CN105729958A - High-temperature-resistant and high-barrier multilayer compound film for packaging bags - Google Patents

High-temperature-resistant and high-barrier multilayer compound film for packaging bags Download PDF

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Publication number
CN105729958A
CN105729958A CN201610136616.0A CN201610136616A CN105729958A CN 105729958 A CN105729958 A CN 105729958A CN 201610136616 A CN201610136616 A CN 201610136616A CN 105729958 A CN105729958 A CN 105729958A
Authority
CN
China
Prior art keywords
polyethylene
layer
film layers
10min
density polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610136616.0A
Other languages
Chinese (zh)
Inventor
吴春锋
张俊杰
王勇
唐海波
汪桂林
陈小平
胡毅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HAINING CHANGLIN PACKAGING MATERIALS Co Ltd
Original Assignee
HAINING CHANGLIN PACKAGING MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HAINING CHANGLIN PACKAGING MATERIALS Co Ltd filed Critical HAINING CHANGLIN PACKAGING MATERIALS Co Ltd
Priority to CN201610136616.0A priority Critical patent/CN105729958A/en
Publication of CN105729958A publication Critical patent/CN105729958A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/327Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/246All polymers belonging to those covered by groups B32B27/32 and B32B27/30
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • B32B2255/205Metallic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)
  • Bag Frames (AREA)

Abstract

The invention discloses a high-temperature-resistant and high-barrier multilayer compound film for packaging bags. The high-temperature-resistant and high-barrier multilayer compound film comprises polyester film layers, polyester aluminized film layers and polyethylene film layers which are sequentially compounded with one another. The polyethylene film layers comprise, by weight, 20-30 parts of low-density polyethylene, 15-25 parts of polypropylene random copolymers and 45-62 parts of linear low-density polyethylene or metallocene polyethylene. The high-temperature-resistant and high-barrier multilayer compound film for the packaging bags has the advantages that the aluminized film layers are high in barrier, various raw materials are reasonably proportioned, accordingly, synergistic effects of the various raw materials can be sufficiently realized, the polyethylene film layers are excellent in high-temperature resistance, products in the packaging bags are stable in property, and the shelf lives of packaged contents can be prolonged; solvent-free compounding processes are implemented for the adjacent film layers, the gluing amount is 1.4-1.6 g/m<2> under the control, accordingly, the hygienic properties of the products can be improved while the compound bonding strength is guaranteed, residual solvents can be prevented, and contamination on the packaged contents can be reduced.

