CN105772990A - Titanic-acid stainless steel welding electrode and manufacturing method thereof - Google Patents
Titanic-acid stainless steel welding electrode and manufacturing method thereof Download PDFInfo
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- CN105772990A CN105772990A CN201610247088.6A CN201610247088A CN105772990A CN 105772990 A CN105772990 A CN 105772990A CN 201610247088 A CN201610247088 A CN 201610247088A CN 105772990 A CN105772990 A CN 105772990A
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/365—Selection of non-metallic compositions of coating materials either alone or conjoint with selection of soldering or welding materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/40—Making wire or rods for soldering or welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/40—Making wire or rods for soldering or welding
- B23K35/404—Coated rods; Coated electrodes
Abstract
The invention discloses a titanic-acid stainless steel welding electrode and a manufacturing method thereof. The titanic-acid stainless steel welding electrode comprises a core wire and a coating, wherein the coating comprises the following ingredients in parts by weight: 20-40 parts of rutile, 5-10 parts of marble, 5-10 parts of X-type titanium dioxide, 4-12 parts of fluorite, 10-20 parts of gold feldspar, 2-8 parts of ferrotitanium, 5-10 parts of phlogopite, 8-20 parts of micro-carbon ferrochrome, 0.1-1 part of antimony oxide, 3-10 parts of electrolytic manganese, 2-8 parts of potassium titanate and 3-10 parts of Haitai powder. The titanic-acid stainless steel welding electrode and the manufacturing method have the advantages that the surface tension of a molten drop is reduced, so as to achieve a fine molten drop spraying process; and not only is the welding efficiency improved, is the welding period shortened, and are the tendencies to redness and cracking reduced, but also the technological performance is improved.
Description
Technical field
The disclosure relates generally to welding technology field, is specifically related to welding rod field, particularly relates to one
Plant metatitanic acid type stainless steel electrode and manufacture method thereof.
Background technology
Stainless steel electrode can be divided into straight-chromiun stainless steel welding rod and chromium nickel stainless steel welding rod, this two classes welding rod
In all that meet GB, all by GB GB/T983-1995 regulation examination.Straight-chromiun stainless steel has
Certain anti-corrosion (oxidizing acid, organic acid, cavitation erosion) heat-resisting and corrosion resisting property.The most selected
Make the equipment and materials such as power station, chemical industry, oil.But straight-chromiun stainless steel generally solderability is poor,
It should be noted that welding procedure, heat treatment condition and select suitable welding rod.Chromium nickel stainless steel welding rod
There is good corrosion resistance and non-oxidizability, be widely used in chemical industry, chemical fertilizer, oil, medical treatment
Machine-building.For preventing from producing intercrystalline corrosion due to heating, welding current should not be too big, than
Carbon steel less about 20%, electric arc is unsuitable long, and interlayer rapid cooling is advisable with string(er) bead.
The resistance to rubescent high efficiency stainless steel electrode of metatitanic acid Ultra-low carbon, have resistance to rubescent, splash little,
Striking and restarting is good, the de-features such as slag is easy, weld seam is attractive in appearance, has broad at present
Application.
In prior art, in use, there is welding efficiency relatively in metatitanic acid type stainless steel electrode
The problems such as the easy rubescent cracking of low, length weld interval, weld seam, processing performance difference.
Summary of the invention
In view of drawbacks described above of the prior art or deficiency, it is desirable to provide a kind of weld interval short,
Efficiency is high, improve the metatitanic acid type stainless steel electrode of weld seam processing performance.
The present invention provides a kind of metatitanic acid type stainless steel electrode, including core wire and coating, with weight portion
Number meter, the coating of metatitanic acid type stainless steel electrode comprises following components:
Rutile: 20-40 part, marble: 5-10 part, X-type titanium dioxide: 5-10 part, firefly
Stone: 4-12 part, gold Anhydrite: 10-20 part, ferrotianium: 2-8 part, phlogopite: 5-10 part, micro-
Carbon ferrochrome: 8-20 part, stibium oxide: 0.1-1 part, electrolytic manganese: 3-10 part, potassium titanate: 2-8
Part, Haitai powder: 3-10 part;
Core wire is H08Cr21Ni10Core wire, in terms of parts by weight, core wire comprises following components:
C:0.030~0.080 part, Si:0.25~0.60 part, Mn:1.0~2.0 parts, Cr:
18~22 parts, Ni:8-11 part, S is less than 0.020 part, and P is less than 0.025 part.
