Al-Cu system cast aluminium alloy material and preparation method thereof
Technical field
The present invention relates to a kind of Al-Cu system cast aluminium alloy material and preparation method thereof, belong to material technology
Field.
Background technology
Al-Cu system Cast aluminium alloy gold utensil has family that gentle high-temperature mechanical property is good, machinability is good, with
And the feature such as fine heat-resisting performance, aircraft industry occupies highly important status, is aircraft industry weight
Want one of structural material, also obtain extensively application in fields such as civilian industries.But owing to Al-Cu system casts
Making aluminum alloy solidification temperature range big, hot tearing and loose tendency are big, poor fluidity, easily occur crackle,
The casting flaw such as loose, so its casting character is poor.
Research currently for Al-Cu system Cast aluminium alloy gold is concentrated mainly on high-strength toughness reinforcing aspect, research
Personnel have been developed over many representative alloys, such as the A-U5GT alloy of France;The U.S.
KO-1 alloy;Muscovite BA Л 10 alloy;The ZL205A alloy etc. of China.Wherein, ZL205A
It is the cast aluminium alloy material that current intensity is the highest, but it contains Cu, Mn, Zr, V, Cd, Ti, B
Deng 7 kinds of alloying elements, complicated component, especially containing V precious metal element, price is high;And
And this ZL205A alloy is poor in mobility, hot-cracking resistance is the most poor, causes the casting character of alloy relatively
Difference, application is restricted.
Summary of the invention
The present invention provides a kind of Al-Cu system Cast aluminium alloy gold, without precious metal element, reduces alloy
Formulation cost, and while maintaining alloy high strength, improve the elongation percentage of alloy-steel casting.
The present invention also provides for the preparation method of a kind of above-mentioned Al-Cu system Cast aluminium alloy gold, and step is simple, becomes
This is relatively low.
On the one hand, the present invention provides a kind of Al-Cu system cast aluminium alloy material, by weight percentage,
The composition of Al-Cu system cast aluminium alloy material be Cu4.5-6.5%, Mn0.35-0.80%, Zn 0.05-1.0%,
Ti0.05-0.45%, Zr0.05-0.45%, rare earth element 0.05-0.5% and the Al of surplus and trace are miscellaneous
Prime element.
Further, by weight percentage, the composition of Al-Cu system cast aluminium alloy material is Cu
4.7-5.7%;Mn 0.45-0.70%;Zn 0.05-0.50%;Ti 0.15-0.35 ... %;Zr 0.05-0.25%;
Rare earth element 0.05-0.35%;Remaining is Al and micro impurity element.
Further, described rare earth element is Ce or the mischmetal with Ce as essential element.
Further, in described mischmetal, the weight percentage of Ce is 40-50%.
On the other hand, the present invention also provides for the system of a kind of Al-Cu system as above cast aluminium alloy material
Preparation Method, including:
Make aluminium ingot melt and be incubated, obtaining aluminum melt;
Adding the material containing remaining alloying element in described aluminium ingot melt and make it be completely melt, stirring is all
Even, obtain aluminium alloy melt;
Refining agent, cast molding after carrying out refine degassing processing and skimming is added in described aluminium alloy melt.
Further, the described material containing remaining alloying element is the intermediate alloy containing remaining element or alloy
Element additive.
Further, in described aluminium alloy melt, add refining agent, carry out refine degassing processing and skim
Rear standing 15-25 minute, cast molding.
Further, after described cast molding, also include foundry goods is carried out solid solution and Ageing Treatment.
Further, solid solution treatment process is to be incubated 3-30 hour at 480-580 DEG C, and then quench cooling.
Further, aging treatment process is to be incubated 3-30 hour, the most in atmosphere at 120-220 DEG C
Cooling.
