CN105692904B - A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification - Google Patents

A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification Download PDF

Info

Publication number
CN105692904B
CN105692904B CN201610258730.0A CN201610258730A CN105692904B CN 105692904 B CN105692904 B CN 105692904B CN 201610258730 A CN201610258730 A CN 201610258730A CN 105692904 B CN105692904 B CN 105692904B
Authority
CN
China
Prior art keywords
reactor
autotrophic denitrification
upflow
water tank
type reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610258730.0A
Other languages
Chinese (zh)
Other versions
CN105692904A (en
Inventor
彭永臻
牟东阳
靳鹏飞
王淑莹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING TANSI ENVIRONMENTAL PROTECTION TECHNOLOGYCO., Ltd.
Original Assignee
Beijing University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing University of Technology filed Critical Beijing University of Technology
Priority to CN201610258730.0A priority Critical patent/CN105692904B/en
Publication of CN105692904A publication Critical patent/CN105692904A/en
Application granted granted Critical
Publication of CN105692904B publication Critical patent/CN105692904B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/308Biological phosphorus removal
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/006Regulation methods for biological treatment

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

A kind of device and method that realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification is related to technical field of biological sewage treatment.Device is equipped with city domestic sewage raw water water tank, biology except carbon dephosphorizing reactor, intermediate water tank and integrated autotrophic denitrification upflow-type reactor.Two kinds of bacterium: the ammonia oxidation bacteria of wadding body form and the anaerobic ammonia oxidizing bacteria being attached on filler are primarily present in integrated autotrophic denitrification upflow-type reactor.Municipal sewage initially enters biology except carbon dephosphorizing reactor, carries out anaerobism during water inlet and puts phosphorus;It is aerated after water inlet end, removal Organic substance in water is acted on by activated sludge absorption, while carrying out aerobic phosphorus absorption.Then sewage continuously enters integrated autotrophic denitrification upflow-type reactor through intermediate water tank, by intermittent aerating, realizes short distance nitration-anaerobic ammoxidation.The present invention separates flora without adding outer carbon source, guarantees that the efficiency of system dephosphorization denitrogenation, energy saving are with the obvious advantage.

