CN105708019B - Waistband provided with regulating buckle and production method thereof - Google Patents
Waistband provided with regulating buckle and production method thereof Download PDFInfo
- Publication number
- CN105708019B CN105708019B CN201610030988.5A CN201610030988A CN105708019B CN 105708019 B CN105708019 B CN 105708019B CN 201610030988 A CN201610030988 A CN 201610030988A CN 105708019 B CN105708019 B CN 105708019B
- Authority
- CN
- China
- Prior art keywords
- woven tape
- elastic woven
- terylene
- belt
- ribbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41F—GARMENT FASTENINGS; SUSPENDERS
- A41F9/00—Belts, girdles, or waistbands for trousers or skirts
- A41F9/02—Expansible or adjustable belts or girdles ; Adjustable fasteners comprising a track and a slide member
- A41F9/025—Adjustable belts or girdles
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
Abstract
The invention relates to a production method of a waistband provided with a regulating buckle; the waistband is molded through integrally weaving, and the waistband comprises terylene ribbons, elastic ribbons and the regulating buckle, wherein the elastic ribbons include an inner elastic ribbon and outer elastic ribbons; the outer elastic ribbons include a first outer elastic ribbon and a second outer elastic ribbon; the inner elastic ribbon comprises elastic fixed regions and elastic regions; the elastic fixed regions are located at two ends of the inner elastic ribbon; the first outer elastic ribbon is arranged in the first elastic fixed region of the inner elastic ribbon; and the second outer elastic ribbon is arranged in the second elastic fixing region of the inner elastic ribbon. According to the production method disclosed by the invention, the waistband provided with the regulating buckle is manufactured by virtue of an integrally molding process, and meanwhile, elastic and non-elastic fibers are used, so that the reasonable distribution of application of elastic and non-elastic regions in the waistband is achieved, and the service convenience and comfort of the waistband are enhanced; and meanwhile, by virtue of the adjustable regulating buckle on the waistband, the waistband can meet using demands of people of different body sizes, so that the waistband is more concise and convenient.
Description
Technical field
The present invention relates to belt production technical field, is a kind of belt with adjusting button and its production method specifically.
Background technology
Chinese Patent Application No. 201380062588.7 is related to a kind of belt, and belt has belt strip and is arranged in the waist
Hasp on one end of tape;The belt strip supports retaining element, the retaining element to dismantle on an end
Be connected to the hasp.
Chinese Patent Application No. 201410008352.1 is related to belt, including:Belt body, one end has draw-in groove band;Pressure
Power detecting means, for detecting the concurrent pressurization pressure numerical information of pressure that belt body is subject to;And compensating roller portion, with pressure
Control unit and the slip installed in the belt body other end that the connected comparing unit of power detecting means is connected with comparing unit
Unit.Wherein, comparing unit compares the excessively loose threshold value of the pressure value information for receiving and pressure and pressure tension threshold value, and
Comparative result is sent to into control unit;Sliding unit matches with draw-in groove band, and control unit is slided according to comparative result, control
Unit brings line slip into or stops sliding along draw-in groove;The belt for being provided can automatically adjust what belt was formed around human body waist
The size of belt tight ring, it is achieved thereby that the Intelligent adjustment to belt elasticity, preferably alleviates belly and extrude belt
The change of power size makes the sense of discomfort that human body is produced.
Chinese Patent Application No. 201310634538.3 is related to a kind of belt, including the first belt, the second belt, auxiliary are strangled
Tight portion, first belt and second belt one end are provided with the other end and auxiliary of terylene thread gluing, the first belt and the second belt
Tie tight portion connection, it is described auxiliary the portion of tying tight be provided with adjustment the first belt and the second belt spacing rope of tying tight, the rope of tying tight
End be provided with and handle, the auxiliary portion of tying tight is provided with the first auxiliary material and the second auxiliary material, first auxiliary material and the second auxiliary material
Between be provided with and combine protruding point by rope connection of tying tight, first belt and the second belt, first auxiliary material and first
Combination protruding point on belt is fastened, and the combination protruding point in second auxiliary material and the second belt is fastened, first auxiliary material
Rotatable roller is provided with the second auxiliary material, the roller periphery is connected with rope of tying tight;Realizing front and rear can enter
Row is tied tight, realizes effect of tying tight, convenient use.
Chinese Patent Application No. 201110364764.5 is related to a kind of belt, and it can not only make skin of lumbar region ventilated,
Can also allow people's normal activity;It is network that belt has double-deck elongated belt body, outer layer for waist leather belt, internal layer, is easy to skin
It is ventilated.
Chinese Patent Application No. 201510394182.X is related to a kind of belt discount and belt.A circuit is provided with discount
Plate, circuit board includes SOC(system on a chip) module and the gps satellite locating module, the mobile communication module that are connected with SOC(system on a chip) module
And rechargeable battery;Gps satellite locating module is used to position discount, and location information is sent to into SOC(system on a chip) module;
Mobile communication module is used to receive location information from SOC(system on a chip) module, and transmits it out;And external information is received, and
External information is sent to into SOC(system on a chip) module;Attitude transducer is additionally provided with circuit board, attitude transducer is used to detect button
The kinestate of head, and movement state information is sent to into SOC(system on a chip) module;Motion shape of the SOC(system on a chip) module according to discount
State control mobile communication module sends location information;Old man wear containing this discount belt after, can real time remote to old man
Play long distance monitoring effect;Meanwhile, belt need not be removed, and old man will not be carried and be caused burden.
Chinese Patent Application No. 201310744199.4 is related to a kind of belt, including belt body, and the belt is from centre
It is divided into the left and right two parts being fixedly connected, the left-half belt is double-deck elongated cavity, outside the left-half belt
Layer is smooth, and the double-deck elongated cavity is provided with supporting fixed structure, the left-half waist with the right half part belt
The end of band is opening-like, and the left-half waistband end has the decorative waistband head of flexible connection, the right half part belt
Width ratio described in left-half belt narrow width, the right half part belt can stretch into described left half by the opening of end
Part belt, when the belt is used, belt surface there is no longer belt hole, and profile is more attractive in appearance, meet the demand of people.
Chinese Patent Application No. 200910210119.0 is related to a kind of heating belt, (is made with plastics with belt body
The elongate tube of water can be filled), outside is cased with one layer of good-looking figured cloth, has at an opening in one end of belt body, uses screw stopper
Clog, belt body two is provided with the belt buckle that can be buckled together.
Chinese Patent Application No. 201210467321.3 is related to a kind of belt, more particularly to a kind of belt with steering indicating light.
Point to belt, including belt strip, belt buckle, LED indicators, left direction button and right direction button, described belt strip one end
It is fixedly connected with belt buckle one end, wherein belt buckle includes control device, there is light-emitting device in belt strip, and belt strip has one
Layer luminescent powder, by control device the LED indicators on belt are controlled;One indicator device is provided on the person, not only can be by
The steering of oneself indicates other people, moreover it is possible to when steering indicating light is not played in noctilucence, at night in situation about going out or cycle
It is lower to provide safeguard for personal road safety.
Chinese Patent Application No. 201380047548.5 is related to belt bracelet, more particularly to the following belt bracelet for constituting,
In the state of belt is worn, belt can be easily untied, and belt can be also untied without over-tilting belt belt body, be entered
And belt belt body can be prevented to be damaged.Belt bracelet of the invention for reaching above-mentioned purpose includes:Belt belt body, to above-mentioned waist
Length direction with belt body is formed with multiple holes;Bracelet, the side of above-mentioned bracelet is fixed with the end of belt belt body, for wrapping
The above-mentioned bracelet of leading section insertion of the belt belt body of waist;Connecting pin, by hinge in combination with bracelet, is inserted in belt belt body
Hole in a hole, and the terminal part of above-mentioned connecting pin is formed with engaging portion, and above-mentioned engaging portion is used to be inserted in above-mentioned connecting pin
To enter prevent in the state of hole belt belt body and move to length direction.
