CN105729603A - Composite type wood softening agent - Google Patents
Composite type wood softening agent Download PDFInfo
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- CN105729603A CN105729603A CN201610148902.9A CN201610148902A CN105729603A CN 105729603 A CN105729603 A CN 105729603A CN 201610148902 A CN201610148902 A CN 201610148902A CN 105729603 A CN105729603 A CN 105729603A
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- softening agent
- acid ester
- fatty acid
- stearate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/06—Softening or hardening of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a composite type wood softening agent. The composite type wood softening agent is prepared from the following components in parts by weight: 2-5 parts of talcum powder, 2-6 parts of organic bentonite, 10-20 parts of polyoxyethylene aliphatate, 2-5 parts of dodecyldimethyl betaine, 1-4 parts of lauryl sodium sulfate, 2-4 parts of zinc stearate, 1-3 parts of calcium stearate, 1-3 parts of sodium stearate, 60-70 parts of chlorinated paraffin, 2-8 parts of fatty alcohol-polyoxyethylene ether, 3-7 parts of polyglycerol fatty acid ester, 1-3 parts of polydimethylsiloxane, 1-2 parts of ethylene diamine tetraacetic acid, 1-2 parts of triethanolamine and 120-150 parts of deionized water. The composite type wood softening agent disclosed by the invention has a reasonable formula, good softening effect, less treatment time, and high safety, and can be applied to softening various kinds of wood.
Description
Technical field
The present invention relates to a kind of composite wood softening agent, belong to wood anatomy field.
Background technology
Timber is one of four universally acknowledged big materials, have renewable, pollution-free, cost is low, ratio of strength to weight advantages of higher, as product and the raw materials as papermaking, chemical fibres industry such as sheet material, furniture, plywoods, modern construction can be played great effect.Along with the raising of people's quality of the life and improving constantly of aesthetic standard, to the demand of timber and goods thereof increasing while, also it is required also increasingly stricter, such as bending.It is known that timber is a kind of polymer, it is difficult to brake forming at typical condition.Therefore, want to realize wood-bending molding, it is necessary to timber is carried out sofening treatment.
The method of timber sofening treatment can be divided into two kinds: physical method and chemical method.Physical method, also known as hydrothermal treatment consists method, common are baking method, water-boiling method, steam method, high-frequency heating method, microwave heating method etc., wherein water-boiling method and steam method are the most simple methods, but steam method is only capable of making the local of process material be softened, so that degree of crook is restricted；Chemical method is to utilize the chemical agents such as liquefied ammonia, ammonia, ammonia, imines, sodium hydroxide solution, potassium hydroxide solution, carbamide to carry out sofening treatment timber, wherein best with the resultant effect of liquefied ammonia Chemical treatment timber, but liquefied ammonia is high and dangerous to the requirement of equipment, and there is certain harm to operator are healthy.In view of the above circumstances, it is badly in need of a kind of bating effect good, and the high sofening treatment method of safety solves the problems referred to above.
In order to solve this technical problem, timber sofening treatment method is carried out deep research by people.In recent years, people obtain certain Research Achievement in timber sofening treatment method, as Chinese patent CN104890074A discloses " a kind of timber softening agent ", this timber softening agent is that the composition of raw materials component adopting following mass percent prepares: 100-150 part propylene glycol, 10-12 part polybutylene terephthalate, 30-35 part ethylene glycol, 20-25 part phenoxyethanol, 10-15 part Polyethylene Glycol, 3-5 part fatty alcohol-polyoxyethylene ether, 3-5 part dioctyl sodium sulfosuccinate, 5-10 part glyceryl tristearate, 80-100 part deionized water.Although the process time of this timber softening agent is few, energy consumption is low, soft condition relative loose, do not need High Temperature High Pressure and steam-heated adjustment, low for equipment requirements, to human body without any murder by poisoning, ensure that operator's is healthy, decrease the pollution to ecological environment, but its bating effect is less than ideal, this popularization hindering timber softening agent to a certain extent and application.Therefore, it is very valuable for continuing to explore with research timber softening agent.
Summary of the invention
For above-mentioned the deficiencies in the prior art, the technical problem to be solved is that to propose a kind of bating effect good, processes the time few, and the timber softening agent that safety is high.
