CN105734372A - Al-Cu aluminum alloy casting material and preparation method thereof - Google Patents

Al-Cu aluminum alloy casting material and preparation method thereof Download PDF

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Publication number
CN105734372A
CN105734372A CN201610146885.5A CN201610146885A CN105734372A CN 105734372 A CN105734372 A CN 105734372A CN 201610146885 A CN201610146885 A CN 201610146885A CN 105734372 A CN105734372 A CN 105734372A
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aluminium alloy
alloy material
cast aluminium
melt
cast
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CN105734372B (en
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刘玉林
朱训明
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Wanfeng Magnesium Industry Sci & Tech Development Co Ltd Weihai
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/18Alloys based on aluminium with copper as the next major constituent with zinc
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/057Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention provides an al-Cu aluminum alloy casting material and a preparation method thereof. The Al-Cu aluminum alloy casting material comprises the following components in percentage by weight: 4.5-6.5% of Cu, 0.35-0.85% of Mn, 0.05-1.0% of Zn, 0.05-0.45% of Ti, 0.05-0.45% of Zr, 0.05-0.5% of rare earth elements, with the balance being AI and traces of impurity elements . The Al-Cu aluminum alloy casting material, provided by the invention, contains no precious metal elements, reduces the alloy formula cost, and improves the alloy casting performance when maintaining high alloy strength.

Description

Al-Cu system cast aluminium alloy material and preparation method thereof
Technical field
The present invention relates to a kind of Al-Cu system cast aluminium alloy material and preparation method thereof, belong to material technology Field.
Background technology
Al-Cu system Cast aluminium alloy gold utensil has family that gentle high-temperature mechanical property is good, machinability is good, with And the feature such as fine heat-resisting performance, aircraft industry occupies highly important status, is aircraft industry weight Want one of structural material, also obtain extensively application in fields such as civilian industries.But owing to Al-Cu system casts Making aluminum alloy solidification temperature range big, hot tearing and loose tendency are big, poor fluidity, easily occur crackle, The casting flaw such as loose, so its casting character is poor.
Research currently for Al-Cu system Cast aluminium alloy gold is concentrated mainly on high-strength toughness reinforcing aspect, research Personnel have been developed over many representative alloys, such as the A-U5GT alloy of France;The U.S. KO-1 alloy;Muscovite BA Л 10 alloy;The ZL205A alloy etc. of China.Wherein, ZL205A It is the cast aluminium alloy material that current intensity is the highest, but it contains Cu, Mn, Zr, V, Cd, Ti, B Deng 7 kinds of alloying elements, complicated component, especially containing V precious metal element, price is high;And And this ZL205A alloy is poor in mobility, hot-cracking resistance is the most poor, causes the casting character of alloy relatively Difference, application is restricted.
Summary of the invention
The present invention provides a kind of Al-Cu system Cast aluminium alloy gold, without precious metal element, reduces alloy Formulation cost, and while maintaining alloy high strength, improve the elongation percentage of alloy-steel casting.
The present invention also provides for the preparation method of a kind of above-mentioned Al-Cu system Cast aluminium alloy gold, and step is simple, becomes This is relatively low.
On the one hand, the present invention provides a kind of Al-Cu system cast aluminium alloy material, by weight percentage, The composition of Al-Cu system cast aluminium alloy material be Cu4.5-6.5%, Mn0.35-0.80%, Zn 0.05-1.0%, Ti0.05-0.45%, Zr0.05-0.45%, rare earth element 0.05-0.5% and the Al of surplus and trace are miscellaneous Prime element.
Further, by weight percentage, the composition of Al-Cu system cast aluminium alloy material is Cu 4.7-5.7%;Mn 0.45-0.70%;Zn 0.05-0.50%;Ti 0.15-0.35 ... %;Zr 0.05-0.25%; Rare earth element 0.05-0.35%;Remaining is Al and micro impurity element.
