CN105755353A - Corrosion-resistant automobile accessory alloy steel material and preparation method thereof - Google Patents
Corrosion-resistant automobile accessory alloy steel material and preparation method thereof Download PDFInfo
- Publication number
- CN105755353A CN105755353A CN201610201010.0A CN201610201010A CN105755353A CN 105755353 A CN105755353 A CN 105755353A CN 201610201010 A CN201610201010 A CN 201610201010A CN 105755353 A CN105755353 A CN 105755353A
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- corrosion
- alloy steel
- steel material
- auto parts
- parts machinery
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/006—Making ferrous alloys compositions used for making ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
Abstract
The invention discloses a corrosion-resistant automobile accessory alloy steel material and a preparation method thereof.According to the corrosion-resistant automobile accessory alloy steel material, 0.35-0.6 part of carbon, 0.1-0.3 part of manganese, 0.42-0.6 part of titanium, 0.15-0.18 part of molybdenum, 0.45-0.6 part of silicon, 0.12-0.3 part of vanadium, 0.015-0.04 part of boron, 0.35-0.5 part of cobalt, 0.05-0.1 part of copper and 96-105 parts of iron are put into a medium-frequency induction furnace to be molten in proportion; the temperature is raised to 1,400 DEG C at the speed of 50 DEG C/min, and discharge and casting are carried out; quenching treatment is carried out, wherein the quenching temperature is 900 DEG C, heat preservation is carried out for 1 h, and discharge and air cooling are carried out; tempering treatment is carried out, wherein the tempering temperature is 300 DEG C, heat preservation is carried out for 1 h, discharge and air cooling are carried out, and the corrosion-resistant automobile accessory alloy steel material is prepared.The alloy steel material is excellent in corrosion resistance and suitable for being applied and popularized, and has high market value.
Description
Technical field
The invention belongs to auto parts manufacturing technology field, be specifically related to a kind of corrosion-resistant auto parts machinery alloy steel material and preparation method thereof.
Background technology
Automobile has the part of more than 90% to be metal parts, and the drawback of metal parts is exactly easily be corroded, and the corrosion of auto parts is mainly atmospheric corrosion, belongs to electrochemical corrosion, is modal in metal erosion.According to statistics, in metal erosion, atmospheric corrosion accounts for more than half, and most parts of automobile are all directly and atmosphere.So-called atmospheric corrosion refers to metal rust corrosion under the effect of humid air at normal temperatures.When being substantially free of moisture in an atmosphere, due to the effect of oxygen in air, even if metal surface at room temperature also can be made to produce moisture film one layer very thin, corrosion carries out in moisture film.In air, not only metal can be corrosive by oxygen, even the gas such as carbon dioxide, copper dioxide or the impurity such as dust, salt all can accelerate electrochemical corrosion and make metal damage.
As the part of automobile, not only structural strength with functionally have higher requirement, no less important in machining simultaneously, such requirement is not only and is met the primary condition that automobile uses, and is also the safe and reliable guarantee increased the service life simultaneously.
In prior art, the steel of production auto parts machinery are common middle low content steel alloy, and because these automobile metal accessories are functionally usually moving component frequently in use, wear rate is significantly high, changes frequently, adds maintenance cost;Searching out a kind of raising hardness and anti-wear performance, the steel alloy of the middle low content that piece surface heat resistance is high is extremely important with regard to what show simultaneously.
Summary of the invention
Goal of the invention: a kind of corrosion-resistant auto parts machinery alloy steel material and preparation method thereof is provided.
Technical scheme:
A kind of corrosion-resistant auto parts machinery alloy steel material, it is characterised in that it is to use following Material synthesis:
Ferrum 95~100 parts, 0.2~0.3 part of carbon, silicon 0.06~0.1 part, 0.15~0.5 part of tungsten, titanium 0.12~0.3 part, 0.02~0.05 part of nickel, copper 0.12~0.15 part, 0.005~0.01 part of phosphorus, 0.32~0.48 part of zinc, 0.01~0.05 part of aluminum, 0.01~0.03 part of magnesium.
Preferred as the present invention, it is to use following Material synthesis:
Ferrum 98 parts, 0.22 part of carbon, silicon 0.08 part, 0.3 part of tungsten, titanium 0.2 part, 0.03 part of nickel, copper 0.14 part, 0.008 part of phosphorus, 0.4 part of zinc, 0.03 part of aluminum, 0.02 part of magnesium.
Preferred as the present invention, it is to use following Material synthesis:
Ferrum 95 parts, 0.2 part of carbon, silicon 0.06 part, 0.15 part of tungsten, titanium 0.12 part, 0.02 part of nickel, copper 0.12 part, 0.005 part of phosphorus, 0.32 part of zinc, 0.01 part of aluminum, 0.01 part of magnesium.
Preferred as the present invention, it is to use following Material synthesis:
Ferrum 100 parts, 0.3 part of carbon, silicon 0.1 part, 0.5 part of tungsten, titanium 0.3 part, 0.05 part of nickel, copper 0.15 part, 0.01 part of phosphorus, 0.48 part of zinc, 0.05 part of aluminum, 0.03 part of magnesium.
