CN105714295A - Enamel manufacturing method - Google Patents

Enamel manufacturing method Download PDF

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Publication number
CN105714295A
CN105714295A CN201610079401.XA CN201610079401A CN105714295A CN 105714295 A CN105714295 A CN 105714295A CN 201610079401 A CN201610079401 A CN 201610079401A CN 105714295 A CN105714295 A CN 105714295A
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CN
China
Prior art keywords
inlay
tire
enamel
utilize
wire
Prior art date
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Granted
Application number
CN201610079401.XA
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Chinese (zh)
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CN105714295B (en
Inventor
熊玮
郝亮
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China University of Geosciences
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China University of Geosciences
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Priority to CN201610079401.XA priority Critical patent/CN105714295B/en
Publication of CN105714295A publication Critical patent/CN105714295A/en
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Publication of CN105714295B publication Critical patent/CN105714295B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • B22F10/28Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/02Coating with enamels or vitreous layers by wet methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • B22C9/046Use of patterns which are eliminated by the liquid metal in the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/50Treatment of workpieces or articles during build-up, e.g. treatments applied to fused layers during build-up
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/22Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
    • B22F3/227Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip by organic binder assisted extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D13/00After-treatment of the enamelled articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/30Process control
    • B22F10/36Process control of energy beam parameters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F12/00Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
    • B22F12/40Radiation means
    • B22F12/49Scanners
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)

Abstract

The invention discloses an enamel manufacturing method. The method comprises the steps that a 3D printing technology is utilized for replacing a traditional base bottom and inlaid wire manufacturing process to manufacture a base bottom and an inlaid wire, and then the base bottom and the inlaid wire are pretreated; enamel applying is carried out in a concave area formed by the inlaid wire; a base obtained after enamel applying is put into a baking oven to be repeatedly roasted, and the oven temperature is controlled to range from 400 DEG C to 900 DEG C; and an enamel product obtained after roasting is electroplated. The technical problem that the requirement for the handcraft level is high in a traditional wiry enamel process is solved based on a series of processes, the work efficiency and the rate of finished products are increased, the labor intensity is lowered, the time of working procedures is shortened, and the manpower cost is reduced.

Description

A kind of enamel manufacture method
Technical field
The application relates to application and the enamel processing technology of 3D printing technique, particularly relates to a kind of enamel and makes Method.
Background technology
3D printing technique is a kind of novel technology that is layering, and is primarily now applied to technical grade metal, pottery Porcelain, macromolecule etc., production and processing current or small lot, personalized.
In recent years, three-dimensional printing technology is progressively attempted for bullion, artware, art work field, But the application in these fields is still in researching and developing and the commercialization trial stage in early days.Such as, some is golden at present Silver jewellery increases material and manufactures Forming Equipments, uses precinct laser fusion (SLM) technology to manufacture art up, individual The metallic article of property, and have been commercialized.
Meanwhile, the traditional handicraft history of China is of long standing and well established, embodies industry and the wisdom of the Chinese nation.Its Consummate technique, moulding attractive in appearance, lucky implied meaning carry deep cultureal value and artistic value, from Gu is the most all liked by deep people.
But tradition enamel technique is the highest to the skill and technique level requirement making implementor, and man-hour therefore can be caused long, Complex operation, conforming product rate is low, the problem that process efficiency is low, and this is also that traditional handicraft much the most urgently passes Accept insurance the reason protected.
Summary of the invention
Invention provides a kind of enamel manufacture method, long for man-hour to solve existing enamel technique, operate numerous Trivial, conforming product rate is low, the technical problem that process efficiency is low.
For solving above-mentioned technical problem, the invention provides a kind of enamel manufacture method, described method includes:
Utilize 3D printing technique make at the bottom of tire with wire inlay, described in wire inlay and be arranged at the bottom of described tire, described in wire inlay All kinds of sunk area can be formed;
To at the bottom of described tire and described wiring inlay carries out pretreatment;
The described sunk area wiring inlay and being formed is filled enamel;
The carcass obtained after filling enamel is placed in repeated calcination in baker, and Control for Kiln Temperature is between 400-900 DEG C;
The enamelwork obtained after roasting is electroplated.
