CN105696354A - Post-treatment method for silver-plated textile fabrics - Google Patents
Post-treatment method for silver-plated textile fabrics Download PDFInfo
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- CN105696354A CN105696354A CN201610079629.9A CN201610079629A CN105696354A CN 105696354 A CN105696354 A CN 105696354A CN 201610079629 A CN201610079629 A CN 201610079629A CN 105696354 A CN105696354 A CN 105696354A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/252—Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Abstract
The invention discloses a post-treatment method for silver-plated textile fabrics.Raw materials for implementing the post-treatment method include a post-treatment agent, organic solvents and the silver-plated textile fabrics.The concentration of the post-treatment agent is 0.01-1 mol/L, and a bath ratio of the post-treatment agent is 1-100:1.The post-treatment method has the advantages that the post-treatment agent can be n-octadecyl mercaptan after processes are adopted, and the silver-plated textile fabrics obtained by the aid of the post-treatment method are environmentally friendly, are good in corrosion resistance and have functional characteristics such as water repellency; the processes are simple and are low in cost, and uniform water-repellency protective films with high fastness can be formed on the surfaces of the textile fabrics.
Description
Technical field
The invention belongs to and there is multifunctional textile lining processing technology field, be specifically related to the post-processing approach of a kind of silver-plated textile fabric。
Background technology
Nano level metal thin film is deposited on textile material surface, it can be made to obtain various new function, expand range of application and the field of textile, in fiber solaode, shielding electromagnetic wave, conduction or antistatic, fiber sensor, uvioresistant outdoor goods and antibacterial weaving face fabric etc.。Method at textile material surface plated film mainly has chemical deposit method, vacuum vapour deposition, magnetron sputtering plating method etc.。Chemical deposit method is widely used, but the resistance to taking and water-wash resistance etc. of environmental pollution in the stability of plating solution, coating process and fabric also need to do bigger improvement。Equipment and the technique of vacuum vapour deposition are simple, thin film is pure, but thin film is poor with substrate adhesion。Magnetron sputtering embrane method is a kind of efficient thin film deposition processes, has sputtering raste height, an advantage such as base material temperature is low, device performance is stable, convenient operation and control, non-environmental-pollution, it is possible to be coated with single or multiple lift functional metal film at substrate surface。
Nano silver grain, except possessing that the skin effect of general nano material, small-size effect, catalytic efficiency be strong and except the character of many special chemicals being better than Conventional solid material such as macro quanta tunnel effect and physical property, also has the catalytic property of uniqueness, excellent biocompatibility and sensitivities etc. preferably。Argent is deposited on textile surface by magnetron sputtering method, can obtain and there is polyfunctional argent weaving face fabric, along with development in science and technology and people's living standard improve constantly, argent weaving face fabric is subject to people's favor, nano silver plating brings beyond example performance to textile, give a series of function of textile, such as functions such as uvioresistant, anti-electromagnetic shielding, antibacterial, automatically cleanings, have broad application prospects at protective garment, medical textile, gym suit, textile for automobile。
Silver coating fabric is of a great variety, has silver-plated dacron, nanometer silver to process bafta, development fabric, nanometer silver linen, nanometer silver high-performance fiber etc.。But due to silver coating fabric in atmosphere, or easily corrode in electrolyte solution, reduce it functional, or make its color change, affect its durability and attractive in appearance, therefore, silver coating fabric is carried out anticorrosion post processing, to guarantee that silver-plated textile product keep the function of its excellence, strengthen its ruggedness。
