CN105713638A - Raw materials for producing 70# asphalt through Venezuela Boscan crude oil and technological method - Google Patents

Raw materials for producing 70# asphalt through Venezuela Boscan crude oil and technological method Download PDF

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Publication number
CN105713638A
CN105713638A CN201610141452.0A CN201610141452A CN105713638A CN 105713638 A CN105713638 A CN 105713638A CN 201610141452 A CN201610141452 A CN 201610141452A CN 105713638 A CN105713638 A CN 105713638A
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CN
China
Prior art keywords
crude oil
tower
venezuela
vacuum
asphalt
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CN201610141452.0A
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Chinese (zh)
Inventor
刘仪凤
蒲旭斌
巫兴朋
黄爱春
官见龙
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Foshan Gaofu CNPC Fuel Asphalt Co Ltd
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Foshan Gaofu CNPC Fuel Asphalt Co Ltd
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Application filed by Foshan Gaofu CNPC Fuel Asphalt Co Ltd filed Critical Foshan Gaofu CNPC Fuel Asphalt Co Ltd
Priority to CN201610141452.0A priority Critical patent/CN105713638A/en
Publication of CN105713638A publication Critical patent/CN105713638A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10CWORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C3/00Working-up pitch, asphalt, bitumen
    • C10C3/06Working-up pitch, asphalt, bitumen by distillation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Working-Up Tar And Pitch (AREA)

Abstract

The invention discloses raw materials for producing 70# asphalt through Venezuela Boscan crude oil and a technological method. The raw materials include Bachaquero Boscan crude oil and Bachaquero crude oil. The produced 70# heavy traffic road asphalt conforms to the 70# A-level road petroleum asphalt index formulated in MOT road asphalt pavement construction technical regulations JTGF40-2004 and is superior to various indexes in the national standard (GB50092-96). An atmospheric and vacuum distillation unit is adopted for producing high-level road asphalt in a straight-run distillation mode, the production process is simple, the method is the most economic and convenient method for producing asphalt, and the produced product is superior in performance, and can completely replace imported high-level road asphalt and meet the requirements of rapidly-developing road construction and national economic development in China.