Description

A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification
Technical field
The present invention relates to technical field of biological sewage treatment more particularly to a kind of realization municipal sewage integral anaerobic ammonia oxygen Change the system and method for autotrophic denitrification.
Background technique
Nitrogen content is the important indicator of Water-quality control.The aggravation of nitrate pollution is also to cause China lake, river in recent years One of an important factor for waters wawter bloom such as stream and coastal waters and red tide large-scale outbreak, therefore cause the extensive concern of people. The ammonia nitrogen removal of conventional waste water processing realizes generally by nitrification and denitrification process, but this process need a large amount of aerations, Organic carbon source and basicity are additionally added, investment and operating cost are high, but also can generate secondary pollution.Anammox denitrogenation It is a kind of new and effective bio-denitrification technology to grow up the nineties in last century.The anaerobism ammonia compared with traditional biological denitrogenation technology Oxidation reaction approach is shorter, it is not necessary to which basicity compensates and adds organic carbon source, to save a large amount of energy and material, saves The problems such as operating cost, the low ratio of carbon to ammonium denitrogenation of waste water faced to the current sewage treatment interface in China is difficult, energy consumption is high, sludge yield is big Bring dawn.Therefore, the extensive research of domestic and foreign scholars has been attracted.
Anammox refers to that under anaerobism or anoxia condition, microorganism is directly with NO2 -For electron acceptor, with NH4 +For electricity Sub- donor, converts two kinds of nitrogens to the bioprocesses of nitrogen simultaneously, and the energy that this process generates can make anaerobism ammonia oxygen Change bacterium to survive under anaerobic.Anammox technology is the most economical bio-denitrification technology being currently known, and traditional Nitration denitrification technology is compared, and has many advantages, such as that oxygen demand is low, and operating cost is low and does not need additional carbon.
Anammox technology is to be currently known most economical bio-denitrification technology, this is because its technical characterstic is determined Fixed.Reason is: 1. in anaerobic ammonium oxidation process, since anaerobic ammonia oxidizing bacteria is autotrophic bacterium, CO2Or carbonate is its life Long required inorganic carbon source, so NH4 +The oxidation of-N is not necessarily to O2It participates in, while NO2 -Without organic carbon source, this will for the reduction of-N A large amount of operating costs for reducing sewage aerobic biological denitrificaion;2. the growth rate (doubling time 11d) of anaerobic ammonia oxidation microbiological With yield (0.11g [VSS]/g [NH4 +]) be low-down, therefore sludge yield is low, however the conversion ratio of nitrogen be but 0.25mg [N]/ (mg [SS] d), it is suitable with traditional aerobic nitrification.
But Anammox technology also fails to be used widely in engineering practice at present, main reason is that: 1. detest Sewage used by anaerobic ammonium oxidation technology experiment is studied is mostly artificial distribution, and there are biggish differences with the water quality of actual sewage Away from;2. being easy to be lost in Anammox reaction initial operating stage sludge, keep enrichment anaerobic ammonia oxidizing bacteria and stable operation more tired It is difficult.
Thus, a technical problem for needing to solve at this stage is: how to propose a kind of effective measures, passes through one Body Anammox autotrophic denitrification Process for Treating Municipal, enables Anammox technology to be successfully applied in actual city In city's sanitary sewage, and Anammox reaction initial operating stage can more enrichment anaerobic ammonia oxidizing bacteria and stable operation it is anti- Device is answered, sludge is not easily runed off.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of integral anaerobic ammoxidation autotrophic denitrification Treating Municipal Sewages System and method, actual cities sewage treatment will be applied to except carbon dephosphorization, short distance nitration, Anammox, and realize that city will be dirty The energy-efficient processing of water.
In order to solve the above-mentioned technical problems, the present invention provides a kind of integral anaerobic ammoxidation autotrophic denitrifications to handle city The system of sewage first passes around biology except carbon dephosphorizing reactor carries out the removal of organic matter and phosphorus, after guarantee by sanitary sewage The stable operation of continuous integral anaerobic ammoxidation;Suitable biofilm packing is placed in anaerobic ammonia oxidation reactor, guarantees to detest The sludge concentration of anaerobic ammonium oxidation bacterium.The system includes raw water water tank, biology except carbon dephosphorizing reactor, intermediate water tank, integration are detested Anaerobic ammonium oxidation upflow-type reactor and its On-line Control and detection system;Wherein, the raw water water tank is removed by peristaltic pump biology Carbon dephosphorizing reactor is connected;Biology is connected except carbon dephosphorizing reactor outlet valve passes through outlet pipe with intermediate water tank;Intermediate water tank is logical Peristaltic pump is crossed to be connected with integral anaerobic ammoxidation upflow-type reactor;And it is attached in integral anaerobic ammoxidation upflow-type reactor There is a certain amount of polyethylene biofilm packing.
A kind of device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification, it is characterised in that:
Including municipal sewage raw water water tank, biology except carbon dephosphorizing reactor, intermediate water tank and integrated autotrophic denitrification up-flow Formula reactor;Municipal sewage raw water water tank is by peristaltic pump with biology except carbon dephosphorizing reactor is connected;The biology is removed except carbon Phosphorus reaction device is equipped with blender, aeration head, gas flowmeter, aeration pump, water inlet pipe, outlet pipe and outlet valve;Biology is removed except carbon Phosphorus reaction device outlet valve is connected by outlet pipe with intermediate water tank;Intermediate water tank is flowed up by peristaltic pump with integrated autotrophic denitrification Formula reactor water inlet pipe is connected;Wherein, the integrated autotrophic denitrification upflow-type reactor includes water inlet pipe, outlet pipe, three-phase Separator, exhaust pipe;Polyethylene biofilm packing is equipped in integrated autotrophic denitrification upflow-type reactor, packing volume ratio is 30%-40%;Integral anaerobic ammoxidation autotrophic denitrification real-time control system includes pH and DO sensing and analyzer, data-signal Input and output interface, Inlet and outlet water relay, aeration relay, electric mixer relay.
Further, the raw water water tank and intermediate water tank are closed box, are equipped with overflow pipe and blow-down pipe.
A method of realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification, feature includes the following steps:
1) system start-up phase: biology discharges sludge except the remaining of carbon dephosphorizing reactor inoculation municipal wastewater treatment plant secondary settling tank, So that sludge concentration is in 2000-5000mg/L;Integrated autotrophic denitrification upflow-type reactor inoculation Treating Municipal Sewage stablizes fortune Capable short distance nitration sludge, so that sludge concentration is in 2000-5000mg/L;In from the anaerobic ammonia oxidation reactor of stable operation A certain amount of anaerobic ammonium oxidation granular sludge or floc sludge is taken to be inoculated with, sludge concentration is in 5000-8000mg/L, and in body Change and is put into polyethylene biofilm packing progress biofilm, packing ratio 30%-40% in autotrophic denitrification upflow-type reactor;When body Autotrophic denitrification up-flow is discharged NH4 +- N concentration≤1mg/L or NO2 -When-N concentration≤1mg/L time was up to 10 days or more, complete Starting;
2) the system operation phase: 1. biology removes the method for operation of carbon dephosphorizing reactor are as follows: 10- of intaking in anaerobism stirring 30min, then aerobic aeration 40-60min is carried out, to complete the removal of degradable COD in raw water;30- is precipitated after reaction 50min, draining is than being 50%-70%, and at 2-5 days, Dissolved Oxygen concentration Control was discharged into 0.5-2mg/L, water outlet for sludge age control Intermediate water tank;2. the method for operation of integrated autotrophic denitrification upflow-type reactor are as follows: intake by intermediate water tank, pass through Gas rotameters Flowmeter adjusts aeration quantity, makes Dissolved Oxygen concentration Control in 0.5-1mg/L, and control aeration is intermittent aerating, every aeration 10- Stop 40-50min after 20min, starts to stop 40-50min after being aerated 10-20min later again, so aeration, stopping circulation are past It is multiple;Integrated autotrophic denitrification upflow-type reactor continuous effluent, is discharged by outlet valve;Integrated autotrophic denitrification up-flow reaction Device hydraulic detention time is 20-40min;
If integrated autotrophic denitrification upflow-type reactor reactor water outlet ammonia nitrogen concentration is higher than 5mg/L, system need to be aerated Time rises to higher than 20min;It is recalled to when reactor water outlet ammonia nitrogen concentration is again below 5mg/L, then by system aeration time To 10-20min.
After system commencement of commercial operation, the process flow of municipal sewage in this device are as follows: sewage enters raw water water tank, passes through Peristaltic pump makes raw water enter biology except carbon dephosphorizing reactor, and the side Bian Jinshui anaerobism is stirred to carry out releasing phosphorus process;Subsequent biology removes Carbon dephosphorizing reactor carries out aerobic aeration, removes the labile organic compound in water and carries out inhaling phosphorus process simultaneously, to make phosphorus in dirt It is enriched in mud;Biology enters intermediate water tank except the water outlet of carbon dephosphorizing reactor, the intermediate water tank play the enough waters of storage for The effect of integral anaerobic ammoxidation autotrophic denitrification upflow-type reactor continuum micromeehanics;Raw water through except after carbon dephosphorization through peristaltic pump into Enter integrated autotrophic denitrification upflow-type reactor, intermittent aerating carried out by aeration pump, control dissolved oxygen concentration in 1mg/L hereinafter, Make ammonia oxidation bacteria in reactor (AOB) by NH4 +N section short distance nitration is NO2 -Anaerobic ammonia oxidizing bacteria utilizes NH while-N4 +-N And NO2 -- N carries out Anammox reaction and generates N2Discharge system.By the above process finally by organic matter, phosphorus and nitrogen from sewage In efficiently remove.
To sum up, the present invention has the advantage that as follows:
1) system and method for integral anaerobic ammoxidation autotrophic denitrification Treating Municipal Sewage provided by the invention, will be biological Except carbon dephosphorization, short distance nitration and Anammox are applied in the advanced nitrogen processing of sanitary sewage, relative to traditional denitrogenation work Skill reduces 60% or more aeration quantity, while without adding outer carbon source and neutralizer, easy to operate, nitric efficiency is high.
2) two different mushrooms are cultivated in different systems respectively according to growth characteristics and sludge age: heterotroph in Biology is except in carbon dephosphorizing reactor, autotrophic bacterium, that is, short distance nitration bacterium and anaerobic ammonia oxidizing bacteria are in upflow-type reactor, thus It can be placed it under the best growing condition according to the characteristics of every kind of mushroom, avoid the sludge age contradiction of denitrogenation and dephosphorization, protected The efficient stable operation for having demonstrate,proved each system, realizes the advanced nitrogen of municipal sewage.
