CN105694583A - Photoinduced energy-storing environment-friendly ink - Google Patents
Photoinduced energy-storing environment-friendly ink Download PDFInfo
- Publication number
- CN105694583A CN105694583A CN201610149014.9A CN201610149014A CN105694583A CN 105694583 A CN105694583 A CN 105694583A CN 201610149014 A CN201610149014 A CN 201610149014A CN 105694583 A CN105694583 A CN 105694583A
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- China
- Prior art keywords
- diluent
- rare earth
- synthetic resin
- prepared
- ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses photoinduced energy-storing environment-friendly ink which is prepared from rare earth, synthetic resin and diluent. The weight ratio of rare earth to synthetic resin to diluent is 10:5:0.2. Rare earth is prepared from strontium carbonate, aluminum oxide, europium oxide and azobisformamide. Synthetic resin is prepared from amino resin, epoxy resin, cyclohexanone, butyl cellosolve, dimethylbenzene and an antifoaming agent. Diluent is prepared from isophoron and dissolving oil. Compared with the prior art, the ink has the following advantages of being long in fluorescent lifetime, free of radioactive elements, resistant to acid and base, resistant to corrosion, free of maintenance and the like after being dried at a high temperature by means of the silk-screen printing or roller coating or embedding technologies, and is widely applied to social public security.
Description
Technical field
The present invention relates to coating processing technique field, particularly to a kind of photo-induced energy storage environment-friendly ink。
Background technology
Now, increasing product uses luminous ink, is mainly used in means of transportation, military installations, public place of entertainment, public place, emergency indicating system, billboard, civil buildings decoration aspect, fire emergency escape system。Facilitate daily life, the purpose of protection people life property safety to a certain extent。Due to the huge difference between luminous ink and common ink, the applicable situation of luminous ink is made to get more and more。But, luminous ink on the market now, test through specialty, the persistence of its noctilucent function is not enough, the function of noctilucence is just lost after employing hundreds of time, existing polyester luminous powder is a kind of fugitive luminescent powder of zinc sulfide, at dark place, fluorescent lifetime is short, night resolving ability poor, powder construction is difficult, easy to fall off, variable color。
Summary of the invention
The present invention is directed to short defect of existing polyester luminescent powder continuous illumination time, environment-friendly type new material is now adopted to make liquid ink, even if people are stranded under severe dark environment, photo-induced energy storage environment-friendly ink optkmal characteristics can be passed through, make mark continuous illumination, guide people's safe escape hazardous environment, it is ensured that people's property life security。
For achieving the above object, the present invention adopts following technical proposals:
A kind of photo-induced energy storage environment-friendly ink, including rare earth, synthetic resin, diluent, described rare earth, synthetic resin, diluent percentage by weight be 10:5:0.2；Described rare earth is made up of strontium carbonate, aluminium oxide, europium oxide, azodicarbonamide；Described synthetic resin is made up of amino resins, epoxy resin, cyclohexanone, butyl glycol ether, dimethylbenzene, defoamer；Described diluent is made up of isophorone, dissolved oil。
Preferably, in the every 1000g of described rare earth, the mass ratio of various compositions is strontium carbonate 260g, aluminium oxide 540g, europium oxide 195g, azodicarbonamide 5g。
Preferably, in the every 500g of described synthetic resin, the mass ratio of various compositions is amino resins 150g, epoxy resin 125g, cyclohexanone 50g, butyl glycol ether 100g, dimethylbenzene 50g, defoamer 25g。
Preferably, in the every 20g of described diluent, the mass ratio of various compositions is isophorone 16g, dissolved oil 4g。
The manufacture method of described rare earth is: strontium carbonate, aluminium oxide, europium oxide, azodicarbonamide, in proportion: 260:540:195:5 mixes, within 1 hour, completes for 500rpm stirring with speed with high speed dispersor。
The manufacture method of described synthetic resin is: amino resins, epoxy resin, cyclohexanone, butyl glycol ether, dimethylbenzene, defoamer, 150:125:50:100:50:20 mixes in proportion, stirring 1 hour for 800rpm with speed with high speed dispersor, adjusting viscosity is that 650Mpa.s synthetic resin completes。
