CN105731642A - Method for lowering para-toluenesulfonic acid waste water COD through A2/O2 biological method - Google Patents
Method for lowering para-toluenesulfonic acid waste water COD through A2/O2 biological method Download PDFInfo
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- CN105731642A CN105731642A CN201610087777.5A CN201610087777A CN105731642A CN 105731642 A CN105731642 A CN 105731642A CN 201610087777 A CN201610087777 A CN 201610087777A CN 105731642 A CN105731642 A CN 105731642A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
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- Hydrology & Water Resources (AREA)
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- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
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- Organic Chemistry (AREA)
- Activated Sludge Processes (AREA)
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Abstract
The invention discloses a method for lowering para-toluenesulfonic acid waste water COD through an A2/O2 biological method. Waste water sequentially flows through a water inlet adjusting tank, a first-level anaerobic mixing tank, a first-level anaerobic mud lifting tank, a first-level aerobic aeration tank, a first-level aerobic mud lifting tank, a second-level anaerobic mixing tank, a second-level anaerobic mud lifting tank, a second-level aerobic aeration tank, a second-level aerobic mud lifting tank and a final sedimentation tank; water soluble alcohols and micromolecule organic acid are added to anaerobic activated sludge of the mixing tank at the anaerobic stage; water soluble alcohols, organic acid and monosaccharide are added to aerobic activated sludge of the aeration tank at the aerobic stage. By means of the method, biodegradability of para-toluenesulfonic acid can be improved, and para-toluenesulfonic acid pretreatment time and cost are reduced. Added agentia is safe, free of toxicity, sufficient in agentia source, easy and convenient to make, low in production cost, long in shelf life and can obviously lower the value of COD in waste water, so that safe emission is reached.
Description
Technical field
The present invention relates to a kind of method of wastewater treatment, waste water especially contains the method for wastewater treatment of p-methyl benzenesulfonic acid.
Background technology
P-methyl benzenesulfonic acid is a kind of important industrial chemicals, has stronger bio-toxicity and inhibitory action.Traditional biological A/O method is difficult to its waste water is processed.Owing to the biodegradability of p-methyl benzenesulfonic acid is poor.Current p-methyl benzenesulfonic acid wastewater biological A/O processes needs multiple method to carry out pretreatment, such as By Ozone, photocatalytic oxidation etc., these methods can improve wastewater biodegradability to a certain extent, but there is number of drawbacks, as: operating cost is higher, and materialization reagent consumption amount is big, and solid waste yield is big.
Summary of the invention
It is an object of the invention to provide a kind of method that can effectively reduce p-methyl benzenesulfonic acid waste water COD.
The technical solution adopted for the present invention to solve the technical problems is:
To sequentially pass through into water regulating reservoir, one-level anaerobism mixing pit containing p-methyl benzenesulfonic acid waste water, one-level anaerobism carries mud sump, one-level aerobic aeration pond, one-level is aerobic carries mud sump, secondary anaerobic mixing pit, secondary anaerobic carries mud sump, two grades of aerobic aeration ponds, and two grades aerobic carries mud sump and final deposition pool；Mixing pit and interpolation water soluble alcohols and small molecular organic acid in the anaerobic activated sludge carried in mud sump at anaerobic stages；Aeration tank and interpolation water soluble alcohols, organic acid and monosaccharide in the aerobic activated sludge carried in mud sump at aerobic stage；Interpolation water soluble alcohols is methanol, ethanol, ethylene glycol, propanol, propylene glycol, the one of butanol or two kinds or three kinds.
Small molecular organic acid is formic acid, acetic acid, propanoic acid, butanoic acid, lactic acid and the one in sodium salt thereof or two kinds or three kinds.
Anaerobic stages anaerobic activated sludge adds the volume that volume is water soluble alcohols 5 to 25 times of small molecular organic acid, according to wastewater volume 100,000/prepare to one of percentage.
Organic acid is malic acid, citric acid and the one in sodium salt two kinds or three kinds thereof.
