CN105755860B - A kind of high-efficiency environment friendly dyeing promoter and preparation method thereof - Google Patents
A kind of high-efficiency environment friendly dyeing promoter and preparation method thereof Download PDFInfo
- Publication number
- CN105755860B CN105755860B CN201610104941.9A CN201610104941A CN105755860B CN 105755860 B CN105755860 B CN 105755860B CN 201610104941 A CN201610104941 A CN 201610104941A CN 105755860 B CN105755860 B CN 105755860B
- Authority
- CN
- China
- Prior art keywords
- parts
- environment friendly
- dyeing promoter
- efficiency environment
- emulsifying agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6536—Aromatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
Abstract
The invention discloses a kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：28 parts of modification of chitosan; 35 parts of calcium chloride; 5 12 parts of menthyl salicylate; 6 10 parts of N (4 hydroxyphenyl) Stearyl Amine; 48 parts of didodecyldimethylammbromide bromide, 8 15 parts of N lauroyl glutamates, 0.8 1.2 parts of nano-titanium oxide; 25 parts of compound emulsifying agent, 10 15 parts of deionized water.The invention also discloses the preparation method of the high-efficiency environment friendly dyeing promoter.Dyeing promoter prepared by the present invention can effectively improve the dye-uptake of fabric, and the wet fastness of the fabric after dyeing and fastness to light all greatly improve, and Color is excellent, and the dyeing promoter has certain biological degradability, nontoxic, be advantageous to environmental protection.
Description
Technical field：
The present invention relates to technical field of textile auxiliary agent, is specifically related to a kind of high-efficiency environment friendly dyeing promoter.
Background technology：
In recent years, as people's environmental protection consciousness is constantly strengthened, Nature Fibre Textile product are increasingly subject to the green grass or young crops of consumer
Look at.Silk fiber has the laudatory title of " fiber queen ", has impayable special performance：It is frivolous smooth, soft comfortable, good
Moisture absorption, gas permeability, distinctive soft beautiful gloss, and it is with health role to human body；Therefore true silk products enjoy people to like
Love.Cotton fiber has good hygroscopicity, dyeability and a certain wearability as native cellulose fibre, good permeability,
It is comfortable and easy to wear that clothes are made with it, are not easy balling-up.In addition, the natural fibre products such as flaxen fiber industry is with its excellent moisture absorption, health care
Performance and attract attention.
Acid fiber by polylactic is a kind of synthetic fibers of new fully biodegradable, and it has the comprehensive of general synthetic fibers
Close premium properties, especially biodegradability, be other polyester fibers it is incomparable, therefore, it is textile field
New development space is brought, but also brings new challenge for dyeing and finishing processing simultaneously.PLA mainly uses disperse dyeing,
But compared with polyester fiber, dye-uptake of the conventional commodity disperse dyes on acid fiber by polylactic is far below PET, it contaminates
Depth is poor, and because PLA is in itself without the group for absorbing ultraviolet, after disperse dyeing fabric through illumination fugitive color,
Therefore the raising of color fastness to light is also a urgent problem to be solved.
Chinese patent (CN201310276149.8) discloses a kind of preparation method of dyeing promoter, and it is first with four
Chlorination carbon, BFEE, ethylene glycol, epichlorohydrin reaction, then purified, added using acetone-ethanol mixed liquor
The tetrasodium ethylenediamine tetraacetate aqueous solution removes the low-molecular-weight oligomer in extract, obtains Based On Hydroxy-terminated Polyepichlorohydrin；Then
Based On Hydroxy-terminated Polyepichlorohydrin and dimethylamine agueous solution split two containers, are added dropwise into the container for be placed in Hydrin
Dimethylamine agueous solution, react under certain condition, that is, obtain dyeing promoter DL-71.What this method was prepared can effectively carry
The dye-uptake of high natural silk fiber, but its preparation technology is complicated, the solvent used in preparation process is volatile, is unfavorable for ring
Protect in border.
The content of the invention：
It is an object of the invention to provide a kind of high-efficiency environment friendly dyeing promoter, and it can effectively improve the dye-uptake of fabric,
The wet fastness of fabric and fastness to light after dyeing all greatly improve, and Color is excellent.And the dyeing promoter has necessarily
Biological degradability, it is nontoxic, be advantageous to environmental protection.
It is a further object to provide the preparation method of the high-efficiency environment friendly dyeing promoter.
