CN105696341A - Antistatic spinning paste and preparation method thereof - Google Patents
Antistatic spinning paste and preparation method thereof Download PDFInfo
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- CN105696341A CN105696341A CN201610205865.0A CN201610205865A CN105696341A CN 105696341 A CN105696341 A CN 105696341A CN 201610205865 A CN201610205865 A CN 201610205865A CN 105696341 A CN105696341 A CN 105696341A
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- China
- Prior art keywords
- weight portion
- sizing agent
- spinning sizing
- antistatic spinning
- antistatic
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- 238000009987 spinning Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 claims abstract description 26
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 14
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 14
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims abstract description 14
- 229930195725 Mannitol Natural products 0.000 claims abstract description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 14
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 14
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 14
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 14
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 14
- 239000000594 mannitol Substances 0.000 claims abstract description 14
- 235000010355 mannitol Nutrition 0.000 claims abstract description 14
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 14
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 14
- WCRMDMYSQWZTSF-UHFFFAOYSA-N 2-hydroxy-1-methoxy-3-methylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(O)=C2OC WCRMDMYSQWZTSF-UHFFFAOYSA-N 0.000 claims abstract description 13
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960001748 allylthiourea Drugs 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 238000004513 sizing Methods 0.000 claims description 33
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 20
- 150000001412 amines Chemical group 0.000 claims description 13
- 150000002596 lactones Chemical class 0.000 claims description 13
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 12
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims description 11
- 229930003633 citronellal Natural products 0.000 claims description 11
- 235000000983 citronellal Nutrition 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 abstract 1
- HZVVJJIYJKGMFL-UHFFFAOYSA-N almasilate Chemical compound O.[Mg+2].[Al+3].[Al+3].O[Si](O)=O.O[Si](O)=O HZVVJJIYJKGMFL-UHFFFAOYSA-N 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 abstract 1
- 235000008777 kaempferol Nutrition 0.000 abstract 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 abstract 1
- 229940078490 n,n-dimethylglycine Drugs 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 238000011056 performance test Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004744 fabric Substances 0.000 description 6
- 239000003599 detergent Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/31—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated nitriles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses antistatic spinning paste and a preparation method thereof. The antistatic spinning paste is prepared from the following components in parts by weight: 60-70 parts of acrylonitrile fibers, 30-40 parts of polyethylene glycol, 12-16 parts of mannitol, 8-12 parts of vinylidene chloride, 5-8 parts of carboxymethyl cellulose, 3-5 parts of epoxypolysilicone acrylate, 2-3 parts of N-dodecyl-N,N-dimethylglycine, 0.5-1 part of allylthiourea, 0.5-1 part of polydimethylsiloxane divalent quaternary ammonium salt, 0.2-0.8 part of 2-methyl-3-hydroxyl-4-methoxyanthraquinone, 0.2-0.6 part of magnesium aluminosilicate and 0.02-0.08 part of kaempferol. The invention further provides the preparation method of the antistatic spinning paste.
Description
Technical field
The invention belongs to textile material field, particularly to a kind of antistatic spinning sizing agent and preparation method thereof。
Background technology
In fibrous material, often contain hydrophilic-OH and-NH2Deng group, therefore easily there is storing of electric charge。Along with people are for improving constantly that the washing of each kind fabric and detergent require, while the dirt-removing power of washing and detergent is had high requirement, also require that fabric is had certain maintenance effect by washing and detergent。
