CN105713408A - Natural environment-friendly multifunctional polymer insect-repellent antibacterial material and preparation method thereof - Google Patents

Natural environment-friendly multifunctional polymer insect-repellent antibacterial material and preparation method thereof Download PDF

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CN105713408A
CN105713408A CN201610104323.4A CN201610104323A CN105713408A CN 105713408 A CN105713408 A CN 105713408A CN 201610104323 A CN201610104323 A CN 201610104323A CN 105713408 A CN105713408 A CN 105713408A
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刘俊松
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
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Abstract

The invention discloses a natural environment-friendly multifunctional polymer insect-repellent antibacterial material. The material is prepared from, by mass, 50-65% of pure natural carbohydrate polymer material, 10-15% of filler, 8-10% of mesh fiber, 5-10% of foaming agent, 5-10% of adhesive, 5-10% of moisture preserving agent and 0.5-1% of hydrocarbon hydropholic molecule. Pure natural carbohydrate polymer material, filler and mesh fiber are all waste, so cost is low; filler is natural coal and natural mineral material, so water retention can be achieved; by means of moisture preserving agent, moisture preservation can be achieved; the soil moisture content of soil can be kept, and therefore good conditions are provided for growth of plants; by means of the hydrocarbon hydropholic molecule, a plastic function and a moisture preservation function are achieved.

Description

A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof
Technical field
The present invention relates to environmental technology field, specifically a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and Preparation method.
Background technology
Natural resources, also known as natural resources, refer under its initial condition with regard to valuable goods.If in general obtaining The major project taking this goods isCollectWithPurificationRather than if producing, then this goods is a kind of natural resources.Adopt Ore deposit,Recover the oil, fishery and forestry be therefore generally seen as obtaining the industry of natural resources, agricultural is not.Natural resources is into Natural wealth for goods.
China region is vast, and carbohydrate sources enriches, geological and mineral huge number, but the limited profit of natural resource Low by degree, product is few, not only causes the wasting of resources, and easily causes environmental pollution, society's pipe because preparation is unreasonable naturally Reason cost is high, and therefore, the above-mentioned natural resource of Appropriate application saves environmental friendliness society to greatly developing pollution-free industry Resources for construction Can be significant.
Summary of the invention
It is an object of the invention to provide a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof, With the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof, by pure natural carbon water macromolecular material, Inserts, reticular fiber, foaming agent, binding agent, wetting agent and hydrocarbon hydrophobic molecule are prepared from；Percent mass shared by each raw material Ratio is: pure natural carbon water macromolecular material 50-65%, inserts 10-15%, reticular fiber 8-10%, foaming agent 5-10%, viscous Knot agent 5-10%, wetting agent 5-10%, hydrocarbon hydrophobic molecule 0.5-1%；Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, lamp Core grass, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, Folium Pini, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, Any one in sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is ground into powdery or any two above is ground into the mixing after powdery, and appoints Anticipate more than two kinds time proportioning be any proportioning；Described inserts is natural coal body and natural mineral materials, natural coal body It is 1: 3-6 with the mass ratio of natural mineral materials.
As the further scheme of the present invention: described reticular fiber is mesh polypropylene-fibre, knits webbed monofilament Or it is slit into the Retinervus Luffae Fructus of lamellar.
As the further scheme of the present invention: described reticular fiber is mesh polypropylene-fibre, knits webbed monofilament Or it is slit into the Retinervus Luffae Fructus of lamellar.
As the further scheme of the present invention: described foaming agent is Pentamethylene., hydrogenation halothane hydrocarbon, N, N-dinitroso five Methine tetramine, N, N-dimethyl-N, N-bis-sub-terephthalamide, azodicarbonamide, azodiisobutyronitrile, azo diformazan Isopropyl propionate, diethyl azodiformate, two azoaminobenzenes, Barium azodicarboxylate, 4,4-disulfonyl hydrazide diphenyl ether, to benzene sulphur Hydrazides, 3,3-disulfonyl hydrazide diphenyl sulphone (DPS), 4,4-bis-benzene disulfohydrazide, 1,3-benzene disulfohydrazide or Isosorbide-5-Nitrae-benzene disulfohydrazide.
