayed on ship anchor chains and can quickly be formed The paint film that adhesive force is extremely strong and hardness is big, this paint film has excellent resistance to corrosion seawater, weatherability and water-fast Property, can alleviate sea water and outdoor environment to the corrosion of anchor chain and loss, and preparation cost is low, thus subtract Use input less.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
(1) 12 parts of fluorocarbon resins and 8 parts of Low Density Polyethylenes are sufficiently mixed, are first heated to 130-140 insulation Mixing 10min, adds 6 parts of disproportionated rosins, 4 parts of adhesion promoters and 15 parts of paraffin oil, continues insulation Mixing 10min, obtains material I；
(2) in 150 parts of water, add 40 parts of epoxide coal bituminous and 6 parts of double stearates of polyethylene glycol 6000, fill Point mixing after under microwave frequency 2450MHz, power 700W microwave treatment 5min, be subsequently adding 5 parts of silicon Acid salt cement and 3 parts of carbomers, continue microwave treatment 10min, obtain material II；
(3) in material II, material I, 10 parts of volcanic ash, 6 parts of spermols, 5 parts of lauryl alcohol polyethylene glycol oxides are added Ether, 2 parts of carbamide, 2 parts of glass powder, 1 part of nanometer aluminium powder and 1 part of sodium hexameta phosphate, send into after being sufficiently mixed In ball mill, it is milled to fineness less than 50 μm.
The preparation of adhesion promoter: first add in 60 parts of ethanol 15 parts of terpene resins, 5 parts of petroleum cokes and 1 part of bone black, after being uniformly dispersed under microwave frequency 2450MHz, power 700W microwave treatment 5min, then Add 8 parts of polyvinyl alcohol, 4 parts of hydroxypropyl guar gum and 4 parts of PEG400s, continue micro-after being sufficiently mixed Ripple processes 10min, and then mixture is sent into spray dryer, and powder made by the size-reduced machine of gained granule, It is eventually adding 8 parts of active hargil, 6 parts of microcrystalline Cellulose, 4 parts of nanometer titanium dioxides, 3 parts of Oleum Ricini and 1 part of fertilizer Soap powder, is sufficiently mixed uniformly.
Embodiment 2
(1) 15 parts of fluorocarbon resins and 8 parts of Low Density Polyethylenes are sufficiently mixed, are first heated to 130-140 insulation Mixing 10min, adds 6 parts of disproportionated rosins, 6 parts of adhesion promoters and 12 parts of paraffin oil, continues insulation Mixing 10min, obtains material I；
(2) in 200 parts of water, add 50 parts of epoxide coal bituminous and 8 parts of double stearates of polyethylene glycol 6000, fill Point mixing after under microwave frequency 2450MHz, power 700W microwave treatment 5min, be subsequently adding 4 parts of silicon Acid salt cement and 4 parts of carbomers, continue microwave treatment 10min, obtain material II；
(3) in material II, material I, 15 parts of volcanic ash, 8 parts of spermols, 3 parts of lauryl alcohol polyethylene glycol oxides are added Ether, 3 parts of carbamide, 1 part of glass powder, 1 part of nanometer aluminium powder and 2 parts of sodium hexameta phosphate, send into after being sufficiently mixed In ball mill, it is milled to fineness less than 50 μm.
The preparation of adhesion promoter: first add in 50 parts of ethanol 10 parts of terpene resins, 4 parts of petroleum cokes and 2 parts of bone black, after being uniformly dispersed under microwave frequency 2450MHz, power 700W microwave treatment 5min, then Add 8 parts of polyvinyl alcohol, 6 parts of hydroxypropyl guar gum and 3 parts of PEG400s, continue micro-after being sufficiently mixed Ripple processes 10min, and then mixture is sent into spray dryer, and powder made by the size-reduced machine of gained granule, It is eventually adding 8 parts of active hargil, 6 parts of microcrystalline Cellulose, 3 parts of nanometer titanium dioxides, 4 parts of Oleum Ricini and 2 parts of fertilizer Soap powder, is sufficiently mixed uniformly.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (3)