In coating, the mass component content of each component, granularity requirement are:
Marble: CaCO3> 96%, S < 0.03%, P < 0.03%, granularity is 40-180 mesh;
Fluorite: CaF2> 96%, S < 0.03%, P < 0.02%, granularity is 40-180 mesh;
Rutile: TiO > 90%, S < 0.03%, P < 0.04%, granularity is 40-160 mesh;
X-type titanium dioxide: TiO > 98%, S < 0.05%, P < 0.05%, granularity is 120-200 mesh;
Gold Anhydrite: SiO2: 63-73%, AL2O3: 15-24%, K2O and Na2Total amount >=12% of O,
S≤0.050%, P≤0.050%, granularity is 40-200 mesh;
Ferrotianium: Mn > 75%, S < 0.03%, P < 0.33%, granularity is 80-120 mesh;
Phlogopite: SiO2: 45-55%, AL2O3: 25-35%, K2O and Na2Total amount >=7% of O,
S≤0.030%, P≤0.040%, granularity is 10-60 mesh;
Chromic carbide iron: Cr:64~67%, C≤0.03%, S≤0.025%, P≤0.030%, granularity
For 20-160 mesh;
Stibium oxide: Sb2O3>=99%, granularity is 140-160 mesh;
Electrolytic manganese: Mn >=99.5%, S≤0.10%, P≤0.010%, C≤0.08%, granularity
For 40-160 mesh;
Potassium titanate: KaCO3>=96%, S≤0.05%, P≤0.05%, granularity is 180-200
Mesh;
Haitai powder: CaCO3> 80%, CaF2> 60%, S < 0.03%, P < 0.03%, granularity is
40-180 mesh.
The present invention provides the manufacture method of a kind of metatitanic acid type stainless steel electrode, the steps include:
Make the coating of metatitanic acid type stainless steel electrode, count by weight, take following components:
Rutile: 20-40 part, marble: 5-10 part, X-type titanium dioxide: 5-10 part, firefly
Stone: 4-12 part, gold Anhydrite: 10-20 part, ferrotianium: 2-8 part, phlogopite: 5-10 part, micro-
Carbon ferrochrome: 8-20 part, stibium oxide: 0.1-1 part, electrolytic manganese: 3-10 part, potassium titanate: 2-8
Part, Haitai powder: 3-10 part;
The component of acquirement is dry mixed, is subsequently adding waterglass, continue stirring, make patent medicine
Skin;
Being evenly coated on core wire by coating after stirring, suppression electrode, wherein core wire is
H08Cr21Ni10Core wire, in terms of parts by weight, core wire comprises following components:
C:0.030~0.080 part, Si:0.25~0.60 part, Mn:1.0~2.0 parts, Cr:
18~22 parts, Ni:8~11 parts, S is less than 0.020 part, and P is less than 0.025 part;
Compressing welding rod is sent into after natural drying high temperature drying stove bakee.
The metatitanic acid type rustless steel weldering that the metatitanic acid type stainless steel electrode of the present invention and manufacture method thereof manufacture
Bar, reduces the content of calcite and fluorite in coating component, and introduces potassium titanate novel-section
Material, is greatly lowered the surface tension of molten of liquid, thus becomes the most molten course of injection, both
Improve welding efficiency, shorten weld interval, reduce rubescent tearing tendency, improve again processing performance.
Detailed description of the invention
Below in conjunction with embodiment, the application is described in further detail.It is understood that
Specific embodiment described herein is used only for explaining related invention, rather than the limit to this invention
Fixed.
It should be noted that in the case of not conflicting, the embodiment in the application and embodiment
In feature can be mutually combined.The application is described in detail below with reference to embodiment.
Embodiment one
Count by weight, take following components:
Rutile: 20 parts, marble: 5 parts, X-type titanium dioxide: 5 parts, fluorite: 4 parts,
Gold Anhydrite: 10 parts, ferrotianium: 2 parts, phlogopite: 5 parts, chromic carbide iron: 8 parts, stibium oxide:
0.1 part, electrolytic manganese: 3 parts, potassium titanate: 2 parts, Haitai powder: 3 parts;
The component of acquirement is dry mixed, is subsequently adding 1:1 potassium-sodium water glass, continue stirring,
It is fabricated to coating;
Being evenly coated on core wire by coating after stirring, suppression electrode, wherein core wire is
H08Cr21Ni10 core wire, in terms of parts by weight, core wire comprises following components:
C:0.030 part, Si:0.25 part, Mn:1.0 part, Cr:18 part, Ni:8 part,
S:0.019 part, P:0.0:4 part;
Compressing welding rod is sent into after natural drying high temperature drying stove bakee, dry
Roasting temperature is 280 degree.