Chinese Patent Application No. 201410448292.5 is related to a kind of belt, including belt body, girdle lock catch, the waist
One section of band body is connected with film photovoltaic cell, and the film photovoltaic cell is wrapped in belt body, the girdle lock catch
Front SD card player is installed, the inside of the belt body is provided with Intelligent controller for recharging/discharging and energy storage battery;
In addition to the function of tightening clothes, also power supply is provided for SD card player using the solar energy of cleaning, environmental protection, be can be applicable to
Various occasions appreciate music entertainment, are particularly well-suited to out on tours, extend the purposes of belt, with energy-saving and environmental protection, easily system
Make, it is easy to use the advantages of.
Chinese Patent Application No. 201110201366.1 is related to a kind of back belt, including belt body, the belt body
It is made up of upper and lower two-layer elastic fabric, forms a wide cut cavity, massage particle is provided with the cavity, in belt body
Magnetic therapy layer of cloth is connected with the fabric of side;The back belt of offer is rational in infrastructure, energy effective protection lumbar vertebra, with body shaping, insulation, magnetic therapy
Health care etc. is acted on, while can also provide good support for waist during sitting.
Chinese Patent Application No. 201110194617.8 is related to a kind of belt, and the waistcloth is one equipped with warming silk flosssilk wadding
Belt body, being provided with the two ends of belt body can be interconnected to the adhesion button of waistcloth, be provided with belt body one band slide fastener
Pocket, on belt body surrounding cross band is provided with;Setting fastening can be enclosed in winter and thermal effect is played on waist, set on belt body in addition
There is pocket, can be used for folding and unfolding coin and vade mecum, be particularly suitable for old people and use.
Chinese Patent Application No. 201010505342.0 is related to a kind of belt, including tapered end and belt, and the two of the belt
End is designed with lockhole, and the tapered end is designed with the dop being adapted with lockhole on upper and lower both sides;The belt of offer, due in skin
The two ends of band are designed with lockhole, using cooperatively by tapered end, can extend the service life of belt.
Chinese Patent Application No. 201310583711.1 is related to a kind of belt for carrying out storing, using following technical side
Case:A kind of belt mainly includes belt, strap lug, storage mouth;Belt connects strap lug, has storage mouth on belt, in belt
Loop section is covered on belt and storage mouth;The article of some comparison privacies can be placed in storage mouth for Emergency use, be made
Use simple and fast.
Chinese Patent Application No. 201310644914.7 is related to a kind of elastic waistbelt, the elastic hosel structure on belt,
The elastic force hosel structure includes corresponding sheath shell connection end and sheath tongue connection end, and connects both elastic force connection ribbons,
The size and shape that sheath shell connection end has dead slot structure, sheath tongue connection end can be inserted in the dead slot of sheath shell connector, in sheath
Shell connection end and sheath tongue connection end away from when, elastic force connection ribbon is that sheath shell connection end and sheath tongue connection end provide the bullet for furthering
Power, elastic waistbelt when by external force length can natural expansion, make human body sensory comfortably without constriction, can easily put on or
Take off, product of the present invention has scalable regular length, fixed moulding has easily dimmable, using the advantage of comfort and convenient again.
Chinese Patent Application No. 201510067608.0 is related to a kind of belt, is made up of belt belt body and belt buckle;Belt
Belt body is made up of belt and strip flexible plastic piece, and strip flexible plastic piece is arranged on belt medial surface, strip
With the fixed circular hole of occlusion on flexible plastic piece;Belt buckle is made up of U-shaped metalwork, occlusion metalwork and screw column, U-shaped metal
Part carries Fang Huan, and the inner left and right termination of U-shaped metalwork carries a horizontal circular hole;Occlusion metalwork is inner to carry bar shaped side
Hole, occlusion metalwork is connected and fixed by bar shaped square hole with one end of belt;Occlusion metalwork outer end inner side carries stings
Tooth is closed, occlusion crest end is spherical shape;Occlusion metalwork middle part is bent outwardly projection;Occlusion metalwork is inner to carry a column
Nut is carried in projection, columnar projections;Screw column through U-shaped metalwork the inner end horizontal circular hole after be engaged metalwork
Nut in inner columnar projections is installed together, and U-shaped metalwork all swings with metalwork is engaged by axle of screw column.
Chinese Patent Application No. 201310704911.8 is related to a kind of waistband, including:Body, row's button and memorial alloy,
The mass percent of the material of the body is 65% chinlon and 35% spandex, and the fabric of the body is reticulate structure, described
Body includes liner, is fixed on the bottom of the inner side of the body, and row's button is vertically fixed in the both sides of the body, described
Row's button includes some ZIKOU, and the quantity of the ZIKOU is more than 12, and the number of the memorial alloy is more than or equal to 7;It is logical
Cross aforesaid way, waistband has that structure is novel, be conducive to large-scale production, good permeability, snug fit, it is docile it is natural, make
The advantages of with convenient, vdiverse in function, novel fashion, long service life, there is extensive market prospect in the popularization of waistband.
The content of the invention
It is an object of the invention to overcome the deficiencies in the prior art, there is provided a kind of belt with adjusting button and its producer
Method.
The purpose of the present invention is achieved through the following technical solutions:
A kind of belt with adjusting button, using one tatting molding, comprising terylene ribbon, elastic woven tape and adjusting button, bullet
Property ribbon comprising interior elastic woven tape and outer elastic woven tape, outer elastic woven tape is knitted comprising the first outer elastic woven tape and the second outer elasticity
Band, interior elastic woven tape includes flexible fastening area and elastic region, and flexible fastening area is arranged on the end positions of interior elastic woven tape, as
First flexible fastening area of interior elastic woven tape and the second flexible fastening area of interior elastic woven tape, the first outer elastic woven tape is arranged on interior
First flexible fastening area of elastic woven tape, the second outer elastic woven tape is arranged on the second flexible fastening area of interior elastic woven tape;
Adjusting button includes pin thread and box;
Terylene ribbon is arranged on outer elastic woven tape, and terylene ribbon is two, as the first terylene ribbon and the second terylene
Ribbon, the position of the first terylene ribbon and the second terylene ribbon on outer elastic woven tape can be entered as needed during warp knit
Row is adjusted;
One end of first terylene ribbon is connected with the first outer elastic woven tape by warp knit yarns interwoven, the first terylene ribbon
The other end arranges the pin thread of adjusting button;
One end of second terylene ribbon is connected with the second outer elastic woven tape by warp knit yarns interwoven, the second terylene ribbon
The other end arranges the box of adjusting button;
A kind of belt with adjusting button, its production stage is:
(1) using warp knit technique is integrally formed, with terylene and spandex as raw material, in warp knit technical process, using bilayer
Ribbon warp knit, with terylene as parallel, terylene is wrap yarn with spandex, obtains interior elasticity by the intertexture connection of warp and parallel and knits
First flexible fastening area of band and the first outer elastic woven tape;
(2) and then the first outer elastic woven tape stops braiding, on the first outer elastic woven tape with polyster fibre as warp and latitude
Line, by the intertexture of warp and parallel the first terylene ribbon is obtained;
(3) elastic region of interior elastic woven tape carries out warp knit intertexture, obtains interior elastic woven tape elastic region;
(4) with polyster fibre as warp and parallel and then on outer elastic woven tape, obtained by the intertexture of warp and parallel
Second terylene ribbon;
(5) with parallel as polyster fibre, warp is the wrap yarn material of polyster fibre and spandex, carries out double braid and obtains interior
Second flexible fastening area of elastic woven tape and the second outer elastic woven tape;
(6) pin thread of adjusting button is fixed on first terylene ribbon one end, and the box of adjusting button is fixed on the second terylene and knits
On one end of band, the belt with adjusting button is finally given.