The preparation method of described corrosion-resistant auto parts machinery alloy steel material, comprises the steps:
(1) all raw materials are put in proportion in intermediate frequency furnace and melt;
(2) 1300~1400 DEG C it are warming up to, tapping casting;
(3) Quenching Treatment: hardening heat is 800~900 DEG C, insulation 1~2h, air cooling of coming out of the stove,
(4) temper: temperature is 300~600 DEG C, is incubated 1~3h, air cooling of coming out of the stove, namely obtains corrosion-resistant auto parts machinery alloy steel material.
In step (2), programming rate is the speed of 50 DEG C/min.
In step (3), described hardening heat is 850 DEG C.
In step (4), described temperature is 500 DEG C.
Beneficial effect: the corrosion resistance of corrosion-resistant auto parts machinery alloy steel material prepared by the present invention is good, suitable popularization and application, there is wide market value.
Detailed description of the invention
According to following embodiment, it is possible to be more fully understood that the present invention.But, as it will be easily appreciated by one skilled in the art that the content described by embodiment is merely to illustrate the present invention, and should without the present invention described in detail in restriction claims.
Embodiment 1:
(1) by ferrum 98 parts, 0.22 part of carbon, silicon 0.08 part, 0.3 part of tungsten, titanium 0.2 part, 0.03 part of nickel, copper 0.14 part, 0.008 part of phosphorus, 0.4 part of zinc, 0.03 part of aluminum, 0.02 part of magnesium.Put in intermediate frequency furnace in proportion and melt;
(2) 1300~1400 DEG C it are warming up to, tapping casting;
(3) Quenching Treatment: hardening heat is 850 DEG C, insulation 2h, air cooling of coming out of the stove,
(4) temper: temperature is 400 DEG C, is incubated 3h, air cooling of coming out of the stove, namely obtains corrosion-resistant auto parts machinery alloy steel material.
After testing: the corrosion condition in the NaCl solution of the 5wt% of this alloy steel material is 0.0003~0.0005mm/, in the copper acid solution of 10wt%, corrosion condition is 0.002-0.0028mm/, and in the potassium hydroxide solution of 10wt%, corrosion condition is 0.001~0.003mm/.
Embodiment 2:
(1) by ferrum 95 parts, 0.2 part of carbon, silicon 0.06~part, 0.15 part of tungsten, titanium 0.12 part, 0.02 part of nickel, copper 0.12 part, 0.005 part of phosphorus, 0.32 part of zinc, 0.01 part of aluminum, 0.01 part of magnesium.Put in intermediate frequency furnace in proportion and melt;
(2) 1300~1400 DEG C it are warming up to, tapping casting;
(3) Quenching Treatment: hardening heat is 900 DEG C, insulation 1h, air cooling of coming out of the stove,
(4) temper: temperature is 600 DEG C, is incubated 2h, air cooling of coming out of the stove, namely obtains corrosion-resistant auto parts machinery alloy steel material.
After testing: the corrosion condition in the NaCl solution of the 5wt% of this alloy steel material is 0.0003~0.0004mm/, in the copper acid solution of 10wt%, corrosion condition is 0.0018-0.0025mm/, and in the potassium hydroxide solution of 10wt%, corrosion condition is 0.001~0.003mm/.
Embodiment 3:
(1) by ferrum 100 parts, 0.3 part of carbon, silicon 0.1 part, 0.5 part of tungsten, titanium 0.3 part, 0.05 part of nickel, copper 0.15 part, 0.01 part of phosphorus, 0.48 part of zinc, 0.05 part of aluminum, 0.03 part of magnesium.Put in intermediate frequency furnace in proportion and melt;
(2) 1300~1400 DEG C it are warming up to, tapping casting;
(3) Quenching Treatment: hardening heat is 800 DEG C, insulation 1h, air cooling of coming out of the stove,
(4) temper: temperature is 300 DEG C, is incubated 1h, air cooling of coming out of the stove, namely obtains corrosion-resistant auto parts machinery alloy steel material.
After testing: the corrosion condition in the NaCl solution of the 5wt% of this alloy steel material is 0.0003~0.0004mm/, in the copper acid solution of 10wt%, corrosion condition is 0.0018-0.0023mm/, and in the potassium hydroxide solution of 10wt%, corrosion condition is 0.001~0.002mm/.
Claims (8)
1. a corrosion-resistant auto parts machinery alloy steel material, it is characterised in that it is to use following Material synthesis:
0.35 ~ 0.6 part of carbon, 0.1 ~ 0.3 part of manganese, titanium 0.42 ~ 0.6 part, molybdenum 0.15 ~ 0.18 part, silicon 0.45 ~ 0.6 part, vanadium 0.12 ~ 0.3 part, boron 0.015 ~ 0.04 part, cobalt 0.35 ~ 0.5 part, copper 0.05 ~ 0.1 part, ferrum 96 ~ 105 parts.