Embodiment two
Count by weight, take following components:
Rutile: 40 parts, marble: 10 parts, X-type titanium dioxide: 10 parts, fluorite: 12
Part, gold Anhydrite: 20 parts, ferrotianium: 8 parts, phlogopite: 10 parts, chromic carbide iron: 20 parts,
Stibium oxide: 1 part, electrolytic manganese: 10 parts, potassium titanate: 8 parts, Haitai powder: 10 parts;
The component of acquirement is dry mixed, is subsequently adding 1:1 potassium-sodium water glass, continue stirring,
It is fabricated to coating;
Being evenly coated on core wire by coating after stirring, suppression electrode, wherein core wire is
H08Cr21Ni10 core wire, in terms of parts by weight, core wire comprises following components:
C:0.080 part, Si:0.60 part, Mn:2.0 part, Cr:22 part, Ni:11 part,
S:0.019 part, P:0.0:4 part;
Compressing welding rod is sent into after natural drying high temperature drying stove bakee, dry
Roasting temperature is 280 degree.
Embodiment three
Count by weight, take following components:
Rutile: 29 parts, marble: 6 parts, X-type titanium dioxide: 7 parts, fluorite: 5 parts,
Gold Anhydrite: 13 parts, ferrotianium: 4 parts, phlogopite: 6 parts, chromic carbide iron: 10 parts, oxidation
Antimony: 0.2 part, electrolytic manganese: 4 parts, potassium titanate: 3 parts, Haitai powder: 5 parts;
The component of acquirement is dry mixed, is subsequently adding 1:1 potassium-sodium water glass, continue stirring,
It is fabricated to coating;
Being evenly coated on core wire by coating after stirring, suppression electrode, wherein core wire is
H08Cr21Ni10 core wire, in terms of parts by weight, core wire comprises following components:
C:0.060 part, Si:0.40 part, Mn:1.5 part, Cr:20 part, Ni:10 part,
S:0.019 part, P:0.0:4 part;
Compressing welding rod is sent into after natural drying high temperature drying stove bakee, dry
Roasting temperature is 280 degree.
Embodiment four
Count by weight, take following components:
Rutile: 38 parts, marble: 9 parts, X-type titanium dioxide: 9 parts, fluorite: 11 parts,
Gold Anhydrite: 18 parts, ferrotianium: 7 parts, phlogopite: 8 parts, chromic carbide iron: 18 parts, oxidation
Antimony: 0.8 part, electrolytic manganese: 8 parts, potassium titanate: 7 parts, Haitai powder: 8 parts;
The component of acquirement is dry mixed, is subsequently adding 1:1 potassium-sodium water glass, continue stirring,
It is fabricated to coating;
Being evenly coated on core wire by coating after stirring, suppression electrode, wherein core wire is
H08Cr21Ni10 core wire, in terms of parts by weight, core wire comprises following components:
C:0.030 part, Si:0.25 part, Mn:1.0 part, Cr:18 part, Ni:8 part, S:
0.019 part, P:0.0:4 part;
Compressing welding rod is sent into after natural drying high temperature drying stove bakee, dry
Roasting temperature is 320 degree.
Embodiment five
Count by weight, take following components:
Rutile: 30 parts, marble: 7 parts, X-type titanium dioxide: 8 parts, fluorite: 8 parts,
Gold Anhydrite: 15 parts, ferrotianium: 5 parts, phlogopite: 8 parts, chromic carbide iron: 14 parts, oxidation
Antimony: 0.5 part, electrolytic manganese: 7 parts, potassium titanate: 5 parts, Haitai powder: 6 parts;
The component of acquirement is dry mixed, is subsequently adding 1:1 potassium-sodium water glass, continue stirring,
It is fabricated to coating;
Being evenly coated on core wire by coating after stirring, suppression electrode, wherein core wire is
H08Cr21Ni10 core wire, in terms of parts by weight, core wire comprises following components:
C:0.030 part, Si:0.25 part, Mn:1.0 part, Cr:18 part, Ni:8 part, S:
0.019 part, P:0.0:4 part;
Compressing welding rod is sent into after natural drying high temperature drying stove bakee, dry
Roasting temperature is 300 degree.
