CN105776440B - The water treatment facilities of fluorine ion in a kind of absorption water - Google Patents
The water treatment facilities of fluorine ion in a kind of absorption water Download PDFInfo
- Publication number
- CN105776440B CN105776440B CN201610136032.3A CN201610136032A CN105776440B CN 105776440 B CN105776440 B CN 105776440B CN 201610136032 A CN201610136032 A CN 201610136032A CN 105776440 B CN105776440 B CN 105776440B
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- CN
- China
- Prior art keywords
- water
- juicer
- pipeline
- treatment facilities
- fluorine ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 56
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title claims abstract description 27
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 12
- 230000001105 regulatory effect Effects 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 abstract description 7
- 239000011737 fluorine Substances 0.000 abstract description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract description 6
- 235000015203 fruit juice Nutrition 0.000 abstract description 6
- 238000000034 method Methods 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 239000003463 adsorbent Substances 0.000 description 4
- 239000003651 drinking water Substances 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 208000004042 dental fluorosis Diseases 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 206010016818 Fluorosis Diseases 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002384 drinking water standard Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
- C02F2001/46138—Electrodes comprising a substrate and a coating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
- C02F2101/14—Fluorine or fluorine-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Electrochemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a kind of water treatment facilities of fluorine ion in absorption water, including：The both ends of electrolytic cell, effluent trough and interconnecting part, interconnecting part are connected to electrolytic cell and effluent trough respectively；Interconnecting part includes water supply pipe and feed portion, and feed portion includes the first pipeline, juicer, and juicer is in cone, and surface is equipped with several first through hole, and the fin that multiple sections are triangle is additionally provided on the conical surface of juicer；And lid, it can constitute by the unclosed circular groove in both ends and along the blind end that circular groove length direction moves, a pull rod be vertically and fixedly provided on blind end, one end of circular groove is equipped with the annular seal ring for preventing blind end from removing circular groove.Water treatment facilities of the present invention can be dual-purpose, occupies small, and fluoride removing rate is high, and the fluorine removal time is short, while can be used as juicer when citizen think drink fruit juices, it is very convenient with it is multi-functional.
Description
Technical field
The invention belongs to technical field of water treatment, it is more particularly related to fluorine ion in a kind of absorption water
Water treatment facilities.
Background technology
Fluorinated volume must not exceed 1mg/L in China's drinking water standard (GB5749-2006) regulation drinking water.Human body is long
Phase, which drinks high-fluorine water, can cause fluorine poisoning, show as den tal fluorosis, fluorosis of bone.Absorption method fluorine removal is that current water process fluorine removal process is answered
With widest method, adsorbent mainly active aluminium oxide, bone black and zeolite, but pass through absorption method and need a large amount of absorption
Agent, and adsorbent is usually some chemical substances, and a certain amount of adsorbent how much can be contained in last drinking water, people takes for a long time
With can be impacted to body.It is longer using the time used in adsorbent absorption fluorine simultaneously, in order to shorten the time, it is desirable to provide one
The device of fluorine ion in the more efficient absorption water of kind.
Invention content
It is excellent it is an object of the invention to solve at least the above and/or defect, and provide at least to will be described later
Point.
A further object of the invention be by the way that self-made electrode is arranged in water treatment facilities, provide it is a kind of it is easy to operate,
The water treatment facilities that easy to implement, cheap, family can use by oneself adsorbs the ability of fluorine ion in water with realization device.
In order to realize these purposes and other advantages according to the present invention, a kind of adsorb in water at the water of fluorine ion is provided
Device is managed, including：The both ends of electrolytic cell, effluent trough and interconnecting part, interconnecting part are connected to electrolytic cell and effluent trough respectively；
Wherein, interconnecting part includes：
One end of water supply pipe, water supply pipe is connected to electrolytic cell；And
Feed portion comprising：
First pipeline, the first pipeline be equipped with the first branch line and second branched pipe road, first point
Bye-pass is connected to second branched pipe Lu Junyu effluent troughs；
Juicer, juicer are in cone, and surface is equipped with several first through hole, the cone of juicer
The fin that multiple sections are triangle is additionally provided on face；
Lid, by the unclosed circular groove in both ends and can be along the blind end structure that circular groove length direction moves
At being vertically and fixedly provided with a pull rod on blind end, one end of circular groove, which is equipped with, prevents blind end from removing circular groove
Annular seal ring；
Wherein, one end of the first pipeline is connected to the other end of water supply pipe, and the other end and the juicer of the first pipeline can
Dismounting is fixedly connected, and lid is arranged juicer, and is detachably secured to the other end of the first pipeline.
