CN105599089A - Treating agent for softening wood - Google Patents
Treating agent for softening wood Download PDFInfo
- Publication number
- CN105599089A CN105599089A CN201610148901.4A CN201610148901A CN105599089A CN 105599089 A CN105599089 A CN 105599089A CN 201610148901 A CN201610148901 A CN 201610148901A CN 105599089 A CN105599089 A CN 105599089A
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- China
- Prior art keywords
- parts
- softening
- timber
- fatty acid
- inorganic agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/06—Softening or hardening of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
Abstract
The invention discloses a treating agent for softening wood. The treating agent for softening wood is prepared from the following components in parts by weight: 1-3 parts of talcum powder, 3-5 parts of organic bentonite, 15-20 parts of polyoxyethylene aliphatate, 1-3 parts of octadecyldimethyl betaine, 1-3 parts of sodium dodecyl benzene sulfonate, 2-4 parts of zinc stearate, 3-5 parts of calcium stearate, 40-50 parts of chlorinated paraffin, 4-6 parts of polyoxyethylene polyoxypropylene ether, 5-7 parts of polyglycerol fatty acid ester, 1-3 parts of polydimethylsiloxane, 1-2 parts of ethylene diamine tetraacetic acid disodium salt, 1-2 parts of triethanolamine, 40-50 parts of glycerinum and 100-150 parts of deionized water. The treating agent for softening wood has reasonable formulation, good softening effect and high safety, and can be used for softening various woods with short treatment time.
Description
Technical field
The present invention relates to the softening inorganic agent of a kind of timber, belong to wood anatomy field.
Background technology
Timber is one of four universally acknowledged large materials, have renewable, pollution-free, cost is low, strongAnharmonic ratio advantages of higher, can be used as the products such as sheet material, furniture, glued board and as papermaking, chemical fibreThe raw material of industry plays great effect in modern construction. Along with carrying of people's quality of the lifeImproving constantly of height and aesthetic standard, increasing to the demand of timber and goods thereof time, alsoAlso more and more stricter to its requirement, as bending. As everyone knows, timber is a kind of polymer, conventionallyUnder condition, be difficult to brake forming. Therefore, want to realize wood-bending moulding, need to carry out soft to timberChange and process.
The softening method of processing of timber can be divided into two kinds: physical method and chemical method. Physical method,Claim again hydrothermal treatment consists method, common are the roasting method of fire, water-boiling method, steam method, high-frequency heating method, microwaveHeating etc., wherein water-boiling method and steam method are the most simple methods, but steam method only can makeProcess the part of material and softened, thereby degree of crook is restricted; Chemical method be utilize liquefied ammonia,The chemical agents such as ammoniacal liquor, ammonia, imines, sodium hydroxide solution, potassium hydroxide solution, urea come softChange and process timber, wherein with resultant effect the best of liquefied ammonia Chemical treatment timber, but liquefied ammonia pairRequiring of equipment is high and dangerous, and has certain harm to operating personnel are healthy. In view of more thanSituation, is badly in need of a kind of bating effect good, and safe softening processing method solves the problems referred to above.
In order to solve this technical problem, people carry out deep research to the softening processing method of timber.In recent years, people obtain certain research achievement in the softening processing method of timber, as Chinese patentCN104890074A discloses " a kind of timber softening agent ", and this timber softening agent is to adopt following matterThe composition of raw materials component of amount percentage makes: 100-150 part propane diols, the poly-terephthaldehyde of 10-12 partAcid fourth diester, 30-35 part ethylene glycol, 20-25 part Phenoxyethanol, 10-15 part polyethylene glycol, 3-5Part AEO, 3-5 part dioctyl sodium sulfosuccinate, 5-10 part three stearic acid are sweetGrease, 80-100 part deionized water. Although the processing time of this timber softening agent is few, energy consumption is low,Softening condition is relatively loose, does not need HTHP and steam-heated adjusting, low for equipment requirements, rightHuman body, without any murder by poisoning, has ensured the healthy of operating personnel, has reduced the pollution to ecological environment,But its bating effect is not so desirable, and this has hindered the popularization of timber softening agent to a certain extentWith application. Therefore it is very valuable, continuing to explore with research timber softening agent.
Summary of the invention
For above-mentioned the deficiencies in the prior art, technical problem to be solved by this invention is to have proposed oneBating effect is good, and the processing time is few, and the softening inorganic agent of safe timber.
The softening inorganic agent of a kind of timber, made by each component of following weight portion proportioning: talcum powder 1～3 parts, 3～5 parts of organobentonites, 15～20 parts of polyoxyethylene fatty acid esters, octadecyl diformazan1～3 part of base betaine, 1～3 part of neopelex, 2～4 parts of zinc stearates, tristearin3～5 parts of acid calcium, 40～50 parts of chlorinated paraffin waxs, 4～6 parts of polyoxyethylene poly-oxygen propylene aethers, poly-sweet5～7 parts of oil and fat acid esters, 1～3 part of dimethyl silicone polymer, disodium ethylene diamine tetraacetate 1～2Part, 1～2 part of triethanolamine, 40～50 parts of glycerine, 100～150 parts of deionized waters.