As the further scheme of the present invention: described binding agent be hydrophobicity carbon water fatty acid material or with Carbonyl, the carbon water fatty acid material of hydroxyl, or the carbonyl compound and many of process with nitrogen element are dynamically tied The complex material closed.
As the further scheme of the present invention: described wetting agent be glycerol, butanediol, Polyethylene Glycol, propylene glycol, oneself Glycol, xylitol, polypropylene glycol, Sorbitol one of which or the many of complex material through dynamic bind.
As the further scheme of the present invention: described natural mineral materials is red soil, Kaolin, montmorillonite, Erie Stone, chlorite or bentonite.
System according to the described natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material of any one in above technical scheme Preparation Method, comprises the following steps:
(1) pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic is chosen Molecular raw material；
(2) raw material is mixed；
(3) pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic is added After the water of molecular raw material gross mass 0.1%-20%, foam in foaming machine；
(4) raw material after foaming in step (3) is carried out curing molding, be prepared as bulk, flake or film body shape.
Compared with prior art, the invention has the beneficial effects as follows:
1, use pure natural carbon water macromolecular material, inserts, reticular fiber, be all the thing gone out of use, so cost of the present invention Low；
2, inserts uses natural coal body and natural mineral materials, can water conservation；Use wetting agent energy moisturizing；The present invention can keep Soil tilth, thus provide good condition for plant growing；
3, hydrocarbon hydrophobic polymeric is used to have plastic function；
4, use reticular fiber to play a supporting role, intensity can be strengthened；
5, above-mentioned complex material has a plasticity, therefore can machine-shaping, it is possible to produce for building and environment-friendly materials processing Industry, it is possible to be manufactured into powder body, solid, bar-shaped, tabular, drum, bulk, film body shape etc.；
6, it is antibacterial that above-mentioned complex material has anthelmintic, is suitable for pollution-free food anti-corrosive fresh-keeping materials processing industry, application ten Divide ground extensively.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the technical scheme of this patent is described in more detail.
Embodiment 1
A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material, by pure natural carbon water macromolecular material, inserts, netted fibre Dimension, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic molecule etc. are prepared from；Shared by each raw material, mass percent is: pure natural Carbon water macromolecular material 50%, inserts 10%, reticular fiber 9.5%, foaming agent 10%, binding agent 10%, wetting agent 10%, Hydrocarbon hydrophobic molecule 0.5%.
Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, Medulla Junci, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, pine Any one in leaf, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is pulverized Powdering or any two above be ground into the mixing after powdery, and proportioning when any two is above is any proportioning, described Pure natural carbon water macromolecular material be that above plant tissue is ground into 20-100 mesh；Described inserts is natural coal body and sky So mineral material, natural coal body is 1: 3 with the mass ratio of natural mineral materials；Described reticular fiber is webbed for knitting Monofilament；Described foaming agent is Pentamethylene.；Described binding agent is Semen Maydis pulp；Described wetting agent is glycerol；Described carbon Hydrogen hydrophobic molecule is fatty acid molecule；Described natural mineral materials is red soil or Kaolin.
The preparation of above-mentioned a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof: choose above-mentioned former Material, mixing humidification, add pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, carbon The water of hydrogen hydrophobic molecule raw material gross mass 0.1-20%, then foams (according to a conventional method) in foaming machine, curing molding, preparation Become block (thin piece, or thin slice) or film body shape.
Embodiment 2
A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof, it is by pure natural carbon water macromolecule material Material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic molecule etc. are prepared from；Quality shared by each raw material Percentage ratio is: pure natural carbon water macromolecular material 65%, inserts 10%, reticular fiber 9%, foaming agent 5%, binding agent 5%, Wetting agent 5%, hydrocarbon hydrophobic molecule 1%.
Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, Medulla Junci, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, pine Any one in leaf, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is pulverized Powdering or any two above be ground into the mixing after powdery, and proportioning when any two is above is any proportioning, described Pure natural carbon water macromolecular material be that above-mentioned plant tissue is ground into powdery；Described inserts is natural coal body and natural ore Material, natural coal body is 1: 4 with the mass ratio of natural mineral materials；Described reticular fiber is the Fructus Luffae being slit into lamellar Network；Described foaming agent is hydrogenation halothane hydrocarbon (HFC) foaming agent；Described binding agent is Radix Pachyrhizi Erosi slurry；Described wetting agent is fourth Glycol；Described hydrocarbon hydrophobic molecule is Oleum Brassicae campestris；Described natural mineral materials is montmorillonite.
The preparation of above-mentioned a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof: choose above-mentioned former Material, mixing humidification, add pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, carbon The water of hydrogen hydrophobic molecule raw material gross mass 0.1-20%, then foams (according to a conventional method) in foaming machine, curing molding, preparation Become block (thin piece, or thin slice) or film body shape.
Embodiment 3
A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof, it is by pure natural carbon water macromolecule material Material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic molecule etc. are prepared from；Quality shared by each raw material Percentage ratio is: pure natural carbon water macromolecular material 59%, inserts 15%, reticular fiber 10%, foaming agent 5%, binding agent 5%, wetting agent 5%, hydrocarbon hydrophobic molecule 1%.
Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, Medulla Junci, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, pine Any one in leaf, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is pulverized Powdering or any two above be ground into the mixing after powdery, and proportioning when any two is above is any proportioning, described Pure natural carbon water macromolecular material be that above-mentioned plant tissue is ground into 20-100 mesh；Described inserts is natural coal body and sky So mineral material, natural coal body is 1: 6 with the mass ratio of natural mineral materials；Described reticular fiber is to be slit into lamellar Retinervus Luffae Fructus；Described foaming agent is N, N-dinitrosopentamethlyene tetramine (DPT)；Described binding agent is Rhizoma Solani tuber osi slurry；Described Wetting agent be the third Polyethylene Glycol；Described hydrocarbon hydrophobic molecule is Oleum Glycines；Described natural mineral materials is illite.
The preparation of above-mentioned a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof: choose above-mentioned former Material, mixing humidification, add pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, carbon The water of hydrogen hydrophobic molecule raw material gross mass 0.1-20%) after in foaming machine foam (according to a conventional method), curing molding, be prepared as Bulk or film body shape.
Embodiment 4
A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof, it is by pure natural carbon water macromolecule material Material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic molecule etc. are prepared from；Quality shared by each raw material Percentage ratio is: pure natural carbon water macromolecular material 59.3%, inserts 10%, reticular fiber 8%, foaming agent 7%, binding agent 7%, wetting agent 8%, hydrocarbon hydrophobic molecule 0.7%.
Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, Medulla Junci, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, pine Any one in leaf, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is pulverized Powdering or any two above be ground into the mixing after powdery, and proportioning when any two is above is any proportioning, described Pure natural carbon water macromolecular material be that leaf powder is broken into powdery；Described inserts is natural coal body and natural mineral matter material Material, natural coal body is 1: 5 with the mass ratio of natural mineral materials；Described reticular fiber is for knitting webbed monofilament；Described Foaming agent azodicarbonamide (ADC)；Described binding agent is epoxy resin；Described wetting agent is propylene glycol；Described Hydrocarbon hydrophobic molecule is hydrophobic polymeric fatty acid；Described natural mineral materials is chlorite.
The preparation of above-mentioned a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof: choose above-mentioned former Material, mixing humidification, add pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, carbon The water of hydrogen hydrophobic molecule raw material gross mass 0.1-20%, then foams (according to a conventional method) in foaming machine, curing molding, preparation Become block or film body shape.
Embodiment 5
A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof, it is by pure natural carbon water macromolecule material Material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic molecule etc. are prepared from；Quality shared by each raw material Percentage ratio is: pure natural carbon water macromolecular material 54%, inserts 10-15%, reticular fiber 8-10%, foaming agent 5-10%, Binding agent 5-10%, wetting agent 5-10%, hydrocarbon hydrophobic molecule 0.5-1%.
Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, Medulla Junci, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, pine Any one in leaf, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is pulverized Powdering or any two above be ground into the mixing after powdery, and proportioning when any two is above is any proportioning, described Pure natural carbon water macromolecular material be the mixing after above-mentioned plant tissue is ground into powdery, the quality of each component respectively accounts for 1/N；Institute The inserts stated is natural coal body and natural mineral materials, and natural coal body is 1: 6 with the mass ratio of natural mineral materials；Institute The reticular fiber stated is the Retinervus Luffae Fructus being slit into lamellar；Described foaming agent is 4,4-disulfonyl hydrazide diphenyl ether (OBSH)；Described Binding agent is formaldehyde；Described wetting agent is xylitol；Described hydrocarbon hydrophobic molecule is Oleum Gossypii semen；Described natural mineral matter Material is bentonite.
The preparation of above-mentioned a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof: choose above-mentioned former Material, mixing humidification, add pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, carbon The water of hydrogen hydrophobic molecule raw material gross mass 0.1-20%, then foams (according to a conventional method) in foaming machine, curing molding, preparation Become block or film body shape.
Embodiment 6
A kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof, it is by pure natural carbon water macromolecule material Material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic molecule etc. are prepared from；Quality shared by each raw material Percentage ratio is: pure natural carbon water macromolecular material 50%, inserts 10%, reticular fiber 9.5%, foaming agent 10%, binding agent 10%, wetting agent 10%, hydrocarbon hydrophobic molecule 0.5%.
Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, Medulla Junci, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, pine Any one in leaf, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is pulverized Powdering or any two above be ground into the mixing after powdery, and proportioning when any two is above is any proportioning, described Pure natural carbon water macromolecular material be that pure natural fiber is ground into 20-100 mesh；Described inserts is coal body and natural minerals Material, natural coal body is 1: 4 with the mass ratio of natural mineral materials；Described reticular fiber is mesh polypropylene-fibre； Described foaming agent is Pentamethylene.；Described binding agent is konjak starch slurry；Described wetting agent is glycerol；Described is hydrocarbon Hydrophobic molecule is fatty acid；Described natural mineral materials is red soil, or Kaolin.
The preparation of above-mentioned a kind of natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material and preparation method thereof: choose above-mentioned former Material, mixing humidification, add pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, carbon The water of hydrogen hydrophobic molecule raw material gross mass 0.1-20%, then foams (according to a conventional method) in foaming machine, curing molding, preparation Become block (thin piece, or thin slice) or film body shape.
The pure natural carbon water macromolecular material of the present invention, inserts, reticular fiber, foaming agent, binding agent, wetting agent, carbon The respective concrete raw material of hydrogen hydrophobic molecule, and their bound value, interval value can realize the present invention, just differs at this One enumerates embodiment.
The present invention uses pure natural carbon water macromolecular material, inserts, reticular fiber, is all the thing gone out of use, so this Invention low cost；Inserts uses natural coal body and natural mineral materials, can water conservation；Use wetting agent energy moisturizing；The present invention Can keep soil tilth, thus provide good condition for plant growing；Hydrocarbon hydrophobic polymeric is used to have plastic function；Adopt Can play a supporting role with reticular fiber, intensity can be strengthened；Above-mentioned complex material has plasticity, therefore can be processed into Type, it is possible to for building and environment-friendly materials secondary industry, above-mentioned complex material has anthelmintic antimicrobial natural composition, shows anthelmintic Antibacterial effect, processes for food antiseptic Perserving materials, it is possible to be manufactured into powder body, solid, bar-shaped, tabular, drum, bulk, Film body shapes etc., application is the most extensive.
Above the better embodiment of this patent is explained in detail, but this patent is not limited to above-mentioned embodiment party Formula, in the ken that one skilled in the relevant art is possessed, it is also possible on the premise of without departing from this patent objective Make a variety of changes.