By the connection for combining to form belt, realizing terylene ribbon of pin thread and box;Pin thread and box are in terylene ribbon
On position be adjusted;
The width of outer elastic woven tape is 4/5ths of interior elastic woven tape width, and the elastic section length of interior elastic woven tape can be with
It is adjusted as needed.
Terylene ribbon raw material is polyster fibre, and elastic woven tape raw material is polyster fibre and spandex.
Described polyster fibre is the antibiotic polyester fiber containing cuprous material, and its production method is concretely comprised the following steps:
The preparation of (a) doped sulfuric acid barium
With aluminum hydroxide sol and barium hydroxide solution as raw material, the mass fraction of aluminum hydroxide sol is 0.1~
0.5%, the mass fraction of barium hydroxide is 2.5~3.75%, and the volume ratio of aluminum hydroxide sol and barium hydroxide is 1:1, hydrogen
The mean diameter of alumina sol is 20~45 nanometers;Under agitation, barium hydroxide solution is slowly added to aluminium hydroxide
Mixed in colloidal sol, after barium hydroxide is added completely, 45~60min of pretreatment is carried out at 75~80 DEG C, made nanoscale
Aluminum hydroxide sol surface and the substantial amounts of barium ionss of internal gutter internal adsorption, then add dilute sulfuric acid molten in sol system
Liquid, carries out Deca dilution heat of sulfuric acid, make barium sulfate drive aluminum hydroxide sol formed barium sulfate precipitate, the barium sulfate of filtration,
60 DEG C, vacuum drying 48h is carried out, obtain doped sulfuric acid barium;Control dilute sulfuric acid molar fraction be 0.1~1.0mol/L, hydrogen-oxygen
It is 1 to change barium with the ratio of the mole of dilute sulfuric acid:0.9~1.25;
Aluminum hydroxide sol its dehydration after form rigid aluminium oxide, it has the mechanicalnesses such as excellent wear-resisting, high rigidity
Can, while the addition by controlling sulphuric acid, makes barium sulfate form whisker and aluminum hydroxide precipitation, reach aluminium hydroxide doping sulfur
The purpose of sour barium, improves the hardness and anti-wear performance of barium sulfate, simultaneously because aluminium hydroxide is neutralized reaction with sulphuric acid, it is micro
Sulphuric acid aluminium hydroxide can be corroded, make barium sulfate crystal formation form certain defect, so as to improve barium sulfate crystal whisker sheet
The roughness of body, carries out low-surface-energy and is modified beneficial to the later stage, so as to reduce the skin-friction coefficient of material, improves the wear-resisting of material
Performance and the adhesion with terylene matrix.
The preparation of (b) antibacterial barium sulfate
The doped sulfuric acid barium that above-mentioned steps (a) are obtained, using the method for ultrasonic disperse, doped sulfuric acid barium body is dispersed in
Product is than being 1:In the aqueous solution of 1 isopropanol, and it is 8~10 to control the pH in aqueous solution, and using ammonia pH regulator is carried out, and is controlled
Doped sulfuric acid barium mass fraction in aqueous is 10~20%, then under the conditions of 45~60 DEG C, adds hydrophobically modified
Agent, the response time is 60~90min, then adds cuprous nitrate, reacts 45~55min, make cuprous ion by with amino
Chelation be attached to fixed on barium sulfate surface, you can improve barium sulfate antibiotic property, while can also ensure that barium sulfate is low
The stability of surface energy, and by the chelation of amino in cuprous ion and terylene matrix, improve the dispersion of antibacterial barium sulfate
Property, active force of the antibacterial barium sulfate component in terylene matrix is improved, improve wear-resisting and antibacterial effect;React after terminating to product
Centrifugation, obtains lower floor's centrifugation product, and then lower floor's centrifugation product is carried out to obtain antibacterial sulphuric acid after 45 DEG C of vacuum drying 48h
Barium;
Hydrophobic modifier is 1 with the mass values of doped sulfuric acid barium:5~10;
Hydrophobic modifier is MTES and aminopropyl triethoxysilane hybrid silicone compound, methyl
The mol ratio of triethoxysilane and aminopropyl triethoxysilane is 1:0.06~0.1;
Described cuprous nitrate is 1 with the mol ratio of hydrophobic modifier:0.1~0.15;
Organosilicon material has excellent low-surface-energy characteristic, is usually used in the dispersant of inorganic particle, and surface treatment
Agent, you can for improving the dispersibility of powder body, simultaneously because improving the combination of powder body and matrix after inorganic powder surface organises
Power, reduces the reunion of inorganic particle;It has excellent surface reaction activity to silicone compounds, especially methyl triethoxy
Under acid or alkalescence condition, be hydrolyzed ethyoxyl condensation, can live in silane and aminopropyl triethoxysilane molecule
Property hydroxyl polar reaction, and modified barium sulphate surface had both included the active hydroxyl groups of nano barium sulfate, while also including hydrogen-oxygen
Change the substantial amounts of activity hydroxy of aluminum, make inorganic surfaces methylate by condensation reaction, at the same make containing amino can reactive functionality draw
In entering molecule, the introducing of amino can and carboxyl reaction, simultaneously because the amide after amino and amino and carboxylic acid reaction with wash
The similarity of synthetic fibre matrix, can increase dispersibility of the modified barium sulphate in terylene matrix, further improve the anti-wear performance of material.Together
When cuprous ion and its broad-spectrum antimicrobial effect of derivant be widely used in the exploitation of anti-biotic material, while cuprous ion conduct
Antibacterial agent, with the efficient effect of low toxicity, by the hydroxyl in the hydrophobic modifier in cuprous ion and antibacterial barium sulfate
And amino carries out chelation, make antibacterial ion be fixed on barium sulfate surface, reduce the migration of antibacterial components, while by Asia
The interaction of the amide group in copper ion and terylene matrix, improves peptizaiton of the antibacterial components in terylene matrix, and
The interaction force of antibacterial components and terylene matrix, so as to improve the antibacterial and anti-wear performance of terylene.
Simultaneously the roughness on barium sulfate surface is improved, and after low-surface-energy process, by the in-situ polymerization of barium sulfate,
The barium sulfate for making wearability is distributed in terylene matrix surface, is formed and has concaveconvex structure, makes the sliding friction of terylene matrix surface
Area is reduced, and sliding friction is changed into a contact from face contact, while the hardness and rigidity of the barium sulfate by improving contact point,
The wearability of barium sulfate itself is lifted, and barium sulfate reduces point contact barium sulfate surface after the process of surface low-surface-energy
Surface energy, reduces its coefficient of friction, so as to improve the anti-wear performance of terylene matrix.
The preparation of (c) antibacterial functions modified component
Antibacterial barium sulfate prepared by step (b) is 1 according to mass values with adipic acid:0.5~5 is fed intake, 160
Under~180 DEG C of nitrogen inert gas conditions, the response time is 0.5~0.8h, and then hot wash is adopted after reaction, then 60
After DEG C vacuum drying 48h, the modified component of antibacterial functions is prepared;
The preparation of (d) antibacterial dacron section
Using the method for in-situ polymerization, with p-phthalic acid and ethylene glycol as raw material, antibacterial functions are proportionally added to change
Property component and bisphenol-A, in nitrogen atmosphere, under the conditions of 0.2~0.4MPa, by mole material to p-phthalic acid and ethylene glycol
Than for 1:0.95~1.35;P-phthalic acid carries out esterification with dihydroxylic alcohols under conditions of being pressurizeed by the first step, forms pre-
Aggressiveness, reaction temperature reacts 3~5h at 240~260 DEG C.Second step first carries out prepolymerization reaction, reaction temperature under high-temperature pressure
Degree keeps 1~1.5h at 260~280 DEG C;Then aftercondensated is carried out under high temperature, high vacuum condition, vacuum is less than 60Pa,
At 270~290 DEG C, the response time is 1.0~3.0h to reaction temperature, after reaction terminates, carries out melt pelletization, prepares antibacterial
Terylene chips;
The modified component of described antibacterial functions is the 2~5% of the mass fraction of p-phthalic acid;
Described bisphenol-A is 0.01~0.05 with the mol ratio of p-phthalic acid:1;
The preparation of (e) antibiotic polyester fiber
Antibacterial dacron section is raw material, using the method for melt spinning, obtains antibiotic polyester fiber.