Further,
The softening inorganic agent of a kind of timber, made by each component of following weight portion proportioning: talcum powder 1～3 parts, 3～5 parts of organobentonites, 18～20 parts of polyoxyethylene fatty acid esters, octadecyl diformazan1～3 part of base betaine, 1～3 part of neopelex, 2～4 parts of zinc stearates, tristearin3～5 parts of acid calcium, 45～50 parts of chlorinated paraffin waxs, 4～6 parts of polyoxyethylene poly-oxygen propylene aethers, poly-sweet5～7 parts of oil and fat acid esters, 1～3 part of dimethyl silicone polymer, disodium ethylene diamine tetraacetate 1～2Part, 1～2 part of triethanolamine, 45～50 parts of glycerine, 120～150 parts of deionized waters.
Further,
The softening inorganic agent of a kind of timber, is made up of each component of following weight portion proportioning: talcum powder 2Part, 4 parts of organobentonites, 19 parts of polyoxyethylene fatty acid esters, octodecyl betaine2 parts, 2 parts of neopelexes, 3 parts of zinc stearates, 4 parts of calcium stearates, chlorinated paraffin wax48 parts, 5 parts of polyoxyethylene poly-oxygen propylene aethers, 6 parts of polyglyceryl fatty acid esters, poly dimethyl silica2 parts, alkane, 2 parts of disodium ethylene diamine tetraacetates, 1 part of triethanolamine, 48 parts of glycerine, deionized water130 parts.
Wherein, described talcous order number is 800～1000 orders; Described bentonite orderNumber is 200～400 orders.
In the present invention, talcum powder has good lubricity, anti-stickiness and flexibility, can reduce woodViscosity between the each composition of material, improves timber plasticity ability; Organobentonite can be in water or organic solventThere is dispersing characteristic, can make, between the each composition of timber, complicated dynamic balancing process occurs, improve timber curvedQu Xingneng; The profits such as polyoxyethylene fatty acid ester, zinc stearate, calcium stearate, chlorinated paraffin wax, glycerineLubrication prescription carries out composite, between each lubricant, produces coordinating effect, can form on wood-cellulose surfaceMore stable lubricating film, reduces frictional force between wood-cellulose, thereby makes softening inorganic agent easierEnter among wood-cellulose crystal region, make cellulose lattice expand and become loose, cause celluloseIntermolecular mutual movement becomes and is easy to occur, thereby makes timber have good plasticity, and then makes timberPresent good softening performance; Octodecyl betaine, neopelex, polyoxyThe surfactants such as ethene polyethenoxy ether, polyglyceryl fatty acid ester, dimethyl silicone polymer are answeredJoin, between each surfactant, produce coordinating effect, can form more excellent wetting, permeability and suctionAttached performance and the capillary ability of reduction, thus softening inorganic agent length of penetration improved, and then improveTimber bating effect, meanwhile, can also ionization form charged ion, destroys timber inside formerSome charge balances, make wood-cellulose change orientation, and can make lignin plasticizing, thereby make woodMaterial has good plasticizing capacity.
Disodium ethylene diamine tetraacetate is a kind of complexing agent, can be in the noncrystalline domain of wood-cellulose, crystallizationIn district, destroyed original hydrogen bond between cellulose macromolecule, thereby timber has good softening function;Triethanolamine has moisturizing, humidification, pH poising agent and plasticization, and adding of its, can be furtherGround improves timber bating effect.
Compared with prior art, the invention has the beneficial effects as follows:
By adopting, multiple lubricant is composite and kinds of surface activating agent is composite in the present invention, and is equipped with talcumUnder powder, organobentonite, disodium ethylene diamine tetraacetate and triethanolamine interact, obtain softening effectFruit is good, and the processing time is few, and the softening inorganic agent of safe timber.
First, multiple lubricant and kinds of surface activating agent composite, overcomes the defect of single agents,Thereby improve the performance of the softening inorganic agent of timber; The lubricity that then, talcum powder is good, anti-stickiness,The dispersiveness of flexibility and organobentonite uniqueness, can reduce viscosity and generation between the each composition of timberComplicated dynamic balancing process, improves timber plasticity ability; Finally, disodium ethylene diamine tetraacetate has destroyed fibreThe large intermolecular original hydrogen bond action of dimension element and triethanolamine moisturizing, humidification, pH poising agent, plasticising are doneWith, can improve further timber bating effect.