To achieve the above object, the present invention uses following technical scheme：
A kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：
Modification of chitosan 2-8 parts,
Calcium chloride 3-5 parts,
Menthyl salicylate 5-12 parts,
N- (4- hydroxyphenyls) Stearyl Amine 6-10 parts,
Didodecyldimethylammbromide bromide 4-8 parts,
N- lauroyl glutamate 8-15 parts,
Nano-titanium oxide 0.8-1.2 parts,
Compound emulsifying agent 2-5 parts,
Deionized water 10-15 parts.
As the preferred of above-mentioned technical proposal, a kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including with the following group
Point：
5 parts of modification of chitosan,
4.5 parts of calcium chloride,
10 parts of menthyl salicylate,
7 parts of N- (4- hydroxyphenyls) Stearyl Amine,
5 parts of didodecyldimethylammbromide bromide,
12 parts of N- lauroyl glutamates,
1 part of nano-titanium oxide,
3.5 parts of compound emulsifying agent,
12 parts of deionized water.
As the preferred of above-mentioned technical proposal, the modification of chitosan is carboxylated chitosan.
As the preferred of above-mentioned technical proposal, the nano-titanium oxide is Detitanium-ore-type, particle size 20-40nm.
As the preferred of above-mentioned technical proposal, the compound emulsifying agent is by span80, Tween-80, silane coupler and helps
Emulsifying agent forms.
As the preferred of above-mentioned technical proposal, the span80, Tween-80, silane coupler, the volume ratio of assistant for emulsifying agent
For 10:8:2-3:1.
As the preferred of above-mentioned technical proposal, the assistant for emulsifying agent is the one or more in ethanol, glycerine, n-butanol
Mixing.
A kind of preparation method of high-efficiency environment friendly dyeing promoter, comprises the following steps：
(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, add nano-titanium oxide,
Ultrasonic 20-30min, obtains uniform dispersion under 500W power；
(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- bays
Acyl glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and 1-2h is stirred in the state of 8000-10000 revs/min,
Obtain mixed liquor；
(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains height
Imitate environmentally friendly dyeing promoter.
As the preferred of above-mentioned technical proposal, in step (1), the ultrasonic time is 20min.
As the preferred of above-mentioned technical proposal, in step (2), the condition of the stirring is stirred in the state of being 8000 revs/min
Mix 1.5h.
The invention has the advantages that：
When the dyeing promoter handles fabric, it can make its fabric fibre that there are more dye seats, dye fabric
Cheng Zhong, there is more preferable absorption to dyestuff, the dyeing promoter can crosslink with fabric fibre produces stable spatial network
Structure, so that dyestuff securely fixes the dye-uptake and fastness to washing in the network architecture, substantially increasing fabric；
The present invention adds nano-titanium oxide in dyeing promoter, and it can effectively absorb ultraviolet, disperse dyes dye
Fabric substantially increases the fastness to light after textile dyeing, and nano-titanium oxide surface has through illumination fabric not fugitive color after color
More active group, can effectively it adsorb in fabric face.
Dyeing promoter provided by the invention, preparation method is simple, is discharged in preparation process without noxious material, has certain
Biodegradable, be advantageous to environmental protection.
Embodiment：
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving
The present invention is released, any restriction will not be formed to the present invention.
Embodiment 1
A kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：
2 parts of modification of chitosan, 3 parts of calcium chloride,
5 parts of menthyl salicylate,
6 parts of N- (4- hydroxyphenyls) Stearyl Amine,
4 parts of didodecyldimethylammbromide bromide,
8 parts of N- lauroyl glutamates,
0.8 part of nano-titanium oxide,
2 parts of compound emulsifying agent,
10 parts of deionized water.
Its preparation method comprises the following steps：
(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, add nano-titanium oxide,
Ultrasonic 20min, obtains uniform dispersion under 500W power；
(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- bays
Acyl glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and stir 1h in the state of 8000 revs/min, are mixed
Liquid；
(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains height
Imitate environmentally friendly dyeing promoter.
Embodiment 2
A kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：
8 parts of modification of chitosan, 5 parts of calcium chloride,
12 parts of menthyl salicylate,
10 parts of N- (4- hydroxyphenyls) Stearyl Amine,
8 parts of didodecyldimethylammbromide bromide,
15 parts of N- lauroyl glutamates,
1.2 parts of nano-titanium oxide,
5 parts of compound emulsifying agent,
15 parts of deionized water.
