CN105778282A - Composite conductive plastic - Google Patents

Composite conductive plastic Download PDF

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Publication number
CN105778282A
CN105778282A CN201610160637.6A CN201610160637A CN105778282A CN 105778282 A CN105778282 A CN 105778282A CN 201610160637 A CN201610160637 A CN 201610160637A CN 105778282 A CN105778282 A CN 105778282A
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CN
China
Prior art keywords
parts
conductive plastic
composite conductive
composite
chopped
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610160637.6A
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Chinese (zh)
Inventor
周建
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Xiangyuan Special Fine Chemical Co Ltd
Original Assignee
Suzhou Xiangyuan Special Fine Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Xiangyuan Special Fine Chemical Co Ltd filed Critical Suzhou Xiangyuan Special Fine Chemical Co Ltd
Priority to CN201610160637.6A priority Critical patent/CN105778282A/en
Publication of CN105778282A publication Critical patent/CN105778282A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses composite conductive plastic. The composite conductive plastic comprises, by weight, 20-30 parts of polypropylene, 10-20 parts of POE, 10-15 parts of SEBS, 5-10 parts of melamine resin, 5-8 parts of stainless steel fiber, 10-15 parts of chopped polyester silver-plated fiber, 5-10 parts of chopped carbon fiber, 5-10 parts of conductive carbon black, 3-5 parts of methyl silicone oil, 3-4 parts of barium stearate, 5-8 parts of silane coupling agent and 1-3 parts of antioxidant. The volume resistivity of the composite conductive plastic is 0.15-0.2ohm cm, the tensile strength of the composite conductive plastic is higher than 58MPa, and the breaking elongation rate of the breaking elongation is larger than 10%. The composite conductive plastic has the advantages that various base materials and conductive fibers are used to allow the conductive plastic to have both excellent conductive performance and excellent mechanical performance, and the composite conductive plastic is excellent in comprehensive performance and promising in market prospect.

Description

A kind of composite conductive plastic
Technical field
The present invention relates to conductive plastics field, particularly relate to a kind of composite conductive plastic.
Background technology
Conductive plastics is to be mixed by resin and conductive materials, the functional macromolecule material being processed with the processing mode of plastics, is widely used in electronics and appliance field, the shell of anti-explosion product and structural member, cable the shielding shell of semiconductive shieldin material and the electronic product used.
Existing conductive plastics relies on single conductive filler to be difficult to prepare low resistance conductive composite, and when filler is more, mechanical properties decrease is serious, and resin matrix kind is single so that the combination property of conductive plastics is not enough.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of composite conductive plastic, it is possible to solve the weak point that existing conductive plastics exists.
For solving above-mentioned technical problem, the technical scheme that the present invention adopts is: provide a kind of composite conductive plastic, including following parts by weight of component: polypropylene 20~30 parts, POE10~20 part, SEBS10~15 part, melamine resin 5~10 parts, stainless steel fibre 5~8 parts, chopped polyester silver plated fiber 10~15 parts, chopped carbon fiber 5~10 parts, conductive black 5~10 parts, methyl-silicone oil 3~5 parts, barium stearate 3~4 parts, silane coupler 5~8 parts, 1~3 part of antioxidant.
In a preferred embodiment of the present invention, described silane coupler is VTES.
In a preferred embodiment of the present invention, the particle diameter of described conductive black is 10~30nm.
In a preferred embodiment of the present invention, the diameter of described stainless steel fibre is 0.5~2 μm, and length is 3~5mm.
In a preferred embodiment of the present invention, the diameter of described chopped polyester silver plated fiber is 0.5~3 μm, and length is 30~100 μm.
The invention has the beneficial effects as follows: one composite conductive plastic of the present invention, selection by multiple matrix material and conductive fiber so that conductive filler is possessing on the basis of superior electrical conductivity energy, has the mechanical performance of excellence concurrently, excellent combination property, wide market.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention being made apparent clear and definite defining.
The embodiment of the present invention includes:
Embodiment 1
A kind of composite conductive plastic, including following parts by weight of component: polypropylene 20 parts, POE10 part, SEBS10 part, melamine resin 5 parts, stainless steel fibre 5 parts, chopped polyester silver plated fiber 10 parts, chopped carbon fiber 5 parts, conductive black 5 parts, methyl-silicone oil 3 parts, barium stearate 3 parts, silane coupler--VTES 5 parts, antioxidant 1010 1 part.Wherein, the particle diameter of described conductive black is 10~30nm;The diameter of described stainless steel fibre is 0.5~2 μm, and length is 3~5mm;The diameter of described chopped polyester silver plated fiber is 0.5~3 μm, and length is 30~100 μm.
Embodiment 2
A kind of composite conductive plastic, including following parts by weight of component: polypropylene 30 parts, POE20 part, SEBS15 part, melamine resin 10 parts, stainless steel fibre 8 parts, chopped polyester silver plated fiber 15 parts, chopped carbon fiber 10 parts, conductive black 10 parts, methyl-silicone oil 5 parts, barium stearate 4 parts, silane coupler--VTES 8 parts, 3 parts of antioxidant.Wherein, the particle diameter of described conductive black is 10~30nm;The diameter of described stainless steel fibre is 0.5~2 μm, and length is 3~5mm;The diameter of described chopped polyester silver plated fiber is 0.5~3 μm, and length is 30~100 μm.
Above-mentioned composite conductive plastic, after tested, its specific insulation is 0.15~0.2 Ω cm, and hot strength is higher than 58MPa, and elongation at break is more than 10%.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the present invention to make or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, all in like manner include in the scope of patent protection of the present invention.