Further, described rare earth element is Ce or the mischmetal with Ce as essential element.
Further, in described mischmetal, the weight percentage of Ce is 40-50%.
On the other hand, the present invention also provides for the system of a kind of Al-Cu system as above cast aluminium alloy material Preparation Method, including:
Make aluminium ingot melt and be incubated, obtaining aluminum melt;
Adding the material containing remaining alloying element in described aluminium ingot melt and make it be completely melt, stirring is all Even, obtain aluminium alloy melt;
Refining agent, cast molding after carrying out refine degassing processing and skimming is added in described aluminium alloy melt.
Further, the described material containing remaining alloying element is the intermediate alloy containing remaining element or alloy Element additive.
Further, in described aluminium alloy melt, add refining agent, carry out refine degassing processing and skim Rear standing 15-25 minute, cast molding.
Further, after described cast molding, also include foundry goods is carried out solid solution and Ageing Treatment.
Further, solid solution treatment process is to be incubated 3-30 hour at 480-580 DEG C, and then quench cooling.
Further, aging treatment process is to be incubated 3-30 hour, the most in atmosphere at 120-220 DEG C Cooling.
The Al-Cu system Cast aluminium alloy gold composition that the present invention provides is reasonable, is main constituent at Al-Cu-Mn On the basis of add trace alloying element Ti, Zr, Zn and rare earth etc., thus maintaining alloy high strength Improve the casting character of Al-Cu system Cast aluminium alloy gold simultaneously;This Al-Cu system Cast aluminium alloy gold is not simultaneously Containing precious metal element, reduce production cost.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below in the embodiment of the present invention Technical scheme be clearly and completely described, it is clear that described embodiment be the present invention part Embodiment rather than whole embodiments.Based on the embodiment in the present invention, ordinary skill people The every other embodiment that member is obtained under not making creative work premise, broadly falls into the present invention and protects The scope protected.
The present invention provides a kind of Al-Cu system cast aluminium alloy material, by weight percentage, this Al-Cu Be cast aluminium alloy material composition be Cu4.5-6.5%, Mn0.35-0.80%, Zn 0.05-1.0%, Ti0.05-0.45%, Zr0.05-0.45%, rare earth element 0.05-0.5% and the Al of surplus and trace are miscellaneous Prime element.
Wherein, described rare earth element is Ce or the mischmetal with Ce as essential element.Described mixing is dilute Soil comprises the rare earth element of at least two in addition to Ce, and the weight percentage of Ce is 40-50%.
The preparation method of the Al-Cu system cast aluminium alloy material that the present invention provides can refer to following steps and enters OK:
1, aluminium ingot and the material containing remaining alloying element are got out by formula proportion.For making remaining alloy unit Element quickly fuses in aluminum liquid, for refractory alloy elements such as copper, manganese, titanium, zirconiums, it is also possible to aluminium is closed Intermediate alloy that gold casting industry is conventional or alloying element additive.
2, adding in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and is incubated to maintain melt temperature At 700-800 DEG C, obtain aluminum melt.
3, press formula proportion again and add the material containing remaining alloying element, and agitation as appropriate, obtain aluminium alloy Melt, after remaining alloying element is completely melt, stirs aluminium alloy melt.
4, being subsequently adding refining agent and carry out furnace refining, refining agent typically can be selected for aluminium alloy casting industry Conventional refining agent, the RJ-1 refining agent in such as non-ferrous metal industry standard YS/T491-2005.
5, more refining aluminium alloy melt carried out degassing processing and skims, being then cast into Type.Wherein, degassing processing can use common method of the prior art, such as with getter to adding aluminum Alloy melt is passed through argon.Refine degassing processing after skimming, can stand 15-25 minute by melt, Make the contamination precipitation in melt or floating, make cleaning molten, the most again cast molding further.