3) biology is except carbon dephosphorization is using sbr reactor device, and the method for operation is flexible, good denitrogenation and dephosphorization effect, anti impulsion load, place Reason ability is strong, and can effectively prevent sludge bulking.
4) integral anaerobic ammoxidation denitrogenation uses upflow-type reactor, and sludge concentration is high, and processing capacity is strong, and using poly- The form of ethylene biofilm packing is enriched anaerobic ammonia oxidizing bacteria, is effectively reduced the loss of anaerobic ammonia oxidizing bacteria, and without mixed Mixing plant is closed, low dissolved oxygen intermittent aerating is energy-efficient.
5) present invention uses integral anaerobic ammoxidation autotrophic denitrification technique, without NO, N in denitrification process2The pernicious gases such as O It generates, it is environmentally protective.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of present system.
As shown, 1 being sanitary sewage raw water water tank, 2 being biology except carbon dephosphorizing reactor, 3 are intermediate water tank, 4 are one Body Anammox autotrophic denitrification upflow-type reactor;1.1 it is sanitary sewage raw water water tank overflow pipe, 1.2 is sanitary sewage Raw water water tank blow-down pipe;2.1 it is intake pump, 2.2 be agitating paddle, 2.3 be blender, 2.4 be aeration head, 2.5 is Gas rotameters Flowmeter, 2.6 be air pump, 2.7 be pH analyzer, 2.8 be DO analyzer, 2.9 be pH and DO analyzer, 2.10 be blow valve, 2.11 being outlet valve;3.1 it is intermediate water tank overflow pipe, 3.2 is intermediate water tank blow-down pipe;4.1 be intake pump, 4.2 be blow-down pipe, 4.3 be three phase separator, and 4.4 be that exhaust pipe 4.5 is pH analyzer, 4.6 is DO analyzer, 4.7 is pH and DO analyzer, 4.8 It is executing agency for host computer and display, 4.9,4.10 be operator signals output interface, 4.11 is polyethylene biology Film filler, 4.12 be aeration head, 4.13 be gas rotameter, 4.14 be air pump.
Specific embodiment
The present invention will be further described with application example with reference to the accompanying drawing.
The integral anaerobic ammoxidation autotrophic denitrification Treating Municipal Sewage system equipment therefor is by municipal sewage raw water Water tank, biology are except carbon dephosphorizing reactor, intermediate water tank and integrated autotrophic denitrification upflow-type reactor and its on-line monitoring and instead Feedback system composition;Municipal sewage raw water water tank is equipped with raw water water tank overflow pipe and raw water water tank blow-down pipe;Municipal sewage raw water water Case is by peristaltic pump with biology except carbon dephosphorizing reactor is connected;Biology is equipped with air pump, Gas rotameters stream except carbon dephosphorizing reactor Meter, aeration head, blender, pH and DO analyzer, reactor blow-down pipe and reactor outlet valve;Biology removes carbon dephosphorizing reactor Outlet valve is connected by outlet pipe with intermediate water tank;Intermediate water tank is equipped with intermediate water tank overflow pipe, intermediate water tank blow-down pipe;It is intermediate Water tank is connected by peristaltic pump with integrated autotrophic denitrification upflow-type reactor inlet valve;Integrated autotrophic denitrification up-flow reaction Device be equipped with air pump, gas rotameter, aeration head, reactor blow valve, polyethylene biofilm packing, pH and DO analyzer and Reactor outlet valve;Wherein, polyethylene carrier is the honeycomb cylindrical body substance that diameter is 1cm, packing ratio 30%- 40%.
Process flow of the municipal sewage in this technique are as follows: municipal sewage initially enters biology except the completion of carbon dephosphorizing reactor has The absorption or removal of machine object, and carry out by anaerobism, aerobic alternation procedure absorptions that be released to of phosphorus, the intermediate water of water outlet entrance Case;Intermediate water tank water outlet enters integral anaerobic ammoxidation autotrophic denitrification upflow-type reactor, realizes the part short distance nitre of sewage Change, i.e., by the NH in water4 +N section is converted into NO2 -- N, then NH4 +-N、NO2 -- N is occurred by the effect of anaerobic ammonia oxidizing bacteria Anammox reaction, generates N2Reactor is discharged, realizes the purpose of domestic sewage advanced denitrogenation.
Treating Municipal Sewage method specifically includes the following steps:
1) system start-up phase: the excess sludge for taking municipal sewage plant's secondary settling tank to discharge is added to biology except carbon dephosphorization Reactor, so that sludge concentration MLSS=2000-5000mg/L;Integrated autotrophic denitrification upflow-type reactor inoculation processing city The short distance nitration sludge of sewage, so that sludge concentration MLSS=5000-10000mg/L;It is anti-from the Anammox of stable operation A certain amount of anaerobic ammonia oxidizing bacteria is taken to be inoculated in answering in device, sludge concentration is in 5000-8000mg/L, and in integrated autotrophy It is put into polyethylene biofilm packing in denitrogenation upflow-type reactor and carries out biofilm, packing ratio 30%-40%;When integrated autotrophy Denitrogenation upflow-type reactor is discharged NH4 +- N concentration≤1mg/L or NO2 -It is complete when-N concentration≤1mg/L time was up to 10 days or more The starting of integralization Anammox autotrophic denitrification upflow-type reactor.