A kind of composite wood softening agent, it is made up of each component of following weight: Pulvis Talci 2～5 parts, organobentonite 2～6 parts, polyoxyethylene fatty acid ester 10～20 parts, dodecyldimethylammonium hydroxide inner salt 2～5 parts, sodium lauryl sulphate 1～4 part, zinc stearate 2～4 parts, calcium stearate 1～3 part, sodium stearate 1～3 part, chlorinated paraffin 60～70 parts, fatty alcohol-polyoxyethylene ether 2～8 parts, polyglyceryl fatty acid ester 3～7 parts, polydimethylsiloxane 1～3 part, disodiumedetate 1～2 part, triethanolamine 1～2 part, deionized water 120～150 parts.
Further,
A kind of composite wood softening agent, it is made up of each component of following weight: Pulvis Talci 3～5 parts, organobentonite 4～6 parts, polyoxyethylene fatty acid ester 15～20 parts, dodecyldimethylammonium hydroxide inner salt 3～5 parts, sodium lauryl sulphate 2～4 parts, zinc stearate 2～4 parts, calcium stearate 1～3 part, sodium stearate 1～3 part, chlorinated paraffin 65～70 parts, fatty alcohol-polyoxyethylene ether 6～8 parts, polyglyceryl fatty acid ester 5～7 parts, polydimethylsiloxane 1～3 part, disodiumedetate 1～2 part, triethanolamine 1～2 part, deionized water 130～150 parts.
Further,
A kind of composite wood softening agent, is made up of each component of following weight: Pulvis Talci 4 parts, organobentonite 4 parts, polyoxyethylene fatty acid ester 15 parts, dodecyldimethylammonium hydroxide inner salt 3 parts, sodium lauryl sulphate 3 parts, zinc stearate 3 parts, calcium stearate 2 parts, sodium stearate 2 parts, chlorinated paraffin 65 parts, fatty alcohol-polyoxyethylene ether 5 parts, polyglyceryl fatty acid ester 5 parts, polydimethylsiloxane 2 parts, disodiumedetate 1.5 parts, triethanolamine 1.5 parts, deionized water 140 parts.
Wherein, described talcous order number is 800～1000 orders；Described bentonite order number is 200～400 orders.
In the present invention, Pulvis Talci has good lubricity, anti-stickiness and flexibility, it is possible to reduce viscosity between each composition of timber, improves timber plasticity ability；Organobentonite can have dispersing characteristic in water or organic solvent, it is possible to makes complicated dynamic balancing process between each composition of timber, improves wood-bending performance；The lubricants such as polyoxyethylene fatty acid ester, zinc stearate, calcium stearate, sodium stearate, chlorinated paraffin carry out composite, coordinating effect is produced between each lubricant, more stable lubricating film can be formed on wood-cellulose surface, reduce frictional force between wood-cellulose, so that softening agent is easier to enter among wood-cellulose crystal region, cellulose lattice is made to expand and become loose, cause being mutually shifted between cellulosic molecule and become prone to occur, so that timber has good plasticity, and then timber is made to present good softening performance；Dodecyldimethylammonium hydroxide inner salt, sodium lauryl sulphate, fatty alcohol-polyoxyethylene ether, polyglyceryl fatty acid ester, the surfactants such as polydimethylsiloxane carry out composite, coordinating effect is produced between each surfactant, more excellent moistening can be formed, permeability and absorption property and the capillary ability of reduction, thus improving softening agent length of penetration, and then improve timber bating effect, simultaneously, ionizing can also form charged ion, destroy the original charge balance of wood internal, wood-cellulose is made to change orientation, and lignin can be made to plastify, so that timber has excellent plasticizing capacity.
Disodiumedetate is a kind of chelating agent, can destroy original hydrogen bond between cellulose macromolecule, thus timber has good softening function in the noncrystalline domain of wood-cellulose, crystal region；Triethanolamine has moisturizing, humidification, pH poising agent and plasticization, its addition, can improve timber bating effect further.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention is by adopting multiple lubricant composite composite with kinds of surface activating agent, and it is equipped with under Pulvis Talci, organobentonite, disodiumedetate and triethanolamine interaction, acquisition bating effect is good, processes the time few, and the timber softening agent that safety is high.