Its preparation method comprises the following steps：
(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, add nano-titanium oxide,
Ultrasonic 30min, obtains uniform dispersion under 500W power；
(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- bays
Acyl glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and stir 2h in the state of 10000 revs/min, are mixed
Liquid；
(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains height
Imitate environmentally friendly dyeing promoter.
Embodiment 3
A kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：
5 parts of modification of chitosan, 4.5 parts of calcium chloride,
10 parts of menthyl salicylate,
7 parts of N- (4- hydroxyphenyls) Stearyl Amine,
5 parts of didodecyldimethylammbromide bromide,
12 parts of N- lauroyl glutamates,
1 part of nano-titanium oxide,
3.5 parts of compound emulsifying agent,
12 parts of deionized water.
Its preparation method comprises the following steps：
(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, add nano-titanium oxide,
Ultrasonic 25min, obtains uniform dispersion under 500W power；
(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- bays
Acyl glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and stir 1.2h in the state of 8500 revs/min, are mixed
Close liquid；
(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains height
Imitate environmentally friendly dyeing promoter.
Embodiment 4
A kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：
3 parts of modification of chitosan, 3.5 parts of calcium chloride,
7 parts of menthyl salicylate,
7 parts of N- (4- hydroxyphenyls) Stearyl Amine,
5 parts of didodecyldimethylammbromide bromide,
10 parts of N- lauroyl glutamates,
0.9 part of nano-titanium oxide,
3 parts of compound emulsifying agent,
11 parts of deionized water.
Its preparation method comprises the following steps：
(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, add nano-titanium oxide,
Ultrasonic 20min, obtains uniform dispersion under 500W power；
(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- bays
Acyl glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and stir 1.4h in the state of 9000 revs/min, are mixed
Close liquid；
(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains height
Imitate environmentally friendly dyeing promoter.
Embodiment 5
A kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：
4 parts of modification of chitosan, 4 parts of calcium chloride,
9 parts of menthyl salicylate,
8 parts of N- (4- hydroxyphenyls) Stearyl Amine,
6 parts of didodecyldimethylammbromide bromide,
12 parts of N- lauroyl glutamates,
1.0 parts of nano-titanium oxide,
4 parts of compound emulsifying agent,
12 parts of deionized water.
Its preparation method comprises the following steps：
(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, add nano-titanium oxide,
Ultrasonic 30min, obtains uniform dispersion under 500W power；
(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- bays
Acyl glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and stir 1.6h in the state of 9500 revs/min, are mixed
Close liquid；
(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains height
Imitate environmentally friendly dyeing promoter.
Embodiment 6
A kind of high-efficiency environment friendly dyeing promoter, in parts by weight, including following components：
7 parts of modification of chitosan, 4.5 parts of calcium chloride,
11 parts of menthyl salicylate,
9 parts of N- (4- hydroxyphenyls) Stearyl Amine,
7 parts of didodecyldimethylammbromide bromide,
13 parts of N- lauroyl glutamates,
1.1 parts of nano-titanium oxide,
4.5 parts of compound emulsifying agent,
14 parts of deionized water.
Its preparation method comprises the following steps：
(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, add nano-titanium oxide,
Ultrasonic 20min, obtains uniform dispersion under 500W power；
(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- bays
Acyl glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and stir 1.8h in the state of 10000 revs/min, are mixed
Close liquid；
(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains height
Imitate environmentally friendly dyeing promoter.
Performance test is carried out to high-efficiency environment friendly dyeing promoter provided by the invention below.
(1) dye uptake measure is (to disperse dark blue HGL)
Dye uptake uses raffinate colorimetric method for determining：A certain amount of dyeing stoste and dyeing residual night are poured into respectively
In 500ml volumetric flask, the raffinate after fabric cleaning 2 times is poured into wherein, the raffinate of reduction cleaning is also poured into volumetric flask, is added
Water is to scale；Solution 5ml is taken in 10ml volumetric flasks.Adding 5ml acetone makes dye liquor be described in throwing, with this solution in spectrophotometric
Absorbance A is measured on meter, dye uptake E% is calculated with following formula, wherein, A1For raffinate absorbance, A0For stoste absorbance；
E%=100 (1-A1/A0)
(2) soaping fastness
According to GB/T 3921-1997《Textile color stability tests color fastness to washing》Test.
(3) sublimation reliability
According to GB/T 6152-1997《Textile color stability tests color fastness to hot pressing》Test.