2) the system operation phase: 1. biology removes the method for operation of carbon dephosphorizing reactor are as follows: 10- of intaking in anaerobism stirring 30min, then aerobic aeration 40-60min is carried out, to complete the removal of degradable COD in raw water;30- is precipitated after reaction 50min, draining is than being 50%-70%, and sludge age control was at 2-5 days, and Dissolved Oxygen concentration Control is in 0.5-2mg/L;When biology removes Carbon dephosphorizing reactor is discharged COD≤80mg/L, and Nitrification rate≤5% completes the starting of reactor, out when being discharged P≤1mg/L Water is discharged into intermediate water tank;2. the method for operation of integrated autotrophic denitrification upflow-type reactor are as follows: intake by intermediate water tank, pass through gas Body spinner flowmeter adjusts aeration quantity, is in Dissolved Oxygen concentration Control sludge and filler in 0.5-1mg/L, aeration process and fills Divide suspended state, control aeration is interval starting, stops 40-50min after every aeration 10-20min, starts to be aerated 10- later again Stop 40-50min after 20min, so aeration, stopping moves in circles.Reactor continuous effluent, is discharged by outlet valve;Reaction Device hydraulic detention time is 20-40min.
After each reactor successfully starts up, system commencement of commercial operation.Sewage enters raw water water tank, by peristaltic pump make raw water into Enter biology except carbon dephosphorizing reactor, the side Bian Jinshui anaerobism is stirred to carry out releasing phosphorus process;Then biology except carbon dephosphorizing reactor into Row aerobic aeration removes the labile organic compound in water and carries out inhaling phosphorus process simultaneously, so that phosphorus be made to be enriched in sludge;Biology removes The water outlet of carbon dephosphorizing reactor enters intermediate water tank, which plays the enough waters of storage for integral anaerobic ammoxidation The effect of autotrophic denitrification upflow-type reactor continuum micromeehanics;Raw water enters integrated autotrophic denitrification through peristaltic pump after except carbon dephosphorization Upflow-type reactor carries out intermittent aerating by aeration pump, controls dissolved oxygen concentration in 1mg/L hereinafter, making ammoxidation in reactor Bacterium (AOB) is by NH4 +N section short distance nitration is NO2 -Anaerobic ammonia oxidizing bacteria utilizes NH while-N4 +- N and NO2 -- N carries out anaerobism Ammoxidation reaction generates N2Discharge system.Finally organic matter, phosphorus and nitrogen are efficiently removed from sewage by the above process.
It is as follows that specific test water is derived from Beijing University of Technology's its water quality of dependents' district sanitary sewage: COD concentration is 120mg/ L-250mg/L;NH4 +- N concentration is 50mg/L-90mg/L;NO2 N concentration < 0.8mg/L;NO3 -- N concentration is 0.1mg/L- 0.6mg/L;P concentration is 3mg/L-8mg/L.Pilot system is as shown in Figure 1, biology removes carbon dephosphorizing reactor, integral anaerobic ammonia Oxidation autotrophic denitrification upflow-type reactor is all made of organic glass, the reaction of integral anaerobic ammoxidation autotrophic denitrification up-flow Device reaction zone internal diameter is 5cm, dischargeable capacity 2L;Biology is 10L except carbon dephosphorizing reactor dischargeable capacity.
Carrying out practically operation is as follows:
1) excess sludge for taking municipal sewage plant's secondary settling tank to discharge is added to biology except carbon dephosphorizing reactor, so that dirty Mud concentration MLSS=2000-5000mg/L;The short distance nitre of integrated autotrophic denitrification upflow-type reactor inoculation Treating Municipal Sewage Change sludge, so that sludge concentration MLSS=5000-10000mg/L;One is taken in from the anaerobic ammonia oxidation reactor of stable operation Quantitative anaerobic ammonia oxidizing bacteria is inoculated with, and sludge concentration is put into poly- second in 5000-8000mg/L in upflow-type reactor Alkene biofilm packing carries out biofilm, packing ratio 30%;When integrated autotrophic denitrification upflow-type reactor is discharged NH4 +- N concentration≤ 1mg/L or NO2 -When-N concentration≤1mg/L time was up to 10 days or more, integral anaerobic ammoxidation autotrophic denitrification up-flow is completed The starting of reactor.2) biology is intake 20min when anaerobism stirs except carbon dephosphorizing reactor, then carries out aerobic aeration 40min, with Complete the removal of degradable COD in raw water;30min is precipitated after reaction, than being 60%, sludge age was controlled at 2-5 days for draining, Dissolved Oxygen concentration Control is in 1-2mg/L;After domestication 20 days, biology is discharged COD < 80mg/L, and Nitrification rate except carbon dephosphorizing reactor < 3% is discharged P < 1mg/L, completes the starting of reactor, water outlet is discharged into intermediate water tank;
3) integrated autotrophic denitrification upflow-type reactor is intake by intermediate water tank, is adjusted and is aerated by gas rotameter Amount makes Dissolved Oxygen concentration Control sludge and filler in 0.5-1mg/L, aeration process be in abundant suspended state, control aeration Intermittently to start, stop 45min after every aeration 15min, starts to stop 40-50min after being aerated 10-20min later again, so expose Gas, stopping move in circles.Reactor continuous effluent, is discharged by outlet valve;Reactor hydraulic detention time is 30min.When anti- Device is answered to be discharged NH4 +- N concentration < 1mg/L, NO2 -When-N concentration < 1mg/L, integral anaerobic ammoxidation autotrophic denitrification up-flow is completed The removal of nitrogen in sewage is realized in the starting of formula reactor.
The system and method for integral anaerobic ammoxidation autotrophic denitrification Treating Municipal Sewage of the invention can be widely used for city The processing of city's sewage and other organic industrial sewages containing ammonia nitrogen.
Above to the system and method for integral anaerobic ammoxidation autotrophic denitrification Treating Municipal Sewage provided by the present invention It is described in detail, specific case used herein is expounded the principle of the present invention and implementation method, the above implementation The explanation of example is merely used to help understand the present invention and its core concept;At the same time, for those skilled in the art, foundation Thought of the invention, there will be changes in the specific implementation manner and application range, in conclusion the content of the present specification is not It is interpreted as limitation of the present invention.