Claims (5)

1. a composite conductive plastic, it is characterized in that, including following parts by weight of component: polypropylene 20~30 parts, POE10~20 part, SEBS10~15 part, melamine resin 5~10 parts, stainless steel fibre 5~8 parts, chopped polyester silver plated fiber 10~15 parts, chopped carbon fiber 5~10 parts, conductive black 5~10 parts, methyl-silicone oil 3~5 parts, barium stearate 3~4 parts, silane coupler 5~8 parts, 1~3 part of antioxidant.
2. composite conductive plastic according to claim 1, it is characterised in that described silane coupler is VTES.
3. composite conductive plastic according to claim 1, it is characterised in that the particle diameter of described conductive black is 10~30nm.
4. composite conductive plastic according to claim 1, it is characterised in that the diameter of described stainless steel fibre is 0.5~2 μm, length is 3~5mm.
5. composite conductive plastic according to claim 1, it is characterised in that the diameter of described chopped polyester silver plated fiber is 0.5~3 μm, and length is 30~100 μm.
CN201610160637.6A 2016-03-21 2016-03-21 Composite conductive plastic Pending CN105778282A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610160637.6A CN105778282A (en) 2016-03-21 2016-03-21 Composite conductive plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610160637.6A CN105778282A (en) 2016-03-21 2016-03-21 Composite conductive plastic

Publications (1)

Publication Number Publication Date
CN105778282A true CN105778282A (en) 2016-07-20

Family

ID=56394196

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610160637.6A Pending CN105778282A (en) 2016-03-21 2016-03-21 Composite conductive plastic

Country Status (1)

Country Link
CN (1) CN105778282A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109735111A (en) * 2018-12-20 2019-05-10 上海衣页信息科技有限公司 The highly conductive sticky add-on type conductive silicon rubber of one kind and preparation method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1761706A (en) * 2003-03-14 2006-04-19 陶氏环球技术公司 Electrically conductive thermoplastic polymer composition
CN102070830A (en) * 2010-12-21 2011-05-25 上海林洋储能科技有限公司 Highly conductive composite material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1761706A (en) * 2003-03-14 2006-04-19 陶氏环球技术公司 Electrically conductive thermoplastic polymer composition
CN102070830A (en) * 2010-12-21 2011-05-25 上海林洋储能科技有限公司 Highly conductive composite material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李昭: "三聚氰胺树脂的合成工艺研究", 《山东化工》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109735111A (en) * 2018-12-20 2019-05-10 上海衣页信息科技有限公司 The highly conductive sticky add-on type conductive silicon rubber of one kind and preparation method

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Application publication date: 20160720

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