CN105733767A - High-efficiency rolling mill oil film bearing oil composition - Google Patents
High-efficiency rolling mill oil film bearing oil composition Download PDFInfo
- Publication number
- CN105733767A CN105733767A CN201610086060.9A CN201610086060A CN105733767A CN 105733767 A CN105733767 A CN 105733767A CN 201610086060 A CN201610086060 A CN 201610086060A CN 105733767 A CN105733767 A CN 105733767A
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- Prior art keywords
- oil
- effect
- fluid composition
- filmatic bearing
- press fluid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a high-efficiency rolling mill oil film bearing oil composition.The composition is prepared from, by weight, 1-85% of API first-type deep refined basic oil, 14.47-92% of API second-type hydrogenation mineral oil, 0.5-3.0% of high-efficiency complexing agent, 0.01-2.0% of anti-wear reagent at extreme pressure, 0.01-1.0% of demulsifier and 0.01-1.0% of pour point depressant.The composition is prepared by using API first-type deep refined basic oil and API second-type hydrogenation mineral oil as the basic oil, selecting import high-efficiency complexing agent, compounding anti-wear reagent at extreme pressure, demulsifier and pour point depressant through scientific matching and optimal designing; the composition has excellent anti-wear performance at extreme pressure and excellent oil-water separation performance, scratching and meshing between toothed surfaces can be effectively reduced, sintering during startup is prevented, the actual service life of an oil product is greatly prolonged, maintenance expenditures are greatly reduced, the service life of a machine is prolonged, and huge resource waste caused by unexpected shutdown is reduced.
Description
Technical field
The invention belongs to petrochemical industry, be specifically related to a kind of high-effect filmatic bearing of press fluid composition.
Background technology
Oil Film of Bearing Oil is mainly used in large high-speed rolling mill roll and high-speed rod-rolling mill group, middle tandem mill and finishing mill
Group (including pre-finish rolling) roll.Abroad Ge great oil product company Oil Film of Bearing Oil is developed relatively early, technology development comparative maturity, therefore,
Classification variety protection is many, mainly Mobil company, next to that Shell.External Oil Film of Bearing Oil has been developed in three generations so far, the
One on behalf of the antioxidant Oil Film of Bearing Oil without additive；Second on behalf of adding agent emulsion resistance antioxygen rust-proof type Oil Film of Bearing Oil；The
Three on behalf of the heavy load Oil Film of Bearing Oil adding the antirust wear-resistant type of agent antioxygen emulsion resistance.For convenience, Mobil company is summarized
It is three series, respectively 100 series, 300 series and 500 series.The Oil Film of Bearing Oil of other offshore company, all can be with
The kind of one of them series of Mobil company is corresponding, can exchange in using.
Domestic Oil Film of Bearing Oil development arises from the later stage seventies, relatively starts late, and has the most developed part oil film
Bearing oil.If Jinxi oil five factory is that Wuhan Iron and Steel Plant is developed into No. 21 Oil Film of Bearing Oils, this oil belongs to 100 series oil products, and viscosity grade is
220, the beginning of the eighties is used for Wuhan steel cold rolling factory single stand skin pass mill machine.Along with rubbing, root high-speed rod-rolling mill introduces China, oil in a large number
The units such as chemical engineering research institute, Shenyang dimension China, blue refining and Shanghai Hai Lian started to develop 500 series oil film axles in the later stage eighties
Hold oil, and it is used for commercial production.
At present Oil Film of Bearing Oil also do not have can national standard for reference, the other lubrication of ad eundem that market has occurred
Oil is all to carry out oneself's specification with the form of company standard, and it is shorter that these oil products also exist service life mostly, extreme pressure anti-wear
Can be not enough, oil-water separativeness is poor, easily the problem of oxidation deterioration.Meanwhile, moving in a large number of International Lubricants enterprise pours in, and depends on
According to advanced technical advantage, monopolizing domestic high-end refined products market, other markets of internal lube oil are main by Great Wall and the Kunlun two again
The business monopoly of big tap, all occupy high-order from the point of view of market price Lube Oil Market at home.In South China of China, especially Guangdong
Area, is eager to promote the competitive advantage of oneself, reduces price one after another, produces numerous nonstandard lubricating oil, drives internal lube oil city
The confusion of field.Secondly, China's lubricating oil uses flow process the most lack of standardization, and the refining of upstream base oil generally falls behind on treatment technology
External advanced OIL IN LUBRICATING OIL PRODUCTION technology, some long-term dependence on import of high-end oil product, certainly will industry autonomous to China's military affairs, space flight etc.
Development bring serious impact.
In recent years, metallurgy industry was relatively big by the impact in market, and the whole industry is carrying out the activity of increasing income and economizing on spending, therefore, exploitation
The special Oil Film of Bearing Oil of domestic high speed wire rod finishing block of super quality and competitive price will have economic and social benefit significantly.