Further, after described cast molding, also include foundry goods is carried out solution treatment and Ageing Treatment. The technique of described solution treatment and Ageing Treatment can refer to conventional method and carries out, such as, can be:
Solid solution treatment process is to be incubated 3-30 hour at 480-580 DEG C, and then quench cooling;Ageing Treatment Technique is to be incubated 3-30 hour at 120-220 DEG C, cools down the most in atmosphere.
Below by way of specific embodiment to the Al-Cu system cast aluminium alloy material of the present invention and preparation side thereof Method elaborates.
Embodiment 1:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 1.
Its preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 1 are pressed.
Table 1
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700-800 DEG C Insulation.
(3) preprepared intermediate alloy or alloying element additive are added by several times, and agitation as appropriate.
(4) after alloying element is completely melt, alloy melt is stirred, be subsequently adding refining agent and enter Row furnace refining.The RJ-1 refining agent that refining agent aluminium alloy casting industry is conventional, then produces refine Raw aluminum slag claws.
(5) in melt, it is passed through argon with getter and carries out degassing processing, then it is taken off Slag treatment, Stand about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property Test, result is: under T5 state, tensile strength 452MPa, elongation percentage 10.9%.
Alloy in the present embodiment is near with ZL204 Cast aluminium alloy metallographic, according to national standard The regulation of GB/T1173-2013, ZL204 Cast aluminium alloy gold is under T5 state, and tensile strength is 440MPa, Elongation percentage is 4%.Alloy in the present embodiment is compared with ZL204 alloy, equally under T5 state, by force Degree is suitable, but the elongation percentage of foundry goods is improved, and plasticity strengthens.
Embodiment 2:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 1.Its Preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 2 are pressed.
Table 2
Element Design composition (wt%) Addition element alloy or additive Alloy or additive amount (kg)
Al Aluminium ingot 81.59
Cu 5.9 Al-50Cu intermediate alloy 11.80
Mn 0.35 85 manganese agent 0.41
Zn 0.2 Pure zinc 0.20
Ti 0.15 Al-10Ti intermediate alloy 1.50
Zr 0.05 Al-10Zr intermediate alloy 0.50
Ce 0.4 Al-10Re intermediate alloy 4.00
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700 800 DEG C Lower insulation.
(3) addition gets out intermediate alloy or alloying element additive, and agitation as appropriate in advance by several times.
(4) after alloying element is completely melt, alloy melt is stirred.It is subsequently adding refining agent to enter Row furnace refining.The RJ-1 refining agent of refining agent aluminium alloy casting industry universal, then produces refine Raw aluminum slag claws.
(5) it is passed through argon with getter to the melt blend adding refining agent and carries out degassing processing, then It is taken off Slag treatment, stands about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property Test, result is: under T6 state, tensile strength 495MPa, elongation percentage 6.1%.
Embodiment 3:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 3.
Its preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 3 are pressed.
Table 3
Element Design composition (wt%) Addition element alloy or additive Alloy or additive amount (kg)
Al Surplus Aluminium ingot 83.66
Cu 4.5 Fine copper 4.50
Mn 0.8 85 manganese agent 0.94
Zn 0.9 Pure zinc 0.90
Ti 0.45 Al-10Ti intermediate alloy 4.50
Zr 0.45 Al-10Zr intermediate alloy 4.50
Ce 0.1 Al-10Re intermediate alloy 1.00
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700 800 DEG C Lower insulation.
(3) addition gets out intermediate alloy or alloying element additive, and agitation as appropriate in advance by several times.
(4) after alloying element is completely melt, alloy melt is stirred.It is subsequently adding refining agent to enter Row furnace refining.The RJ-1 refining agent of refining agent aluminium alloy casting industry universal, then produces refine Raw aluminum slag claws.
(5) it is passed through argon with getter to the melt blend adding refining agent and carries out degassing processing, then It is taken off Slag treatment, stands about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property Test, result is: under T6 state, tensile strength 489MPa, elongation percentage 6.4%.