Preferably, wherein the electrode in electrolytic cell is made of collector with the gel layer for being set to collector surface；Its
There is the second through-hole of perforation on middle collector, several conical protrusions are provided in the second through-hole.
Preferably, wherein the bottom of electrolytic cell and effluent trough is equipped with supporting table, and supporting table is in rectangular parallelepiped structure, in
Portion is in hollow form to accommodate interconnecting part.
Preferably, wherein the side wall of effluent trough is equipped with tap.
Preferably, wherein the dismountable fixation of the other end of juicer and the first pipeline is by the bottom of juicer
External screw thread is arranged in portion, is realized in the other end setting internal thread of the first pipeline；The other end of lid and the first pipeline is removable
The fixation unloaded is that internal thread is arranged by the other end of the circular groove in lid, real in the other end setting external screw thread of the first pipeline
Existing.
Preferably, wherein the first branch line is disposed in proximity to the side of electrolytic cell, and second branched pipe road, which is set to, to be leaned on
The side of nearly juicer, effluent trough are provided with filter mantle with second branched pipe road connectivity part.
Preferably, wherein the aperture of filter mantle is 0.5-1.5mm.
Preferably, wherein the first regulating valve is provided on water supply pipe.
Preferably, wherein be provided with the second regulating valve on the first pipeline, be located at the first branch line and the second branch
Between pipeline.
The present invention includes at least following advantageous effect：
1, go Natural zeolite using special electrode, in collector the fluoride ion removing in water using electrolytic cell
Gel layer is arranged in surface, and gel layer is that the degree of polymerization is larger, made of the rubber chain aggregation with branch or cross-linked structure
The middle layer of rubber particles can in a relatively short period of time adsorb the fluorine ion in water after energization, be inhaled compared to tradition
Attached dose, speed is doubled.
2, the water treatment facilities of fluorine ion can be used as direct drinking water in absorption water of the invention, therefore, in interconnecting part
Equipped with juicer, small bulk can be cut the fruit into and be positioned in lid, lid and the first pipeline are fixed, pushed and covered by pull rod
Body makes fruit chunk in juicer mantle friction, and fruit juice of squeezing out makes the first through hole that fruit juice passes through juicer enter the first pipeline,
Effluent trough is entered by second branched pipe road later.
3, filter mantle is set in effluent trough and second branched pipe road connectivity part, prevents pulp in juicer from first through hole
Into effluent trough, avoid having suspended matter in effluent trough.
4, the second regulating valve of setting can prevent the fruit juice in juicer from entering in electrolytic cell when the second regulating valve is closed,
The work of electrolytic cell is influenced, if close the first regulating valve, the second regulating valve can be opened, fruit juice is accelerated to enter effluent trough.
5, second through-hole is set on the current collector and conical protrusions are set in the second through-hole, can be improved collector and
Adhesion between gel layer, while can effectively reduce impedance.
6, water treatment facilities of the present invention can be dual-purpose, and occupancy is small, and fluoride removing rate is high, and the fluorine removal time is short, while can be in citizen
When thinking drink fruit juices, can be used as juicer, it is very convenient with it is multi-functional.
Part is illustrated to embody by further advantage, target and the feature of the present invention by following, and part will also be by this
The research and practice of invention and be understood by the person skilled in the art.
Description of the drawings
Fig. 1 is the structural schematic diagram for adsorbing the water treatment facilities of fluorine ion in water of the present invention；
Fig. 2 is the structural schematic diagram of the juicer of the present invention.
Specific implementation mode
Present invention will be described in further detail below with reference to the accompanying drawings, to enable those skilled in the art with reference to specification text
Word can be implemented according to this.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein do not allot one or more
The presence or addition of a other elements or combinations thereof.