Stearylmercaptan (ODT) is a kind of environmentally friendly metal post-treatment agent。Being commonly used in metal surface and prepare self-assembled film (SAMs), self-assembled film (SAMs) is that molecule is spontaneous in solution or gaseous state is firmly adsorbed on the Organized Molecular Films formed on matrix by chemical bond。This self-assembled film is a kind of organic superthin film system, rete one layer fine and close can be formed in metal surface, by inhibitor molecular self assembly in metal surface, form self-assembled film fine and close, constitutionally stable and namely blocker ring border medium metal erosion can be played inhibitory action by the erosion of metal, there is good corrosion inhibition。At present, stearylmercaptan is used for the corrosion-resistant anti-oxidation protection of metal electrode, for instance; Du Wei et al. adopts stearylmercaptan at silver strip surface self-organization film; prevent silver strip variable color, it is shown that cathodic reduction and the anode reduction of silver slice corrosion are had good inhibiting effect by stearylmercaptan；Cui Wei really adopts stearylmercaptan at copper electrode surface self-organization film, the corrosion resistance of film forming copper electrode, electric double layer capacitance Changing Pattern, the inhibition of copper electrode is had good effect；Ten thousand clevers et al. adopt stearylmercaptan to be prepared for self-assembled film at bronze and silver surface, have functioned well as the effect of radioprotective, Anti-tarnishing。
At present, great majority research is concentrated mainly on the chemical preparating process of nano silver particles, and the research anticorrosive, antioxygenic property of silver fabric is also less。Not yet have been reported that silver-plated textile product are carried out anticorrosion post processing by employing stearylmercaptan。
Summary of the invention
It is an object of the invention to provide a kind of silver-plated textile product that silver-plated textile fabric is carried out anti-corrosion-resistant treatments and gained and there is good antioxidation and corrosion resistance。
Technical scheme:
The present invention is to provide a kind of silver-plated textile fabric post-processing approach, its raw material includes post-treatment agent, organic solvent and silver-plated textile fabric, and the concentration of described post-treatment agent is 0.01～1mol/L, and the bath raio of post-treatment agent is 1～100: 1。
First just post-treatment agent is dissolved in organic solvent and makes treatment fluid, and adds silver-plated weaving face fabric, is then at 20 DEG C～100 DEG C in temperature, and the process time is 3min～30h, and bath raio is 1～85: 1, finally by silver-plated textile fabric through washing, dry。
The fabric of described silver-plated textile fabric is at least one in natural fabric material or chemosynthesis weaving face fabric。
The fabric of described silver-plated textile fabric is at least one in bamboo pulp fiber, cotton, hair, fiber crops, silk, terylene, viscose glue, polyester or acrylon。
Described post-treatment agent is stearylmercaptan；Described organic solvent is at least one in ethanol, acetone, DMF (dimethylformamide) or DMAc (dimethyl acetylamide)；In described treatment fluid, the concentration of stearylmercaptan is 0.01～0.04mol/L, and described temperature is 20 DEG C～80 DEG C, and described heat time heating time is 30min～25h, and concussion when processing。
Described organic solvent is ethanol。
Described organic solvent is ethanol and the mixture of one or more in acetone, DMF or DMAc。
Beneficial effects of the present invention:
The present invention can adopt stearylmercaptan as post-treatment agent after adopting above-mentioned technique, the silver-plated textile fabric obtained has environmental protection, corrosion resistance is good, have the functional characteristics such as water repellency。The method technique is simple, and cost is low, it is possible to formed on weaving face fabric surface uniformly, water repellency protecting film that fastness is high。
Accompanying drawing explanation