Description

The raw material of a kind of Venezuela Persian No. 70 Colophoniumes of bank crude oil production and process
Technical field
The invention belongs to road asphalt technical field, be specifically related to raw material and the process of a kind of Venezuela Persian No. 70 Colophoniumes of bank crude oil production.
Background technology
In recent years, the prosperity of China's economy has promoted the high speed development of highway communication cause, large quantities of highways build up or under construction in succession, but the yield of China's Colophonium particularly asphalt for high grade road does not also catch up with far away the needs of highway construction, and Imported Asphalt still occupies the important market share.Due to the restriction by domestic oil property, the road asphalt of most of domestic crude oil production can not meet requirement in quality.It is said that in general, wax content is lower than 2.2%, the 15 DEG C of ductilities of Thin Film Oven Test TFOT No. 70 Colophoniumes more than 15cm, traffic department just uses it as high grade pavement pavement material.Crude oil in China more than 80% belongs to paraffinic base crude oil, and paraffin content is higher, should not produce road asphalt.
Along with highway in China transport and communications amount sharply increases, overload, heavy duty phenomenon are serious, and the damaged condition of pavement structure is increasingly sharpened, and bituminous concrete high-temperature stability deficiency forms rut, are one of the Major Diseases forms of China Higher level asphalt highway.
Along with the increase of imported crude oil particularly heavy crude ratio, adopt import heavy crude to produce heavy duty road asphalt, have important practical significance.
Venezuela's Persian bank crude oil belongs to high-sulfur naphthene base crude oil, and oil density is big, and viscosity is big, condensation point is low, and gasoline, diesel fraction yield is about 30%, and hydrocarbon when carbon residue is all higher, and its character is similar to the vacuum residue fraction of general crude oil.Because of this acid value for crude oil, content of beary metal height, carbon residue is high, should not make catalytically cracked material, and saturated hydrocarbon content is low, and colloid, asphalt content are high, and wax content is little, is suitable for making high-quality asphalt raw material very much.
Summary of the invention
Instant invention overcomes shortcoming of the prior art, provide raw material and the process of a kind of Venezuela Persian No. 70 Colophoniumes of bank crude oil production, these No. 70 heavy duty road asphalt excellent product performance, meet No. 70 A level bi tumenf orr oad indexs formulated in " Ministry of Communications's standard specification for construction and acceptance of highway asphalt pavement " JTGF40-2004, be better than the indices of GB (GB50092-96).
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of raw material of Venezuela Persian No. 70 Colophoniumes of bank crude oil production, including: Venezuela's Persian bank crude oil and Bachaquero crude oil.
Further, La Guna crude oil is also included.
Further, include by weight percentage: Venezuela Persian bank crude oil 70-90%, Bachaquero crude oil 5-20% and La Guna crude oil 2-10%.
The process of a kind of Venezuela Persian No. 70 Colophoniumes of bank crude oil production, comprises the following steps:
A) just oil vapour in top distillates through fore-running tower top, and the first base oil bottom primary distillation tower enters through pump pressurization and enters atmospheric tower fractional distillation after atmospheric pressure kiln heating;
B) often top oil distillates through Atmospheric Tower, and atmospheric side draw oil product distillates through atmospheric tower side line, and normal base oil enters through pump pressurization and enters vacuum tower fractional distillation after vacuum furnace heating;
C) subtract top oil to distillate through Top of Vacuum Tower evacuation, decompression sideline product distillates through vacuum tower side line, the decompression residuum of vacuum tower bottoms and Colophonium are after pump pressurizes, carrying device after heat exchange, cooling, obtains No. 70 Colophoniumes by controlling vacuum furnace furnace temperature, Top of Vacuum Tower vacuum and asphaltic products needle penetration.
Further, entering atmospheric tower temperature is 340~370 DEG C, and entering vacuum tower temperature is 330~360 DEG C, and the operation pressure of vacuum tower is 92~100kPa.
Further, entering atmospheric tower temperature is 348~350 DEG C, and entering vacuum tower temperature is 352~354 DEG C, and the operation pressure of vacuum tower is 97~99kP.
Further, entering atmospheric tower temperature is 350~352 DEG C, and entering vacuum tower temperature is 354~356 DEG C, and the operation pressure of vacuum tower is 96~98kPa.
Compared with prior art, the invention has the beneficial effects as follows:
The raw material of a kind of Venezuela of the present invention Persian No. 70 Colophoniumes of bank crude oil production and process, No. 70 heavy duty road asphalts of its production meet No. 70 A level bi tumenf orr oad indexs formulated in " Ministry of Communications's standard specification for construction and acceptance of highway asphalt pavement " JTGF40-2004, are better than the indices of GB (GB50092-96).Atmospheric and vacuum distillation unit straight run is adopted to produce asphalt for high grade road, production process is simple, it is produce that Colophonium is most economical, method easily, and the excellent product performance produced, may replace import asphalt for high grade road completely, meet the road construction of China's high speed development and the needs of the national economic development.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is merely to illustrate and explains the present invention, is not intended to limit the present invention.
Embodiment 1
The raw material of a kind of Venezuela Persian No. 70 Colophoniumes of bank crude oil production, includes by weight percentage: Venezuela's Persian bank crude oil 75%, Bachaquero crude oil 18% and La Guna crude oil 7%.
Venezuela's Persian bank crude oil, belongs to high-sulfur naphthene base crude oil, and oil density is big, and viscosity is big, condensation point is low, and gasoline, diesel fraction yield is about 30%, and hydrocarbon when carbon residue is all higher, and its character is similar to the vacuum residue fraction of general crude oil.Because of this acid value for crude oil, content of beary metal height, carbon residue is high, should not make catalytically cracked material, and saturated hydrocarbon content is low, and colloid, asphalt content are high, and wax content is little, is suitable for making high-quality asphalt raw material very much.
Its process comprises the following steps:
A) just oil vapour in top distillates through fore-running tower top, and the first base oil bottom primary distillation tower enters through pump pressurization and enters atmospheric tower fractional distillation after atmospheric pressure kiln heating;
B) often top oil distillates through Atmospheric Tower, and atmospheric side draw oil product distillates through atmospheric tower side line, and normal base oil enters through pump pressurization and enters vacuum tower fractional distillation after vacuum furnace heating;
C) subtract top oil to distillate through Top of Vacuum Tower evacuation, decompression sideline product distillates through vacuum tower side line, the decompression residuum of vacuum tower bottoms and Colophonium are after pump pressurizes, carrying device after heat exchange, cooling, obtains No. 70 Colophoniumes by controlling vacuum furnace furnace temperature, Top of Vacuum Tower vacuum and asphaltic products needle penetration.
It is 348~350 DEG C that mixed material enters atmospheric tower temperature; entering vacuum tower temperature is 352~354 DEG C, and the operation pressure of vacuum tower is 97~99kPa, controls higher vacuum and relatively low furnace temperature in production process; the method flow process is short, cost is low, is suitable for large-scale production.
Decompression residuum penetration number is 65-7510-1mm, decompression residuum obtain road asphalt, and result is in Table 1, and this Colophonium meets the index request of " Ministry of Communications's standard specification for construction and acceptance of highway asphalt pavement " (JTGF40-2004) No. 70 A level road asphalts.
Embodiment 2
The raw material of a kind of Venezuela Persian No. 70 Colophoniumes of bank crude oil production, includes by weight percentage: Venezuela's Persian bank crude oil 85%, Bachaquero crude oil 10% and La Guna crude oil 5%.
Its process comprises the following steps:
C) just oil vapour in top distillates through fore-running tower top, and the first base oil bottom primary distillation tower enters through pump pressurization and enters atmospheric tower fractional distillation after atmospheric pressure kiln heating;
D) often top oil distillates through Atmospheric Tower, and atmospheric side draw oil product distillates through atmospheric tower side line, and normal base oil enters through pump pressurization and enters vacuum tower fractional distillation after vacuum furnace heating;
C) subtract top oil to distillate through Top of Vacuum Tower evacuation, decompression sideline product distillates through vacuum tower side line, the decompression residuum of vacuum tower bottoms and Colophonium are after pump pressurizes, carrying device after heat exchange, cooling, obtains No. 70 Colophoniumes by controlling vacuum furnace furnace temperature, Top of Vacuum Tower vacuum and asphaltic products needle penetration.
It is 350~352 DEG C that mixed material enters atmospheric tower temperature, and entering vacuum tower temperature is 354~356 DEG C, and the operation pressure of vacuum tower is 96~98kPa.
Decompression residuum penetration number is 65-7510-1mm, decompression residuum obtain road asphalt, and result is in Table 1, and this Colophonium meets the index request of " Ministry of Communications's standard specification for construction and acceptance of highway asphalt pavement " (JTGF40-2004) No. 70 A level road asphalts.
Table 1 embodiment 1, embodiment 2 Colophonium character
Last it is noted that these are only the preferred embodiments of the present invention; it is not limited to the present invention; although the present invention being described in detail with reference to embodiment; for a person skilled in the art; technical scheme described in foregoing embodiments still can be modified by it; or wherein portion of techniques feature is carried out equivalent replacement; but all within the spirit and principles in the present invention; any amendment of being made, equivalent replacement, improvement etc., should be included within protection scope of the present invention.