Preferably, described at the bottom of described tire and described wiring inlay carries out pretreatment, specifically include:
To polishing at the bottom of described tire, cleaning;
Described wiring inlay is polished, cleaned.
Preferably, the described 3D of utilization printing technique make at the bottom of tire with wire inlay, specifically include:
Utilize 3D wax spray to print at the bottom of the lost wax process described tire of making to wire inlay with described;Or
Utilize 3D metal paste to print at the bottom of the sintering process described tire of making to wire inlay with described;Or
Utilize 3D metal dust selective laser sintering process to make at the bottom of described tire to wire inlay with described.
Preferably, the described 3D of utilization wax spray print lost wax process make at the bottom of tire with wire inlay, specifically include:
Set up at the bottom of described tire and the described 3D digital model wired inlay;
3D wax spray printer is utilized to make at the bottom of described tire and the described wax-pattern wired inlay;
Make at the bottom of described tire based on described wax-pattern by lost wax process and the described metal objects wired inlay.
Preferably, the described 3D of utilization metal paste wires inlay with described, specifically at the bottom of printing the sintering process described tire of making Including:
Set up at the bottom of described tire and the described 3D digital model wired inlay;
Utilize tablet machine that metal material is pressed at the bottom of described tire;
Utilize and wire inlay described in the printing of 3D metal paste printer;
By at the bottom of described tire and described wiring inlay sinters metal objects into.
Preferably, described utilize 3D metal dust selective laser sintering process make at the bottom of described tire with described pinch Silk, specifically includes:
Set up at the bottom of described tire and the described 3D digital model wired inlay;
Utilize tablet machine that metal material is pressed at the bottom of described tire;
Utilize and wire inlay described in the printing of 3D metal dust selective laser sintering printer.
Preferably, before wiring inlay described in the printing of the described 3D of utilization metal dust selective laser sintering printer, Described method method also includes:
The print area of described 3D metal dust selective laser sintering printer will be put at the bottom of described tire, utilize Described 3D metal dust selective laser sintering printer wires inlay described in successively printing at the bottom of tire.
Preferably, described will fill enamel after the carcass that obtains be placed in repeated calcination in baker, specifically include:
Described carcass is placed in repeated calcination 3-5 time in baker.
Preferably, before the described enamelwork to obtaining after roasting is electroplated, specifically include:
Described enamelwork is polished, cleans.
Preferably, described in the silk width that wires inlay be 0.1mm-3mm, the silk height wired inlay is 0.1mm-2mm.
By one or more technical scheme of the present invention, the invention have the advantages that or advantage:
The invention discloses a kind of enamel manufacture method, utilize 3D printing technique replace at the bottom of traditional tire with wire inlay Processing technology make at the bottom of tire with wire inlay, then at the bottom of described tire and described wiring inlay carries out pretreatment;Described Wire inlay formed sunk area in fill enamel;The carcass obtained after filling enamel is placed in repeated calcination in baker, Control for Kiln Temperature is between 400-900 DEG C;The enamelwork obtained after roasting is electroplated, a series of based on this Technique solves opponent's technological level in tradition thread weaving enamel technique and requires high technical problem, improves work Efficiency and yield rate, reduce labor intensity, shortens activity time, saves human cost.
Accompanying drawing explanation
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to enforcement In example description, the required accompanying drawing used is briefly described, it should be apparent that, the accompanying drawing in describing below It is some embodiments of the present invention, for those of ordinary skill in the art, is not paying creative work On the premise of, it is also possible to other accompanying drawing is obtained according to these accompanying drawings.