Chinese patent CN1553978A discloses a kind of fabric-treating agent, comprise a kind of aqueous dispersion, this aqueous dispersion is mainly made up of the polyurethane of a kind of closing and a kind of hydrophobic solvent, the inorganic agent prepared still has good stability at low temperatures, makes the textile that the fabric-treating agent through the present invention processed possess the feel of softness and the resistance to contractility of improvement。But the antistatic performance persistency of the textile material after this inorganic agent processes is poor, it is impossible to meet long-term needs。
Therefore, need one badly and there is antistatic fabric, but the breathability of such fabric existing and wearability are not good。
Summary of the invention
For above-mentioned demand, invention especially provides a kind of antistatic spinning sizing agent and preparation method thereof。
The purpose of the present invention can be achieved through the following technical solutions:
A kind of antistatic spinning sizing agent, is made up of the component comprising following weight portion:
Dralon 60-70 part,
Polyethylene Glycol 30-40 part,
Mannitol 12-16 part,
Vinylidene chloride 8-12 part,
Carboxymethyl cellulose 5-8 part,
Epoxypolysilicone acrylate 3-5 part,
Dodecyl-dimethyl amine second lactone 2-3 part,
Allylthiourea 0.5-1 part,
Polydimethylsiloxane two quaternary amine 0.5-1 part,
2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.2-0.8 part,
Aluminosilicate magnesium 0.2-0.6 part,
Nimbecetin 0.02-0.08 part。
Described component also includes zinc oxide 0-1 weight portion。
Described component also includes 3,7-dimethyl-6-octenal 0-1 weight portions。
A kind of preparation method of antistatic spinning sizing agent, the method comprises the following steps:
(1) Dralon 60-70 weight portion, Polyethylene Glycol 30-40 weight portion, mannitol 12-16 weight portion, vinylidene chloride 8-12 weight portion, epoxypolysilicone acrylate 3-5 weight portion, dodecyl-dimethyl amine second lactone 2-3 weight portion, allylthiourea 0.5-1 weight portion, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.2-0.8 weight portion and nimbecetin 0.02-0.08 weight portion are weighed, in a kettle. stirring 1-3 hour at 90-100 DEG C；
(2) system pH is adjusted to 6-7, it is sequentially added into carboxymethyl cellulose 5-8 weight portion, polydimethylsiloxane two quaternary amine 0.5-1 weight portion, aluminosilicate magnesium 0.2-0.6 weight portion, zinc oxide 0-1 weight portion and 3,7-dimethyl-6-octenal 0-1 weight portion, stir 10-20 minute at 50-60 DEG C, obtain antistatic spinning sizing agent。
Pressure in described reactor is 8-12MPa。
Compared with prior art, it has the beneficial effect that the present invention
(1) the antistatic spinning sizing agent of the present invention is with Dralon for primary raw material, by adding Polyethylene Glycol, mannitol, vinylidene chloride, carboxymethyl cellulose, epoxypolysilicone acrylate, dodecyl-dimethyl amine second lactone, allylthiourea, polydimethylsiloxane two quaternary amine, 2-methyl-3-hydroxyl-4-methoxy anthraquinone, aluminosilicate magnesium and nimbecetin, the fabric that the antistatic spinning sizing agent of the present invention prepares has good mechanical strength, toughness and wearability。
(2) fabric that the antistatic spinning sizing agent of the present invention prepares has good antistatic performance。
(3) the antistatic spinning sizing agent of the present invention, its preparation method is simple, it is easy to industrialized production。
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated。
Embodiment 1
(1) Dralon 60kg, Polyethylene Glycol 30kg, mannitol 12kg, vinylidene chloride 8kg, epoxypolysilicone acrylate 3kg, dodecyl-dimethyl amine second lactone 2kg, allylthiourea 0.5kg, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.2kg and nimbecetin 0.02kg are weighed, 90 DEG C in a kettle., stirring 1 hour under 8MPa；
(2) system pH is adjusted to 6, is sequentially added into carboxymethyl cellulose 5kg, polydimethylsiloxane two quaternary amine 0.5kg and aluminosilicate magnesium 0.2kg, stir 10 minutes at 50 DEG C, obtain antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