Summary of the invention
It is an object of the invention to provide a kind of high-effect filmatic bearing of press fluid composition so that it is at a high speed, heavy duty or have
Working under impact load, have higher extreme pressure anti-wear, and oil-water separation is fast, after effectively preventing oil product from mixing water, emulsifying causes
Heel and toe wear, it is possible to reduce the tremendous economic loss that UNPLANNED DOWNTIME causes.
The present invention high-effect filmatic bearing of press fluid composition, is prepared from by following components in percentage by weight:
Described API mono-class deep refining base oil is Russia 250SN, in Dalian 400SN, Thailand 150BS or Indonesia 150BS
The combination of one or more.
Described API bis-class hydrogenation mineral oil is that platform moulds 500N, GS600N, one or more in Chinese ground 500N or SK500N
Combination.
Described high efficiency composition agent is the irgalube 2030A of BASF, the combination of one or more in 2030C, 2030D.
Described extreme pressure anti-wear additives be dialkyl dithiophosphate and derivant thereof, Keywords dibutyl dithiocarbamate or
The combination of one or more in triphenylphosphorothionate.
Described demulsifier is amine and in ethylene oxide condensate, expoxy propane/ethylene oxide copolymer, glycol ester
Kind or several combinations.
Described pour-point depressant is one or both the combination in polyalphaolefin, polymethacrylates.
Described API mono-class deep refining base oil kinematic viscosity at 40 DEG C is 40-600mm2/s。
Described API bis-class hydrogenation mineral oil kinematic viscosity at 40 DEG C is 80-400mm2/s。
Compared with prior art, the invention have the benefit that the present invention high-effect filmatic bearing of press fluid composition, by
Oil based on API mono-class deep refining base oil and API bis-class hydrogenation mineral oil, selects import high efficiency composition agent, compounding pole
Pressure antiwear additive, demulsifier and pour-point depressant, by scientific matching with optimize design modulation and form, have excellence extreme pressure anti-wear and
Oil-water separation performance, can effectively reduce the scratch between the flank of tooth, occlusion, and when preventing from starting, the generation of sintering phenomenon, is greatly prolonged oil
The actual life of product, expenditures for maintenance being greatly reduced, extend the service life of machine, it is huge that minimizing UNPLANNED DOWNTIME causes
Large resource is wasted.
Detailed description of the invention
Embodiment 1
High-effect filmatic bearing of press fluid composition
First the base oil of the present invention high-effect filmatic bearing of press fluid composition is configured: at the mediation still of belt stirrer
In, add GS600N 76.5%, Dalian 400SN 18.5%, Thailand 150BS 1.5%, at 50-70 DEG C, stir 1-4h allotment
Becoming the base oil of compositions, then add following material in base oil, stirring obtains compositions of the present invention.
Embodiment 2
High-effect filmatic bearing of press fluid composition
First the base oil of the present invention high-effect filmatic bearing of press fluid composition is configured.Mediation still at belt stirrer
In, add platform and mould 500N 89.4%, Indonesia 150BS 7%, at 50-70 DEG C, stir 1-4h be deployed into the base oil of compositions,
Then adding following material in base oil, stirring obtains compositions of the present invention.
Embodiment 3
High-effect filmatic bearing of press fluid composition
First the base oil of the present invention high-effect filmatic bearing of press fluid composition is configured.Mediation still at belt stirrer
In, add SK500N 58%, Indonesia 150BS 10%, Russia 250SN 27.9%, at 50-70 DEG C, stir 1-4h allocate in groups
The base oil of compound, then adds following material in base oil, and stirring obtains compositions of the present invention.
Embodiment 4
High-effect filmatic bearing of press fluid composition
First the base oil of the present invention high-effect filmatic bearing of press fluid composition is configured.Mediation still at belt stirrer
In, add SK500N 46.4%, Dalian 400SN 45%, Thailand 150BS 3.5%, at 50-70 DEG C, stir 1-4h be deployed into
The base oil of compositions, then adds following material in base oil, and stirring obtains compositions of the present invention.
High-effect filmatic bearing of press fluid composition main performance is evaluated.
The compositions of example 1 and example 3 is carried out assessment of performance, and result is as shown in table 1.
Table 1: high-effect filmatic bearing of press fluid composition example 1 and example 3 main performance evaluation result
Filmatic bearing for the high-speed rod-rolling mill that assay device is certain steel mill of following embodiment.This equipment fills respectively
Enter the lubricating oil (B) purchased on the compositions (A) of the embodiment of the present invention 1 and market, after using 7 days, measure oil-water separation
Property:
A oil-water separativeness (40-37-3ml 82 DEG C, tap water) 8 '
B oil-water separativeness (40-37-3ml 82 DEG C, tap water) 30 ' separates water outlet 5ml, 35ml oil mixing with water.
The A oil-water separativeness relative to B improves, and extends the service life of equipment greatly.