Description

High temperature resistant high-barrier multi-layer compound package bag film
Technical field
The invention belongs to packaging bag manufacturing technology field, be specifically related to a kind of high temperature resistant high-barrier multilamellar multiple Close bag membrane.
Background technology
Packaging bag refers to the sack for packing various articles for use, makes goods convenient in producing the process of circulation Transport, easily stores.It is widely used in daily life and commercial production.Prior art is used for manufacture The most generally there is high temperature resistant and that barrier is poor problem in bag membrane, causes bag membrane in some field
Summary of the invention
To this, it is desirable to provide a kind of barrier and the good combined package bag film of resistance to elevated temperatures.
The technical scheme realizing the object of the invention is:
A kind of high temperature resistant high-barrier multi-layer compound package bag film, by polyester film, polyester aluminium plating membrane and Polyethylene film layer is sequentially compounding, and described polyethylene film layer is made up of the proportioning raw materials of following weight portion: Low Density Polyethylene 20-30 part, polypropylene random copolymer 15-25 part, linear low density polyethylene or Person's metallocene PE 45-62 part;
The melt index of described Low Density Polyethylene is 1.0-2.0g/10min, described polypropylene random copolymerization The melt index of thing is 1.0-3.0g/10min, and the melt index of described linear low density polyethylene is 1.0-2.0g/10min, or the melt index of described metallocene PE is 0.5-2.5g/10min.
In technique scheme, the thickness of described polyethylene film layer accounts for more than the 60% of bag membrane thickness, And the thickness of described polyethylene film layer is not less than 20um.
In technique scheme, described polyethylene film layer outer layer has corona processing layer, and its corona value exists Between 38-42.
The present invention has a positive effect: in (1) bag membrane of the present invention due to have aluminium plating membrane because of And there is higher barrier, and simultaneously because polyethylene film layer has polyethylene film layer, described poly-second Alkene film layer is made up of the proportioning raw materials of following weight portion: Low Density Polyethylene 20-30 part, polypropylene without Rule copolymer 1 5-25 part, linear low density polyethylene or metallocene PE 45-62 part, and institute The melt index stating Low Density Polyethylene is 1.0-2.0g/10min, melting of described polypropylene random copolymer Melting index is 1.0-3.0g/10min, and the melt index of described linear low density polyethylene is 1.0-2.0g/10min, or when the melt index of described metallocene PE is 0.5-2.5g/10min, logical Cross the above-mentioned rational proportioning of each raw material, give full play to the synergism between each raw material, so that resistance to Polyethylene film layer has good resistance to elevated temperatures.
Detailed description of the invention
Below the particular content in the present invention is done with explanation:
Embodiment 1
High temperature resistant high-barrier multi-layer compound package bag film in the present embodiment, by polyester film, polyester plating Aluminum membranous layer and polyethylene film layer are sequentially compounding, and described polyethylene film layer is by the raw material of following weight portion Proportioning is made: Low Density Polyethylene 20 parts, polypropylene random copolymer 15 parts, and linea low density gathers Ethylene or metallocene PE 45 parts, the melt index of described Low Density Polyethylene is 1.0g/10min, The melt index of described polypropylene random copolymer is 1.0g/10min, described linear low density polyethylene Melt index is 1.0g/10min, if selecting metallocene PE, and melting of the most described metallocene PE Index is 0.5g/10min.
In the present embodiment, the thickness of described polyethylene film layer account for the 60% of described polyethylene film layer thickness with On, and the thickness of described polyethylene film layer is not less than 20um, so can reach more preferable high-temperature resistant result.
Further, described polyethylene film layer outer layer has corona processing layer, its corona value between 38-42, Use this structure just can be easy at polyethylene film layer surface printing or with other material to be combined.
Embodiment 2
High temperature resistant high-barrier multi-layer compound package bag film in the present embodiment, by polyester film, polyester plating Aluminum membranous layer and polyethylene film layer are sequentially compounding, and described polyethylene film layer is by the raw material of following weight portion Proportioning is made: Low Density Polyethylene 25 parts, polypropylene random copolymer 20 parts, and linea low density gathers Ethylene or metallocene PE 54 parts, the melt index of described Low Density Polyethylene is 1.5g/10min, The melt index of described polypropylene random copolymer is 1.5g/10min, described linear low density polyethylene Melt index is 1.5g/10min, or the melt index of described metallocene PE is 1.5g/10min.
In the present embodiment, the thickness of described polyethylene film layer accounts for more than the 60% of bag membrane thickness, and The thickness of described polyethylene film layer is not less than 20um, so can reach more preferable high-temperature resistant result.
Further, described polyethylene film layer outer layer has corona processing layer, its corona value between 38-42, Use this structure just can be easy at polyethylene film layer surface printing or with other material to be combined.
Embodiment 3
High temperature resistant high-barrier multi-layer compound package bag film in the present embodiment, by polyester film, polyester plating Aluminum membranous layer and polyethylene film layer are sequentially compounding, and described polyethylene film layer is by the raw material of following weight portion Proportioning is made: Low Density Polyethylene 30 parts, polypropylene random copolymer 25 parts, and linea low density gathers Ethylene or metallocene PE 62 parts, the melt index of described Low Density Polyethylene is 2.0g/10min, The melt index of described polypropylene random copolymer is 3.0g/10min, described linear low density polyethylene Melt index is 2.0g/10min, or the melt index of described metallocene PE is 2.5g/10min.
In the present embodiment, the thickness of described polyethylene film layer accounts for more than the 60% of bag membrane thickness, and The thickness of described polyethylene film layer is not less than 20um, so can reach more preferable high-temperature resistant result.
Further, described polyethylene film layer outer layer has corona processing layer, its corona value between 38-42, Use this structure just can be easy at polyethylene film layer surface printing or with other material to be combined.
In experiment test uses the various embodiments described above, the heatproof of the bag membrane that formula is made is higher than common Bag membrane more than 15 DEG C, the manufacture method of the bag membrane in the various embodiments described above is art technology Well known to personnel, the present invention does not illustrates.
Obviously, the above embodiment of the present invention is only for clearly demonstrating example of the present invention, And it is not the restriction to embodiments of the present invention.For those of ordinary skill in the field, Can also make other changes in different forms on the basis of the above description.Here without also Cannot all of embodiment be given exhaustive.And these connotations belonging to the present invention are extended out Obvious change or variation still fall within protection scope of the present invention.