Fig. 1-2 shows a kind of way of realization according to the present invention, provides a kind of water process for adsorbing fluorine ion in water
Device, including：Electrolytic cell 100, effluent trough 200 and interconnecting part 300, the both ends of interconnecting part 300 respectively with electrolytic cell 100 and water outlet
Slot 200 is connected to；
Wherein, interconnecting part 300 includes：
One end of water supply pipe 310, water supply pipe 310 is connected to electrolytic cell 100；And
Feed portion 320 comprising：
First pipeline 321, the first pipeline 321 are equipped with the first branch line and second branched pipe road, the first branch line
It is connected to second branched pipe Lu Junyu effluent troughs 200；
Juicer 330, juicer 330 are in cone, and surface is equipped with several first through hole 333, the conical surface of juicer 330
On be additionally provided with multiple sections be triangle fin 332；
Lid 322 can be constituted by the unclosed circular groove in both ends and along the blind end that circular groove length direction moves, blind end
On be vertically and fixedly provided with a pull rod, one end of circular groove is equipped with the annular seal ring for preventing blind end from removing circular groove；
Wherein, one end of the first pipeline 321 is connected to the other end of water supply pipe 310, the other end of the first pipeline 321 with
Juicer 330 is removably fixedly connected, and juicer 330 is set in its circular groove by lid 322, and is detachably secured to
The other end of one pipeline 321.
Wherein, the electrode 110 in electrolytic cell 100 is made of collector with the gel layer for being set to collector surface；Wherein
There is the second through-hole of perforation on collector, several conical protrusions are provided in the second through-hole.
Wherein, the bottom of electrolytic cell 100 and effluent trough 200 is equipped with supporting table 400, and supporting table 400 is in rectangular parallelepiped structure,
Inside is in hollow form to accommodate interconnecting part 300.
Wherein, the side wall of effluent trough 200 is equipped with tap 210.
Wherein, the dismountable fixation of the other end of juicer 330 and the first pipeline 321 is by the bottom of juicer 330
External screw thread 331 is arranged in portion, is realized in the other end setting internal thread of the first pipeline 321；Lid 322 and the first pipeline 321
Dismountable fixation of the other end be other end setting internal thread by the circular groove in lid 322, in the another of the first pipeline 321
One end is arranged external screw thread to realize.
Wherein, the first branch line is disposed in proximity to the side of electrolytic cell 100, and second branched pipe road is disposed in proximity to squeeze the juice
The side of device 330, effluent trough 200 are provided with filter mantle 220 with second branched pipe road connectivity part.
Wherein, the aperture of filter mantle 220 is 0.5-1.5mm.
Wherein, the first regulating valve 311 is provided on water supply pipe 310.
Wherein, it is provided with the second regulating valve 323 on the first pipeline 321, is located at the first branch line and second branched pipe
Between road.
Advantageous effect in order to further illustrate the present invention, the comparison for providing fluorine ion adsorption rate are as follows：
1 fluorine ion adsorption rate of table compares
By table 1, it can be seen that, the present invention is adsorbed with using aluminium oxide in water compared with fluorine ion method, adsorbs fluorine ion
Time it is shorter, and in the unit interval, the adsorption rate higher of fluorine ion.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details and legend shown and described herein.
Claims (8)
1. the water treatment facilities of fluorine ion in a kind of absorption water, which is characterized in that including：Electrolytic cell, effluent trough and interconnecting part, even
The both ends in logical portion are connected to electrolytic cell and effluent trough respectively；
Wherein, interconnecting part includes：
One end of water supply pipe, water supply pipe is connected to electrolytic cell；And
Feed portion comprising：
First pipeline, the first pipeline are equipped with the first branch line and second branched pipe road, the first branch line and the second branch
Pipeline is connected to effluent trough；
Juicer, juicer are in cone, and surface is equipped with several first through hole, multiple sections are additionally provided on the conical surface of juicer
For the fin of triangle；
Lid can be constituted by the unclosed circular groove in both ends and along the blind end that circular groove length direction moves, vertical on blind end
It is fixed with a pull rod, one end of circular groove is equipped with the annular seal ring for preventing blind end from removing circular groove；
Wherein, one end of the first pipeline is connected to the other end of water supply pipe, and the other end and juicer of the first pipeline are detachable
Be fixedly connected, lid is arranged juicer, and is detachably secured to the other end of the first pipeline；
Electrode in electrolytic cell is made of collector with the gel layer for being set to collector surface；There is perforation wherein on collector
The second through-hole, be provided with several conical protrusions in the second through-hole.