Fig. 1 is the implementation process figure of enamel manufacture method in the embodiment of the present application;
The enamel manufacture method that Fig. 2-Fig. 4 is formed by utilizing different 3D printing technique in the embodiment of the present application Implementation process figure;
Fig. 5-Fig. 6 is the process structure schematic diagram in present application example.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, Below in conjunction with detailed description of the invention, the present invention is expanded on further.But embodiments of the present invention are not by above-mentioned The restriction of embodiment, any without departing from the change made under the principle of the invention, modify, substitute, combine, letter Change, all should be the substitute mode of equivalence, within being included in protection scope of the present invention.
Enamel processing technology efficiency is low, man-hour is long, complex operation to the present invention is to solve tradition, and product is qualified Rate is low, provides a kind of enamel manufacture method for this.
Specifically, refer to Fig. 1, the enamel manufacture method of the present invention includes following making part:
S1, utilize 3D printing technique make at the bottom of tire with wire inlay, wire inlay and be arranged at the bottom of tire, wiring inlay, it is each to be formed Class sunk area.
S2, carries out pretreatment at the bottom of tire with wiring inlay.
S3, fills enamel in the sunk area formed that wires inlay.
S4, the carcass obtained after filling enamel is placed in repeated calcination in baker, and Control for Kiln Temperature is between 400-900 DEG C.
S5, electroplates the enamelwork obtained after roasting.
The present invention is based on different 3D printing techniques, it is proposed that three kinds of instantiation methods, in different demands Under, concrete technological process be can be optimized.Example 1 is to print lost wax process based on 3D wax spray to complete enamel Processing technology.Example 2 is to print sintering process based on 3D metal paste to complete enamel processing technology.Example 3 is Enamel processing technology is completed based on 3D metal dust selective laser sintering process.
It is described based on different enamel processing technology separately below.
Example 1, referring to Fig. 2:
Step 101, set up at the bottom of tire with the 3D digital model wired inlay.
Set up the software of 3D digital model include but not limited to utilize rhinocero, MaYa, 3DMAX, JewelCAD, Artcam etc. can set up the software of 3D digital model.Wherein software rhinocero is English Referred to as Rhino, Chinese is referred to as rhinoceros, in August, 1998 official listing, is U.S. Robert McNeel Professional 3D modeling software powerful on the PC of &Associates exploitation;Software Maya, full name Autodesk Maya, is the top Three-dimensional Animation Software in the world produced of autodesk, inc. of the U.S.;Software 3DMAX, Have another name called 3D Studio Max, be often simply called 3ds Max or MAX, be that Discreet company develops (quilt afterwards Autodesk, inc. merges) three-dimensional animation of Based PC system renders and Software for producing, its predecessor be based on The 3D Studio groupware of dos operating system;Software JewelCAD is for jewelry design/system The specialized CAD/CAM software made, JewelCAD has a highly-specialised, high workload efficiency, the most easily The feature learned, is the CAD/CAM software system of industry accreditation first-selection;Software ArtCAM product line is Unique CAD moulding and CNC, CAM that Delcam company of Britain produces process solution, are multiple The first-selected CAD/CAM software solution of miscellaneous stereoscopic three-dimensional embossed designs, jewel design and processing, can be fast Two dimension design is converted into three-dimensional aesthetic product by speed.
During modeling, design is needed to draw at the bottom of tire: general surfacing at the bottom of tire, it is possibility to have tiny Decorative pattern.Moulding can be plane (two-dimentional), it is also possible to for three-dimensional (three-dimensional).
Design drafting is wired inlay grain pattern: design is drawn the effect wired inlay and is to form the thread of projection at tire basal surface Grain pattern, on the one hand it play the effect of decoration, when on the other hand can prevent enameling operation later, melted Enamel glaze product surface unordered excessive, flowing, make the enamel glaze of different colours control accordingly Within the sunk area that the grain pattern that wires inlay surrounds.So the grain pattern that wires inlay of design may eventually form and closes one by one Sunk area.Designed by the silk width that wires inlay be generally 0.1mm-3mm, (i.e. silk is higher than the silk height wired inlay Height at the bottom of tire) generally 0.1mm-2mm, concrete size needs to be as the criterion with design and craft.