Antibacterial dacron section is raw material, using the method for melt spinning, antibacterial dacron 120 DEG C of dryings under vacuum
48h, then carries out feeding, logical to make screw rod melting extrusion, and fused spinning assembling parts are entered after metering, through side-blown air cooling, collection
Beam, oils, hot-rolling drawing-off, and winding obtains antibiotic polyester fiber.
Described melt spinning condition is:Spinning temperature is 265~270 DEG C, and spinning winding speed is 3000~4000m/
Min, side-blown air temperature is 23~28 DEG C, and cross air blasting wind speed is 0.1~0.5m/s, and drafting multiple is 2.2~3.2 times of employings that oil
Hot-rolling oils spinning mode, and upper oil temperature is 145~160 DEG C, oils the time of staying for 0.1~0.3ms.
Compared with prior art, the positive effect of the present invention is:
The present invention prepares the belt with adjusting button by integrally formed technique, you can reduce the ammonia of high price in raw material
The usage amount of synthetic fibre, reduces product cost, while also reducing later stage stitch-bonding processes again, lifts preparation efficiency.Simultaneously by adopting
Use with elastic and stiff fiber, the use of elasticity and inelastic region in reasonable layout belt lifts making for belt
With convenience and comfortableness, while belt realizes the use requirement of belt different building shape crowd with adjustable adjusting button, make
It has more succinct simplicity.
Description of the drawings
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the structural representation of the interior elastic woven tape of the present invention;
Labelling in accompanying drawing for:1 is the first terylene ribbon, and 2 is interior elastic woven tape, and 3 is the second terylene ribbon, and 4 is first
Outer elastic reducing-fixing band, 5 is the second outer elastic reducing-fixing band, and 201 is the first flexible fastening area of interior elastic woven tape, and 202 is interior elasticity
The elastic region of ribbon, 203 is the second flexible fastening area of interior elastic woven tape.
Specific embodiment
The specific embodiment of a kind of belt with adjusting button of the present invention presented below and its production method.
Embodiment 1
Refer to accompanying drawing 1,2, a kind of belt with adjusting button, using one tatting molding, comprising terylene ribbon, elasticity is knitted
Band and adjusting button, elastic woven tape includes interior elastic woven tape 2 and outer elastic woven tape, and outer elastic woven tape includes the first outer elastic woven tape 4
With the second outer elastic woven tape 5, interior elastic woven tape includes flexible fastening area and elastic region 202, and flexible fastening area is arranged on interior elasticity
The end positions of ribbon, the first flexible fastening area 201 of as interior elastic woven tape and the second flexible fastening area of interior elastic woven tape
203, the first outer elastic woven tape is arranged on the first flexible fastening area of interior elastic woven tape, and the second outer elastic woven tape is arranged on interior elasticity
Second flexible fastening area of ribbon;
A kind of belt with adjusting button, using one tatting molding, comprising terylene ribbon, elastic woven tape and adjusting button, bullet
Property ribbon comprising interior elastic woven tape 2 and outer elastic woven tape, outer elastic woven tape is knitted comprising the first outer elastic woven tape 4 and the second outer elasticity
Band 5, interior elastic woven tape includes flexible fastening area and elastic region, and flexible fastening area is arranged on the end positions of interior elastic woven tape, i.e.,
The second flexible fastening area 203 in the first flexible fastening area 201 and interior elastic woven tape for interior elastic woven tape, the first outer elastic woven tape
The first flexible fastening area of interior elastic woven tape is arranged on, the second outer elastic woven tape is arranged on the second flexible fastening of interior elastic woven tape
Area;
Adjusting button includes pin thread and box;
Terylene ribbon is arranged on outer elastic woven tape, and terylene ribbon is two, and as the first terylene ribbon 1 and second is washed
Synthetic fibre ribbon 3, the position of the first terylene ribbon and the second terylene ribbon on outer elastic woven tape can as needed in warp knit process
In be adjusted;
One end of first terylene ribbon is connected with the first outer elastic woven tape by warp knit yarns interwoven, the first terylene ribbon
The other end arranges the pin thread of adjusting button;
One end of second terylene ribbon is connected with the second outer elastic woven tape by warp knit yarns interwoven, the second terylene ribbon
The other end arranges the box of adjusting button;
A kind of belt with adjusting button, its production stage is:
(1) using warp knit technique is integrally formed, with terylene and spandex as raw material, in warp knit technical process, using bilayer
Ribbon warp knit, with terylene as parallel, terylene is wrap yarn with spandex, obtains interior elasticity by the intertexture connection of warp and parallel and knits
First flexible fastening area of band and the first outer elastic woven tape;
(2) and then the first outer elastic woven tape stops braiding, on the first outer elastic woven tape with polyster fibre as warp and latitude
Line, by the intertexture of warp and parallel the first terylene ribbon is obtained;
(3) elastic region of interior elastic woven tape carries out warp knit intertexture, obtains interior elastic woven tape elastic region;
(4) with polyster fibre as warp and parallel and then on outer elastic woven tape, obtained by the intertexture of warp and parallel
Second terylene ribbon;
(5) with parallel as polyster fibre, warp is the wrap yarn material of polyster fibre and spandex, carries out double braid and obtains interior
Second flexible fastening area of elastic woven tape and the second outer elastic woven tape;
(6) pin thread of adjusting button is fixed on first terylene ribbon one end, and the box of adjusting button is fixed on the second terylene and knits
On one end of band, the belt with adjusting button is finally given.
By the connection for combining to form belt, realizing terylene ribbon of pin thread and box;Pin thread and box are in terylene ribbon
On position be adjusted;
The width of outer elastic woven tape is 4/5ths of interior elastic woven tape width, and the elastic section length of interior elastic woven tape can be with
It is adjusted as needed.
Terylene ribbon raw material is polyster fibre, and elastic woven tape raw material is polyster fibre and spandex.
Described polyster fibre is the antibiotic polyester fiber containing cuprous material, and its production method is concretely comprised the following steps:
The preparation of (a) doped sulfuric acid barium
With aluminum hydroxide sol and barium hydroxide solution as raw material, the mass fraction of aluminum hydroxide sol is 0.1%, hydrogen-oxygen
The mass fraction for changing barium is 2.5%, and the volume ratio of aluminum hydroxide sol and barium hydroxide is 1:1, aluminum hydroxide sol it is average
Particle diameter is 20~45 nanometers;Under agitation, barium hydroxide solution is slowly added to be mixed in aluminum hydroxide sol, is treated
After barium hydroxide is added completely, 45~60min of pretreatment is carried out at 75~80 DEG C, make nano-grade aluminum hydroxide sol surface with
And the substantial amounts of barium ionss of internal gutter internal adsorption, dilution heat of sulfuric acid is then added in sol system, carry out Deca dilute sulfuric acid molten
Liquid, makes barium sulfate drive aluminum hydroxide sol to form barium sulfate precipitate, and the barium sulfate of filtration, at 60 DEG C, is vacuum dried
48h, obtains doped sulfuric acid barium;The molar fraction for controlling dilute sulfuric acid is 0.22mol/L, the mole of barium hydroxide and dilute sulfuric acid it
Than for 1:0.9;
Aluminum hydroxide sol its dehydration after form rigid aluminium oxide, it has the mechanicalnesses such as excellent wear-resisting, high rigidity
Can, while the addition by controlling sulphuric acid, makes barium sulfate form whisker and aluminum hydroxide precipitation, reach aluminium hydroxide doping sulfur
The purpose of sour barium, improves the hardness and anti-wear performance of barium sulfate, simultaneously because aluminium hydroxide is neutralized reaction with sulphuric acid, it is micro
Sulphuric acid aluminium hydroxide can be corroded, make barium sulfate crystal formation form certain defect, so as to improve barium sulfate crystal whisker sheet
The roughness of body, carries out low-surface-energy and is modified beneficial to the later stage, so as to reduce the skin-friction coefficient of material, improves the wear-resisting of material
Performance and the adhesion with terylene matrix.