Test result is as shown in table 1：
(4) test of color fastness to light
With air-cooled light fastness tester by the PLA fabric after co-bathing dyeing according to standard 8427-1998《Textile color
Fastness test artificial light color fastness carries out weathering color fastness test》；Exposure to Sunlight has been tested with color measurement and color match instrument test aberration.Exposure to Sunlight bar
Part：Exposure to Sunlight intensity 95%, relative humidity 60%, temperature 50 C, rotating speed 8rpm, Exposure to Sunlight time 50h.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Dye uptake, % | 96.5 | 97.2 | 96.8 | 98.5 | 97.9 | 98.2 |
| Soaping fastness, level | 5 | 5 | 4-5 | 5 | 5 | 5 |
| Sublimation reliability, level | 4-5 | 5 | 5 | 4-5 | 5 | 4-5 |
| Fastness to light, level | 4-5 | 5 | 5 | 5 | 4-5 | 5 |
From shown in table 1, the high-efficiency environment friendly dyeing promoter prepared by the present invention, the dye-uptake of fabric can be effectively improved,
And fabric is dyed enough, washing fastness, color fastness to light are good.
Claims (6)
- A kind of 1. high-efficiency environment friendly dyeing promoter, it is characterised in that in parts by weight, including following components：Modification of chitosan 2-8 parts,Calcium chloride 3-5 parts,Menthyl salicylate 5-12 parts,N- (4- hydroxyphenyls) Stearyl Amine 6-10 parts,Didodecyldimethylammbromide bromide 4-8 parts,N- lauroyl glutamate 8-15 parts,Nano-titanium oxide 0.8-1.2 parts,Compound emulsifying agent 2-5 parts,Deionized water 10-15 parts；Wherein, the modification of chitosan is carboxylated chitosan；The compound emulsifying agent is by span80, Tween-80, silane coupled Agent and assistant for emulsifying agent are using volume ratio as 10:8:2-3:1 composition；Its preparation method comprises the following steps：(1) modification of chitosan, calcium chloride and deionized water are mixed into solid dissolving, adds nano-titanium oxide, 500W work( Ultrasonic 20-30min, obtains uniform dispersion under rate；(2) by menthyl salicylate, N- (4- hydroxyphenyls) Stearyl Amine, didodecyldimethylammbromide bromide, N- lauroyls Glutamic acid, compound emulsifying agent and deionized water are mixed evenly, and 1-2h is stirred in the state of 8000-10000 revs/min, are obtained Mixed liquor；(3) the mixed liquor mixing that the uniform dispersion and step (2) obtained step (1) obtains, stirs, obtains Efficient Ring Protect dyeing promoter.
- A kind of 2. high-efficiency environment friendly dyeing promoter as claimed in claim 1, it is characterised in that in parts by weight, including it is following Component：5 parts of modification of chitosan,4.5 parts of calcium chloride,10 parts of menthyl salicylate,7 parts of N- (4- hydroxyphenyls) Stearyl Amine,5 parts of didodecyldimethylammbromide bromide,12 parts of N- lauroyl glutamates,1 part of nano-titanium oxide,3.5 parts of compound emulsifying agent,12 parts of deionized water.
- 3. a kind of high-efficiency environment friendly dyeing promoter as claimed in claim 1, it is characterised in that the nano-titanium oxide is rutile titania Ore deposit type, particle size 20-40nm.
- A kind of 4. high-efficiency environment friendly dyeing promoter as claimed in claim 1, it is characterised in that the assistant for emulsifying agent be ethanol, One or more of mixing in glycerine, n-butanol.
- 5. a kind of high-efficiency environment friendly dyeing promoter as claimed in claim 1, it is characterised in that described ultrasonic in step (1) Time is 20min.