In computer software, 3D model at the bottom of tire is become a 3D model with the grain pattern 3D model combination that wires inlay, Save as the digitized 3D model file that 3D wax spray printer is capable of identify that.
Step 102, utilize 3D wax spray printer make at the bottom of tire with the wax-pattern wired inlay.
Wherein, 3D wax spray printer refers to that printing head sprays waxy materials, by printhead at three direction of principal axis Motion, successively a kind of 3D printer of superposition bonding forming.
One replacement scheme of this step, be utilize at the bottom of 3D photosensitive resin printer one-shot forming tire with the portion of wiring inlay The resin mold divided.Wherein, 3D photosensitive resin printer refers to use the liquid light that can solidify under certain light source Quick resin is raw material, uses successively light source to irradiate specific region and forms a kind of 3D printing of solidification resin and molding Machine.
Step 103, based on wax-pattern by lost wax process make at the bottom of tire with the metal objects wired inlay.
Lost wax process, for a kind of method of metal casting, general procedure is: assemble cast gate, painting to wax-pattern Expect shell processed, melt wax-pattern, roasting mold shell, casting of molten metal, taking-up foundry goods, cleaning cast gate and burr.Institute The casting metal material related to includes gold, silver, copper, ferrum.
In replacement scheme, resin molding is equally applicable.General procedure is: assemble cast gate, coating system to resin mold Shell, thawing resin mold, roasting mold shell, casting of molten metal, taking-up foundry goods, cleaning cast gate and burr.Involved And casting metal material include gold, silver, copper, ferrum and alloy.
Step 104, at the bottom of tire, wire inlay and polish, clean.Specifically, to polishing at the bottom of tire, clearly Wash;Polish to wiring inlay, clean.
Step 105, fills enamel in the sunk area formed that wires inlay.
Fill enamel, be that assorted enamel glaze is applied the operation within the different sunk area that the grain pattern that wires inlay surrounds. As the method applying enamel glaze, it is known to dry process and damp process, in the technique of the present invention, the wettest Formula method.And insert glaze and highly flush or slightly higher with the silk wired inlay.
Enamel glaze is that the glaze using the mineral such as quartz, Anhydrite, oxidized metal to be configured to is ground and make Become, through constantly filling enamel on metal tire more constantly to entering kiln sinters colour generation repeatedly, finally come out of the stove one The exquisite enamel art work.Enamel color is the most gorgeous, has the gloss as gem and texture, corrosion-resistant, Wear-resistant, high temperature resistant, waterproof and dampproof, hard solid, the most aging never degenerate, go through 1,100 and colour-fast, Not loss of gloss.
Step 106, the carcass obtained after filling enamel is placed in repeated calcination in baker, and Control for Kiln Temperature is at 400-900 DEG C Between.
Specifically, being that the carcass after filling enamel is placed in repeated calcination 3-5 time in baker, Control for Kiln Temperature exists Between 400-900 DEG C.
Concrete furnace temperature is with different from the selected metal material that wires inlay at the bottom of tire and change, and different metal materials is also Different enamel glazes can be selected, but furnace temperature is all without the fusing point exceeding metal material used.Enamel after roasting Thinkling sound's glaze highly should flush with the silk wired inlay, and as depression occurs in enamel glaze, again performs step 104-step 105-step 106, until enamel glaze highly should flush with the silk wired inlay.
Step 107, electroplates the enamelwork obtained after roasting.
Specifically, first need before plating to be polished enamelwork cleaning.Utilize electrolysis principle at enamel The operation of one layer of other metal or alloy of goods metal surface plating.In any case, this step can be omitted, Complete polished and cleaned.
Example 2, referring to Fig. 3:
Step 201, set up at the bottom of tire with the 3D digital model wired inlay.