2. as described in claim 1 in absorption water fluorine ion water treatment facilities, which is characterized in that electrolytic cell and effluent trough
Bottom is equipped with supporting table, and supporting table is in rectangular parallelepiped structure, and inside is in hollow form to accommodate interconnecting part.
3. adsorbing the water treatment facilities of fluorine ion in water as claimed in claim 2, which is characterized in that the side wall of effluent trough is equipped with
Tap.
4. adsorbing the water treatment facilities of fluorine ion in water as claimed in claim 3, which is characterized in that juicer and the first pipeline
Dismountable fixation of the other end be by the way that external screw thread is arranged in the bottom of juicer, in the interior spiral shell of other end setting of the first pipeline
Line is realized；The dismountable fixation of the other end of lid and the first pipeline is in the other end setting by the circular groove in lid
Screw thread is realized in the other end setting external screw thread of the first pipeline.
5. adsorbing the water treatment facilities of fluorine ion in water as claimed in claim 4, which is characterized in that the first branch line is arranged
In close to the side of electrolytic cell, second branched pipe road is disposed in proximity to the side of juicer, and effluent trough connects with second branched pipe road
Logical place is provided with filter mantle.
6. adsorbing the water treatment facilities of fluorine ion in water as claimed in claim 5, which is characterized in that the aperture of filter mantle is
0.5-1.5mm。
7. adsorbing the water treatment facilities of fluorine ion in water as claimed in claim 6, which is characterized in that be provided on water supply pipe
First regulating valve.
8. adsorbing the water treatment facilities of fluorine ion in water as claimed in claim 7, which is characterized in that be provided on the first pipeline
Second regulating valve, between the first branch line and second branched pipe road.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2015105230733 | 2015-08-25 | ||
| CN201510523073 | 2015-08-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105776440A CN105776440A (en) | 2016-07-20 |
| CN105776440B true CN105776440B (en) | 2018-07-17 |
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ID=56388415
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610136032.3A Active CN105776440B (en) | 2015-08-25 | 2016-03-10 | The water treatment facilities of fluorine ion in a kind of absorption water |
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| CN (1) | CN105776440B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110255788B (en) * | 2019-07-29 | 2021-09-28 | 马鞍山市新桥工业设计有限公司 | Garbage sorting pretreatment system |
| CN110282790A (en) * | 2019-07-29 | 2019-09-27 | 马鞍山市新桥工业设计有限公司 | A kind of self-cleaning sewage disposal device |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2079614U (en) * | 1990-12-19 | 1991-06-26 | 新疆维吾尔自治区环境保护科学研究所 | Device for f content reducing treatment of drinking water |
| CN1609011A (en) * | 2003-10-17 | 2005-04-27 | 财团法人工业技术研究院 | Electrolytic bath for processing waste liquid containing high concentration cyanide |
| JP5634759B2 (en) * | 2010-06-16 | 2014-12-03 | 日本植生株式会社 | Fluorine removal method and fluorine removal system |
-
2016
- 2016-03-10 CN CN201610136032.3A patent/CN105776440B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2079614U (en) * | 1990-12-19 | 1991-06-26 | 新疆维吾尔自治区环境保护科学研究所 | Device for f content reducing treatment of drinking water |
| CN1609011A (en) * | 2003-10-17 | 2005-04-27 | 财团法人工业技术研究院 | Electrolytic bath for processing waste liquid containing high concentration cyanide |
| JP5634759B2 (en) * | 2010-06-16 | 2014-12-03 | 日本植生株式会社 | Fluorine removal method and fluorine removal system |
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| CN105776440A (en) | 2016-07-20 |
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Effective date of registration: 20180528 Address after: 536100 2 Qingyun South Road, Lian Zhou Town, Hepu County, Beihai, the Guangxi Zhuang Autonomous Region Applicant after: Chen Dexing Address before: 536100 No. 10, Huan Zhu Road, Hepu Town, Hepu City, the Guangxi Zhuang Autonomous Region Applicant before: Luo Jiezhi |
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