In addition, the softening inorganic agent of timber disclosed in this invention have formula rationally, bating effect is good,Processing time is few, and safe, can be applicable to the softening of various timber.
Detailed description of the invention
Embodiment 1
In this enforcement, talcous order number is 1000 orders; Bentonite order number is 400 orders;
The softening inorganic agent of a kind of timber, is made up of each component of following weight portion proportioning: talcum powder 2Part, 4 parts of organobentonites, 19 parts of polyoxyethylene fatty acid esters, octodecyl betaine2 parts, 2 parts of neopelexes, 3 parts of zinc stearates, 4 parts of calcium stearates, chlorinated paraffin wax48 parts, 5 parts of polyoxyethylene poly-oxygen propylene aethers, 6 parts of polyglyceryl fatty acid esters, poly dimethyl silica2 parts, alkane, 2 parts of disodium ethylene diamine tetraacetates, 1 part of triethanolamine, 48 parts of glycerine, deionized water130 parts.
Embodiment 2
In this enforcement, talcous order number is 800 orders; Bentonite order number is 200 orders;
The softening inorganic agent of a kind of timber, is made up of each component of following weight portion proportioning: talcum powder 1Part, 3 parts of organobentonites, 15 parts of polyoxyethylene fatty acid esters, octodecyl betaine1 part, 1 part of neopelex, 2 parts of zinc stearates, 3 parts of calcium stearates, chlorinated paraffin wax40 parts, 4 parts of polyoxyethylene poly-oxygen propylene aethers, 5 parts of polyglyceryl fatty acid esters, poly dimethyl silica1 part, alkane, 1 part of disodium ethylene diamine tetraacetate, 1 part of triethanolamine, 40 parts of glycerine, deionized water100 parts.
Embodiment 3
In this enforcement, talcous order number is 1000 orders; Bentonite order number is 400 orders;
The softening inorganic agent of a kind of timber, is made up of each component of following weight portion proportioning: talcum powder 3Part, 5 parts of organobentonites, 20 parts of polyoxyethylene fatty acid esters, octodecyl betaine3 parts, 3 parts of neopelexes, 4 parts of zinc stearates, 5 parts of calcium stearates, chlorinated paraffin wax50 parts, 6 parts of polyoxyethylene poly-oxygen propylene aethers, 7 parts of polyglyceryl fatty acid esters, poly dimethyl silica3 parts, alkane, 2 parts of disodium ethylene diamine tetraacetates, 2 parts of triethanolamines, 50 parts of glycerine, deionized water150 parts.
Embodiment 4
In this enforcement, talcous order number is 1000 orders; Bentonite order number is 400 orders;
The softening inorganic agent of a kind of timber, is made up of each component of following weight portion proportioning: talcum powder 1Part, 3 parts of organobentonites, 18 parts of polyoxyethylene fatty acid esters, octodecyl betaine1 part, 1 part of neopelex, 2 parts of zinc stearates, 3 parts of calcium stearates, chlorinated paraffin wax45 parts, 4 parts of polyoxyethylene poly-oxygen propylene aethers, 5 parts of polyglyceryl fatty acid esters, poly dimethyl silica1 part, alkane, 1 part of disodium ethylene diamine tetraacetate, 1 part of triethanolamine, 45 parts of glycerine, deionized water120 parts.
In addition, for the effect of the softening inorganic agent of timber of the present invention is described, applicant tests,Result of the test is as shown in table 1:
Table 1 timber softens inorganic agent result of the test
As known from Table 1, compare with ammonium nitrate+ammoniacal liquor prior art with background technology of the present invention, thisBright have low treatment temperature, few processing time and a low minimum profile curvature radius, and this has shown thisThe softening inorganic agent of bright provided timber has significant bating effect.
Certainly, just the preferred embodiments of the disclosure is described in detail above, not with thisLimit practical range of the present invention, all equivalences of doing according to principle of the present invention, structure and structure becomeChange, all should be covered by protection scope of the present invention.
Claims (5)
1. the softening inorganic agent of timber, is characterized in that: by each component of following weight portion proportioningMake: 1～3 part of talcum powder, 3～5 parts of organobentonites, polyoxyethylene fatty acid ester 15～20Part, 1～3 part of octodecyl betaine, 1～3 part of neopelex, stearic acid2～4 parts, zinc, 3～5 parts of calcium stearates, 40～50 parts of chlorinated paraffin waxs, polyoxyethylene polyoxypropylene4～6 parts, ether, 5～7 parts of polyglyceryl fatty acid esters, 1～3 part of dimethyl silicone polymer, ethylenediamine1～2 part of tetraacethyl disodium, 1～2 part of triethanolamine, 40～50 parts of glycerine, deionized water 100～150 parts.