The preparation of (b) antibacterial barium sulfate
The doped sulfuric acid barium that above-mentioned steps (a) are obtained, using the method for ultrasonic disperse, doped sulfuric acid barium body is dispersed in
Product is than being 1:In the aqueous solution of 1 isopropanol, and it is 8~10 to control the pH in aqueous solution, and using ammonia pH regulator is carried out, and is controlled
Doped sulfuric acid barium mass fraction in aqueous is 10~20%, then under the conditions of 45~60 DEG C, adds hydrophobically modified
Agent, the response time is 60~90min, then adds cuprous nitrate, reacts 45~55min, make cuprous ion by with amino
Chelation be attached to fixed on barium sulfate surface, you can improve barium sulfate antibiotic property, while can also ensure that barium sulfate is low
The stability of surface energy, and by the chelation of amino in cuprous ion and terylene matrix, improve the dispersion of antibacterial barium sulfate
Property, active force of the antibacterial barium sulfate component in terylene matrix is improved, improve wear-resisting and antibacterial effect;React after terminating to product
Centrifugation, obtains lower floor's centrifugation product, and then lower floor's centrifugation product is carried out to obtain antibacterial sulphuric acid after 45 DEG C of vacuum drying 48h
Barium;
Hydrophobic modifier is 1 with the mass values of doped sulfuric acid barium:6;
Hydrophobic modifier is MTES and aminopropyl triethoxysilane hybrid silicone compound, methyl
The mol ratio of triethoxysilane and aminopropyl triethoxysilane is 1:0.06;
Described cuprous nitrate is 1 with the mol ratio of hydrophobic modifier:0.1;
Organosilicon material has excellent low-surface-energy characteristic, is usually used in the dispersant of inorganic particle, and surface treatment
Agent, you can for improving the dispersibility of powder body, simultaneously because improving the combination of powder body and matrix after inorganic powder surface organises
Power, reduces the reunion of inorganic particle;It has excellent surface reaction activity to silicone compounds, especially methyl triethoxy
Under acid or alkalescence condition, be hydrolyzed ethyoxyl condensation, can live in silane and aminopropyl triethoxysilane molecule
Property hydroxyl polar reaction, and modified barium sulphate surface had both included the active hydroxyl groups of nano barium sulfate, while also including hydrogen-oxygen
Change the substantial amounts of activity hydroxy of aluminum, make inorganic surfaces methylate by condensation reaction, at the same make containing amino can reactive functionality draw
In entering molecule, the introducing of amino can and carboxyl reaction, simultaneously because the amide after amino and amino and carboxylic acid reaction with wash
The similarity of synthetic fibre matrix, can increase dispersibility of the modified barium sulphate in terylene matrix, further improve the anti-wear performance of material.Together
When cuprous ion and its broad-spectrum antimicrobial effect of derivant be widely used in the exploitation of anti-biotic material, while cuprous ion conduct
Antibacterial agent, with the efficient effect of low toxicity, by the hydroxyl in the hydrophobic modifier in cuprous ion and antibacterial barium sulfate
And amino carries out chelation, make antibacterial ion be fixed on barium sulfate surface, reduce the migration of antibacterial components, while by Asia
The interaction of the amide group in copper ion and terylene matrix, improves peptizaiton of the antibacterial components in terylene matrix, and
The interaction force of antibacterial components and terylene matrix, so as to improve the antibacterial and anti-wear performance of terylene.
Simultaneously the roughness on barium sulfate surface is improved, and after low-surface-energy process, by the in-situ polymerization of barium sulfate,
The barium sulfate for making wearability is distributed in terylene matrix surface, is formed and has concaveconvex structure, makes the sliding friction of terylene matrix surface
Area is reduced, and sliding friction is changed into a contact from face contact, while the hardness and rigidity of the barium sulfate by improving contact point,
The wearability of barium sulfate itself is lifted, and barium sulfate reduces point contact barium sulfate surface after the process of surface low-surface-energy
Surface energy, reduces its coefficient of friction, so as to improve the anti-wear performance of terylene matrix.
The preparation of (c) antibacterial functions modified component
Antibacterial barium sulfate prepared by step (b) is 1 according to mass values with adipic acid:0.85 is fed intake, 160~
Under 180 DEG C of nitrogen inert gas conditions, the response time is 0.5~0.8h, and then hot wash is adopted after reaction, then at 60 DEG C
After vacuum drying 48h, the modified component of antibacterial functions is prepared;
The preparation of (d) antibacterial dacron section
Using the method for in-situ polymerization, with p-phthalic acid and ethylene glycol as raw material, antibacterial functions are proportionally added to change
Property component and bisphenol-A, in nitrogen atmosphere, under the conditions of 0.2~0.4MPa, by mole material to p-phthalic acid and ethylene glycol
Than for 1:0.95;P-phthalic acid carries out esterification with dihydroxylic alcohols under conditions of being pressurizeed by the first step, forms performed polymer, instead
Temperature is answered at 240~260 DEG C, 3~5h is reacted.Second step first carries out prepolymerization reaction under high-temperature pressure, and reaction temperature is 260
~280 DEG C, keep 1~1.5h;Then aftercondensated is carried out under high temperature, high vacuum condition, vacuum is less than 60Pa, reaction temperature
At 270~290 DEG C, the response time is 1.0~3.0h, after reaction terminates, carries out melt pelletization, prepares antibacterial dacron and cuts
Piece;
The modified component of described antibacterial functions is the 2.5% of the mass fraction of p-phthalic acid;
Described bisphenol-A is 0.02 with the mol ratio of p-phthalic acid:1;
The preparation of (e) antibiotic polyester fiber
Antibacterial dacron section is raw material, using the method for melt spinning, obtains antibiotic polyester fiber.
Antibacterial dacron section is raw material, using the method for melt spinning, antibacterial dacron 120 DEG C of dryings under vacuum
48h, then carries out feeding, logical to make screw rod melting extrusion, and fused spinning assembling parts are entered after metering, through side-blown air cooling, collection
Beam, oils, hot-rolling drawing-off, and winding obtains antibiotic polyester fiber.
Described melt spinning condition is:Spinning temperature is 265~270 DEG C, and spinning winding speed is 3000~4000m/
Min, side-blown air temperature is 23~28 DEG C, and cross air blasting wind speed is 0.1~0.5m/s, and drafting multiple is 2.2~3.2 times of employings that oil
Hot-rolling oils spinning mode, and upper oil temperature is 145~160 DEG C, oils the time of staying for 0.1~0.3ms.