Set up the software of 3D digital model include but not limited to rhinocero, MaYa, 3DMAX, JewelCAD, Artcam etc. can set up the software of 3D digital model.
Design drafting is wired inlay grain pattern: design is drawn the effect wired inlay and is to form the thread of projection at tire basal surface Grain pattern, on the one hand it play the effect of decoration, when on the other hand can prevent enameling operation later, melted Enamel glaze product surface unordered excessive, flowing, make the enamel glaze of different colours control accordingly Within the sunk area that the grain pattern that wires inlay surrounds.So the grain pattern that wires inlay of design may eventually form and closes one by one Sunk area.Designed by the silk width that wires inlay be generally 0.1mm-3mm, (i.e. silk is higher than the silk height wired inlay Height at the bottom of tire) generally 0.1mm-1mm, concrete size needs to be as the criterion with design and craft.
In computer software, the grain pattern 3D model that wires inlay is saved as 3D metal paste printer and is capable of identify that Digitized 3D model file.
Step 202, makes base.
With tablet machine, metal material being pressed into 0.2-2mm, by mould or cutting tools, sheet metal being made need to Want the tyre shoe of moulding, as at the bottom of tire.
Step 203, utilizes 3D metal paste printer to print part of wiring inlay.
Concrete, before printing step, at the bottom of the tire that previous step is made, it is put in the printing of 3D printer Region, successively prints, with 3D metal paste printer, part of wiring inlay at the bottom of tire.
Wherein, 3D metal paste printer refers to the material that printer head metal injection powder mixes with bonding agent Material, moved at three direction of principal axis by printhead, successively superposition bonding forming a kind of 3D printer.
Step 204, will sinter metal objects into wiring inlay at the bottom of tire.
During sintering, oxidation during in order to prevent from sintering, need to do anoxybiotic and process, can be at activated carbon Under encirclement, it is sintered airtight environment (such as electric furnace) is inner.In its sintering process, along with furnace temperature Raising, first experience skimming processes, constant temperature a period of time when temperature rises towards melting point metal temperature, It is gradually dropped to room temperature again and completes sintering.
Wherein, the maximum temperature that concrete skimming temp and electric furnace rise and constant temperature time with adhesive material, Metal material, goods size, the difference of electric furnace model and different, need concrete condition to make a concrete analysis of.
Step 205, at the bottom of tire, wire inlay and polish, clean.Specifically, to polishing at the bottom of tire, clearly Wash;Polish to wiring inlay, clean.
Step 206, fills enamel in the sunk area formed that wires inlay.
Fill enamel is that assorted enamel glaze is applied the operation within the different sunk area that the grain pattern that wires inlay surrounds. As the method applying enamel glaze, it is known to dry process and damp process, in the technique of the present invention, the wettest Formula method.And insert glaze and highly flush or slightly higher with the silk wired inlay.
Enamel glaze is that the glaze using the mineral such as quartz, Anhydrite, oxidized metal to be configured to is ground and make Become, through constantly filling enamel on metal tire more constantly to entering kiln sinters colour generation repeatedly, finally come out of the stove one The exquisite enamel art work.Enamel color is the most gorgeous, has the gloss as gem and texture, corrosion-resistant, Wear-resistant, high temperature resistant, waterproof and dampproof, hard solid, the most aging never degenerate, go through 1,100 and colour-fast, Not loss of gloss.
Step 207, the carcass obtained after filling enamel is placed in repeated calcination in baker, and Control for Kiln Temperature is at 400-900 DEG C Between.
Carcass after filling enamel is placed in repeated calcination 3-5 time in baker, and Control for Kiln Temperature is between 400-900 DEG C. Concrete furnace temperature is with different from the selected metal material that wires inlay at the bottom of tire and change, and different metal materials also can select With different enamel glazes, but furnace temperature is all without the fusing point exceeding metal material used.Enamel glaze after roasting Face highly should flush with the silk wired inlay, and as depression occurs in enamel glaze, again performs step 205-step 206- Step 207, until enamel glaze highly should flush with the silk wired inlay.