1. a ship anchor chains asphalt caulk, it is characterised in that be made up of the raw material of following parts by weight:
Epoxide coal bituminous 40-50 part, fluorocarbon resin 10-15 part, volcanic ash 10-15 part, low density polyethylene Alkene 8-11 part, disproportionated rosin 6-10 part, polyethylene glycol 6000 double stearate 6-10 part, spermol 5-8 Part, portland cement 4-6 part, adhesion promoter 4-6 part, carbomer 3-5 part, lauryl alcohol polyoxy Vinyl Ether 3-5 part, carbamide 2-3 part, glass powder 1-2 part, nanometer aluminium powder 1-2 part, sodium hexameta phosphate 1-2 Part, paraffin oil 12-17 part, water 150-200 part.
Ship anchor chains asphalt caulk the most according to claim 1, it is characterised in that described adhesive force Accelerator is made up of the raw material of following parts by weight: terpene resin 10-15 part, active hargil 8-12 part, Polyvinyl alcohol 8-12 part, microcrystalline Cellulose 6-10 part, hydroxypropyl guar gum 4-7 part, petroleum coke 4-7 part, Nanometer titanium dioxide 3-5 part, Oleum Ricini 2-4 part, PEG400 2-4 part, soap powder 1-2 part, bone black 1-2 part, ethanol 50-60 part, its preparation method is: first add in ethanol terpene resin, petroleum coke and Bone black, after being uniformly dispersed under microwave frequency 2450MHz, power 700W microwave treatment 5min, then add Enter polyvinyl alcohol, hydroxypropyl guar gum and PEG400, after being sufficiently mixed, continue microwave treatment 10min, Then mixture is sent into spray dryer, and the size-reduced machine of gained granule is made powder, is eventually adding activity Hargil, microcrystalline Cellulose, nanometer titanium dioxide, Oleum Ricini and soap powder, be sufficiently mixed uniformly.
3. the preparation method of a ship anchor chains asphalt caulk, it is characterised in that comprise the steps:
(1) fluorocarbon resin and Low Density Polyethylene are sufficiently mixed, are first heated to 130-140 and are incubated mixing 10 Min, adds disproportionated rosin, adhesion promoter and paraffin oil, continues insulation mixing 10min, to obtain final product Material I；
(2) in water, the epoxide coal bituminous and double stearate of polyethylene glycol 6000 is added, in micro-after being sufficiently mixed Microwave treatment 5min under wave frequency 2450MHz, power 700W, is subsequently adding portland cement and Ka Bo Resin, continues microwave treatment 10min, obtains material II；
(3) in material II add material I, volcanic ash, spermol, polyoxyethylene lauryl ether, carbamide, Glass powder, nanometer aluminium powder and sodium hexameta phosphate, send in ball mill after being sufficiently mixed, be milled to fineness little In 50 μm.
CN201610285080.9A 2016-04-28 2016-04-28 Asphalt paint for ship anchor chains and preparation method of asphalt paint Pending CN105778759A (en)

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CN201610285080.9A CN105778759A (en) 2016-04-28 2016-04-28 Asphalt paint for ship anchor chains and preparation method of asphalt paint

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Application Number Priority Date Filing Date Title
CN201610285080.9A CN105778759A (en) 2016-04-28 2016-04-28 Asphalt paint for ship anchor chains and preparation method of asphalt paint

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CN105778759A true CN105778759A (en) 2016-07-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281010A (en) * 2016-08-10 2017-01-04 东至县洋湖镇希望皮具厂 A kind of PU leather limit oil and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85103608A (en) * 1985-05-17 1985-12-20 石油工业部管道科学研究院 Thick slurry type of epoxide coal bituminous coating
CN1492013A (en) * 2002-10-24 2004-04-28 张晓广 Anti-corrosion paint particularly for pipeline inner wall
CN102250527A (en) * 2011-07-06 2011-11-23 常熟市方塔涂料化工有限公司 Preparation method of epoxy coal tar anti-corrosive paint
CN105273625A (en) * 2014-07-11 2016-01-27 江苏欣安新材料技术有限公司 Preparation method for high-build epoxy coating and prepared coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85103608A (en) * 1985-05-17 1985-12-20 石油工业部管道科学研究院 Thick slurry type of epoxide coal bituminous coating
CN1492013A (en) * 2002-10-24 2004-04-28 张晓广 Anti-corrosion paint particularly for pipeline inner wall
CN102250527A (en) * 2011-07-06 2011-11-23 常熟市方塔涂料化工有限公司 Preparation method of epoxy coal tar anti-corrosive paint
CN105273625A (en) * 2014-07-11 2016-01-27 江苏欣安新材料技术有限公司 Preparation method for high-build epoxy coating and prepared coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281010A (en) * 2016-08-10 2017-01-04 东至县洋湖镇希望皮具厂 A kind of PU leather limit oil and preparation method thereof

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Application publication date: 20160720

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