2. the softening inorganic agent of timber according to claim 1, is characterized in that: by weighing belowEach component of amount part proportioning is made: 1～3 part of talcum powder, 3～5 parts of organobentonites, polyoxyethylene18～20 parts of fatty acid esters, 1～3 part of octodecyl betaine, neopelex1～3 part, 2～4 parts of zinc stearates, 3～5 parts of calcium stearates, 45～50 parts of chlorinated paraffin waxs, poly-4～6 parts of oxygen ethene polyethenoxy ethers, 5～7 parts of polyglyceryl fatty acid esters, dimethyl silicone polymer 1～3 parts, 1～2 part of disodium ethylene diamine tetraacetate, 1～2 part of triethanolamine, 45～50 parts of glycerine,120～150 parts of deionized waters.
3. the softening inorganic agent of timber according to claim 1, is characterized in that: by weighing belowEach component of amount part proportioning is made: 2 parts of talcum powder, 4 parts of organobentonites, polyoxyethylene fatty acid19 parts of esters, 2 parts of octodecyl betaines, 2 parts of neopelexes, stearic acid3 parts, zinc, 4 parts of calcium stearates, 48 parts of chlorinated paraffin waxs, 5 parts of polyoxyethylene poly-oxygen propylene aethers, poly-6 parts of fatty acid glycerides, 2 parts of dimethyl silicone polymers, 2 parts of disodium ethylene diamine tetraacetates, three second1 part of hydramine, 48 parts of glycerine, 130 parts of deionized waters.
4. the softening inorganic agent of timber according to claim 1, is characterized in that: described cunningThe order number of stone flour is 800～1000 orders.
5. the softening inorganic agent of timber according to claim 1, is characterized in that: described hasThe bentonitic order number of machine is 200～400 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610148901.4A CN105599089A (en) | 2016-03-16 | 2016-03-16 | Treating agent for softening wood |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610148901.4A CN105599089A (en) | 2016-03-16 | 2016-03-16 | Treating agent for softening wood |
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| CN105599089A true CN105599089A (en) | 2016-05-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610148901.4A Pending CN105599089A (en) | 2016-03-16 | 2016-03-16 | Treating agent for softening wood |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106217553A (en) * | 2016-09-24 | 2016-12-14 | 安徽宏润工艺品有限公司 | A kind of bar that improves compiles softening agent and the using method thereof of Vitex chinensis Mill. fragility |
| CN106854461A (en) * | 2016-12-11 | 2017-06-16 | 周益铭 | A kind of preparation method of Thief zone fast water injection well scale remover |
| CN107520928A (en) * | 2017-09-12 | 2017-12-29 | 阜南县永兴工艺品有限公司 | A kind of handicraft timber sofening treatment technique |
| CN108748543A (en) * | 2018-06-25 | 2018-11-06 | 安徽宏润工艺品有限公司 | A kind of processing method promoting maize straw skin knitting intensity and service life |
| CN108858607A (en) * | 2018-06-25 | 2018-11-23 | 安徽宏润工艺品有限公司 | A kind of twigs of the chaste tree sofening treatment liquid |
| CN109056324A (en) * | 2018-06-25 | 2018-12-21 | 安徽省创安体育用品有限公司 | A kind of processing method for promoting apocynum fibre weaving and using characteristic |
| CN110494610A (en) * | 2018-03-14 | 2019-11-22 | 三吉油脂株式会社 | Stationery inorganic agent |
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| CN104893318A (en) * | 2015-06-19 | 2015-09-09 | 陈新棠 | Softener for bamboo weaving |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106217553A (en) * | 2016-09-24 | 2016-12-14 | 安徽宏润工艺品有限公司 | A kind of bar that improves compiles softening agent and the using method thereof of Vitex chinensis Mill. fragility |
| CN106854461A (en) * | 2016-12-11 | 2017-06-16 | 周益铭 | A kind of preparation method of Thief zone fast water injection well scale remover |
| CN107520928A (en) * | 2017-09-12 | 2017-12-29 | 阜南县永兴工艺品有限公司 | A kind of handicraft timber sofening treatment technique |
| CN110494610A (en) * | 2018-03-14 | 2019-11-22 | 三吉油脂株式会社 | Stationery inorganic agent |
| CN110494610B (en) * | 2018-03-14 | 2021-09-28 | 三吉油脂株式会社 | Paper treating agent |
| CN108748543A (en) * | 2018-06-25 | 2018-11-06 | 安徽宏润工艺品有限公司 | A kind of processing method promoting maize straw skin knitting intensity and service life |
| CN108858607A (en) * | 2018-06-25 | 2018-11-23 | 安徽宏润工艺品有限公司 | A kind of twigs of the chaste tree sofening treatment liquid |
| CN109056324A (en) * | 2018-06-25 | 2018-12-21 | 安徽省创安体育用品有限公司 | A kind of processing method for promoting apocynum fibre weaving and using characteristic |
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Application publication date: 20160525 |