Step 208, electroplates the enamelwork obtained after roasting.
First need before plating to be polished enamelwork cleaning.Utilize electrolysis principle at enamelwork metal watch The operation of one layer of other metal or alloy of face plating.In any case, this step can be omitted, and completes polishing Clean.
Example 3, referring to Fig. 4:
Step 301, set up at the bottom of tire with the 3D digital model wired inlay.
Set up the software of 3D digital model include but not limited to rhinocero, MaYa, 3DMAX, JewelCAD, Artcam etc. can set up the software of 3D digital model.
Design drafting is wired inlay grain pattern: design is drawn the effect wired inlay and is to form the thread of projection at tire basal surface Grain pattern, on the one hand it play the effect of decoration, when on the other hand can prevent enameling operation later, melted Enamel glaze product surface unordered excessive, flowing, make the enamel glaze of different colours control accordingly Within the sunk area that the grain pattern that wires inlay surrounds.So the grain pattern that wires inlay of design may eventually form and closes one by one Sunk area.Designed by the silk width that wires inlay be generally 0.1mm-3mm, (i.e. silk is higher than the silk height wired inlay Height at the bottom of tire) generally 0.1mm-1mm, concrete size needs to be as the criterion with design and craft.
In computer software, wiring inlay, grain pattern 3D model saves as 3D metal dust selective laser sintering The digitized 3D model file that printer is capable of identify that.
Step 302, makes base.With tablet machine, metal material is pressed into 0.2-2mm, by mould or sawing work Tool makes sheet metal needs the tyre shoe of moulding, as at the bottom of tire.
Step 303, utilizes 3D metal dust selective laser sintering printer to print part of wiring inlay.
Certainly, in actual applications, it is also possible to directly utilize 3D metal dust selective laser sintering printer Print at the bottom of tire and wire inlay part.
Concrete, before printing step, at the bottom of the tire that previous step is made, it is put in the printing of 3D printer Region, successively prints, with 3D metal dust selective laser sintering printer, part of wiring inlay at the bottom of tire.
Wherein, 3D metal dust selective laser sintering printer refers to a kind of rapid shaping 3D printer, It is with laser instrument as energy source, is sintered in equably on machined surface by the powder of laser beam causes metallic.Swash Light beam under control of the computer, presses the two dimension in layering face by scanning device with certain speed and energy density Data scanning.In place of laser beam flying, the certain thickness entity layering of powder sintered one-tenth, the place do not scanned Appoint the powder so keeping loose.Cutting layer thickness and self-powered platform according to object, paving powder cylinder again will Powder paves platform, starts the scanning of new one layer.The most repeatedly, until scanning through structure at all levels.It is unnecessary to remove Powder, obtains metallic article after reconditioning etc. processes.At present with the M080 metallic print machine of EO company of Germany For representing.
Step 304, at the bottom of tire, wire inlay and polish, clean.
Specifically, to polishing at the bottom of tire, cleaning;Polish to wiring inlay, clean.
Step 305, fills enamel in the sunk area formed that wires inlay.
Fill enamel is that assorted enamel glaze is applied the operation within the different sunk area that the grain pattern that wires inlay surrounds. As the method applying enamel glaze, it is known to dry process and damp process, in the technique of the present invention, the wettest Formula method.And insert glaze and highly flush or slightly higher with the silk wired inlay.
Enamel glaze is that the glaze using the mineral such as quartz, Anhydrite, oxidized metal to be configured to is ground and make Become, through constantly filling enamel on metal tire, more constantly to entering kiln sinters colour generation repeatedly, finally come out of the stove one The enamel art work that part is exquisite.Enamel color is the most gorgeous, has the gloss as gem and texture, corrosion-resistant, Wear-resistant, high temperature resistant, waterproof and dampproof, hard solid, the most aging never degenerate, go through 1,100 and colour-fast, Not loss of gloss.