Fig. 1 is the silver-plated dacron pictorial diagram of sputtering of the embodiment of the present invention 1 preparation。
Fig. 2 is the silver-plated dacron of sputtering of the embodiment of the present invention 1 preparation pictorial diagram after peroxidating is tested。
Fig. 3 is that the silver-plated dacron of sputtering of the embodiment of the present invention 1 preparation is through anticorrosive post processing 40min pictorial diagram。
Fig. 4 is the silver-plated dacron contact angle of sputtering of the embodiment of the present invention 1 preparation。
Fig. 5 is the silver-plated dacron scanning electron microscope (SEM) photograph of sputtering (amplifying 30000 times) of the embodiment of the present invention 2 preparation。
Fig. 6 is scanning electron microscope (SEM) photograph (amplifying 30000 times) after the silver-plated dacron oxidation test of sputtering prepared by the embodiment of the present invention 2。
Fig. 7 is the silver-plated dacron scanning electron microscope (SEM) photograph of sputtering (amplifying 1000 times) of the embodiment of the present invention 2 preparation。
Fig. 8 is the sputtering silver-plated dacron scanning electron microscope (SEM) photograph (amplifying 1000 times) through anticorrosive post processing 24h of the embodiment of the present invention 2 preparation。
Detailed description of the invention
The present invention is to provide a kind of silver-plated textile fabric post-processing approach, its raw material includes post-treatment agent, organic solvent and silver-plated textile fabric, and the concentration of described post-treatment agent is 0.01～1mol/L, and the bath raio of post-treatment agent is 1～100: 1。
First just post-treatment agent is dissolved in organic solvent and makes treatment fluid, and adds silver-plated weaving face fabric, is then at 20 DEG C～100 DEG C in temperature, and the process time is 3min～30h, and bath raio is 1～85: 1, finally by silver-plated textile fabric through washing, dry。
The fabric of described silver-plated textile fabric is at least one in natural fabric material or chemosynthesis weaving face fabric。
The fabric of described silver-plated textile fabric is at least one in bamboo pulp fiber, cotton, hair, fiber crops, silk, terylene, viscose glue, polyester or acrylon。
Described post-treatment agent is stearylmercaptan；Described organic solvent is at least one in ethanol, acetone, DMF or DMAc；In described treatment fluid, the concentration of stearylmercaptan is 0.01～0.04mol/L, and described temperature is 20 DEG C～80 DEG C, and described heat time heating time is 30min～25h, and concussion when processing。
Described organic solvent is ethanol。
Described organic solvent is ethanol and the mixture of one or more in acetone, DMF or DMAc。
By the examples below the present invention is specifically described; it is important to point out that embodiment is served only for further illustrating the present invention; it is not intended that limiting the scope of the invention, these those skilled in the art can make some nonessential improvement and adjustment according to the present invention。
Embodiment 1
The dacron that will be of a size of 10cm × 10cm cleans 30min with acetone and EtOH Sonicate ripple respectively, takes out the drying of 50 DEG C of fabric；Take 1 piece through the cleaned dacron of ethanol acetone, with highly purified silver target (99.99%), deposit nanometer silverskin silver target diameter 50mm, thick 5mm on dacron surface by magnetically controlled sputter method。After sample is placed, vacuum sputtering room evacuated pressure controls 5 × 10-4Pa。In the deposition process of magnetron sputtering silverskin, substrate holder rotates with the speed of 100 rpms, to guarantee that nanometer silver uniform deposition is on dacron。Passing into high-purity argon gas as bombarding gas, pressure is maintained at 2Pa, sputtering current voltage respectively 0.15A and 115V, sedimentation time 30min。Subsequently, being put into by silver-plated dacron in the alcoholic solution of stearylmercaptan, the concentration of stearylmercaptan is 0.01mol/L, and bath raio is 50: 1, processes time 40min, and temperature is 50 DEG C, and water-bath is vibrated, and finally takes out, and washes through deionization, dries。