- A kind of 6. high-efficiency environment friendly dyeing promoter as claimed in claim 1, it is characterised in that in step (2), the stirring Condition stirs 1.5h in the state of being 8000 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610104941.9A CN105755860B (en) | 2016-02-26 | 2016-02-26 | A kind of high-efficiency environment friendly dyeing promoter and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610104941.9A CN105755860B (en) | 2016-02-26 | 2016-02-26 | A kind of high-efficiency environment friendly dyeing promoter and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105755860A CN105755860A (en) | 2016-07-13 |
| CN105755860B true CN105755860B (en) | 2018-03-16 |
Family
ID=56331365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610104941.9A Active CN105755860B (en) | 2016-02-26 | 2016-02-26 | A kind of high-efficiency environment friendly dyeing promoter and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105755860B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106223078A (en) * | 2016-07-29 | 2016-12-14 | 桐乡市素丝五祁服饰有限公司 | A kind of fabric high-efficiency environment friendly colouring method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736611A (en) * | 2009-12-14 | 2010-06-16 | 浙江理工大学 | Dyeing promoter of acrylic fiber cationic dye and application thereof |
| CN103333332A (en) * | 2013-07-01 | 2013-10-02 | 达利(中国)有限公司 | Preparation method and application off dyeing promoter |
| CN103757944A (en) * | 2014-01-14 | 2014-04-30 | 傅科杰 | Composite printing and dyeing auxiliary as well as preparation method and application of auxiliary |
-
2016
- 2016-02-26 CN CN201610104941.9A patent/CN105755860B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736611A (en) * | 2009-12-14 | 2010-06-16 | 浙江理工大学 | Dyeing promoter of acrylic fiber cationic dye and application thereof |
| CN103333332A (en) * | 2013-07-01 | 2013-10-02 | 达利(中国)有限公司 | Preparation method and application off dyeing promoter |
| CN103757944A (en) * | 2014-01-14 | 2014-04-30 | 傅科杰 | Composite printing and dyeing auxiliary as well as preparation method and application of auxiliary |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105755860A (en) | 2016-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Umbreen et al. | Dyeing properties of natural dyes extracted from turmeric and their comparison with reactive dyeing | |
| CN107044055A (en) | A kind of method of the few water dyed cotton fabric of cochineal red pigment | |
| CN102561053A (en) | Method for dyeing silk by using laccase-catalyzed tea polyphenols | |
| CN106087470A (en) | A kind of environment-friendly type terylene fabric sand washing dyeing | |
| CN110042677A (en) | A kind of fabric vegetable colour and preparation method thereof | |
| CN106592272B (en) | A kind of method of natural black dyes real silk fabric | |
| CN105671940B (en) | A kind of polyester or the long-acting mosquito-proof knitting fabric of its blend fabric and preparation method thereof | |
| CN105755860B (en) | A kind of high-efficiency environment friendly dyeing promoter and preparation method thereof | |
| CN110965356A (en) | Environment-friendly fabric coloring agent | |
| CN104448927A (en) | Composite active blue dye | |
| CN108354855A (en) | Composition and preparation method thereof and application method | |
| CN105544238B (en) | Print paste and its printing technology containing grape pigment | |
| CN104032602B (en) | Anti-REACTIVE DYES staining agent | |
| CN107022906A (en) | The dyeing that Roselle dyestuff is dyed to silk fabric | |
| CN103572616A (en) | Piling and printing method of cotton fabric by reactive dye | |
| CN106638027B (en) | A method of being derived from the natural dye dyeing wool fabric of Testa sojae atricolor | |
| CN106012591A (en) | Environment-friendly sand washing and dyeing technology for habotai real silk fabric | |
| CN113774685B (en) | Preparation method of anti-wrinkle antibacterial intelligent home textile fabric | |
| CN101705627A (en) | Leather dyeing method | |
| CN101418138B (en) | Navy blue reactive dyes composite for low salt dyeing and dyeing application thereof | |
| Liu et al. | Preparation of a cationic environment-friendly fixing agent | |
| CN112127177B (en) | Special modified terylene cationic dye composition integrating level dyeing and deepening | |
| CN111663344A (en) | Natural dye dyeing method suitable for real silk fabric | |
| Onal et al. | Use of fermented dough extract in the dyeing of wool fabrics | |
| CN106758319A (en) | A kind of fluorescence washs the processing technology of numb blended yarn weaved fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Wenqing Inventor before: Wei Tiantang |
|
| CB03 | Change of inventor or designer information | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180130 Address after: 523000 Guangdong province Dongguan Songshan Lake high tech Industrial Development Zone Productivity building 406 Applicant after: Dongguan Lianzhou Intellectual Property Operation Management Co.,Ltd. Address before: No. 153, tree garden road, Dong Zhu Town, Suzhou high tech Zone, Jiangsu Province Applicant before: Suzhou Sanhe Kaitai Yarn Weaving Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181211 Address after: 312000 North Six Road, Coastal Industrial Zone, Keqiao District, Shaoxing City, Zhejiang Province Patentee after: ZHEJIANG XINSHU TEXTILE CO., LTD. Address before: 523000 productivity building 406, Songshan Hu high tech Industrial Development Zone, Dongguan, Guangdong Patentee before: Dongguan Lianzhou Intellectual Property Operation Management Co.,Ltd. |
|
| TR01 | Transfer of patent right |