In embodiment one to embodiment five, the mass component content of each component of coating, granularity are wanted
Ask for:
Marble: CaCO3> 96%, S < 0.03%, P < 0.03%, granularity is 40-180 mesh;
Fluorite: CaF2> 96%, S < 0.03%, P < 0.02%, granularity is 40-180 mesh;
Rutile: TiO > 90%, S < 0.03%, P < 0.04%, granularity is 40-160 mesh;
X-type titanium dioxide: TiO > 98%, S < 0.05%, P < 0.05%, granularity is 120-200 mesh;
Gold Anhydrite: SiO2: 63-73%, AL2O3: 15-24%, K2O and Na2Total amount >=12% of O,
S≤0.050%, P≤0.050%, granularity is 40-200 mesh;
Ferrotianium: Mn > 75%, S < 0.03%, P < 0.33%, granularity is 80-120 mesh;
Phlogopite: SiO2: 45-55%, AL2O3: 25-35%, K2O and Na2Total amount >=7% of O,
S≤0.030%, P≤0.040%, granularity is 10-60 mesh;
Chromic carbide iron: Cr:64~67%, C≤0.03%, S≤0.025%, P≤0.030%, granularity
For 20-160 mesh;
Stibium oxide: Sb2O3>=99%, granularity is 140-160 mesh;
Electrolytic manganese: Mn >=99.5%, S≤0.10%, P≤0.010%, C≤0.08%, granularity
For 40-160 mesh;
Potassium titanate: KaCO3>=96%, S≤0.05%, P≤0.05%, granularity is 180-200
Mesh;
Haitai powder: CaCO3> 80%, CaF2> 60%, S < 0.03%, P < 0.03%, granularity is
40-180 mesh.
The metatitanic acid type stainless steel electrode of each embodiment manufacture carries out the every gold of weld seam that welding is formed
Belonging to mechanical property such as following table, wherein guarantee value is the minimum standards of metal welding seam.
By the experimental result of every mechanical property of butt welded seam above, use the present invention's
The metatitanic acid type stainless steel electrode processing weld seam of metatitanic acid type stainless steel electrode and manufacture method thereof, significantly
Improve the properties such as the tensile strength of weld seam, percentage elongation.
The present invention uses the content of the calcite and fluorite reduced in coating composition, introduces potassium titanate
New material, is greatly lowered the surface tension of molten of liquid, thus becomes the most molten and sprayed
Journey, had both improved welding efficiency, shortens weld interval, reduces rubescent tearing tendency, improve again work
Skill performance.
The present invention, in terms of electric arc blows control, uses X-type cellulose to make gas-forming agent, and welding rod is suppressed
Fairly simple, the speed that freezes of welding rod is relatively slow, and gas making amount both can guarantee that the towing force of molten pool metal,
The most do not cause root excessively to burn, form defect.
Above description is only the preferred embodiment of the application and saying institute's application technology principle
Bright.It will be appreciated by those skilled in the art that invention scope involved in the application, do not limit
In the technical scheme of the particular combination of above-mentioned technical characteristic, also should contain simultaneously without departing from
In the case of described inventive concept, above-mentioned technical characteristic or its equivalent feature carry out combination in any
And other technical scheme formed.Such as features described above and (but not limited to) disclosed herein
The technical characteristic with similar functions is replaced mutually and the technical scheme that formed.
Claims (5)
1. a metatitanic acid type stainless steel electrode, including core wire and coating, it is characterised in that with weight
Amount number meter, described coating comprises following components:
Rutile: 20-40 part, marble: 5-10 part, X-type titanium dioxide: 5-10 part, firefly
Stone: 4-12 part, gold Anhydrite: 10-20 part, ferrotianium: 2-8 part, phlogopite: 5-10 part, micro-
Carbon ferrochrome: 8-20 part, stibium oxide: 0.1-1 part, electrolytic manganese: 3-10 part, potassium titanate: 2-8
Part, Haitai powder: 3-10 part;
Described core wire is H08Cr21Ni10Core wire, in terms of parts by weight, described core wire comprises following
Component:
C:0.030~0.080 part, Si:0.25~0.60 part, Mn:1.0~2.0 parts, Cr:
18~22 parts, Ni:8-11 part, S is less than 0.020 part, and P is less than 0.025 part.