Claims (1)

1. a kind of method for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification, applied device includes municipal sewage Raw water water tank, biology are except carbon dephosphorizing reactor, intermediate water tank and integrated autotrophic denitrification upflow-type reactor;Municipal sewage raw water Water tank is by peristaltic pump with biology except carbon dephosphorizing reactor is connected;The biology is equipped with blender, exposure except carbon dephosphorizing reactor Gas head, gas flowmeter, aeration pump, water inlet pipe, outlet pipe and outlet valve;Biology is except carbon dephosphorizing reactor outlet valve is by going out Water pipe is connected with intermediate water tank;Intermediate water tank is connected by peristaltic pump with integrated autotrophic denitrification upflow-type reactor water inlet pipe; Wherein, the integrated autotrophic denitrification upflow-type reactor includes water inlet pipe, outlet pipe, three phase separator, exhaust pipe;Integration Polyethylene biofilm packing is equipped in autotrophic denitrification upflow-type reactor, packing volume ratio is 30%-40%;Integral anaerobic Ammoxidation autotrophic denitrification real-time control system includes pH and DO sensing and analyzer, data-signal input and output interface, disengaging Water relay, aeration relay, electric mixer relay;
It is characterized by comprising the following steps:
1) system start-up phase: biology discharges sludge except the remaining of carbon dephosphorizing reactor inoculation municipal wastewater treatment plant secondary settling tank, so that Sludge concentration is in 2000-5000mg/L;Integrated autotrophic denitrification upflow-type reactor inoculation Treating Municipal Sewage stable operation Short distance nitration sludge, so that sludge concentration is in 2000-5000mg/L;One is taken in from the anaerobic ammonia oxidation reactor of stable operation Quantitative anaerobic ammonium oxidation granular sludge or floc sludge is inoculated with, sludge concentration in 5000-8000mg/L, and bodyization from It supports and is put into polyethylene biofilm packing progress biofilm, packing ratio 30%-40% in denitrogenation upflow-type reactor;When body autotrophy Denitrogenation up-flow is discharged NH4 +- N concentration≤1mg/L or NO2 -When-N concentration≤1mg/L time was up to 10 days or more, starting is completed;
2) the system operation phase: 1. biology removes the method for operation of carbon dephosphorizing reactor are as follows: 10-30min of intaking in anaerobism stirring, Aerobic aeration 40-60min is carried out, again to complete the removal of degradable COD in raw water;30-50min is precipitated after reaction, is arranged Water ratio is 50%-70%, and at 2-5 days, Dissolved Oxygen concentration Control was discharged into intermediate water tank in 0.5-2mg/L, water outlet for sludge age control; 2. the method for operation of integrated autotrophic denitrification upflow-type reactor are as follows: intake by intermediate water tank, pass through gas rotameter tune Whole aeration quantity makes Dissolved Oxygen concentration Control in 0.5-1mg/L, and control aeration is intermittent aerating, stops after every aeration 10-20min 40-50min starts to stop 40-50min after being aerated 10-20min later again, and so aeration, stopping moves in circles;Integration is certainly Denitrogenation upflow-type reactor continuous effluent is supported, is discharged by outlet valve;Integrated autotrophic denitrification upflow-type reactor hydraulic retention Time is 20-40min;
If integrated autotrophic denitrification upflow-type reactor reactor water outlet ammonia nitrogen concentration is higher than 5mg/L, need to be by system aeration time It rises to and is higher than 20min;10- is adjusted back to when reactor water outlet ammonia nitrogen concentration is again below 5mg/L, then by system aeration time 20min。
CN201610258730.0A 2016-04-23 2016-04-23 A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification Active CN105692904B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610258730.0A CN105692904B (en) 2016-04-23 2016-04-23 A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610258730.0A CN105692904B (en) 2016-04-23 2016-04-23 A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification

Publications (2)

Publication Number Publication Date
CN105692904A CN105692904A (en) 2016-06-22
CN105692904B true CN105692904B (en) 2019-04-05

Family

ID=56217482

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610258730.0A Active CN105692904B (en) 2016-04-23 2016-04-23 A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification

Country Status (1)

Country Link
CN (1) CN105692904B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106115920B (en) * 2016-08-31 2019-03-22 北京工业大学 The method and apparatus for realizing municipal sewage part short distance nitration and Anammox using fermented sludge
CN107162194A (en) * 2017-06-30 2017-09-15 青岛大学 It is a kind of while realizing the apparatus and method that municipal sewage treatment and phosphorus are reclaimed
CN107857364A (en) * 2017-11-10 2018-03-30 河南师范大学 A kind of biological denitrificaion sewage-treatment plant and its quick start method
CN108408897B (en) * 2018-03-13 2020-10-13 北京工业大学 Integrated short-cut nitrification anaerobic ammonia oxidation and phosphorus removal intermittent aeration real-time control method
CN109824145B (en) * 2019-03-06 2023-11-03 北京工业大学 Device and method for rapidly realizing autotrophic denitrification of domestic sewage by regulating and controlling flora structure
CN110395851B (en) * 2019-08-24 2022-03-29 东南大学 High-altitude town sewage treatment method based on nitrogen and phosphorus capture and completely autotrophic nitrogen removal
CN113998846A (en) * 2021-12-13 2022-02-01 北京城市排水集团有限责任公司 Efficient carbon adsorption coupled biological nitrogen and phosphorus removal sewage treatment device and method
CN114212887B (en) * 2021-12-16 2023-11-24 北京工业大学 System and method for realizing low ammonia nitrogen wastewater integrated autotrophic denitrification operation
CN114538599A (en) * 2022-02-18 2022-05-27 广州大学 Photoinduction device for realizing autotrophic nitrogen removal and synchronous phosphorus removal of municipal sewage