First, multiple lubricant and kinds of surface activating agent composite, overcome the defect of single agents, thus improving the performance of timber softening agent；Then, the dispersibility that the lubricity that Pulvis Talci is good, anti-stickiness, flexibility and organobentonite are unique, it is possible to reduce viscosity and the complicated dynamic balancing process of generation between each composition of timber, improve timber plasticity ability；Finally, disodiumedetate destroys original hydrogen bond action and triethanolamine moisturizing, humidification, pH poising agent, plasticization between cellulose macromolecule, can improve timber bating effect further.
Additionally, timber softening agent disclosed in this invention has, formula is reasonable, bating effect good, the process time is few, and safety is high, can be applicable to the softening of various timber.
Detailed description of the invention
Embodiment 1
In this enforcement, talcous order number is 1000 orders；Bentonite order number is 400 orders；
A kind of composite wood softening agent, is made up of each component of following weight: Pulvis Talci 4 parts, organobentonite 4 parts, polyoxyethylene fatty acid ester 15 parts, dodecyldimethylammonium hydroxide inner salt 3 parts, sodium lauryl sulphate 3 parts, zinc stearate 3 parts, calcium stearate 2 parts, sodium stearate 2 parts, chlorinated paraffin 65 parts, fatty alcohol-polyoxyethylene ether 5 parts, polyglyceryl fatty acid ester 5 parts, polydimethylsiloxane 2 parts, disodiumedetate 1.5 parts, triethanolamine 1.5 parts, deionized water 140 parts.
Embodiment 2
In this enforcement, talcous order number is 800 orders；Bentonite order number is 200 orders；
A kind of composite wood softening agent, is made up of each component of following weight: Pulvis Talci 2 parts, organobentonite 2 parts, polyoxyethylene fatty acid ester 10 parts, dodecyldimethylammonium hydroxide inner salt 2 parts, sodium lauryl sulphate 1 part, zinc stearate 2 parts, calcium stearate 1 part, sodium stearate 1 part, chlorinated paraffin 60 parts, fatty alcohol-polyoxyethylene ether 2 parts, polyglyceryl fatty acid ester 3 parts, polydimethylsiloxane 1 part, disodiumedetate 1 part, triethanolamine 1 part, deionized water 120 parts.
Embodiment 3
In this enforcement, talcous order number is 1000 orders；Bentonite order number is 400 orders；
A kind of composite wood softening agent, is made up of each component of following weight: Pulvis Talci 5 parts, organobentonite 6 parts, polyoxyethylene fatty acid ester 20 parts, dodecyldimethylammonium hydroxide inner salt 5 parts, sodium lauryl sulphate 4 parts, zinc stearate 4 parts, calcium stearate 3 parts, sodium stearate 3 parts, chlorinated paraffin 70 parts, fatty alcohol-polyoxyethylene ether 8 parts, polyglyceryl fatty acid ester 7 parts, polydimethylsiloxane 3 parts, disodiumedetate 2 parts, triethanolamine 2 parts, deionized water 150 parts.
Embodiment 4
In this enforcement, talcous order number is 1000 orders；Bentonite order number is 400 orders；
A kind of composite wood softening agent, is made up of each component of following weight: Pulvis Talci 3 parts, organobentonite 4 parts, polyoxyethylene fatty acid ester 15 parts, dodecyldimethylammonium hydroxide inner salt 3 parts, sodium lauryl sulphate 2 parts, zinc stearate 2 parts, calcium stearate 1 part, sodium stearate 1 part, chlorinated paraffin 65 parts, fatty alcohol-polyoxyethylene ether 6 parts, polyglyceryl fatty acid ester 5 parts, polydimethylsiloxane 1 part, disodiumedetate 1 part, triethanolamine 1 part, deionized water 130 parts.
It addition, for the effect that timber softening agent of the present invention is described, applicant carried out test, result of the test is as shown in table 1:
Table 1 timber softening agent result of the test
As known from Table 1, compared with background of invention and ammonium nitrate+ammonia prior art, the present invention has low treatment temperature, few process time and low minimum profile curvature radius, this demonstrates timber softening agent provided by the present invention and has significant bating effect.
Certainly, it is that the preferred embodiments of the disclosure is described in detail above, not limits the practical range of the present invention with this, the equivalence change that all principles under this invention, structure and structure are made, all should be covered by protection scope of the present invention.
