CN105733477A - High-fastness acrylic binder and preparation method thereof - Google Patents
High-fastness acrylic binder and preparation method thereof Download PDFInfo
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- CN105733477A CN105733477A CN201610284275.1A CN201610284275A CN105733477A CN 105733477 A CN105733477 A CN 105733477A CN 201610284275 A CN201610284275 A CN 201610284275A CN 105733477 A CN105733477 A CN 105733477A
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- parts
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- high fastness
- acryloid cement
- simethicone
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The invention provides a high-fastness acrylic binder and a preparation method thereof. The overall performances of the acrylic binder are improved by virtue of a method of introducing dimethyl silicone oil into a high-temperature chemical emulsion polymerization process. The preparation method is characterized in that other monomer components except from the dimethyl silicone oil are firstly prepared; in a reaction process, the dimethyl silicone oil is independently added, so that the properties of the silicone oil are sufficiently shown, and therefore, high hand feeling and high fastness, in application, of binder emulsion are realized, performance in mark wiping is excellent and the overall performances of the product are improved.
Description
Technical field
The invention belongs to chemical field, relate to high fastness acryloid cement and preparation method thereof.
Background technology
Dimethicone is the modified silicon oil containing two methyl, in acrylic emulsion is polymerized, introduce silicone oil and can effectively improve the combination property of binding agent, in high temperature emulsion is polymerized, the silicone oil using other prices of dimethyl-silicon oil ratio high has higher cost performance, has obvious advantage in numerous silicone oil.
Summary of the invention
For defect of the prior art, it is an object of the invention to provide a kind of high fastness acryloid cement and preparation method thereof.
The present invention is achieved by the following technical solutions:
First aspect, the present invention provides a kind of high fastness acryloid cement, and described binding agent includes each component of following parts by weight:
Butyl acrylate 250 parts,
Acrylonitrile 30 parts,
Acrylic acid methyl ester. 30 parts,
Simethicone 10-60 part,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1-2 part,
Peregal 5-10 part,
Dodecyl sodium sulfate 5-10 part,
Deionized water 570 parts；
Or described binding agent includes each component of following parts by weight:
Butyl acrylate 250 parts,
Acrylonitrile 20 parts,
Isooctyl acrylate monomer 20 parts,
Styrene 50 parts,
Simethicone 10-60 part,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1-2 part,
Peregal 5-10 part,
Dodecyl sodium sulfate 5-10 part,
Deionized water 570 parts.
Second aspect, the preparation method that the invention still further relates to aforesaid high fastness acryloid cement, described method comprises the steps:
Step 1: other component except simethicone in power 1 is put in emulsifying filling, disperse fully, standby；
Step 2: put into a certain amount of deionized water, emulsifying agent in a kettle., heating；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity drops in reactor, makes each component except simethicone first react；
Step 4: be added drop-wise in reactor by simethicone, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends, then cooling adjustment pH value, discharging,.
Preferably, in step 1, described jitter time is 30 minutes.
Preferably, in step 2, described heating-up temperature is 85 DEG C.
Preferably, in step 3, described time for adding is 3 hours.
Preferably, in step 4, described time for adding is 20 minutes.
Preferably, in step 5, described temperature retention time is 1h.
Preferably, in step 5, described pH value is 7.5.
The present invention forms free radical by initiator under high temperature, and free radical trigger monomer reacts into polymer.
Compared with prior art, the present invention has following beneficial effect:
1, preparation method of the present invention is simple, and cost is low, and efficiency is high；
2, the resin property that prepared by the inventive method is excellent, especially in fastness with feel；
3, resin of the present invention has a wide range of applications textile industry is more multi-field.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.Following example will assist in those skilled in the art and are further appreciated by the present invention, but do not limit the present invention in any form.It should be pointed out that, to those skilled in the art, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement.These broadly fall into protection scope of the present invention.
Embodiment 1
The present embodiment relates to a kind of high fastness feel excellence acryloid cement and preparation method thereof, comprises the steps:
Butyl acrylate 250 parts,
Acrylonitrile 30 parts,
Acrylic acid methyl ester. 30 parts,
Simethicone 10 parts,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1 part,
Peregal 5 parts,
Dodecyl sodium sulfate 5 parts,
Deionized water 570 parts；
Described method comprises the steps:
Step 1: above-mentioned other component except simethicone is put in emulsifying filling, disperse fully, stop after about 30 minutes, standby；
Step 2: put into the water of part and a small amount of emulsifying agent in a kettle., be heated to 85 DEG C；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity dropped in reactor in 3 hours, made each component except silicone oil first react；
Step 4: be added drop-wise in reactor in 20 minutes by silicone oil, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends 1h, then cooling adjustment pH7.5, discharging,.