Claims (3)

1. a high temperature resistant high-barrier multi-layer compound package bag film, by polyester film, polyester plating Aluminum membranous layer and polyethylene film layer are sequentially compounding, it is characterised in that described polyethylene film layer by The proportioning raw materials of following weight portion is made: Low Density Polyethylene 20-30 part, polypropylene random is common Polymers 15-25 part, linear low density polyethylene or metallocene PE 45-62 part;
The melt index of described Low Density Polyethylene is 1.0-2.0g/10min, described polypropylene without The melt index of rule copolymer is 1.0-3.0g/10min, melting of described linear low density polyethylene Melting index is 1.0-2.0g/10min, or the melt index of described metallocene PE is 0.5-2.5g/10min。
High temperature resistant high-barrier multi-layer compound package bag film the most according to claim 1, its Being characterised by, the thickness of described polyethylene film layer accounts for more than the 60% of bag membrane thickness, and institute State the thickness of polyethylene film layer not less than 20um.
High temperature resistant high-barrier multi-layer compound package bag film the most according to claim 1 and 2, It is characterized in that, described polyethylene film layer outer layer has corona processing layer, and its corona value is at 38-42 Between.
CN201610136616.0A 2016-03-11 2016-03-11 High-temperature-resistant and high-barrier multilayer compound film for packaging bags Pending CN105729958A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610136616.0A CN105729958A (en) 2016-03-11 2016-03-11 High-temperature-resistant and high-barrier multilayer compound film for packaging bags

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610136616.0A CN105729958A (en) 2016-03-11 2016-03-11 High-temperature-resistant and high-barrier multilayer compound film for packaging bags

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Publication Number Publication Date
CN105729958A true CN105729958A (en) 2016-07-06

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106985319A (en) * 2017-03-21 2017-07-28 上海迈高新材料科技有限公司 A kind of method that use the tape casting prepares aseptic packaging composite seal
CN107042673A (en) * 2017-04-06 2017-08-15 黄山永新股份有限公司 A kind of not slime body composite package film and its production technology
CN115648765A (en) * 2022-10-26 2023-01-31 江苏利特尔绿色包装股份有限公司 High-barrier heavy-packaging one-way breathable bag and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101081653A (en) * 2007-07-16 2007-12-05 刘建林 High-obstruct multiple-layer film for packaging liquid and manufacturing method thereof
CN202242207U (en) * 2011-06-15 2012-05-30 何凌 Biaxially oriented polypropylene film and composite material thereof
US20120148785A1 (en) * 2010-12-09 2012-06-14 Industrial Technology Research Institute Gas-barrier heat-seal composite films and vacuum insulation panels comprising the same
CN103203919A (en) * 2013-02-22 2013-07-17 浙江诚信包装材料有限公司 High-barrier semi-high temperature cooking liquid packaging material and packaging bag made of the same
CN103707601A (en) * 2013-12-06 2014-04-09 蚌埠天成包装材料有限公司 High-temperature-resistant boiling packaging film with three-layer structure
CN103739962A (en) * 2014-01-02 2014-04-23 上海紫华企业有限公司 Polyolefin microporous air-permeable membrane and preparation method thereof
CN204712572U (en) * 2015-06-26 2015-10-21 浙江金石包装有限公司 A kind of packaging film

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101081653A (en) * 2007-07-16 2007-12-05 刘建林 High-obstruct multiple-layer film for packaging liquid and manufacturing method thereof
US20120148785A1 (en) * 2010-12-09 2012-06-14 Industrial Technology Research Institute Gas-barrier heat-seal composite films and vacuum insulation panels comprising the same
CN202242207U (en) * 2011-06-15 2012-05-30 何凌 Biaxially oriented polypropylene film and composite material thereof
CN103203919A (en) * 2013-02-22 2013-07-17 浙江诚信包装材料有限公司 High-barrier semi-high temperature cooking liquid packaging material and packaging bag made of the same
CN103707601A (en) * 2013-12-06 2014-04-09 蚌埠天成包装材料有限公司 High-temperature-resistant boiling packaging film with three-layer structure
CN103739962A (en) * 2014-01-02 2014-04-23 上海紫华企业有限公司 Polyolefin microporous air-permeable membrane and preparation method thereof
CN204712572U (en) * 2015-06-26 2015-10-21 浙江金石包装有限公司 A kind of packaging film

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106985319A (en) * 2017-03-21 2017-07-28 上海迈高新材料科技有限公司 A kind of method that use the tape casting prepares aseptic packaging composite seal
CN107042673A (en) * 2017-04-06 2017-08-15 黄山永新股份有限公司 A kind of not slime body composite package film and its production technology
CN107042673B (en) * 2017-04-06 2019-04-09 黄山永新股份有限公司 A kind of not slime body composite package film and its production technology
CN115648765A (en) * 2022-10-26 2023-01-31 江苏利特尔绿色包装股份有限公司 High-barrier heavy-packaging one-way breathable bag and preparation method thereof
CN115648765B (en) * 2022-10-26 2023-09-26 江苏利特尔绿色包装股份有限公司 High-barrier heavy-packaging unidirectional air-permeable bag and preparation method thereof

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Application publication date: 20160706

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