The Al-Cu system Cast aluminium alloy gold composition that the present invention provides is reasonable, is main constituent at Al-Cu-Mn
On the basis of add trace alloying element Ti, Zr, Zn and rare earth etc., thus maintaining alloy high strength
Improve the casting character of Al-Cu system Cast aluminium alloy gold simultaneously;This Al-Cu system Cast aluminium alloy gold is not simultaneously
Containing precious metal element, reduce production cost.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below in the embodiment of the present invention
Technical scheme be clearly and completely described, it is clear that described embodiment be the present invention part
Embodiment rather than whole embodiments.Based on the embodiment in the present invention, ordinary skill people
The every other embodiment that member is obtained under not making creative work premise, broadly falls into the present invention and protects
The scope protected.
The present invention provides a kind of Al-Cu system cast aluminium alloy material, by weight percentage, this Al-Cu
Be cast aluminium alloy material composition be Cu4.5-6.5%, Mn0.35-0.80%, Zn 0.05-1.0%,
Ti0.05-0.45%, Zr0.05-0.45%, rare earth element 0.05-0.5% and the Al of surplus and trace are miscellaneous
Prime element.
Wherein, described rare earth element is Ce or the mischmetal with Ce as essential element.Described mixing is dilute
Soil comprises the rare earth element of at least two in addition to Ce, and the weight percentage of Ce is 40-50%.
The preparation method of the Al-Cu system cast aluminium alloy material that the present invention provides can refer to following steps and enters
OK:
1, aluminium ingot and the material containing remaining alloying element are got out by formula proportion.For making remaining alloy unit
Element quickly fuses in aluminum liquid, for refractory alloy elements such as copper, manganese, titanium, zirconiums, it is also possible to aluminium is closed
Intermediate alloy that gold casting industry is conventional or alloying element additive.
2, adding in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and is incubated to maintain melt temperature
At 700-800 DEG C, obtain aluminum melt.
3, press formula proportion again and add the material containing remaining alloying element, and agitation as appropriate, obtain aluminium alloy
Melt, after remaining alloying element is completely melt, stirs aluminium alloy melt.
4, being subsequently adding refining agent and carry out furnace refining, refining agent typically can be selected for aluminium alloy casting industry
Conventional refining agent, the RJ-1 refining agent in such as non-ferrous metal industry standard YS/T491-2005.
5, more refining aluminium alloy melt carried out degassing processing and skims, being then cast into
Type.Wherein, degassing processing can use common method of the prior art, such as with getter to adding aluminum
Alloy melt is passed through argon.Refine degassing processing after skimming, can stand 15-25 minute by melt,
Make the contamination precipitation in melt or floating, make cleaning molten, the most again cast molding further.
Further, after described cast molding, also include foundry goods is carried out solution treatment and Ageing Treatment.
The technique of described solution treatment and Ageing Treatment can refer to conventional method and carries out, such as, can be:
Solid solution treatment process is to be incubated 3-30 hour at 480-580 DEG C, and then quench cooling;Ageing Treatment
Technique is to be incubated 3-30 hour at 120-220 DEG C, cools down the most in atmosphere.
Below by way of specific embodiment to the Al-Cu system cast aluminium alloy material of the present invention and preparation side thereof
Method elaborates.
Embodiment 1:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 1.
Its preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 1 are pressed.
Table 1
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700-800 DEG C
Insulation.
(3) preprepared intermediate alloy or alloying element additive are added by several times, and agitation as appropriate.
(4) after alloying element is completely melt, alloy melt is stirred, be subsequently adding refining agent and enter
Row furnace refining.The RJ-1 refining agent that refining agent aluminium alloy casting industry is conventional, then produces refine
Raw aluminum slag claws.
(5) in melt, it is passed through argon with getter and carries out degassing processing, then it is taken off Slag treatment,
Stand about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is
Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C
It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property
Test, result is: under T5 state, tensile strength 452MPa, elongation percentage 10.9%.
Alloy in the present embodiment is near with ZL204 Cast aluminium alloy metallographic, according to national standard
The regulation of GB/T1173-2013, ZL204 Cast aluminium alloy gold is under T5 state, and tensile strength is 440MPa,
Elongation percentage is 4%.Alloy in the present embodiment is compared with ZL204 alloy, equally under T5 state, by force
Degree is suitable, but the elongation percentage of foundry goods is improved, and plasticity strengthens.