Embodiment 4:
The present embodiment is drawn up for 100kg alloy, and the percentage by weight of the most each element is as shown in table 4.
Its preparation method is as follows:
(1) the good required various alloying elements of the weight weighing of each composition in table 4 are pressed.
Table 4
(2) being added by several times in smelting furnace by aluminium ingot, heating is allowed to be completely melt, and at 700 800 DEG C Lower insulation.
(3) addition gets out intermediate alloy or alloying element additive, and agitation as appropriate in advance by several times.
(4) after alloying element is completely melt, alloy melt is stirred.It is subsequently adding refining agent to enter Row furnace refining.The RJ-1 refining agent of refining agent aluminium alloy casting industry universal, then produces refine Raw aluminum slag claws.
(5) it is passed through argon with getter to the melt blend adding refining agent and carries out degassing processing, then It is taken off Slag treatment, stands about 20 minutes afterwards, can pour into a mould.
(6), after moulding by casting, foundry goods is carried out solid solution and Ageing Treatment.Wherein, solid solution treatment process is Being incubated 3-30 hour at 480-580 DEG C, then quench cooling, and aging treatment process is at 120-220 DEG C It is incubated 3-30 hour, cools down the most in atmosphere.
The sample of the Al-Cu system cast aluminium alloy material foundry goods prepared by the present embodiment carries out tensile property Test, result is: under T6 state, tensile strength 475MPa, elongation percentage 5.1%.
Last it is noted that various embodiments above is only in order to illustrate technical scheme, rather than right It limits;Although the present invention being described in detail with reference to foregoing embodiments, this area common Skilled artisans appreciate that the technical scheme described in foregoing embodiments still can be modified by it, Or the most some or all of technical characteristic is carried out equivalent;And these amendments or replacement, and The essence not making appropriate technical solution departs from the scope of various embodiments of the present invention technical scheme.

Claims (10)

1. an Al-Cu system cast aluminium alloy material, it is characterised in that by weight percentage, Al-Cu Be the composition of cast aluminium alloy material be Cu4.5-6.5%, Mn0.35-0.85%, Zn 0.05-1.0%, Ti0.05-0.45%, Zr0.05-0.45%, rare earth element 0.05-0.5% and the Al of surplus and trace are miscellaneous Prime element.
Al-Cu system the most according to claim 1 cast aluminium alloy material, it is characterised in that by weight Amount percentages, the composition of Al-Cu system cast aluminium alloy material is Cu 4.7-5.7%;Mn 0.45-0.70%; Zn 0.05-0.50%;Ti 0.15-0.35%;Zr 0.05-0.25%;Rare earth element 0.05-0.35%;Remaining For Al and micro impurity element.
Al-Cu system the most according to claim 1 cast aluminium alloy material, it is characterised in that described Rare earth element is Ce or the mischmetal with Ce as essential element.
Al-Cu system the most according to claim 3 cast aluminium alloy material, it is characterised in that described In mischmetal, the weight percentage of Ce is 40-50%.
5. a preparation method for the Al-Cu system cast aluminium alloy material described in any one of claim 1-4, It is characterized in that, including:
Make aluminium ingot melt and be incubated, obtaining aluminum melt;
In described aluminum melt, add the material containing remaining alloying element and make it be completely melt, stirring, Obtain aluminium alloy melt;
Adding refining agent in described aluminium alloy melt and carry out refine, the most deaerated process is also watered after skimming Type casting moulding.
Al-Cu system the most according to claim 5 cast aluminium alloy material, it is characterised in that described Material containing remaining alloying element is the intermediate alloy containing remaining element or alloying element additive.
Al-Cu system the most according to claim 5 cast aluminium alloy material, it is characterised in that to institute Stating and add refining agent in aluminium alloy melt and carry out refine, the most deaerated process also stands 15-25 after skimming Minute, cast molding.