Embodiment 2
The present embodiment relates to a kind of high fastness feel excellence acryloid cement and preparation method thereof, comprises the steps:
Butyl acrylate 250 parts,
Acrylonitrile 30 parts,
Acrylic acid methyl ester. 30 parts,
Simethicone 60 parts,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 2 parts,
Peregal 10 parts,
Dodecyl sodium sulfate 10 parts,
Deionized water 570 parts；
Described method comprises the steps:
Step 1: above-mentioned other component except simethicone is put in emulsifying filling, disperse fully, stop after about 30 minutes, standby；
Step 2: put into the water of part and a small amount of emulsifying agent in a kettle., be heated to 85 DEG C；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity dropped in reactor in 3 hours, made each component except silicone oil first react；
Step 4: be added drop-wise in reactor in 20 minutes by silicone oil, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends 1h, then cooling adjustment pH7.5, discharging,.
Embodiment 3
The present embodiment relates to a kind of high fastness feel excellence acryloid cement and preparation method thereof, comprises the steps:
Butyl acrylate 250 parts,
Acrylonitrile 30 parts,
Acrylic acid methyl ester. 30 parts,
Simethicone 40 parts,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1.5 parts,
Peregal 8 parts,
Dodecyl sodium sulfate 6 parts,
Deionized water 570 parts；
Described method comprises the steps:
Step 1: above-mentioned other component except simethicone is put in emulsifying filling, disperse fully, stop after about 30 minutes, standby；
Step 2: put into the water of part and a small amount of emulsifying agent in a kettle., be heated to 85 DEG C；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity dropped in reactor in 3 hours, made each component except silicone oil first react；
Step 4: be added drop-wise in reactor in 20 minutes by silicone oil, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends 1h, then cooling adjustment pH7.5, discharging,.
Embodiment 4
The present embodiment relates to a kind of high fastness feel excellence acryloid cement and preparation method thereof, comprises the steps:
Butyl acrylate 250 parts,
Acrylonitrile 20 parts,
Isooctyl acrylate monomer 20 parts,
Styrene 50 parts,
Simethicone 10 parts,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1 part,
Peregal 5 parts,
Dodecyl sodium sulfate 5 parts,
Deionized water 570 parts.
Described method comprises the steps:
Step 1: above-mentioned other component except simethicone is put in emulsifying filling, disperse fully, stop after about 30 minutes, standby；
Step 2: put into the water of part and a small amount of emulsifying agent in a kettle., be heated to 85 DEG C；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity dropped in reactor in 3 hours, made each component except silicone oil first react；
Step 4: be added drop-wise in reactor in 20 minutes by silicone oil, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends 1h, then cooling adjustment pH7.5, discharging,.
Embodiment 5
The present embodiment relates to a kind of high fastness feel excellence acryloid cement and preparation method thereof, comprises the steps:
Butyl acrylate 250 parts,
Acrylonitrile 20 parts,
Isooctyl acrylate monomer 20 parts,
Styrene 50 parts,
Simethicone 60 parts,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 2 parts,
Peregal 10 parts,
Dodecyl sodium sulfate 10 parts,
Deionized water 570 parts.
Described method comprises the steps:
Step 1: above-mentioned other component except simethicone is put in emulsifying filling, disperse fully, stop after about 30 minutes, standby；
Step 2: put into the water of part and a small amount of emulsifying agent in a kettle., be heated to 85 DEG C；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity dropped in reactor in 3 hours, made each component except silicone oil first react；
Step 4: be added drop-wise in reactor in 20 minutes by silicone oil, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends 1h, then cooling adjustment pH7.5, discharging,.
Embodiment 6
The present embodiment relates to a kind of high fastness feel excellence acryloid cement and preparation method thereof, comprises the steps:
Butyl acrylate 250 parts,
Acrylonitrile 20 parts,
Isooctyl acrylate monomer 20 parts,
Styrene 50 parts,
Simethicone 50 parts,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1.8 parts,
Peregal 7 parts,
Dodecyl sodium sulfate 8 parts,
Deionized water 570 parts.
Described method comprises the steps:
Step 1: above-mentioned other component except simethicone is put in emulsifying filling, disperse fully, stop after about 30 minutes, standby；
Step 2: put into the water of part and a small amount of emulsifying agent in a kettle., be heated to 85 DEG C；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity dropped in reactor in 3 hours, made each component except silicone oil first react；
Step 4: be added drop-wise in reactor in 20 minutes by silicone oil, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends 1h, then cooling adjustment pH7.5, discharging,.
The method that embodiment 1-6 relates to is the method introducing dimethicone in the process of high temeperature chemistry emulsion polymerization, improves the combination property of acryloid cement；It is specially the inventive method and first prepares except dimethicone other monomer components unexpected, in the process of reaction, it is individually added into dimethicone, the performance making silicone oil is embodied fully, achieve the adhesive agent emulsion high feel in application, high fastness, and in scratch, performance is excellent, improves the combination property of product.
Above specific embodiments of the invention are described.It is to be appreciated that the invention is not limited in above-mentioned particular implementation, those skilled in the art can make various deformation or amendment within the scope of the claims, and this has no effect on the flesh and blood of the present invention.