Monosaccharide is xylose, glucose, fructose, the one in galactose two kinds or three kinds.
Aerobic stage, organic acid is water soluble alcohols 3 to 10 times added in aerobic activated sludge, monosaccharide is water soluble alcohols 2 to 5 times of interpolation, prepare according to million/mono-to one thousandth of wastewater volume.
The present invention can be directly used for biological A2/O2The anaerobic activated sludge of method and aerobic activated sludge, it is possible to improve the biodegradability of p-methyl benzenesulfonic acid, reduce time and the cost of its pretreatment.The own safety non-toxic of medicament added, medicine source is abundant, and simple for production, production cost is relatively low, and the shelf-life is longer, aerobic through secondary anaerobic and two grades, can substantially reduce the COD value in waste water, reach safety dumping.
Detailed description of the invention
Technical scheme described in detail below.The embodiment of the present invention is intended for concrete structure is described, the scale of this structure should not be limited by the examples.
Embodiment 1
P-methyl benzenesulfonic acid waste water, COD value=15037mg/L, A during water inlet2/O2Bioanalysis reaction system is: 9.09 tons of anaerobism segment body system, muddy water ratio is 30%；Aerobic section system 6.83 tons, muddy water ratio is 50%.Sequentially pass through into water regulating reservoir, one-level anaerobism mixing pit containing p-methyl benzenesulfonic acid waste water, one-level anaerobism carries mud sump, one-level aerobic aeration pond, one-level is aerobic carries mud sump, secondary anaerobic mixing pit, secondary anaerobic carries mud sump, two grades of aerobic aeration ponds, and two grades aerobic carries mud sump and final deposition pool；Adding in anaerobism section anaerobic activated sludge: ethanol, propanol, butanol mixed solution be 90.9ml altogether, formic acid, sodium acetate, butanoic acid mixed solution be 454.5ml altogether simultaneously.Aerobic section, aerobic activated sludge add simultaneously: ethylene glycol, propanol, butanol mixed solution be 3.4ml altogether, malic acid 10.3g, fructose 6.8, water outlet COD value=754mg/L after reaction 22h
Embodiment 2:
P-methyl benzenesulfonic acid waste water, COD value=15345mg/L, A during water inlet2/O2Bioanalysis reaction system is: 9.09 tons of anaerobism segment body system, muddy water ratio is 30%；Aerobic section system 6.83 tons, muddy water ratio is 50%.Sequentially pass through into water regulating reservoir, one-level anaerobism mixing pit containing p-methyl benzenesulfonic acid waste water, one-level anaerobism carries mud sump, one-level aerobic aeration pond, one-level is aerobic carries mud sump, secondary anaerobic mixing pit, secondary anaerobic carries mud sump, two grades of aerobic aeration ponds, and two grades aerobic carries mud sump and final deposition pool；In anaerobism section, adding: ethylene glycol in anaerobic activated sludge, mixed with propylene glycol solution is 272.7ml altogether simultaneously, and formic acid, sodium propionate mixed solution be 2454.3ml altogether.Aerobic section, aerobic activated sludge add simultaneously: ethylene glycol, butanol mixed solution be 6.8ml, sodium citrate: 40.8g, xylose: 34g altogether, water outlet COD value=680mg/L after reaction 22h
Embodiment 3:
P-methyl benzenesulfonic acid waste water, COD value=17537mg/L, A during water inlet2/O2Bioanalysis reaction system is: 9.09 tons of anaerobism segment body system, muddy water ratio is 30%；Aerobic section system 6.83 tons, muddy water ratio is 50%.Sequentially pass through into water regulating reservoir, one-level anaerobism mixing pit containing p-methyl benzenesulfonic acid waste water, one-level anaerobism carries mud sump, one-level aerobic aeration pond, one-level is aerobic carries mud sump, secondary anaerobic mixing pit, secondary anaerobic carries mud sump, two grades of aerobic aeration ponds, and two grades aerobic carries mud sump and final deposition pool；In anaerobism section, adding: butanol: 9.09L, formic acid, sodium acetate in anaerobic activated sludge, sodium butyrate mixed solution is 227.25L altogether simultaneously.Aerobic section, aerobic activated sludge add simultaneously: butanol: 546ml, natrium malicum: 2184g, galactose: 2730g, water outlet COD value=792mg/L after reaction 22h.