Al-Cu system the most according to claim 5 cast aluminium alloy material, it is characterised in that described After cast molding, also include foundry goods is carried out solid solution and Ageing Treatment.
Al-Cu system the most according to claim 8 cast aluminium alloy material, it is characterised in that solid solution Processing technique is to be incubated 3-30 hour at 480-580 DEG C, and then quench cooling.
Al-Cu system the most according to claim 8 cast aluminium alloy material, it is characterised in that time It is to be incubated 3-30 hour at 120-220 DEG C that effect processes technique, cools down the most in atmosphere.
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CN106282702A (en) * 2016-10-24 2017-01-04 马鞍山顺发机械制造有限公司 A kind of automotive casting high-quality aluminum alloy material
CN106893911A (en) * 2017-02-27 2017-06-27 广东省材料与加工研究所 A kind of high-strength temperature-resistant Al Cu line aluminium alloys and preparation method thereof
CN108504913A (en) * 2018-05-15 2018-09-07 沈阳明腾科技有限公司 A kind of tough cast aluminium alloy gold of high elongation rate
CN109136697A (en) * 2018-08-28 2019-01-04 兰州飞行控制有限责任公司 A kind of high intensity aluminum bronze line aluminium alloy
CN109182804A (en) * 2018-08-28 2019-01-11 兰州飞行控制有限责任公司 A kind of high intensity aluminum bronze line aluminium alloy preparation method
CN110029253A (en) * 2019-06-01 2019-07-19 合肥磊科机电科技有限公司 A kind of environmental protection highly corrosion resistant electric power copper Al rare earth alloy material and preparation method thereof
CN110592448A (en) * 2019-08-27 2019-12-20 江苏大学 Novel heat-resistant corrosion-resistant 2219 type aluminum alloy and preparation method thereof
CN114318088A (en) * 2021-12-28 2022-04-12 湖南稀土金属材料研究院有限责任公司 Aluminum alloy material and preparation method and application thereof
CN114574736A (en) * 2022-03-03 2022-06-03 威海万丰镁业科技发展有限公司 Preparation method of high-strength aluminum alloy and high-strength aluminum alloy

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106282702A (en) * 2016-10-24 2017-01-04 马鞍山顺发机械制造有限公司 A kind of automotive casting high-quality aluminum alloy material
CN106893911A (en) * 2017-02-27 2017-06-27 广东省材料与加工研究所 A kind of high-strength temperature-resistant Al Cu line aluminium alloys and preparation method thereof
CN108504913A (en) * 2018-05-15 2018-09-07 沈阳明腾科技有限公司 A kind of tough cast aluminium alloy gold of high elongation rate
CN109136697A (en) * 2018-08-28 2019-01-04 兰州飞行控制有限责任公司 A kind of high intensity aluminum bronze line aluminium alloy
CN109182804A (en) * 2018-08-28 2019-01-11 兰州飞行控制有限责任公司 A kind of high intensity aluminum bronze line aluminium alloy preparation method
CN110029253A (en) * 2019-06-01 2019-07-19 合肥磊科机电科技有限公司 A kind of environmental protection highly corrosion resistant electric power copper Al rare earth alloy material and preparation method thereof
CN110592448A (en) * 2019-08-27 2019-12-20 江苏大学 Novel heat-resistant corrosion-resistant 2219 type aluminum alloy and preparation method thereof
CN110592448B (en) * 2019-08-27 2021-06-22 江苏大学 Heat-resistant corrosion-resistant 2219 type aluminum alloy and preparation method thereof
CN114318088A (en) * 2021-12-28 2022-04-12 湖南稀土金属材料研究院有限责任公司 Aluminum alloy material and preparation method and application thereof
CN114574736A (en) * 2022-03-03 2022-06-03 威海万丰镁业科技发展有限公司 Preparation method of high-strength aluminum alloy and high-strength aluminum alloy

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