2. corrosion-resistant auto parts machinery alloy steel material according to claim 1, it is characterised in that it is to use following Material synthesis:
0.5 part of carbon, 0.2 part of manganese, titanium 0.5 part, molybdenum 0.16 part, silicon 0.5 part, vanadium 0.15 part, boron 0.03 part, cobalt 0.4 part, copper 0.08 part, ferrum 100 parts.
3. corrosion-resistant auto parts machinery alloy steel material according to claim 1, it is characterised in that it is to use following Material synthesis:
0.35 part of carbon, 0.1 part of manganese, titanium 0.42 part, molybdenum 0.15 part, silicon 0.45 part, vanadium 0.12 part, boron 0.015 part, cobalt 0.3.5 part, copper 0.05 part, ferrum 96 parts.
4. corrosion-resistant auto parts machinery alloy steel material according to claim 1, it is characterised in that it is to use following Material synthesis:
0.6 part of carbon, manganese 0.3 titanium 0.6 part, molybdenum 0.18 part, silicon 0.6 part, vanadium .3 part, boron 0.04 part, cobalt 0.5 part, copper 0.1 part, ferrum 105 parts.
5. the preparation method of corrosion-resistant auto parts machinery alloy steel material described in any one of claim 1 ~ 4, it is characterised in that comprise the steps:
(1) all raw materials are put in proportion in intermediate frequency furnace and melt;
(2) 1500 ~ 1600 DEG C it are warming up to, tapping casting;
(3) Quenching Treatment: hardening heat is 900 ~ 1000 DEG C, insulation 1 ~ 3h, air cooling of coming out of the stove,
(4) temper: temperature is 450 ~ 550 DEG C, is incubated 1 ~ 4h, air cooling of coming out of the stove, namely obtains corrosion-resistant auto parts machinery alloy steel material.
6. the preparation method of corrosion-resistant auto parts machinery alloy steel material according to claim 5, it is characterised in that in step (2), programming rate is the speed of 80 DEG C/min.
7. the preparation method of corrosion-resistant auto parts machinery alloy steel material according to claim 5, it is characterised in that in step (3), described hardening heat is 950 DEG C.
8. the preparation method of corrosion-resistant auto parts machinery alloy steel material according to claim 5, it is characterised in that in step (4), described temperature is 500 DEG C.
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Citations (7)
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CN1526607A (en) * | 2003-02-26 | 2004-09-08 | 新日本制铁株式会社 | Crude oil tank with welding seam having excellent anti-corrosivity |
CN101932746A (en) * | 2008-01-31 | 2010-12-29 | 杰富意钢铁株式会社 | High-strength steel sheet and process for production thereof |
US20130133786A1 (en) * | 2010-03-09 | 2013-05-30 | Jfe Steel Corporation | Method for manufacturing high strength steel sheet |
CN103290308A (en) * | 2012-02-27 | 2013-09-11 | 株式会社神户制钢所 | High-strength cold-rolled steel plate and manufacturing method thereof |
CN103314120A (en) * | 2010-10-22 | 2013-09-18 | 新日铁住金株式会社 | Process for producing hot stamp molded article, and hot stamp molded article |
US20150059935A1 (en) * | 2012-03-30 | 2015-03-05 | Voestalpine Stahl Gmbh | High strength cold rolled steel sheet and method of producing such steel sheet |
CN105745346A (en) * | 2013-11-19 | 2016-07-06 | 新日铁住金株式会社 | Rod steel |
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2016
- 2016-03-31 CN CN201610201010.0A patent/CN105755353A/en active Pending
Patent Citations (8)
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CN1526607A (en) * | 2003-02-26 | 2004-09-08 | 新日本制铁株式会社 | Crude oil tank with welding seam having excellent anti-corrosivity |
CN101932746A (en) * | 2008-01-31 | 2010-12-29 | 杰富意钢铁株式会社 | High-strength steel sheet and process for production thereof |
US20110030854A1 (en) * | 2008-01-31 | 2011-02-10 | Jfe Steel Corporation | High-strength steel sheet and method for manufacturing the same |
US20130133786A1 (en) * | 2010-03-09 | 2013-05-30 | Jfe Steel Corporation | Method for manufacturing high strength steel sheet |
CN103314120A (en) * | 2010-10-22 | 2013-09-18 | 新日铁住金株式会社 | Process for producing hot stamp molded article, and hot stamp molded article |
CN103290308A (en) * | 2012-02-27 | 2013-09-11 | 株式会社神户制钢所 | High-strength cold-rolled steel plate and manufacturing method thereof |
US20150059935A1 (en) * | 2012-03-30 | 2015-03-05 | Voestalpine Stahl Gmbh | High strength cold rolled steel sheet and method of producing such steel sheet |
CN105745346A (en) * | 2013-11-19 | 2016-07-06 | 新日铁住金株式会社 | Rod steel |
Non-Patent Citations (1)
Title |
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汽车百科全书编撰委员会: "《汽车百科全书》", 31 January 2010 * |
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Application publication date: 20160713 |