Claims (8)

1. a natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material, it is characterised in that by pure natural carbon water macromolecular material, Inserts, reticular fiber, foaming agent, binding agent, wetting agent and hydrocarbon hydrophobic molecule are prepared from；Percent mass shared by each raw material Ratio is: pure natural carbon water macromolecular material 50-65%, inserts 10-15%, reticular fiber 8-10%, foaming agent 5-10%, viscous Knot agent 5-10%, wetting agent 5-10%, hydrocarbon hydrophobic molecule 0.5-1%；Described pure natural carbon water macromolecular material is Caulis et Folium Oryzae, lamp Core grass, Flos nymphaeae (Nymphaea teragona Georgi), Flos Nelumbinis, Herba Scirpi Tabernaemontani, Antirrhinum majus L., Folium Bambusae, Folium Pini, Folium Artemisiae Argyi, Folium Meliae, leaf of Lignum cinnamomi camphorae, Oleum Verniciae fordii leaf, Nicotiana tabacum L., phragmites communis, chrysanthemum leaf, Any one in sweetscented oleander leaf, Folium Persicae, Bulbus Allii leaf is ground into powdery or any two above is ground into the mixing after powdery, and appoints Anticipate more than two kinds time proportioning be any proportioning；Described inserts is natural coal body and natural mineral materials, natural coal body It is 1: 3-6 with the mass ratio of natural mineral materials.
Natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material the most according to claim 1, it is characterised in that described net Shape fiber is mesh polypropylene-fibre, knits webbed monofilament or be slit into the Retinervus Luffae Fructus of lamellar.
Natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material the most according to claim 1, it is characterised in that described sends out Infusion is Pentamethylene., hydrogenation halothane hydrocarbon, N, N-dinitrosopentamethlyene tetramine, N, the sub-terephthaldehyde of N-dimethyl-N, N-bis- Amide, azodicarbonamide, azodiisobutyronitrile, azoformic acid isopropyl ester, diethyl azodiformate, two diazoamino Benzene, Barium azodicarboxylate, 4,4-disulfonyl hydrazide diphenyl ether, to benzene sulfonyl hydrazide, 3,3-disulfonyl hydrazide diphenyl sulphone (DPS), 4,4-hexichol two sulphur Hydrazides, 1,3-benzene disulfohydrazide or Isosorbide-5-Nitrae-benzene disulfohydrazide.
Natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material the most according to claim 1, it is characterised in that described is viscous Knot agent is hydrophobicity carbon water fatty acid material or with carbonyl, the carbon water fatty acid material of hydroxyl, or with nitrogen unit The carbonyl compound of element and the many of complex material through dynamic bind.
Natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material the most according to claim 1, it is characterised in that described guarantor Humectant be glycerol, butanediol, Polyethylene Glycol, propylene glycol, hexanediol, xylitol, polypropylene glycol, Sorbitol one of which or The many of complex material through dynamic bind.
Natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material the most according to claim 1, it is characterised in that described hydrocarbon Hydrophobic molecule is Oleum Verniciae fordii, Oleum Camelliae or Oleum Gossypii semen.
Natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material the most according to claim 1, it is characterised in that described sky So mineral material is red soil, Kaolin, montmorillonite, illite, chlorite or bentonite.
8. a preparation method for the natural environmental-protective multifunctional macromolecule anthelmintic anti-biotic material as described in claim 1-7 is arbitrary, It is characterized in that, comprise the following steps:
(1) pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic is chosen Molecular raw material；
(2) raw material is mixed；
(3) pure natural carbon water macromolecular material, inserts, reticular fiber, foaming agent, binding agent, wetting agent, hydrocarbon hydrophobic is added After the water of molecular raw material gross mass 0.1%-20%, foam in foaming machine；
(4) raw material after foaming in step (3) is carried out curing molding, be prepared as bulk, flake or film body shape.
CN201610104323.4A 2016-02-25 2016-02-25 Natural environment-friendly multifunctional polymer insect-repellent antibacterial material and preparation method thereof Pending CN105713408A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101230144A (en) * 2007-12-28 2008-07-30 刘俊松 All-natural moisture-retention dust-proof insulation weeding multifunctional environmental material
CN105602270A (en) * 2016-01-30 2016-05-25 刘俊松 Multifunctional purely natural environment-friendly material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101230144A (en) * 2007-12-28 2008-07-30 刘俊松 All-natural moisture-retention dust-proof insulation weeding multifunctional environmental material
CN105602270A (en) * 2016-01-30 2016-05-25 刘俊松 Multifunctional purely natural environment-friendly material

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Application publication date: 20160629