The manufacture method of described diluent is: isophorone, dissolved oil, and 16:4 mixes in proportion, and adjusting viscosity is that 100Mpa.s diluent completes。
The present invention compared with prior art, has the advantages that
Silk screen printing, roller coating or embedded process can be passed through, there is fluorescent lifetime length after high temperature is dried, without radioactive element, acid and alkali-resistance, anticorrosive, the advantage such as non-maintaining, it is widely used in social public security。
Detailed description of the invention
The present invention is done supplementary further below in conjunction with specific embodiment, but do not limit the present invention in any way。
Described liquid photopolymerizable energy storage ink operation sequence and performance test:
1000g rare earth adds 500g synthetic resin add 20g mixing diluents again and be sufficiently stirred for 10 minutes, stand 10-15 minute, it is printed on various safety sign base material (such as PMMA material) with 31T thick film half tone, after carrying out three degree of printings, dry actually detected thickness and reach 36 μm, clean top layer again and become double-component height light polishes with acrylic resin, firming agent, mixing diluents, be sprayed at ink pellet surface, dry 30 minutes with constant temperature 80 DEG C。
Now model is carried out 11 technical specifications such as its brightness characteristics, shock resistance, radiance, resist bending performance, outward appearance, luminescent properties, resistance to low temperature, resistance to elevated temperatures, wet-hot aging performance, salt spray corrosion resistance, solvent resistance and all meets national standard JB17733-2008 regulation。Testing result is as follows:
One, brightness characteristics: by 1980B type low-light brightness instrument testing result:
1. original intensity: 41900 (mcd/) meet the requirements；
2. under dark situation, twilight sunset after 10h: 5 (mcd/) meet the requirements。
Two, shock resistance: by HD-211 type falling ball impact test instrument testing result: after impact test, sample is being subject to beyond shock surface, should not occur that crack, interlayer depart from or other damages, result no abnormality seen after testing, meet the requirements。
Three, radiance: by FJ-428G portable multi-purpose radiometer testing result: measured value is less than natural background reading twice, and this truth of a matter is 52cpm, and measured value is 53cpm, meets the requirements。
Four, resist bending performance: after resist bending test, ink should not occur that crack, stripping or interlaminar separation etc. damage, and testing result no abnormality seen meets the requirements。
Five, outward appearance: the space of a whole page is regular, word is proper, marshalling, phonetic spelling specification, testing result no abnormality seen meets the requirements。
Six, luminescent properties: distance label 5m place range estimation luminescence scutcheon picture and text writing plane, should not have obvious non-uniform light, testing result no abnormality seen, meet the requirements。
Seven, resistance to low temperature: after 72 low-temperature-40 ± 2 DEG C is tested, should there is not the phenomenons such as crack, softening, stripping, wrinkle, foaming, warpage and outward appearance be uneven, testing result no abnormality seen in specimen surface, meets the requirements。
Eight, resistance to elevated temperatures: after 24 hours high temperature 70 ± 2 DEG C test, specimen surface should not occur that the phenomenons such as crack, softening, stripping, wrinkle, foaming, warpage and outward appearance be uneven, testing result no abnormality seen should not occur in specimen surface, meets the requirements。
Nine, wet-hot aging performance: after 48 hours damp and hot 96 ± 2%R.H, 47 ± 2 DEG C of tests, phenomenons such as bubbling, get rusty and come off, testing result no abnormality seen should not occur in specimen surface, meets the requirements。
Ten, salt spray corrosion resistance: by YSL/Q-750 type salt air corrosion experimental box testing result: through 120 hours, concentration is that after the salt spray resistance experiment of 5%, specimen surface should not have the phenomenons such as variable color, foaming and erosion, testing result no abnormality seen, meets the requirements。
11, solvent resistance:
1. gasoline: after 10min solvent test, should there is not softening, wrinkle, foaming in ink pellet surface, ftracture or vestige, the testing result no abnormality seen such as be dissolved, and meets the requirements；