The macro property of the magnetron sputtering silver-plated terylene weaving face fabric through post processing is as follows:
1, the silver-plated dacron non-oxidizability of magnetron sputtering:
Fig. 1 is the silver-plated dacron pictorial diagram of magnetron sputtering, it will be seen from figure 1 that through the silver-plated dacron of magnetron sputtering, there is metallic luster on surface, homogeneous, it was shown that can obtain uniform, smooth silver coating fabric by magnetron sputtering is silver-plated。Fig. 2 is for sputtering silver-plated dacron pictorial diagram after peroxidating is tested, and comparison diagram 1 and Fig. 2 are it can be seen that through the silver-plated dacron of magnetron sputtering of peroxidating test, have metachromatism and the uneven oxidation in surface, oxidation mottling occur。But the silver-plated dacron of magnetron sputtering is after stearylmercaptan antioxidant anticorrosive post processing, as shown in Figure 3, the magnetron sputtering silver-plated dacron surface that can be seen that is uniform, metallic luster remains in that, show that stearylmercaptan post processing can allow silver coating fabric keep the superperformance of silver plated metals, keeping its metallic luster, the isolation coat of metal contacts with external environment, anticorrosive and oxidation。
2, the silver-plated dacron super-hydrophobicity of magnetron sputtering:
Fig. 4 is for sputtering silver-plated dacron contact angle, as can be seen from Figure 4, the silver-plated dacron of magnetron sputtering through stearylmercaptan post processing has good water repellency, contact angle is up to 150 °, there is super-hydrophobic performance, illustrate that stearylmercaptan self-assembled film is successfully attached to silver-plated dacron surface, make silver coating fabric have super-hydrophobicity, and play the effect that silvering contacts with external environment that well intercepts。
Embodiment 2
The dacron that will be of a size of 10cm × 10cm cleans 30min with acetone and EtOH Sonicate ripple respectively, takes out the drying of 50 DEG C of fabric；Take 1 piece through the cleaned dacron of ethanol acetone, with highly purified silver target (99.99%), deposit nanometer silverskin silver target diameter 50mm, thick 5mm on dacron surface by magnetically controlled sputter method。After sample is placed, vacuum sputtering room evacuated pressure controls 5 × 10-4Pa。In the deposition process of magnetron sputtering silverskin, substrate holder rotates with the speed of 100 rpms, to guarantee that nanometer silver uniform deposition is on dacron。Passing into high-purity argon gas as bombarding gas, pressure is maintained at 2Pa, sputtering current voltage respectively 0.15A and 115V, sedimentation time 10min。Subsequently, being put into by silver-plated dacron in the alcoholic solution of stearylmercaptan, stearylmercaptan concentration is 0.01mol/L, processes time 25h, and temperature is 50 DEG C, and bath raio is 30: 1, and water-bath is vibrated, and finally takes out, and washes through deionization, dries。
From fig. 5, it can be seen that magnetron sputtering is silver-plated, forming densification, uniform coating at fabric face, coating is uniform small particles shape, close-packed arrays, the surface of covering fabric。Comparison diagram 5, Fig. 6 is the coating of the silver-plated fabric face of magnetron sputtering after peroxidating is tested, it can be seen that coating is oxidized, and the lines on surface is etched, and granule becomes big, and surface uniformity reduces。
From figure 7 it can be seen that fiber surface uniformly, metal-coated silvering densely, fiber surface affects due to coating, becomes comparatively coarse。Sputter the silver-plated dacron scanning electron microscope (SEM) photograph (amplifying 1000 times) through the anticorrosive post processing 24h of stearylmercaptan, as can be seen from Figure 8, not only there is the coating of silver in fiber surface, the stearylmercaptan self-assembled film also having fine and close lamellar covers fiber surface, in the lepidiod arrangement of fiber surface。
Embodiment 3