Embodiment 2
Refer to accompanying drawing 1,2, a kind of belt with adjusting button, using one tatting molding, comprising terylene ribbon, elasticity is knitted
Band and adjusting button, elastic woven tape includes interior elastic woven tape 2 and outer elastic woven tape, and outer elastic woven tape includes the first outer elastic woven tape 4
With the second outer elastic woven tape 5, interior elastic woven tape includes flexible fastening area and elastic region 202, and flexible fastening area is arranged on interior elasticity
The end positions of ribbon, the first flexible fastening area 201 of as interior elastic woven tape and the second flexible fastening area of interior elastic woven tape
203, the first outer elastic woven tape is arranged on the first flexible fastening area of interior elastic woven tape, and the second outer elastic woven tape is arranged on interior elasticity
Second flexible fastening area of ribbon;
A kind of belt with adjusting button, using one tatting molding, comprising terylene ribbon, elastic woven tape and adjusting button, bullet
Property ribbon comprising interior elastic woven tape 2 and outer elastic woven tape, outer elastic woven tape is knitted comprising the first outer elastic woven tape 4 and the second outer elasticity
Band 5, interior elastic woven tape includes flexible fastening area and elastic region, and flexible fastening area is arranged on the end positions of interior elastic woven tape, i.e.,
The second flexible fastening area 203 in the first flexible fastening area 201 and interior elastic woven tape for interior elastic woven tape, the first outer elastic woven tape
The first flexible fastening area of interior elastic woven tape is arranged on, the second outer elastic woven tape is arranged on the second flexible fastening of interior elastic woven tape
Area;
Adjusting button includes pin thread and box;
Terylene ribbon is arranged on outer elastic woven tape, and terylene ribbon is two, and as the first terylene ribbon 1 and second is washed
Synthetic fibre ribbon 3, the position of the first terylene ribbon and the second terylene ribbon on outer elastic woven tape can as needed in warp knit process
In be adjusted;
One end of first terylene ribbon is connected with the first outer elastic woven tape by warp knit yarns interwoven, the first terylene ribbon
The other end arranges the pin thread of adjusting button;
One end of second terylene ribbon is connected with the second outer elastic woven tape by warp knit yarns interwoven, the second terylene ribbon
The other end arranges the box of adjusting button;
A kind of belt with adjusting button, its production stage is:
(1) using warp knit technique is integrally formed, with terylene and spandex as raw material, in warp knit technical process, using bilayer
Ribbon warp knit, with terylene as parallel, terylene is wrap yarn with spandex, obtains interior elasticity by the intertexture connection of warp and parallel and knits
First flexible fastening area of band and the first outer elastic woven tape;
(2) and then the first outer elastic woven tape stops braiding, on the first outer elastic woven tape with polyster fibre as warp and latitude
Line, by the intertexture of warp and parallel the first terylene ribbon is obtained;
(3) elastic region of interior elastic woven tape carries out warp knit intertexture, obtains interior elastic woven tape elastic region;
(4) with polyster fibre as warp and parallel and then on outer elastic woven tape, obtained by the intertexture of warp and parallel
Second terylene ribbon;
(5) with parallel as polyster fibre, warp is the wrap yarn material of polyster fibre and spandex, carries out double braid and obtains interior
Second flexible fastening area of elastic woven tape and the second outer elastic woven tape;
(6) pin thread of adjusting button is fixed on first terylene ribbon one end, and the box of adjusting button is fixed on the second terylene and knits
On one end of band, the belt with adjusting button is finally given.
By the connection for combining to form belt, realizing terylene ribbon of pin thread and box;Pin thread and box are in terylene ribbon
On position be adjusted;
The width of outer elastic woven tape is 4/5ths of interior elastic woven tape width, and the elastic section length of interior elastic woven tape can be with
It is adjusted as needed.
Terylene ribbon raw material is polyster fibre, and elastic woven tape raw material is polyster fibre and spandex.
Described polyster fibre is the antibiotic polyester fiber containing cuprous material, and its production method is concretely comprised the following steps:
The preparation of (a) doped sulfuric acid barium
With aluminum hydroxide sol and barium hydroxide solution as raw material, the mass fraction of aluminum hydroxide sol is 0.5%, hydrogen-oxygen
The mass fraction for changing barium is 3.75%, and the volume ratio of aluminum hydroxide sol and barium hydroxide is 1:1, aluminum hydroxide sol it is average
Particle diameter is 20~45 nanometers;Under agitation, barium hydroxide solution is slowly added to be mixed in aluminum hydroxide sol, is treated
After barium hydroxide is added completely, 45~60min of pretreatment is carried out at 75~80 DEG C, make nano-grade aluminum hydroxide sol surface with
And the substantial amounts of barium ionss of internal gutter internal adsorption, dilution heat of sulfuric acid is then added in sol system, carry out Deca dilute sulfuric acid molten
Liquid, makes barium sulfate drive aluminum hydroxide sol to form barium sulfate precipitate, and the barium sulfate of filtration, at 60 DEG C, is vacuum dried
48h, obtains doped sulfuric acid barium;The molar fraction for controlling dilute sulfuric acid is 1.0mol/L, the mole of barium hydroxide and dilute sulfuric acid it
Than for 1:1.25;
Aluminum hydroxide sol its dehydration after form rigid aluminium oxide, it has the mechanicalnesses such as excellent wear-resisting, high rigidity
Can, while the addition by controlling sulphuric acid, makes barium sulfate form whisker and aluminum hydroxide precipitation, reach aluminium hydroxide doping sulfur
The purpose of sour barium, improves the hardness and anti-wear performance of barium sulfate, simultaneously because aluminium hydroxide is neutralized reaction with sulphuric acid, it is micro
Sulphuric acid aluminium hydroxide can be corroded, make barium sulfate crystal formation form certain defect, so as to improve barium sulfate crystal whisker sheet
The roughness of body, carries out low-surface-energy and is modified beneficial to the later stage, so as to reduce the skin-friction coefficient of material, improves the wear-resisting of material
Performance and the adhesion with terylene matrix.
The preparation of (b) antibacterial barium sulfate
The doped sulfuric acid barium that above-mentioned steps (a) are obtained, using the method for ultrasonic disperse, doped sulfuric acid barium body is dispersed in
Product is than being 1:In the aqueous solution of 1 isopropanol, and it is 8~10 to control the pH in aqueous solution, and using ammonia pH regulator is carried out, and is controlled
Doped sulfuric acid barium mass fraction in aqueous is 20%, then under the conditions of 45~60 DEG C, adds hydrophobic modifier, instead
It is 60~90min between seasonable, then adds cuprous nitrate, react 45~55min, makes cuprous ion by the chelating with amino
Effect is attached to fixed on barium sulfate surface, you can the antibiotic property of barium sulfate is improved, while barium sulfate low-surface-energy can also be ensured
Stability, and by the chelation of amino in cuprous ion and terylene matrix, improve the dispersibility of antibacterial barium sulfate, improve
Active force of the antibacterial barium sulfate component in terylene matrix, improves wear-resisting and antibacterial effect;Reaction divides product centrifugation after terminating
From, lower floor's centrifugation product is obtained, then lower floor's centrifugation product is carried out to obtain antibacterial barium sulfate after 45 DEG C of vacuum drying 48h;
Hydrophobic modifier is 1 with the mass values of doped sulfuric acid barium:9;
Hydrophobic modifier is MTES and aminopropyl triethoxysilane hybrid silicone compound, methyl
The mol ratio of triethoxysilane and aminopropyl triethoxysilane is 1:0.1;
Described cuprous nitrate is 1 with the mol ratio of hydrophobic modifier:0.15;
Organosilicon material has excellent low-surface-energy characteristic, is usually used in the dispersant of inorganic particle, and surface treatment
Agent, you can for improving the dispersibility of powder body, simultaneously because improving the combination of powder body and matrix after inorganic powder surface organises
Power, reduces the reunion of inorganic particle;It has excellent surface reaction activity to silicone compounds, especially methyl triethoxy
Under acid or alkalescence condition, be hydrolyzed ethyoxyl condensation, can live in silane and aminopropyl triethoxysilane molecule
Property hydroxyl polar reaction, and modified barium sulphate surface had both included the active hydroxyl groups of nano barium sulfate, while also including hydrogen-oxygen
Change the substantial amounts of activity hydroxy of aluminum, make inorganic surfaces methylate by condensation reaction, at the same make containing amino can reactive functionality draw
In entering molecule, the introducing of amino can and carboxyl reaction, simultaneously because the amide after amino and amino and carboxylic acid reaction with wash
The similarity of synthetic fibre matrix, can increase dispersibility of the modified barium sulphate in terylene matrix, further improve the anti-wear performance of material.Together
When cuprous ion and its broad-spectrum antimicrobial effect of derivant be widely used in the exploitation of anti-biotic material, while cuprous ion conduct
Antibacterial agent, with the efficient effect of low toxicity, by the hydroxyl in the hydrophobic modifier in cuprous ion and antibacterial barium sulfate
And amino carries out chelation, make antibacterial ion be fixed on barium sulfate surface, reduce the migration of antibacterial components, while by Asia
The interaction of the amide group in copper ion and terylene matrix, improves peptizaiton of the antibacterial components in terylene matrix, and
The interaction force of antibacterial components and terylene matrix, so as to improve the antibacterial and anti-wear performance of terylene.