Metatitanic acid type stainless steel electrode the most according to claim 1, it is characterised in that described
In coating, the mass component content of each component, granularity requirement are:
Described marble: CaCO3>96%, S<0.03%, P<0.03%, granularity is 40-180
Mesh;
Described fluorite: CaF2>96%, S<0.03%, P<0.02%, granularity is 40-180 mesh;
<<0.04%, granularity is 40-160 mesh for 0.03%, P for described rutile: TiO>90%, S;
Described X-type titanium dioxide:<<0.05%, granularity is 120-200 for 0.05%, P for TiO>98%, S
Mesh;
Described gold Anhydrite: SiO2: 63-73%, AL2O3: 15-24%, K2O and Na2The total amount of O
>=12%, S≤0.050%, P≤0.050%, granularity is 40-200 mesh;
<<0.33%, granularity is 80-120 mesh for 0.03%, P for described ferrotianium: Mn>75%, S;
Described phlogopite: SiO2: 45-55%, AL2O3: 25-35%, K2O and Na2The total amount of O
>=7%, S≤0.030%, P≤0.040%, granularity is 10-60 mesh;
Described chromic carbide iron: Cr:64~67%, C≤0.03%, S≤0.025%, P≤0.030%,
Granularity is 20-160 mesh;
Described stibium oxide: Sb2O3>=99%, granularity is 140-160 mesh;
Described electrolytic manganese: Mn >=99.5%, S≤0.10%, P≤0.010%, C≤0.08%,
Granularity is 40-160 mesh;
Described potassium titanate: KaCO3>=96%, S≤0.05%, P≤0.05%, granularity is 180-200
Mesh;
Described Haitai powder: CaCO3> 80%, CaF2>60%, S<0.03%, P<0.03%, grain
Degree is 40-180 mesh.
3. the manufacture method of a metatitanic acid type stainless steel electrode, it is characterised in that the steps include:
Make the coating of metatitanic acid type stainless steel electrode, count by weight, take following components:
Rutile: 20-40 part, marble: 5-10 part, X-type titanium dioxide: 5-10 part, firefly
Stone: 4-12 part, gold Anhydrite: 10-20 part, ferrotianium: 2-8 part, phlogopite: 5-10 part, micro-
Carbon ferrochrome: 8-20 part, stibium oxide: 0.1-1 part, electrolytic manganese: 3-10 part, potassium titanate: 2-8
Part, Haitai powder: 3-10 part;
The component of acquirement is dry mixed, is subsequently adding waterglass, continue stirring, make patent medicine
Skin;
Being evenly coated on core wire by coating after stirring, suppression electrode, wherein core wire is
H08Cr21Ni10Core wire, in terms of parts by weight, described core wire comprises following components:
C:0.030~0.080 part, Si:0.25~0.60 part, Mn:1.0~2.0 parts, Cr:
18~22 parts, Ni:8~11 parts, S is less than 0.020 part, and P is less than 0.025 part;
Compressing welding rod is sent into after natural drying high temperature drying stove bakee.
The manufacture method of metatitanic acid type stainless steel electrode the most according to claim 3, its feature
Being, described waterglass is 1:1 potassium-sodium water glass.
The manufacture method of metatitanic acid type stainless steel electrode the most according to claim 3, its feature
Being, described stoving temperature is 280-320 degree.
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PCT/CN2016/102532 WO2017181633A1 (en) | 2016-04-19 | 2016-10-19 | Titanic-acid-type stainless steel welding electrode and manufacturing method thereof |
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WO2017181633A1 (en) * | 2016-04-19 | 2017-10-26 | 南通豪泰焊材有限公司 | Titanic-acid-type stainless steel welding electrode and manufacturing method thereof |
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WO2017181633A1 (en) * | 2016-04-19 | 2017-10-26 | 南通豪泰焊材有限公司 | Titanic-acid-type stainless steel welding electrode and manufacturing method thereof |
CN106216880A (en) * | 2016-08-25 | 2016-12-14 | 安庆市天涯汽车配件有限公司 | A kind of production technology of stainless steel electrode |
CN110170765A (en) * | 2019-05-24 | 2019-08-27 | 四川大西洋焊接材料股份有限公司 | The mating acidic electrode of high Manganese Austenitic Cryogenic Steels of LNG storage tank peculiar to vessel and preparation method |
CN110170765B (en) * | 2019-05-24 | 2021-05-11 | 四川大西洋焊接材料股份有限公司 | High-manganese austenite ultralow-temperature steel matched acid welding rod for marine LNG storage tank and preparation method thereof |
CN110605502A (en) * | 2019-09-18 | 2019-12-24 | 中国电建集团上海能源装备有限公司 | Titanium-calcium slag system double-phase stainless steel welding rod and preparation thereof |
CN110605502B (en) * | 2019-09-18 | 2022-03-25 | 中国电建集团上海能源装备有限公司 | Titanium-calcium slag system double-phase stainless steel welding rod and preparation thereof |
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