Step 306, the carcass obtained after filling enamel is placed in repeated calcination in baker, and Control for Kiln Temperature is at 400-900 DEG C Between.
Carcass after filling enamel is placed in repeated calcination 3-5 time in baker, and Control for Kiln Temperature is between 400-900 DEG C. Concrete furnace temperature is with different from the selected metal material that wires inlay at the bottom of tire and change, and different metal materials also can select With different enamel glazes, but furnace temperature is all without the fusing point exceeding metal material used.Enamel glaze after roasting Face highly should flush with the silk wired inlay, and as depression occurs in enamel glaze, again performs step 304-step 305- Step 306, until enamel glaze highly should flush with the silk wired inlay.
Step 307, electroplates the enamelwork obtained after roasting.
Before plating, first need to be polished enamelwork cleaning.Utilize electrolysis principle at enamelwork metal The operation of one layer of other metal or alloy of plated surface.In any case, this step can be omitted, and completes to throw Light cleans.
The artware that such as enamel technique in Fig. 5-Fig. 6 makes.Fig. 5 describe wire inlay 1 and tire at the bottom of 2 Schematic diagram.Fig. 6 describes has enamel glaze A, enamel glaze B, the schematic diagram of enamel glaze C.
By one or more embodiment of the present invention, the invention have the advantages that or advantage:
The invention discloses a kind of enamel manufacture method, utilize 3D printing technique replace at the bottom of traditional tire with wire inlay Processing technology make at the bottom of tire with wire inlay, then at the bottom of described tire and described wiring inlay carries out pretreatment;Described Wire inlay formed sunk area in fill enamel;The carcass obtained after filling enamel is placed in repeated calcination in baker, Control for Kiln Temperature is between 400-900 DEG C;The enamelwork obtained after roasting is electroplated, a series of based on this Technique solves opponent's technological level in tradition thread weaving enamel technique and requires high technical problem, improves work Efficiency and yield rate, reduce labor intensity, shortens activity time, saves human cost.
Although having been described for the preferred embodiment of the application, but one of ordinary skilled in the art once learning Basic creative concept, then can make other change and amendment to these embodiments.So, appended power Profit requires to be intended to be construed to include preferred embodiment and fall into all changes and the amendment of the application scope.
Obviously, those skilled in the art can carry out various change and modification without deviating from this Shen to the application Spirit and scope please.So, if the application these amendment and modification belong to the application claim and Within the scope of its equivalent technologies, then the application is also intended to comprise these change and modification.

Claims (10)

1. an enamel manufacture method, it is characterised in that described method includes:
Utilize 3D printing technique make at the bottom of tire with wire inlay, described in wire inlay and be arranged at the bottom of described tire, described in wire inlay All kinds of sunk area can be formed;
To at the bottom of described tire and described wiring inlay carries out pretreatment;
The described sunk area wiring inlay and being formed is filled enamel;
The carcass obtained after filling enamel is placed in repeated calcination in baker, and Control for Kiln Temperature is between 400-900 DEG C;
The enamelwork obtained after roasting is electroplated.
2. the method for claim 1, it is characterised in that described at the bottom of described tire and described wire inlay into Row pretreatment, specifically includes:
To polishing at the bottom of described tire, cleaning;
Described wiring inlay is polished, cleaned.
3. the method for claim 1, it is characterised in that described utilize 3D printing technique make tire The end with wire inlay, specifically include:
Utilize 3D wax spray to print at the bottom of the lost wax process described tire of making to wire inlay with described;Or
Utilize 3D metal paste to print at the bottom of the sintering process described tire of making to wire inlay with described;Or
Utilize 3D metal dust selective laser sintering process to make at the bottom of described tire to wire inlay with described.