Claims (9)
1. a high-effect filmatic bearing of press fluid composition, it is characterised in that prepared by following components in percentage by weight and
Become:
High-effect filmatic bearing of press fluid composition the most according to claim 1, it is characterised in that described API mono-class is deep
The refined base oil of degree is Russia 250SN, the combination of one or more in Dalian 400SN, Thailand 150BS or Indonesia 150BS.
High-effect filmatic bearing of press fluid composition the most according to claim 1, it is characterised in that described API bis-class adds
Hydrogen mineral oil is that platform moulds 500N, GS600N, the combination of one or more in Chinese ground 500N or SK500N.
High-effect filmatic bearing of press fluid composition the most according to claim 1, it is characterised in that described high efficiency composition agent
For the irgalube 2030A of BASF, the combination of one or more in 2030C, 2030D.
High-effect filmatic bearing of press fluid composition the most according to claim 1, it is characterised in that described extreme pressure anti-wear additives
For in dialkyl dithiophosphate and derivant, Keywords dibutyl dithiocarbamate or triphenylphosphorothionate
Kind or several combinations.
High-effect filmatic bearing of press fluid composition the most according to claim 1, it is characterised in that described demulsifier is amine
With the combination of one or more in ethylene oxide condensate, expoxy propane/ethylene oxide copolymer, glycol ester.
High-effect filmatic bearing of press fluid composition the most according to claim 1, it is characterised in that described pour-point depressant is poly-
One or both combination in alhpa olefin, polymethacrylates.
High-effect filmatic bearing of press fluid composition the most according to claim 1 and 2, it is characterised in that described API mono-class
Deep refining base oil kinematic viscosity at 40 DEG C is 40-600mm2/s。
High-effect filmatic bearing of press fluid composition the most according to claim 1, it is characterised in that described API bis-class adds
Hydrogen mineral oil kinematic viscosity at 40 DEG C is 80-400mm2/s。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610086060.9A CN105733767B (en) | 2016-02-15 | 2016-02-15 | High-effect filmatic bearing of press fluid composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610086060.9A CN105733767B (en) | 2016-02-15 | 2016-02-15 | High-effect filmatic bearing of press fluid composition |
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| Publication Number | Publication Date |
|---|---|
| CN105733767A true CN105733767A (en) | 2016-07-06 |
| CN105733767B CN105733767B (en) | 2019-02-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610086060.9A Active CN105733767B (en) | 2016-02-15 | 2016-02-15 | High-effect filmatic bearing of press fluid composition |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181833A (en) * | 2018-10-15 | 2019-01-11 | 山东奇士登润滑科技有限公司 | A kind of Oil Film of Bearing Oil and preparation method thereof |
| CN115491249A (en) * | 2022-10-26 | 2022-12-20 | 中国石油化工股份有限公司 | Oil film bearing oil composition and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1259561A (en) * | 1998-10-30 | 2000-07-12 | 中国石化兰州炼油化工总厂 | Oil film bearing oil composition |
| CN1346874A (en) * | 2001-10-31 | 2002-05-01 | 上海海联润滑材料研究所 | Heavy-duty antiemulsifying oil film bearing oil |
| CN1754951A (en) * | 2004-09-28 | 2006-04-05 | 中国石油化工股份有限公司 | Composite oil composition for film bearing |
| JP2011126976A (en) * | 2009-12-16 | 2011-06-30 | Showa Shell Sekiyu Kk | Lubricant composition |
-
2016
- 2016-02-15 CN CN201610086060.9A patent/CN105733767B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1259561A (en) * | 1998-10-30 | 2000-07-12 | 中国石化兰州炼油化工总厂 | Oil film bearing oil composition |
| CN1346874A (en) * | 2001-10-31 | 2002-05-01 | 上海海联润滑材料研究所 | Heavy-duty antiemulsifying oil film bearing oil |
| CN1754951A (en) * | 2004-09-28 | 2006-04-05 | 中国石油化工股份有限公司 | Composite oil composition for film bearing |
| JP2011126976A (en) * | 2009-12-16 | 2011-06-30 | Showa Shell Sekiyu Kk | Lubricant composition |
Non-Patent Citations (1)
| Title |
|---|
| 鲍丹丹等: "HFF-MB抗磨型油膜轴承油的研制", 《石油商技》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181833A (en) * | 2018-10-15 | 2019-01-11 | 山东奇士登润滑科技有限公司 | A kind of Oil Film of Bearing Oil and preparation method thereof |
| CN109181833B (en) * | 2018-10-15 | 2021-06-11 | 山东奇士登润滑科技有限公司 | Oil film bearing oil and preparation method thereof |
| CN115491249A (en) * | 2022-10-26 | 2022-12-20 | 中国石油化工股份有限公司 | Oil film bearing oil composition and preparation method thereof |
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| Publication number | Publication date |
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| CN105733767B (en) | 2019-02-19 |
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