The dacron that will be of a size of 10cm × 10cm cleans 30min with acetone and EtOH Sonicate ripple respectively, takes out the drying of 50 DEG C of fabric；Take 1 piece through the cleaned dacron of ethanol acetone, with highly purified silver target (99.99%), deposit nanometer silverskin silver target diameter 50mm, thick 5mm on dacron surface by magnetically controlled sputter method。After sample is placed, vacuum sputtering room evacuated pressure controls 5 × 10-4Pa。In the deposition process of magnetron sputtering silverskin, substrate holder rotates with the speed of 100 rpms, to guarantee that nanometer silver uniform deposition is on dacron。Passing into high-purity argon gas as bombarding gas, pressure is maintained at 2Pa, sputtering current voltage respectively 0.15A and 115V, sedimentation time 10min。Subsequently, being put into by silver-plated dacron in ethanol and the acetone mixed solution of stearylmercaptan, stearylmercaptan concentration is 1mol/L, processes time 3min, and temperature is 100 DEG C, and bath raio is 1: 1, and water-bath is vibrated, and finally takes out, and washes through deionization, dries。
Embodiment 4
The dacron that will be of a size of 10cm × 10cm cleans 30min with acetone and EtOH Sonicate ripple respectively, takes out the drying of 50 DEG C of fabric；Take 1 piece through the cleaned dacron of ethanol acetone, with highly purified silver target (99.99%), deposit nanometer silverskin silver target diameter 50mm, thick 5mm on dacron surface by magnetically controlled sputter method。After sample is placed, vacuum sputtering room evacuated pressure controls 5 × 10-4Pa。In the deposition process of magnetron sputtering silverskin, substrate holder rotates with the speed of 100 rpms, to guarantee that nanometer silver uniform deposition is on dacron。Passing into high-purity argon gas as bombarding gas, pressure is maintained at 2Pa, sputtering current voltage respectively 0.15A and 115V, sedimentation time 10min。Subsequently, being put into by silver-plated dacron in ethanol and the DMF solution of stearylmercaptan, stearylmercaptan concentration is 0.04mol/L, processes time 20h, and temperature is 40 DEG C, and bath raio is 100: 1, and water-bath is vibrated, and finally takes out, and washes through deionization, dries。
Embodiment 5
The dacron that will be of a size of 10cm × 10cm cleans 30min with acetone and EtOH Sonicate ripple respectively, takes out the drying of 50 DEG C of fabric；Take 1 piece through the cleaned dacron of ethanol acetone, with highly purified silver target (99.99%), deposit nanometer silverskin silver target diameter 50mm, thick 5mm on dacron surface by magnetically controlled sputter method。After sample is placed, vacuum sputtering room evacuated pressure controls 5 × 10-4Pa。In the deposition process of magnetron sputtering silverskin, substrate holder rotates with the speed of 100 rpms, to guarantee that nanometer silver uniform deposition is on dacron。Passing into high-purity argon gas as bombarding gas, pressure is maintained at 2Pa, sputtering current voltage respectively 0.15A and 115V, sedimentation time 10min。Subsequently, being put into by silver-plated dacron in ethanol and the DMAc solution of stearylmercaptan, stearylmercaptan concentration is 0.03mol/L, processes time 5h, and temperature is 80 DEG C, and bath raio is 20: 1, and water-bath is vibrated, and finally takes out, and washes through deionization, dries。
Embodiment 6
The dacron that will be of a size of 10cm × 10cm cleans 30min with acetone and EtOH Sonicate ripple respectively, takes out the drying of 50 DEG C of fabric；Take 1 piece through the cleaned dacron of ethanol acetone, with highly purified silver target (99.99%), deposit nanometer silverskin silver target diameter 50mm, thick 5mm on dacron surface by magnetically controlled sputter method。After sample is placed, vacuum sputtering room evacuated pressure controls 5 × 10-4Pa。In the deposition process of magnetron sputtering silverskin, substrate holder rotates with the speed of 100 rpms, to guarantee that nanometer silver uniform deposition is on dacron。Passing into high-purity argon gas as bombarding gas, pressure is maintained at 2Pa, sputtering current voltage respectively 0.15A and 115V, sedimentation time 10min。Subsequently, being put into by silver-plated dacron in the acetone soln of stearylmercaptan, stearylmercaptan concentration is 0.01mol/L, processes time 30h, and temperature is 60 DEG C, and bath raio is 85: 1, and water-bath is vibrated, and finally takes out, and washes through deionization, dries。
Above-mentioned raw materials is commercially available commodity。
The silver-plated dacron color analysis of magnetron sputtering:
As can be seen from Table 1, through stearylmercaptan post processing its L*, a*, b*, C* and h value of silver coating fabric remain to after oxidation experiment keep with original silver coating fabric suitable, and without the silver coating fabric of stearylmercaptan post processing, after oxidation experiment, its L*, a*, b*, C* and h value changes greatly, namely after oxidation experiment, occur that the phenomenon of variable color is comparatively serious without the silver coating fabric of stearylmercaptan post processing is oxidized, and the original color of silver coating fabric can be kept preferably through the silver coating fabric of stearylmercaptan post processing, and not oxidized variable color。It is shown that have the effect of good antioxidant anticorrosive through the silver coating fabric of stearylmercaptan post processing。
Silver-plated dacron L*, a*, b*, C* and h value of table 1 magnetron sputtering
| Silver sputtering fabric | L* | a* | b* | C* | h |
| Silver coating fabric | 72.186 | -0.199 | 8.992 | 8.994 | 91.270 |
| Fabric after oxidation | 46.525 | -3.993 | 4.354 | 5.908 | 132.527 |
| After the oxidation of post processing fabric | 67.842 | -0.022 | 8.889 | 8.889 | 90.145 |
Claims (7)
1. the post-processing approach of a silver-plated textile fabric, it is characterised in that: its raw material includes post-treatment agent, organic solvent and silver-plated textile fabric, and the concentration of described post-treatment agent is 0.01～1mol/L, and the bath raio of post-treatment agent is 1～100: 1。
2. the post-processing approach of the silver-plated textile fabric described in claim 1, it is characterized in that: first just post-treatment agent is dissolved in organic solvent and makes treatment fluid, and add silver-plated weaving face fabric, then it is at 20 DEG C～100 DEG C in temperature, the process time is 3min～30h; bath raio is 1～85: 1, finally by silver-plated textile fabric through washing, drying。
3. the post-processing approach of silver-plated textile fabric according to claim 1 and 2, it is characterised in that: the fabric of described silver-plated textile fabric is at least one in natural fabric material or chemosynthesis weaving face fabric。
4. the post-processing approach of silver-plated textile fabric according to claim 3, it is characterised in that: the fabric of described silver-plated textile fabric is at least one in bamboo pulp fiber, cotton, hair, fiber crops, silk, terylene, viscose glue, polyester or acrylon。
5. the post-processing approach of silver-plated textile fabric according to claim 2, it is characterised in that: described post-treatment agent is stearylmercaptan；Described organic solvent is at least one in ethanol, acetone, DMF or DMAc；In described treatment fluid, the concentration of stearylmercaptan is 0.01～0.04mol/L, and described temperature is 20 DEG C～80 DEG C, and described heat time heating time is 30min～25h, and concussion when processing。
6. the post-processing approach of silver-plated textile fabric according to claim 5, it is characterised in that: described organic solvent is ethanol。
7. the post-processing approach of silver-plated textile fabric according to claim 5, it is characterised in that: described organic solvent is ethanol and the mixture of one or more in acetone, DMF or DMAc。
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| CN109837743A (en) * | 2019-02-14 | 2019-06-04 | 珠海鑫康源新材料科技有限公司 | Anti-oxidant silver fiber fabric and preparation method thereof |
| CN109837743B (en) * | 2019-02-14 | 2023-12-01 | 珠海鑫康源新材料科技有限公司 | Antioxidant silver fiber fabric and preparation method thereof |
| CN111286976A (en) * | 2020-03-04 | 2020-06-16 | 盐城工学院 | Preparation method and product of super-hydrophobic oil-water separation polyester fabric based on chemical nickel plating |
| CN111286976B (en) * | 2020-03-04 | 2022-03-08 | 盐城工学院 | Preparation method and product of super-hydrophobic oil-water separation polyester fabric based on chemical nickel plating |
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