4. method as claimed in claim 3, it is characterised in that described utilize 3D wax spray to print to lose wax casting Make legal system make at the bottom of tire with wire inlay, specifically include:
Set up at the bottom of described tire and the described 3D digital model wired inlay;
3D wax spray printer is utilized to make at the bottom of described tire and the described wax-pattern wired inlay;
Make at the bottom of described tire based on described wax-pattern by lost wax process and the described metal objects wired inlay.
5. method as claimed in claim 3, it is characterised in that described utilize 3D metal paste to print to burn Connection makes and wires inlay with described at the bottom of described tire, specifically includes:
Set up at the bottom of described tire and the described 3D digital model wired inlay;
Utilize tablet machine that metal material is pressed at the bottom of described tire;
Utilize and wire inlay described in the printing of 3D metal paste printer;
By at the bottom of described tire and described wiring inlay sinters metal objects into.
6. method as claimed in claim 3, it is characterised in that described utilize 3D metal dust selectivity Laser sintered method makes and wires inlay with described at the bottom of described tire, specifically includes:
Set up at the bottom of described tire and the described 3D digital model wired inlay;
Utilize tablet machine that metal material is pressed at the bottom of described tire;
Utilize and wire inlay described in the printing of 3D metal dust selective laser sintering printer.
7. method as claimed in claim 6, it is characterised in that described utilize 3D metal dust selectivity Before wiring inlay described in the printing of laser sintered printer, described method method also includes:
The print area of described 3D metal dust selective laser sintering printer will be put at the bottom of described tire, utilize Described 3D metal dust selective laser sintering printer wires inlay described in successively printing at the bottom of tire.
8. the method for claim 1, it is characterised in that described will fill enamel after the carcass that obtains be placed in Repeated calcination in baker, specifically includes:
Described carcass is placed in repeated calcination 3-5 time in baker.
9. the method for claim 1, it is characterised in that the described enamelwork to obtaining after roasting Before electroplating, specifically include:
Described enamelwork is polished, cleans.
10. the method for claim 1, it is characterised in that described in the silk width that wires inlay be 0.1mm-3mm, the silk height wired inlay is 0.1mm-2mm.
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CN108246974A (en) * 2016-12-29 2018-07-06 无锡刚正精密吸铸有限公司 A kind of production method of the aluminum products of inner cavity complexity
CN108973493A (en) * 2018-06-13 2018-12-11 中国地质大学(武汉) A kind of gradient color production method of 3D printing enamel
CN108973493B (en) * 2018-06-13 2020-08-07 中国地质大学(武汉) Gradient color manufacturing method for 3D printed enamel
CN109664665A (en) * 2019-01-11 2019-04-23 兰州北方文化影视传媒有限公司 A kind of solid thread weaving enamel production method
CN112355278A (en) * 2020-10-22 2021-02-12 江西桐青金属工艺品股份有限公司 Manufacturing process of thin-blank enamel sculpture product
CN112453319A (en) * 2020-11-20 2021-03-09 广州番禺职业技术学院 Manufacturing method of uniform thick-wall cast body cloisonne enamel ware
CN112759261A (en) * 2021-03-01 2021-05-07 福建省德化顺意发陶瓷有限公司 Cloisonne enamel color porcelain and preparation process thereof
CN113633078A (en) * 2021-08-25 2021-11-12 深圳市甘露珠宝首饰有限公司 Preparation of enamel precious metal ornament and ornament prepared by method
CN113780988A (en) * 2021-09-01 2021-12-10 深圳市至诚峰汇科技有限公司 Factory monitoring system of standard digital production management system
CN115771352A (en) * 2021-09-07 2023-03-10 深圳市香巴拉珠宝首饰有限公司 Manufacturing process of mother-of-pear enamel
CN115838930A (en) * 2022-12-30 2023-03-24 青花设计有限公司 Method for making enamel handicraft
WO2024141007A1 (en) * 2022-12-30 2024-07-04 青花设计有限公司 Manufacturing method for enamel handicraft
CN117284019A (en) * 2023-08-10 2023-12-26 中国地质大学(武汉) Method for manufacturing three-dimensional cloisonne enamel

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