2. ethanol: after 1min solvent test, should there is not softening, wrinkle, foaming in ink pellet surface, ftracture or vestige, the testing result no abnormality seen such as be dissolved, and meets the requirements。
The present invention compared with prior art, has the advantages that
Silk screen printing, roller coating or embedded process can be passed through, there is fluorescent lifetime length after high temperature is dried, without radioactive element, acid and alkali-resistance, anticorrosive, the advantage such as non-maintaining, it is widely used in social public security。
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations。All within the spirit and principles in the present invention, any amendment of making, equivalent replacement, improvement etc., should be included within protection scope of the present invention。
Claims (4)
1. a photo-induced energy storage environment-friendly ink, it is characterised in that: include rare earth, synthetic resin, diluent, described rare earth, synthetic resin, diluent percentage by weight be 10:5:0.2；Described rare earth is made up of strontium carbonate, aluminium oxide, europium oxide, azodicarbonamide；Described synthetic resin is made up of amino resins, epoxy resin, cyclohexanone, butyl glycol ether, dimethylbenzene, defoamer；Described diluent is made up of isophorone, dissolved oil。
2. photo-induced energy storage environment-friendly ink according to claim 1, it is characterised in that: in the every 1000g of described rare earth, the mass ratio of various compositions is strontium carbonate 260g, aluminium oxide 540g, europium oxide 195g, azodicarbonamide 5g。
3. photo-induced energy storage environment-friendly ink according to claim 1, it is characterised in that: in the every 500g of described synthetic resin, the mass ratio of various compositions is amino resins 150g, epoxy resin 125g, cyclohexanone 50g, butyl glycol ether 100g, dimethylbenzene 50g, defoamer 25g。
4. photo-induced energy storage environment-friendly ink according to claim 1, it is characterised in that: in the every 20g of described diluent, the mass ratio of various compositions is isophorone 16g, dissolved oil 4g。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610149014.9A CN105694583A (en) | 2016-03-15 | 2016-03-15 | Photoinduced energy-storing environment-friendly ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610149014.9A CN105694583A (en) | 2016-03-15 | 2016-03-15 | Photoinduced energy-storing environment-friendly ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105694583A true CN105694583A (en) | 2016-06-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610149014.9A Pending CN105694583A (en) | 2016-03-15 | 2016-03-15 | Photoinduced energy-storing environment-friendly ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107226919A (en) * | 2017-06-09 | 2017-10-03 | 广州雷诺丽特塑料有限公司 | A kind of long afterglow PVC paint films and preparation method thereof |
| CN109825038A (en) * | 2019-02-27 | 2019-05-31 | 北斗星光源有限公司 | A kind of luminescent material that light emission rate is high |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183984A (en) * | 2011-12-28 | 2013-07-03 | 广东天龙油墨集团股份有限公司 | Nanometer long afterglow energy storage type ink-jet ink for ink-jet printing |
| CN103351713A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Luminous printing ink for printing outdoor advertisements |
| CN104194485A (en) * | 2014-08-26 | 2014-12-10 | 南昌欧菲生物识别技术有限公司 | Noctilucent ink, fingerprint identification device using same and terminal equipment |
-
2016
- 2016-03-15 CN CN201610149014.9A patent/CN105694583A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183984A (en) * | 2011-12-28 | 2013-07-03 | 广东天龙油墨集团股份有限公司 | Nanometer long afterglow energy storage type ink-jet ink for ink-jet printing |
| CN103351713A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Luminous printing ink for printing outdoor advertisements |
| CN104194485A (en) * | 2014-08-26 | 2014-12-10 | 南昌欧菲生物识别技术有限公司 | Noctilucent ink, fingerprint identification device using same and terminal equipment |
Non-Patent Citations (1)
| Title |
|---|
| 石富: "《稀土冶金技术》", 30 April 2009, 冶金工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107226919A (en) * | 2017-06-09 | 2017-10-03 | 广州雷诺丽特塑料有限公司 | A kind of long afterglow PVC paint films and preparation method thereof |
| CN109825038A (en) * | 2019-02-27 | 2019-05-31 | 北斗星光源有限公司 | A kind of luminescent material that light emission rate is high |
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Application publication date: 20160622 |