Embodiment 2:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 1.Its
Preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 2 are pressed.
Table 2
Element |
Design composition (wt%) |
Addition element alloy or additive |
Alloy or additive amount (kg) |
Al |
|
Aluminium ingot |
81.59 |
Cu |
5.9 |
Al-50Cu intermediate alloy |
11.80 |
Mn |
0.35 |
85 manganese agent |
0.41 |
Zn |
0.2 |
Pure zinc |
0.20 |
Ti |
0.15 |
Al-10Ti intermediate alloy |
1.50 |
Zr |
0.05 |
Al-10Zr intermediate alloy |
0.50 |
Ce |
0.4 |
Al-10Re intermediate alloy |
4.00 |
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700 800 DEG C
Lower insulation.
(3) addition gets out intermediate alloy or alloying element additive, and agitation as appropriate in advance by several times.
(4) after alloying element is completely melt, alloy melt is stirred.It is subsequently adding refining agent to enter
Row furnace refining.The RJ-1 refining agent of refining agent aluminium alloy casting industry universal, then produces refine
Raw aluminum slag claws.
(5) it is passed through argon with getter to the melt blend adding refining agent and carries out degassing processing, then
It is taken off Slag treatment, stands about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is
Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C
It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property
Test, result is: under T6 state, tensile strength 495MPa, elongation percentage 6.1%.
Embodiment 3:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 3.
Its preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 3 are pressed.
Table 3
Element |
Design composition (wt%) |
Addition element alloy or additive |
Alloy or additive amount (kg) |
Al |
Surplus |
Aluminium ingot |
83.66 |
Cu |
4.5 |
Fine copper |
4.50 |
Mn |
0.8 |
85 manganese agent |
0.94 |
Zn |
0.9 |
Pure zinc |
0.90 |
Ti |
0.45 |
Al-10Ti intermediate alloy |
4.50 |
Zr |
0.45 |
Al-10Zr intermediate alloy |
4.50 |
Ce |
0.1 |
Al-10Re intermediate alloy |
1.00 |
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700 800 DEG C
Lower insulation.
(3) addition gets out intermediate alloy or alloying element additive, and agitation as appropriate in advance by several times.
(4) after alloying element is completely melt, alloy melt is stirred.It is subsequently adding refining agent to enter
Row furnace refining.The RJ-1 refining agent of refining agent aluminium alloy casting industry universal, then produces refine
Raw aluminum slag claws.
(5) it is passed through argon with getter to the melt blend adding refining agent and carries out degassing processing, then
It is taken off Slag treatment, stands about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is
Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C
It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property
Test, result is: under T6 state, tensile strength 489MPa, elongation percentage 6.4%.
Embodiment 4:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 4.
Its preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 4 are pressed.
Table 4
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700 800 DEG C
Lower insulation.
(3) addition gets out intermediate alloy or alloying element additive, and agitation as appropriate in advance by several times.
(4) after alloying element is completely melt, alloy melt is stirred.It is subsequently adding refining agent to enter
Row furnace refining.The RJ-1 refining agent of refining agent aluminium alloy casting industry universal, then produces refine
Raw aluminum slag claws.
(5) it is passed through argon with getter to the melt blend adding refining agent and carries out degassing processing, then
It is taken off Slag treatment, stands about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is
Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C
It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property
Test, result is: under T6 state, tensile strength 475MPa, elongation percentage 5.1%.
Last it is noted that various embodiments above is only in order to illustrate technical scheme, rather than right
It limits;Although the present invention being described in detail with reference to foregoing embodiments, this area common
Skilled artisans appreciate that the technical scheme described in foregoing embodiments still can be modified by it,
Or the most some or all of technical characteristic is carried out equivalent;And these amendments or replacement, and
The essence not making appropriate technical solution departs from the scope of various embodiments of the present invention technical scheme.