Claims (7)
1. an A2/O2Bioanalysis reduces the method for p-methyl benzenesulfonic acid waste water COD, it is characterized in that waste water sequentially passes through into water regulating reservoir, one-level anaerobism mixing pit, one-level anaerobism carries mud sump, one-level aerobic aeration pond, one-level is aerobic carries mud sump, secondary anaerobic mixing pit, secondary anaerobic carries mud sump, two grades of aerobic aeration ponds, two grades aerobic carries mud sump and final deposition pool；The anaerobic activated sludge of the mixing pit of anaerobic stages adds water soluble alcohols and small molecular organic acid；The aerobic activated sludge of the Aeration tank of aerobic stage adds water soluble alcohols, organic acid and monosaccharide.
2. an A2/O2Bioanalysis reduces the method for p-methyl benzenesulfonic acid waste water COD, it is characterised in that described interpolation water soluble alcohols is methanol, ethanol, ethylene glycol, propanol, propylene glycol, the one of butanol or two kinds or three kinds.
3. an A2/O2Bioanalysis reduces the method for p-methyl benzenesulfonic acid waste water COD, it is characterised in that described small molecular organic acid is the one in formic acid, acetic acid, propanoic acid, butanoic acid, lactic acid and sodium salt thereof or two kinds or three kinds.
4. an A2/O2The method of bioanalysis reduction p-methyl benzenesulfonic acid waste water COD, it is characterised in that described organic acid is malic acid, citric acid and the one in sodium salt two kinds or three kinds thereof.
5. an A2/O2Bioanalysis reduces the method for p-methyl benzenesulfonic acid waste water COD, it is characterised in that described monosaccharide is xylose, glucose, fructose, the one in galactose two kinds or three kinds.
6. an A2/O2Bioanalysis reduces the method for p-methyl benzenesulfonic acid waste water, it is characterized in that the volume that volume is water soluble alcohols 5 to 25 times of small molecular organic acid added in described anaerobic stages anaerobic activated sludge, according to wastewater volume 100,000/be added to one of percentage.
7. an A2/O2Bioanalysis reduces the method for p-methyl benzenesulfonic acid waste water, it is characterized in that described aerobic stage, organic acid is water soluble alcohols 3 to 10 times added in aerobic activated sludge, monosaccharide is water soluble alcohols 2 to 5 times of interpolation, it is added according to million/mono-to one thousandth of wastewater volume.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935163A (en) * | 2017-11-02 | 2018-04-20 | 北京博汇特环保科技股份有限公司 | Carbon source solution from agriculture derivative and its preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101830602A (en) * | 2010-05-18 | 2010-09-15 | 沈阳石蜡化工有限公司 | Biochemical treatment method of acrylic ester industrial wastewater |
| CN103288299A (en) * | 2013-05-26 | 2013-09-11 | 哈尔滨理工大学 | Biochemical treatment method of coal chemical industry wastewater |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101830602A (en) * | 2010-05-18 | 2010-09-15 | 沈阳石蜡化工有限公司 | Biochemical treatment method of acrylic ester industrial wastewater |
| CN103288299A (en) * | 2013-05-26 | 2013-09-11 | 哈尔滨理工大学 | Biochemical treatment method of coal chemical industry wastewater |
Non-Patent Citations (1)
| Title |
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| 王伟东等主编: "《微生物学》", 3 August 2015, 中国农业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935163A (en) * | 2017-11-02 | 2018-04-20 | 北京博汇特环保科技股份有限公司 | Carbon source solution from agriculture derivative and its preparation method and application |
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