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009214007A (en) * 2008-03-10 2009-09-24 Ihi Corp Activated sludge treating method for wastewater and activated sludge treatment apparatus
CN104058551A (en) * 2014-04-12 2014-09-24 北京工业大学 Energy-saving high-efficiency municipal sewage autotrophic denitrification biological treatment method and device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009214007A (en) * 2008-03-10 2009-09-24 Ihi Corp Activated sludge treating method for wastewater and activated sludge treatment apparatus
CN104058551A (en) * 2014-04-12 2014-09-24 北京工业大学 Energy-saving high-efficiency municipal sewage autotrophic denitrification biological treatment method and device

Also Published As

Publication number Publication date
CN105692904A (en) 2016-06-22

Similar Documents

Publication Publication Date Title
CN105692904B (en) A kind of method and device for realizing municipal sewage integral anaerobic ammoxidation autotrophic denitrification
CN105884028B (en) The apparatus and method of continuous flow municipal sewage short distance nitration Anammox coupling denitrification dephosphorization
CN104986923B (en) A kind of apparatus and method of the multistage A/O biological denitrificaions based on municipal sewage short distance nitration Anammox
CN103601341B (en) SBR (Sequencing Batch Reactor) and SBBR (Sequencing Biofilm Batch Reactor) municipal sewage high-efficiency biological treatment method and device based on anaerobic ammonia oxidation
CN102964035B (en) Device for autotrophic nitrogen removal of composite biological membrane and operation method
CN107032506A (en) It is segmented the apparatus and method that water outlet short distance nitration Anammox/ denitrifications handle sanitary sewage
CN107032489A (en) Realize the method that the short distance Anammoxs of continuous stream AOA half couple endogenous denitrification
CN100569669C (en) Anaerobic-anoxic oxidation pitch technique denitrification dephosphorization device and method thereof
CN100503470C (en) Control method and device of A2/O oxidation trench technology synchronous nitration and denitrification
CN103663725A (en) Continuous flow biological denitrification method based on granular sludge, and apparatus
CN103359827B (en) Fast starting method of MBR (Membrane bioreactor) autotrophic nitrogen removal technique, and method for synchronously removing carbonic nitrogen in domestic sewage by utilizing same
CN106745743A (en) A kind of sewage denitrification dephosphorization system
CN109970200A (en) Device and method based on short-cut denitrification dephosphorization coupling Anammox processing city domestic sewage
CN109485149A (en) A kind of apparatus and method for realizing treatment of advanced stage landfill leachate advanced nitrogen and excess sludge reduction
CN110054291A (en) Low C/N is followed by short-cut denitrification/anaerobic ammonia oxidation process device and method than sanitary sewage short distance nitration/Anammox
CN108862584A (en) A kind of device and method for inhibiting to realize continuous flow short distance nitration-anaerobic ammoxidation Treating Municipal Sewage based on azanol
CN105712584A (en) Denitrification method and device for synchronously treating livestock farm biogas liquid wastewater and municipal sewage through combination of segmented partial nitrification and anaerobic ammonia oxidation
CN109467186A (en) A kind of pre- nitrosation-anaerobic ammoxidation efficient denitrification method in ammonia nitrogen waste water part
CN110127953A (en) A kind of artificial swamp short distance nitration/denitrification biological denitrogenation system and method
CN106045030B (en) A2The apparatus and method of/O-UASB continuous flow city domestic sewage advanced nitrogen dephosphorization
CN209428226U (en) A kind of sludge dual reflux AOA biofilm treatment apparatus applied to sewage water denitrification
CN108658229A (en) A kind of apparatus and method of autotrophy/heterotrophism advanced nitrogen process control
CN108545887A (en) The method of sulfide type DEAMOX postposition anoxics filter tank denitrification and desulfurization hydrogen based on AAO-BAF Process for Effluent
CN204588936U (en) A kind of waste disposal plant of denitrogenation dephosphorizing
CN104591392A (en) Slow-released carbon source biochemical-denitrifying treatment device for swine wastewater with high ammonia nitrogen and low carbon nitrogen ratio as well as method for treating swine wastewater

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20200819

Address after: 705 Fuhai international port, Haidian District, Beijing 100079

Patentee after: BEIJING TANSI ENVIRONMENTAL PROTECTION TECHNOLOGYCO., Ltd.

Address before: 100124 Chaoyang District, Beijing Ping Park, No. 100

Patentee before: Beijing University of Technology

TR01 Transfer of patent right