Claims (7)

1. the raw material of Venezuela's Persian No. 70 Colophoniumes of bank crude oil production, it is characterised in that including: Venezuela's Persian bank crude oil and Bachaquero crude oil.
2. the raw material of No. 70 Colophoniumes of a kind of Venezuela Persian bank crude oil production according to claim 1, it is characterised in that also include La Guna crude oil.
3. the raw material of No. 70 Colophoniumes of a kind of Venezuela Persian bank crude oil production according to claim 2, it is characterised in that include by weight percentage: Venezuela Persian bank crude oil 70-90%, Bachaquero crude oil 5-20% and La Guna crude oil 2-10%.
4. the process of No. 70 Colophoniumes of a kind of Venezuela Persian bank crude oil production according to claim 3, it is characterised in that comprise the following steps:
A) just oil vapour in top distillates through fore-running tower top, and the first base oil bottom primary distillation tower enters through pump pressurization and enters atmospheric tower fractional distillation after atmospheric pressure kiln heating;
B) often top oil distillates through Atmospheric Tower, and atmospheric side draw oil product distillates through atmospheric tower side line, and normal base oil enters through pump pressurization and enters vacuum tower fractional distillation after vacuum furnace heating;
C) subtract top oil to distillate through Top of Vacuum Tower evacuation, decompression sideline product distillates through vacuum tower side line, the decompression residuum of vacuum tower bottoms and Colophonium are after pump pressurizes, carrying device after heat exchange, cooling, obtains No. 70 Colophoniumes by controlling vacuum furnace furnace temperature, Top of Vacuum Tower vacuum and asphaltic products needle penetration.
5. the process of No. 70 Colophoniumes of a kind of Venezuela Persian bank crude oil production according to claim 4, it is characterised in that entering atmospheric tower temperature is 340~370 DEG C, and entering vacuum tower temperature is 330~360 DEG C, and the operation pressure of vacuum tower is 92~100kPa.
6. the process of No. 70 Colophoniumes of a kind of Venezuela Persian bank crude oil production according to claim 4, it is characterised in that entering atmospheric tower temperature is 348~350 DEG C, and entering vacuum tower temperature is 352~354 DEG C, and the operation pressure of vacuum tower is 97~99kP.
7. the process of No. 70 Colophoniumes of a kind of Venezuela Persian bank crude oil production according to claim 4, it is characterised in that entering atmospheric tower temperature is 350~352 DEG C, and entering vacuum tower temperature is 354~356 DEG C, and the operation pressure of vacuum tower is 96~98kPa.
CN201610141452.0A 2016-03-11 2016-03-11 Raw materials for producing 70# asphalt through Venezuela Boscan crude oil and technological method Pending CN105713638A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004346156A (en) * 2003-05-21 2004-12-09 Idemitsu Kosan Co Ltd Propane deasphalted asphalt and straight asphalt manufactured by using the same
CN104073004A (en) * 2014-06-25 2014-10-01 佛山高富中石油燃料沥青有限责任公司 50# asphalt and production method thereof
CN105331383A (en) * 2015-11-26 2016-02-17 佛山高富中石油燃料沥青有限责任公司 No. 70 asphalt and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004346156A (en) * 2003-05-21 2004-12-09 Idemitsu Kosan Co Ltd Propane deasphalted asphalt and straight asphalt manufactured by using the same
CN104073004A (en) * 2014-06-25 2014-10-01 佛山高富中石油燃料沥青有限责任公司 50# asphalt and production method thereof
CN105331383A (en) * 2015-11-26 2016-02-17 佛山高富中石油燃料沥青有限责任公司 No. 70 asphalt and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
小川胜;周玉琛: "《海上溢油鉴别方法的研究—用荧光分光光度法对各种类型的石油进行分类的研究》", 《交通环保》 *
牛毓等: "《进口原油生产道路沥青可行性考察》", 《石油沥青》 *
蒋福山等: "《南美重质原油生产道路沥青技术研究现状》", 《石油沥青》 *

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