Claims (5)
1. a composite wood softening agent, it is characterized in that: be made up of each component of following weight: Pulvis Talci 2～5 parts, organobentonite 2～6 parts, polyoxyethylene fatty acid ester 10～20 parts, dodecyldimethylammonium hydroxide inner salt 2～5 parts, sodium lauryl sulphate 1～4 part, zinc stearate 2～4 parts, calcium stearate 1～3 part, sodium stearate 1～3 part, chlorinated paraffin 60～70 parts, fatty alcohol-polyoxyethylene ether 2～8 parts, polyglyceryl fatty acid ester 3～7 parts, polydimethylsiloxane 1～3 part, disodiumedetate 1～2 part, triethanolamine 1～2 part, deionized water 120～150 parts.
2. composite wood softening agent according to claim 1, it is characterized in that: be made up of each component of following weight: Pulvis Talci 3～5 parts, organobentonite 4～6 parts, polyoxyethylene fatty acid ester 15～20 parts, dodecyldimethylammonium hydroxide inner salt 3～5 parts, sodium lauryl sulphate 2～4 parts, zinc stearate 2～4 parts, calcium stearate 1～3 part, sodium stearate 1～3 part, chlorinated paraffin 65～70 parts, fatty alcohol-polyoxyethylene ether 6～8 parts, polyglyceryl fatty acid ester 5～7 parts, polydimethylsiloxane 1～3 part, disodiumedetate 1～2 part, triethanolamine 1～2 part, deionized water 130～150 parts.
3. composite wood softening agent according to claim 1, it is characterised in that: it is made up of each component of following weight: Pulvis Talci 4 parts, organobentonite 4 parts, polyoxyethylene fatty acid ester 15 parts, dodecyldimethylammonium hydroxide inner salt 3 parts, sodium lauryl sulphate 3 parts, zinc stearate 3 parts, calcium stearate 2 parts, sodium stearate 2 parts, chlorinated paraffin 65 parts, fatty alcohol-polyoxyethylene ether 5 parts, polyglyceryl fatty acid ester 5 parts, polydimethylsiloxane 2 parts, disodiumedetate 1.5 parts, triethanolamine 1.5 parts, deionized water 140 parts.
4. composite wood softening agent according to claim 1, it is characterised in that: described talcous order number is 800～1000 orders.
5. composite wood softening agent according to claim 1, it is characterised in that: described bentonite order number is 200～400 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610148902.9A CN105729603A (en) | 2016-03-16 | 2016-03-16 | Composite type wood softening agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610148902.9A CN105729603A (en) | 2016-03-16 | 2016-03-16 | Composite type wood softening agent |
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| Publication Number | Publication Date |
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| CN105729603A true CN105729603A (en) | 2016-07-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610148902.9A Pending CN105729603A (en) | 2016-03-16 | 2016-03-16 | Composite type wood softening agent |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000071311A2 (en) * | 1999-05-24 | 2000-11-30 | Lonza Inc. | Copper/amine oxide wood preservatives |
| CN104893318A (en) * | 2015-06-19 | 2015-09-09 | 陈新棠 | Softener for bamboo weaving |
| CN104960054A (en) * | 2015-05-29 | 2015-10-07 | 阜南腾强工艺品有限公司 | Vitex negundo softening treatment liquid |
| CN105365016A (en) * | 2015-10-23 | 2016-03-02 | 界首市祥雨竹编专业合作社 | Bamboo batten softening treating fluid for bamboo weaving |
-
2016
- 2016-03-16 CN CN201610148902.9A patent/CN105729603A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000071311A2 (en) * | 1999-05-24 | 2000-11-30 | Lonza Inc. | Copper/amine oxide wood preservatives |
| CN104960054A (en) * | 2015-05-29 | 2015-10-07 | 阜南腾强工艺品有限公司 | Vitex negundo softening treatment liquid |
| CN104893318A (en) * | 2015-06-19 | 2015-09-09 | 陈新棠 | Softener for bamboo weaving |
| CN105365016A (en) * | 2015-10-23 | 2016-03-02 | 界首市祥雨竹编专业合作社 | Bamboo batten softening treating fluid for bamboo weaving |
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