Claims (8)
1. one kind high fastness acryloid cement, it is characterised in that described binding agent includes each component of following parts by weight:
Butyl acrylate 250 parts,
Acrylonitrile 30 parts,
Acrylic acid methyl ester. 30 parts,
Simethicone 10-60 part,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1-2 part,
Peregal 5-10 part,
Dodecyl sodium sulfate 5-10 part,
Deionized water 570 parts；
Or include each component of following parts by weight:
Butyl acrylate 250 parts,
Acrylonitrile 20 parts,
Isooctyl acrylate monomer 20 parts,
Styrene 50 parts,
Simethicone 10-60 part,
6 parts of acrylic acid,
4 parts of itaconic acid,
N hydroxymethyl acrylamide 4 parts,
Acrylamide 1-2 part,
Peregal 5-10 part,
Dodecyl sodium sulfate 5-10 part,
Deionized water 570 parts.
2. the preparation method of a high fastness acryloid cement as claimed in claim 1, it is characterised in that described method comprises the steps:
Step 1: other component except simethicone except in power 1 is put in emulsifying filling, disperses fully, standby；
Step 2: put into a certain amount of deionized water, emulsifying agent in a kettle., heating；
Step 3: the pre-emulsion in emulsifying being filled at the uniform velocity drops in reactor, makes each component except simethicone first react；
Step 4: be added drop-wise in reactor by simethicone, adds silicone oil so that it is be generally in molecule outer layer when reaction does not terminate；
Step 5, preserving heat after reaction ends, then cooling adjustment pH value, discharging,.
3. the preparation method of high fastness acryloid cement as claimed in claim 2, it is characterised in that in step 1, described jitter time is 30 minutes.
4. the preparation method of high fastness acryloid cement as claimed in claim 2, it is characterised in that in step 2, described heating-up temperature is 85 DEG C.
5. the preparation method of high fastness acryloid cement as claimed in claim 2, it is characterised in that in step 3, described time for adding is 3 hours.
6. the preparation method of high fastness acryloid cement as claimed in claim 2, it is characterised in that in step 4, described time for adding is 20 minutes.
7. the preparation method of high fastness acryloid cement as claimed in claim 2, it is characterised in that in step 5, described temperature retention time is 1h.
8. the preparation method of high fastness acryloid cement as claimed in claim 2, it is characterised in that in step 5, described pH value is 7.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610284275.1A CN105733477A (en) | 2016-05-04 | 2016-05-04 | High-fastness acrylic binder and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610284275.1A CN105733477A (en) | 2016-05-04 | 2016-05-04 | High-fastness acrylic binder and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105733477A true CN105733477A (en) | 2016-07-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610284275.1A Pending CN105733477A (en) | 2016-05-04 | 2016-05-04 | High-fastness acrylic binder and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880208A (en) * | 2017-12-12 | 2018-04-06 | 杭州龙驹合成材料有限公司 | A kind of gold stamping slurry emulsion and preparation method thereof |
| CN109456718A (en) * | 2018-11-05 | 2019-03-12 | 合肥聚合辐化技术有限公司 | A kind of high fastness, washing and the superior adhesive of feel and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403522A (en) * | 2002-08-31 | 2003-03-19 | 贾铭琳 | Composite adhesive specially for heat insulating polystyrene outer-wall board |
| CN104961867A (en) * | 2015-06-25 | 2015-10-07 | 合肥聚合辐化技术有限公司 | Anti-stick mucilage resin and preparation method thereof |
| CN105001369A (en) * | 2015-06-25 | 2015-10-28 | 合肥聚合辐化技术有限公司 | Active pigment imitating printing adhesive and preparation method thereof |
| CN105017471A (en) * | 2015-06-25 | 2015-11-04 | 合肥聚合辐化技术有限公司 | Chemical radiation-combined unsaturated monomer water-containing dispersoid polymerization method |
-
2016
- 2016-05-04 CN CN201610284275.1A patent/CN105733477A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403522A (en) * | 2002-08-31 | 2003-03-19 | 贾铭琳 | Composite adhesive specially for heat insulating polystyrene outer-wall board |
| CN104961867A (en) * | 2015-06-25 | 2015-10-07 | 合肥聚合辐化技术有限公司 | Anti-stick mucilage resin and preparation method thereof |
| CN105001369A (en) * | 2015-06-25 | 2015-10-28 | 合肥聚合辐化技术有限公司 | Active pigment imitating printing adhesive and preparation method thereof |
| CN105017471A (en) * | 2015-06-25 | 2015-11-04 | 合肥聚合辐化技术有限公司 | Chemical radiation-combined unsaturated monomer water-containing dispersoid polymerization method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880208A (en) * | 2017-12-12 | 2018-04-06 | 杭州龙驹合成材料有限公司 | A kind of gold stamping slurry emulsion and preparation method thereof |
| CN107880208B (en) * | 2017-12-12 | 2020-06-26 | 杭州龙驹合成材料有限公司 | Gold stamping slurry emulsion and preparation method thereof |
| CN109456718A (en) * | 2018-11-05 | 2019-03-12 | 合肥聚合辐化技术有限公司 | A kind of high fastness, washing and the superior adhesive of feel and preparation method thereof |
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