Embodiment 2
(1) Dralon 60kg, Polyethylene Glycol 30kg, mannitol 12kg, vinylidene chloride 8kg, epoxypolysilicone acrylate 3kg, dodecyl-dimethyl amine second lactone 2kg, allylthiourea 0.5kg, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.2kg and nimbecetin 0.02kg are weighed, 90 DEG C in a kettle., stirring 1 hour under 8MPa；
(2) system pH is adjusted to 6, it is sequentially added into carboxymethyl cellulose 5kg, polydimethylsiloxane two quaternary amine 0.5kg, aluminosilicate magnesium 0.2kg, zinc oxide 1kg and 3,7-dimethyl-6-octenal 1kg, stirs 10 minutes at 50 DEG C, obtains antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
Embodiment 3
(1) Dralon 70kg, Polyethylene Glycol 40kg, mannitol 16kg, vinylidene chloride 12kg, epoxypolysilicone acrylate 5kg, dodecyl-dimethyl amine second lactone 3kg, allylthiourea 1kg, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.8kg and nimbecetin 0.08kg are weighed, 100 DEG C in a kettle., stirring 3 hours under 12MPa；
(2) system pH is adjusted to 7, it is sequentially added into carboxymethyl cellulose 8kg, polydimethylsiloxane two quaternary amine 1kg, aluminosilicate magnesium 0.6kg, zinc oxide 1kg and 3,7-dimethyl-6-octenal 1kg, stirs 20 minutes at 60 DEG C, obtains antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
Embodiment 4
(1) Dralon 70kg, Polyethylene Glycol 40kg, mannitol 16kg, vinylidene chloride 12kg, epoxypolysilicone acrylate 5kg, dodecyl-dimethyl amine second lactone 3kg, allylthiourea 0.5kg, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.8kg and nimbecetin 0.02kg are weighed, 100 DEG C in a kettle., stirring 3 hours under 12MPa；
(2) system pH is adjusted to 7, it is sequentially added into carboxymethyl cellulose 8kg, polydimethylsiloxane two quaternary amine 1kg, aluminosilicate magnesium 0.6kg, zinc oxide 1kg and 3,7-dimethyl-6-octenal 1kg, stirs 20 minutes at 60 DEG C, obtains antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
Embodiment 5
(1) Dralon 65kg, Polyethylene Glycol 35kg, mannitol 14kg, vinylidene chloride 10kg, epoxypolysilicone acrylate 4kg, dodecyl-dimethyl amine second lactone 2.5kg, allylthiourea 0.8kg, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.5kg and nimbecetin 0.05kg are weighed, 95 DEG C in a kettle., stirring 2 hours under 10MPa；
(2) system pH is adjusted to 6.5, it is sequentially added into carboxymethyl cellulose 6kg, polydimethylsiloxane two quaternary amine 0.7kg, aluminosilicate magnesium 0.4kg, zinc oxide 0.5kg and 3,7-dimethyl-6-octenal 0.5kg, stirs 15 minutes at 55 DEG C, obtains antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
Comparative example 1
(1) Dralon 70kg, Polyethylene Glycol 40kg, mannitol 16kg, vinylidene chloride 12kg, epoxypolysilicone acrylate 5kg, dodecyl-dimethyl amine second lactone 3kg, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.8kg and nimbecetin 0.08kg are weighed, 100 DEG C in a kettle., stirring 3 hours under 12MPa；
(2) system pH is adjusted to 7, it is sequentially added into carboxymethyl cellulose 8kg, polydimethylsiloxane two quaternary amine 1kg, aluminosilicate magnesium 0.6kg, zinc oxide 1kg and 3,7-dimethyl-6-octenal 1kg, stirs 20 minutes at 60 DEG C, obtains antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
Comparative example 2
(1) Dralon 70kg, Polyethylene Glycol 40kg, mannitol 16kg, vinylidene chloride 12kg, epoxypolysilicone acrylate 5kg, dodecyl-dimethyl amine second lactone 3kg, allylthiourea 1kg and nimbecetin 0.08kg are weighed, 100 DEG C in a kettle., stirring 3 hours under 12MPa；
(2) system pH is adjusted to 7, it is sequentially added into carboxymethyl cellulose 8kg, polydimethylsiloxane two quaternary amine 1kg, aluminosilicate magnesium 0.6kg, zinc oxide 1kg and 3,7-dimethyl-6-octenal 1kg, stirs 20 minutes at 60 DEG C, obtains antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
Comparative example 3
(1) Dralon 70kg, Polyethylene Glycol 40kg, mannitol 16kg, vinylidene chloride 12kg, epoxypolysilicone acrylate 5kg, dodecyl-dimethyl amine second lactone 3kg, allylthiourea 1kg, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.8kg are weighed, 100 DEG C in a kettle., stirring 3 hours under 12MPa；