Simultaneously the roughness on barium sulfate surface is improved, and after low-surface-energy process, by the in-situ polymerization of barium sulfate,
The barium sulfate for making wearability is distributed in terylene matrix surface, is formed and has concaveconvex structure, makes the sliding friction of terylene matrix surface
Area is reduced, and sliding friction is changed into a contact from face contact, while the hardness and rigidity of the barium sulfate by improving contact point,
The wearability of barium sulfate itself is lifted, and barium sulfate reduces point contact barium sulfate surface after the process of surface low-surface-energy
Surface energy, reduces its coefficient of friction, so as to improve the anti-wear performance of terylene matrix.
The preparation of (c) antibacterial functions modified component
Antibacterial barium sulfate prepared by step (b) is 1 according to mass values with adipic acid:5 are fed intake, 160~180
DEG C nitrogen inert gas conditions under, the response time is 0.5~0.8h, after reaction and then adopts hot wash, then true at 60 DEG C
Sky is dried after 48h, prepares the modified component of antibacterial functions;
The preparation of (d) antibacterial dacron section
Using the method for in-situ polymerization, with p-phthalic acid and ethylene glycol as raw material, antibacterial functions are proportionally added to change
Property component and bisphenol-A, in nitrogen atmosphere, under the conditions of 0.2~0.4MPa, by mole material to p-phthalic acid and ethylene glycol
Than for 1:1.35;P-phthalic acid carries out esterification with dihydroxylic alcohols under conditions of being pressurizeed by the first step, forms performed polymer, instead
Temperature is answered at 240~260 DEG C, 3~5h is reacted.Second step first carries out prepolymerization reaction under high-temperature pressure, and reaction temperature is 260
~280 DEG C, keep 1~1.5h;Then aftercondensated is carried out under high temperature, high vacuum condition, vacuum is less than 60Pa, reaction temperature
At 270~290 DEG C, the response time is 1.0~3.0h, after reaction terminates, carries out melt pelletization, prepares antibacterial dacron and cuts
Piece;
The modified component of described antibacterial functions is the 5% of the mass fraction of p-phthalic acid;
Described bisphenol-A is 0.05 with the mol ratio of p-phthalic acid:1;
The preparation of (e) antibiotic polyester fiber
Antibacterial dacron section is raw material, using the method for melt spinning, obtains antibiotic polyester fiber.
Antibacterial dacron section is raw material, using the method for melt spinning, antibacterial dacron 120 DEG C of dryings under vacuum
48h, then carries out feeding, logical to make screw rod melting extrusion, and fused spinning assembling parts are entered after metering, through side-blown air cooling, collection
Beam, oils, hot-rolling drawing-off, and winding obtains antibiotic polyester fiber.
Described melt spinning condition is:Spinning temperature is 265~270 DEG C, and spinning winding speed is 3000~4000m/
Min, side-blown air temperature is 23~28 DEG C, and cross air blasting wind speed is 0.1~0.5m/s, and drafting multiple is 2.2~3.2 times of employings that oil
Hot-rolling oils spinning mode, and upper oil temperature is 145~160 DEG C, oils the time of staying for 0.1~0.3ms.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, without departing from the inventive concept of the premise, can also make some improvements and modifications, and these improvements and modifications also should be regarded as
In protection scope of the present invention.
Claims (4)
1. a kind of belt with adjusting button, it is characterised in that using one tatting molding, comprising terylene ribbon, elastic woven tape and
Adjusting button, elastic woven tape includes interior elastic woven tape and outer elastic woven tape, and outer elastic woven tape includes the first outer elastic woven tape and second
Outer elastic woven tape, interior elastic woven tape includes flexible fastening area and elastic region, and flexible fastening area is arranged on the two ends of interior elastic woven tape
Position, the first flexible fastening area of as interior elastic woven tape and the second flexible fastening area of interior elastic woven tape, the first outer elasticity is knitted
Band is arranged on the first flexible fastening area of interior elastic woven tape, and the second elasticity that the second outer elastic woven tape is arranged on interior elastic woven tape is solid
Determine area;
Adjusting button includes pin thread and box;
Terylene ribbon is arranged on outer elastic woven tape, and terylene ribbon is two, as the first terylene ribbon and the second terylene ribbon;
One end of first terylene ribbon is connected with the first outer elastic woven tape by warp knit yarns interwoven, the first terylene ribbon it is another
End arranges the pin thread of adjusting button;
One end of second terylene ribbon is connected with the second outer elastic woven tape by warp knit yarns interwoven, the second terylene ribbon it is another
End arranges the box of adjusting button.
2. a kind of production method of the belt with adjusting button as claimed in claim 1, it is characterised in that it is concretely comprised the following steps,
(1)Using warp knit technique is integrally formed, with terylene and spandex as raw material, in warp knit technical process, using double-deck ribbon
Warp knit, with terylene as parallel, terylene is wrap yarn with spandex, and by the intertexture connection of warp and parallel interior elastic woven tape is obtained
First flexible fastening area and the first outer elastic woven tape;
(2)Then the first outer elastic woven tape stops braiding, logical with polyster fibre as warp and parallel on the first outer elastic woven tape
The intertexture for crossing warp and parallel obtains the first terylene ribbon;
(3)The elastic region of interior elastic woven tape carries out warp knit intertexture, obtains interior elastic woven tape elastic region;
(4)Then on outer elastic woven tape with polyster fibre as warp and parallel, by the intertexture of warp and parallel second is obtained
Terylene ribbon;
(5)With parallel as polyster fibre, warp is the wrap yarn material of polyster fibre and spandex, carries out double braid and obtains interior elasticity
Second flexible fastening area of ribbon and the second outer elastic woven tape;
(6)The pin thread of adjusting button is fixed on first terylene ribbon one end, and the box of adjusting button is fixed on the second terylene ribbon
On one end, the belt with adjusting button is finally given.
3. a kind of belt with adjusting button as claimed in claim 1, it is characterised in that terylene ribbon raw material is polyster fibre,
Elastic woven tape raw material is polyster fibre and spandex.