(2) system pH is adjusted to 7, is sequentially added into carboxymethyl cellulose 8kg, polydimethylsiloxane two quaternary amine 1kg, zinc oxide 1kg and 3,7-dimethyl-6-octenal 1kg, stirs 20 minutes at 60 DEG C, obtain antistatic spinning sizing agent。
The performance test results preparing antistatic spinning sizing agent is as shown in table 1。
The antistatic spinning sizing agent of embodiment 1-5 and comparative example 1-3 being made the film that thickness is 0.2, tests its specific performance, result is as shown in table 1。
Table 1
| Test event | Point-to-point resistance (Ω) | Fracture strength (N/mm2) | Abrasion (mg/cm2) |
| Embodiment 1 | 6.6×106 | 73 | 0.26 |
| Embodiment 2 | 3.6×107 | 75 | 0.15 |
| Embodiment 3 | 6.1×107 | 84 | 0.13 |
| Embodiment 4 | 5.9×107 | 77 | 0.14 |
| Embodiment 5 | 7.0×107 | 78 | 0.14 |
| Comparative example 1 | 6.6×104 | 35 | 0.36 |
| Comparative example 2 | 6.8×104 | 40 | 0.42 |
| Comparative example 3 | 5.5×104 | 38 | 0.35 |
The invention is not restricted to embodiment here, those skilled in the art's announcement according to the present invention, the improvement made without departing from scope and amendment all should within protection scope of the present invention。
Claims (5)
1. an antistatic spinning sizing agent, it is characterised in that be made up of the component comprising following weight portion:
Dralon 60-70 part,
Polyethylene Glycol 30-40 part,
Mannitol 12-16 part,
Vinylidene chloride 8-12 part,
Carboxymethyl cellulose 5-8 part,
Epoxypolysilicone acrylate 3-5 part,
Dodecyl-dimethyl amine second lactone 2-3 part,
Allylthiourea 0.5-1 part,
Polydimethylsiloxane two quaternary amine 0.5-1 part,
2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.2-0.8 part,
Aluminosilicate magnesium 0.2-0.6 part,
Nimbecetin 0.02-0.08 part。
2. antistatic spinning sizing agent according to claim 1, it is characterised in that described component also includes zinc oxide 0-1 weight portion。
3. antistatic spinning sizing agent according to claim 1, it is characterised in that described component also includes 3,7-dimethyl-6-octenal 0-1 weight portions。
4. the preparation method of an antistatic spinning sizing agent, it is characterised in that the method comprises the following steps:
(1) Dralon 60-70 weight portion, Polyethylene Glycol 30-40 weight portion, mannitol 12-16 weight portion, vinylidene chloride 8-12 weight portion, epoxypolysilicone acrylate 3-5 weight portion, dodecyl-dimethyl amine second lactone 2-3 weight portion, allylthiourea 0.5-1 weight portion, 2-methyl-3-hydroxyl-4-methoxy anthraquinone 0.2-0.8 weight portion and nimbecetin 0.02-0.08 weight portion are weighed, in a kettle. stirring 1-3 hour at 90-100 DEG C；
(2) system pH is adjusted to 6-7, it is sequentially added into carboxymethyl cellulose 5-8 weight portion, polydimethylsiloxane two quaternary amine 0.5-1 weight portion, aluminosilicate magnesium 0.2-0.6 weight portion, zinc oxide 0-1 weight portion and 3,7-dimethyl-6-octenal 0-1 weight portion, stir 10-20 minute at 50-60 DEG C, obtain antistatic spinning sizing agent。
5. the preparation method of antistatic spinning sizing agent according to claim 4, it is characterised in that the pressure in described reactor is 8-12MPa。
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| CN106592212A (en) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | Anti-static textile sizing agent for fiber fabrics and preparation method of textile sizing agent |
| CN107268115A (en) * | 2017-07-03 | 2017-10-20 | 苏州舒而适纺织新材料科技有限公司 | A kind of composite textile materials added with Kaempferol and preparation method thereof |
| CN107841870A (en) * | 2017-11-29 | 2018-03-27 | 苏州润弘贸易有限公司 | A kind of modified spinning sizing agent |
| CN108103781A (en) * | 2017-12-26 | 2018-06-01 | 安徽羽洁家纺有限公司 | A kind of antistatic spinning sizing agent and preparation method thereof |
| CN116590821B (en) * | 2023-05-10 | 2024-02-06 | 潮州市苏菲亚时装有限公司 | Synthesis method and application of breathable polyester fabric |
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Effective date of registration: 20231129 Address after: No. 2829 Yuanyuan Road, Shengze Town, Wujiang District, Suzhou City, Jiangsu Province, 215000 (Group 4, Bali Village) Patentee after: Suzhou Boze Textile Co.,Ltd. Address before: Group 4, Bali Village, Shengze Town, Wujiang, Suzhou City, Jiangsu Province, China Patentee before: WUJIANG FUHUIYUAN HOME TEXTILE CO.,LTD. |