4. a kind of belt with adjusting button as claimed in claim 3, it is characterised in that described polyster fibre is containing cuprous material
The antibiotic polyester fiber of material, its production method is concretely comprised the following steps:
(a)The preparation of doped sulfuric acid barium
With aluminum hydroxide sol and barium hydroxide solution as raw material, the mass fraction of aluminum hydroxide sol is 0.1~0.5%, hydrogen-oxygen
The mass fraction for changing barium is 2.5~3.75%, and the volume ratio of aluminum hydroxide sol and barium hydroxide is 1:1, aluminum hydroxide sol
Mean diameter is 20~45 nanometers;Under agitation, barium hydroxide solution is slowly added to be mixed in aluminum hydroxide sol
Close, after barium hydroxide is added completely, 45~60min of pretreatment is carried out at 75~80 DEG C, then add in sol system
Dilution heat of sulfuric acid, carries out Deca dilution heat of sulfuric acid, makes barium sulfate drive aluminum hydroxide sol to form barium sulfate precipitate, obtains sulphuric acid
Precipitated barium carries out vacuum drying 48h at 60 DEG C, obtains doped sulfuric acid barium;The molar fraction for controlling dilute sulfuric acid is 0.1~1.0mol/
L, barium hydroxide is 1 with the ratio of the mole of dilute sulfuric acid:0.9~1:1.25;
(b)The preparation of antibacterial barium sulfate
By above-mentioned steps(a)The doped sulfuric acid barium for obtaining, using the method for ultrasonic disperse, doped sulfuric acid barium volume ratio is dispersed in
For 1:In the aqueous solution of 1 isopropanol, and it is 8~10 to control the pH in aqueous solution, and using ammonia pH regulator, control doping are carried out
Barium sulfate mass fraction in aqueous is 10~20%, then under the conditions of 45~60 DEG C, adds hydrophobic modifier, instead
It is 60~90min between seasonable, then adds cuprous nitrate, react 45~55min, reacts after terminating to product centrifugation,
Lower floor's centrifugation product is obtained, then lower floor's centrifugation product is carried out to obtain antibacterial barium sulfate after 45 DEG C of vacuum drying 48h;
Hydrophobic modifier is 1 with the mass values of doped sulfuric acid barium:5~1:10;
Hydrophobic modifier is MTES and aminopropyl triethoxysilane hybrid silicone compound, the second of methyl three
The mol ratio of TMOS and aminopropyl triethoxysilane is 1:0.06~1:0.1;
Described cuprous nitrate is 1 with the mol ratio of hydrophobic modifier:0.1~1:0.15;
(c)The preparation of antibacterial functions modified component
By step(b)The antibacterial barium sulfate of preparation is 1 according to mass values with adipic acid:0.5~1:5 are fed intake, 160~
Under 180 DEG C of nitrogen inert gas conditions, the response time is 0.5~0.8h, and then hot wash is adopted after reaction, then at 60 DEG C
After vacuum drying 48h, the modified component of antibacterial functions is prepared;
(d)The preparation of antibacterial dacron section
Using the method for in-situ polymerization, with p-phthalic acid and ethylene glycol as raw material, the modified group of antibacterial functions is proportionally added
Part and bisphenol-A, in nitrogen atmosphere, under the conditions of 0.2~0.4MPa, be with a mole material ratio for ethylene glycol by p-phthalic acid
1:0.95~1:1.35;P-phthalic acid carries out esterification with dihydroxylic alcohols under conditions of being pressurizeed by the first step, forms pre-polymerization
Body, reaction temperature reacts 3~5h at 240~260 DEG C;Second step first carries out prepolymerization reaction, reaction temperature under high-temperature pressure
At 260~280 DEG C, 1~1.5h is kept;Then aftercondensated is carried out under high temperature and high vacuum condition, vacuum is less than 60Pa, high
Warm reaction temperature is 270~290 DEG C, and the response time is 1.0~3.0h, after reaction terminates, carries out melt pelletization, is prepared anti-
Bacterium terylene chips;
The modified component of described antibacterial functions is the 2~5% of the mass fraction of p-phthalic acid;
Described bisphenol-A is 0.01 with the mol ratio of p-phthalic acid:1~0.05:1;
(e)The preparation of antibiotic polyester fiber
Antibacterial dacron section is raw material, using the method for melt spinning, obtains antibiotic polyester fiber.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610030988.5A CN105708019B (en) | 2016-01-18 | 2016-01-18 | Waistband provided with regulating buckle and production method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610030988.5A CN105708019B (en) | 2016-01-18 | 2016-01-18 | Waistband provided with regulating buckle and production method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105708019A CN105708019A (en) | 2016-06-29 |
CN105708019B true CN105708019B (en) | 2017-05-03 |
Family
ID=56147322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610030988.5A Active CN105708019B (en) | 2016-01-18 | 2016-01-18 | Waistband provided with regulating buckle and production method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105708019B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107313147B (en) * | 2017-07-27 | 2024-04-09 | 东莞百宏实业有限公司 | Asymmetric single-side opening elastic band and weaving process thereof |
CN108588957B (en) * | 2018-07-12 | 2024-03-26 | 中山市鼎伟纺织染整有限公司 | Elastic webbing capable of freely adjusting tightness |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1816656A (en) * | 2003-07-03 | 2006-08-09 | 山德霓股份公司 | Method for manufacturing knitted articles for forming items of clothing, such as body suits, sleeveless tops, undershirts, bras, underpants or the like, without lateral seams, with a circular knitting |
CN201553849U (en) * | 2009-11-20 | 2010-08-18 | 东莞润达弹性织造有限公司 | Double-pull tatting mesh belt |
CN102767009A (en) * | 2012-06-28 | 2012-11-07 | 吴江亚太化纺有限公司 | Antistatic and antibacterial nylon 6/spandex coated yarn |
CN105054337A (en) * | 2015-08-11 | 2015-11-18 | 福建省百凯弹性织造有限公司 | Woven tape for integrating shoulder straps and pectoral girdle of women's bra |
CN105063886A (en) * | 2015-08-11 | 2015-11-18 | 福建省百凯弹性织造有限公司 | Elastic waist woven tape allowing rope to be threaded through |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4122377B2 (en) * | 2004-05-21 | 2008-07-23 | オペロンテックス株式会社 | Elastic resin, elastic resin molding, clothing and secondary materials for clothing |
-
2016
- 2016-01-18 CN CN201610030988.5A patent/CN105708019B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1816656A (en) * | 2003-07-03 | 2006-08-09 | 山德霓股份公司 | Method for manufacturing knitted articles for forming items of clothing, such as body suits, sleeveless tops, undershirts, bras, underpants or the like, without lateral seams, with a circular knitting |
CN201553849U (en) * | 2009-11-20 | 2010-08-18 | 东莞润达弹性织造有限公司 | Double-pull tatting mesh belt |
CN102767009A (en) * | 2012-06-28 | 2012-11-07 | 吴江亚太化纺有限公司 | Antistatic and antibacterial nylon 6/spandex coated yarn |
CN105054337A (en) * | 2015-08-11 | 2015-11-18 | 福建省百凯弹性织造有限公司 | Woven tape for integrating shoulder straps and pectoral girdle of women's bra |
CN105063886A (en) * | 2015-08-11 | 2015-11-18 | 福建省百凯弹性织造有限公司 | Elastic waist woven tape allowing rope to be threaded through |
Also Published As
Publication number | Publication date |
---|---|
CN105708019A (en) | 2016-06-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105708019B (en) | Waistband provided with regulating buckle and production method thereof | |
CN101768789B (en) | Production method of fine-denier hollow nylon 6FDY filament | |
CN202302948U (en) | Self-wound light-emitting band | |
CN105614971A (en) | Preparation method of steel ring belt of steel-ring-free bra | |
CN205285122U (en) | Waistband of detaining is adjusted in area | |
CN113913958A (en) | Multi-principle zero-energy-consumption continuous cooling fiber and fabric thereof | |
CN204898225U (en) | Comfortable body surface fabric of crease -resistance | |
CN105495713A (en) | Machining method of breathable steel ring strap | |
CN206119192U (en) | Polylactic acid nursing pants | |
CN205005974U (en) | Take clothing of intelligent device | |
CN203080210U (en) | Multipurpose hollow tubular webbing | |
CN105212294A (en) | A kind of clothes with far-infrared treatment function | |
CN202043638U (en) | Freely cut elastic fabric for underwear | |
CN208129497U (en) | A kind of novel electrostatic prevention dress ornament | |
CN102648777A (en) | Intelligent temperature regulating underwear | |
CN205907425U (en) | Novel antibiotic cold -proof composite yarn | |
CN218951634U (en) | Temperature-regulating cool knitted fabric | |
CN204432854U (en) | A kind of full encirclement Noctilucent safety electric vehicle windshield quilt | |
CN215775637U (en) | Zinc intelligent uvioresistant fiber seamless knitted vest | |
CN212754295U (en) | Bra convenient to put on and take off | |
CN113273738B (en) | Sweat-absorbing type baby underwear | |
CN216635719U (en) | Down-free nano aerogel down jacket fabric | |
CN219686776U (en) | Superfine sun-proof waterproof elastic fabric | |
CN206493676U (en) | A kind of antibiotic facing material | |
CN220557435U (en) | Functional shoulder strap warm in winter and cool in summer |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |