CN105692810B - Healthy bath water device for making - Google Patents

Healthy bath water device for making Download PDF

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Publication number
CN105692810B
CN105692810B CN201610220533.XA CN201610220533A CN105692810B CN 105692810 B CN105692810 B CN 105692810B CN 201610220533 A CN201610220533 A CN 201610220533A CN 105692810 B CN105692810 B CN 105692810B
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Prior art keywords
electrode
water
active carbon
filter core
carbon filter
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CN201610220533.XA
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CN105692810A (en
Inventor
肖志邦
李烨
滕茂友
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Dalian Shuangdi New Technology Research Institute Co Ltd
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Dalian Shuangdi New Technology Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • B01D71/34Polyvinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/36Hydrophilic membranes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/023Reactive oxygen species, singlet oxygen, OH radical

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The present invention relates to a kind of healthy bath water device for making, which includes the closed vessel equipped with water outlet, paired anodic-cathodic and the electrolysis power for powering to the paired anodic-cathodic;The paired anodic-cathodic includes first electrode and second electrode, and water penetration membrane made of non-conducting material is equipped between the first electrode and second electrode;The positive-negative polarity of the electrolysis power is changeable;The active carbon filter core of the complete coated first electrode is equipped on the outside of the first electrode, the water penetration membrane is close to the outer surface of active carbon filter core so that the active carbon filter core completely cuts off with closed vessel, and the second electrode is located in closed vessel;The closed vessel is connected by the first pipeline with city for tap water, and the active carbon filter core is connected by the second pipeline with city for tap water.The device can generate alkalescence or acid healthy bath water according to actual needs.

Description

Healthy bath water device for making
Technical field
The present invention relates to a kind of healthy bath water device for making, belong to the water quality advanced processing technology field of domestic water.
Background technology
Currently, water environment is exacerbated, but most of waterworks are still disappeared so far using precipitation, filtering, chlorination both at home and abroad The outmoded process of poison, river or underground water are simply processed.It is however, dirty in face of trade effluent, rural sewage and life Water wildness, which is spread unchecked, pours in life water source, and waterworks can't bear the heavy load helpless.
With the problem of contaminated situation of tap water is on the rise, and the mankind are on own health also growing interest, shower It is increasingly attracted much attention, developed and develop before shower water filter has a vast market with the health problem of water Scape.
In daily life, the micro polluting substance during family supplies water generally enters human body by three kinds of channels:It drinks, breathe It is absorbed with skin.During shower, the polluter that we absorb is much more more than in drinking water.During shower, hot water is opened Pore on skin, remaining chlorine residue and other polluters in water will avail oneself of the opportunity to get in.Polluter is absorbed by skin, Blood circulation system is then immediately proceeded to, is had same round into blood circulation by digestive system just as drinking water Harm.Another noticeable place has sucked substantial amounts of steam when being and having a bath, and human body is caused to be easy to sucking chlorine and other water Angry body.
In fact, people is by breathing the chemical substance of sucking than enter from oral cavity more 6~80 times.In water Radon can evaporate after heating, enter human body by breathing, long-term accumulation can form lung cancer.The volatile materials contained in water It is volatile organic matter (VOCs) mostly, skin absorbs and breathing intake is that can not be ignored two endanger the important of health Approach.On the other hand, shampoo, shower cream be in various degree containing harmful or even carcinogenic chemical, should reduce to the greatest extent or even It avoids using.
Existing market finding showering filter product, is addition special filter(Such as calcium sulfite, KDF, solid carbon Layer, high energy activation stone filter material etc.)In a manner of the pure physical cleaning of the water pollutants such as Adsorption chlorine residue, there are performances to have The deficiencies of easily full failure such as limit, filtrate need to be replaced often.
The content of the invention
The invention solves technical problems to be:Offer one kind can safely remove the pollutants such as chlorine residue and radon in water and can The device for making of generation alkalescence or acid healthy bath water according to actual needs.
In order to solve the above-mentioned technical problem, technical solution proposed by the present invention is:A kind of health bath water device for making, Including being equipped with closed vessel, at least a pair of first electrode paired as negative and positive and the second electrode of water outlet and for institute State the electrolysis power of paired anodic-cathodic power supply;It is made between the first electrode and second electrode equipped with non-conductive material Water penetration membrane;The positive-negative polarity of the electrolysis power is changeable;Completely coated described the is equipped on the outside of the first electrode The active carbon filter core of one electrode, the water penetration membrane is close to the outer surface of active carbon filter core so that the active carbon filter core It is separated with closed vessel, the second electrode is located in closed vessel;The closed vessel is by the first pipeline and city for originally Water connects, and the active carbon filter core is connected by the second pipeline with city for tap water;When first pipeline connection, the second pipeline It disconnects and when the electrolysis power Switching power polarity makes second electrode be negative electrode, first electrode is positive electrode, produces alkalescence Bath water;When the second pipeline connection, the disconnection of the first pipeline and the electrolysis power Switching power polarity make second electrode be positive electricity When pole, first electrode are negative electrode, acid bath water is produced.
When the present invention needs to produce alkaline bath water, the first pipeline connection, the second pipeline disconnect, and outer electrolysis power supply is cut It changes electric power polarity second electrode is made to be negative electrode, the first electrode of cladding is positive electrode in active carbon filter core.At this moment the closing Container is using water penetration membrane as boundary, and the negative electrode is in closed vessel, and the positive electrode is outside closed vessel and outside it Surface is coated with active carbon filter core.
The structure of water penetration membrane shows as the water passage region of countless permeable micropores on microcosmic in the present invention, due to Water penetration membrane is made of non-conductive material, thus voltage drop is generated in the water passage of permeable micropore, i.e., when electrolysis electricity The decomposition voltage in source is applied to external electrode(Positive electrode)With interior electrode(Negative electrode)Afterwards, formed in the water passage of permeable micropore Voltage landing relation.The water of crossing that liberation of hydrogen, the gas of oxygen evolution reaction generation during such water electrolysis easily enter permeable micropore leads to Bubble is generated in water in road and in water passage, the narrow and small environment in the water passage of the permeable micropore of water penetration membrane Middle bubble is easy to crush to generate localized hyperthermia's high pressure, and then inspires efficient water body plasma with minimum voltage and put Electricity generates the plasma of hydroxyl free base class transient state oxidation factor in water penetration membrane and in the water of water penetration membrane neighboring area Body(Plasma is the 4th state of substance that same level is in solid-state, liquid, gaseous state, low temperature plasma rich in electronics, from Son, free radical and excited state molecule, electronics have very high reactivity with ion, can make to be difficult under usual conditions or fast The chemical reaction that degree is difficult becomes very rapid, is discharged by water body and generates plasma group, can greatly improved in water body and pollute The degradation efficiency of object), the oxidisability of the hydroxyl radical free radical transient state oxidation factor is extremely strong, has extraordinary bactericidal effect, simultaneously Existence time in water is again shorter, can be reduced directly to water so as to not stay any toxic side effect after sterilization.
During water processed, city enters bath water device of the present invention for tap water, and chlorine residue and radon shift to positive electrode in the water of source, penetrates Water penetration isolation film is tightly held by activated carbon.Noxious pollutant in the water of source(Anion)Also with current through water penetration isolation film and Active carbon filter core is degraded by the direct oxidation of positive electrode surface.Ultralow pressure plasma is also occurred in water penetration isolation film simultaneously to put The transient state cluster ion that electricity is generated(Including e (solvated electron), OH, H+, atom state hydrogen, OH-Deng)Strong oxdiative removes, so as to Obtain removal chlorine residue and radon etc. and in alkalescence, oxidation-reduction potential be bear, the alkaline purified water for the decontamination that is suitble to deoil.
When needing to produce acid bath water, when the second pipeline connection, the first pipeline disconnect, outer electrolysis power supply switching is electric Source polarity makes second electrode be positive electrode, the first electrode of cladding is negative electrode in active carbon filter core.During water processed, city supplies tap water Through active carbon filter core and water penetration membrane, from gap between water penetration membrane and closed vessel housing(Water outlet is arranged at This)Outflow.At this point, forming anode chamber between closed vessel housing and permeable isolation film, cathode chamber is then by the interior work for burying negative electrode Property charcoal is filled.Active carbon filter core has absorption, conductive and catalytic performance, is a kind of electrode material with applications well prospect Material, in the present invention, active carbon filter core is buried with interior together with first electrode, forms three-dimensional combination electrode.Producing acid bath water When, two electronic reduction reactions generation H occurs for activated carbon cathode surface and the oxygen in water effect of high-specific surface area2O2, also add in Into anode chamber's water outlet.Reaction equation is:
O2+2H++2e→H2O2
Because the reaction of electrochemical degradation organic matter is happened at electrode surface, i.e., by the reaction of direct electrode surface or By electrode surface generate reactive intermediates aoxidize, therefore the conversion zone of electrochemical reaction concentrate on electrode surface and its Near zone.And activated carbon has huge specific surface area, oxygen molecule can be reduced more efficiently in cathode surface, so as to increase Generation H is added2O2Concentration.The organic matter in raw water can be adsorbed in electrolytic process due to activated carbon again, be concentrated to electricity Pole surface, so source Organic substance in water is also degraded when into active carbon filter core.
The discharge electrode of numerous higher curvature radius is equivalent to from microcosmic, coarse active carbon particle, is close to it Water penetration membrane in release a large amount of high energy electrons, in addition cell reaction generation hydrogen or oxygen foam participation, in film Middle induction plasma discharge, transient state cluster ion of the generation with good bactericidal effect(The principle of transient state cluster ion is generated referring to system Take the statement of acid bath water), it is added in water outlet, final outflow water is to eliminate the pollutants such as chlorine residue, radon and organic matter, have The slant acidity bath water of good bactericidal effect.
The alkaline bath water and acid bath water that the present invention produces eliminate the pollutants such as chlorine residue and radon in tap water, And the chemical detergents such as shampoo, shower cream and liquid detergent are not required when in use, it avoids family when wanting bathing and supplies water And the micro polluting substance in chemical detergent enters human body.
In order to further improve plasma discharge characteristic in film, can make the water penetration membrane all using it is hydrophilic every Film.Hydrophilic film surface can with water formed hydrogen bond ordered structure, fenestra water-filling wet face state can be improved, be conducive to film it is medium from Electron discharge process persistently carries out.
Preferably, the pore size of the permeable micropore of the water penetration membrane and shape are essentially identical.
In the present invention, if the aperture of the permeable micropore of water penetration membrane is excessive(I.e. microporous space is excessive)Then it is equivalent to change Mutually increase electrode diameter(Electrode curvature radius)Discharge in water starting excitation voltage is caused to increase, and makes generation bubble volume Become larger and reduce the catalytic specific surface area of gas-liquid two-phase.And the aperture of the permeable micropore of water penetration membrane is too small(Cross water Passage is too small), can make that electrolysis aerogenesis can not occur or gas producing efficiency is extremely low, it is small can make to a certain extent electrolysis aerogenesis without Method enters the permeable aperture of micropore, so that plasma discharge can not be normally carried out.Therefore, by the repetition test of inventor, The pore diameter range for determining the permeable micropore of the water penetration membrane is 2 millimeters~1 nanometer, the permeable micropore of the water penetration membrane Aperture size between each other each other difference be less than 20%.
The shape uniformity of membrane micropore and the uniformity of pore size influence plasma discharge in film very big.In order to More preferable more generation hydroxyl radical free radical plasma groups, it is preferred that when in use, each permeable micropore of the water penetration membrane In be respectively formed plasma discharge.So when using electric discharge, the direction of an electric field between anodic-cathodic can penetrate each permeable micropore Plasma group, plasma discharge is directed in all water passages of water penetration membrane and is carried out, so as to minimum voltage be Water-outlet body plasma discharge can be excited, the transient state oxidation factor of a large amount of great sterilizing abilities is generated in water, can greatly improve The degradation efficiency of pollutant in water body preferably carries out sterilizing etc..
In order to preferably obtain the micropore of uniform pore diameter, and further improve the hydrophily of membrane, it is more so as to generate Plasma group(More plasma groups mean to generate the transient state oxidation factor of more great sterilizing abilities in water), the present invention Described in water penetration membrane preferably use membrane made from following method of modifying:
1)By nanometer titanium dioxide titanium solution in the ultraviolet case internal irradiation that temperature is 40 DEG C -60 DEG C 10-30 minutes;
2)Film liquid is formed by the raw material of following mass ratio:
PVDF:20%-30%
Pore-foaming agent:2-5%
Step 1)Nano-titanium dioxide after irradiation:2%-4%
Surfactant:3%-5%
Solvent:70%-80%;
3)The film liquid configured is passed through into supersonic oscillations 20-40 minutes;
4)Liquid film is spread to knifing machine, liquid film is stood to 10-30 seconds in air, is then immersed in solidification liquid and is frozen into Aqueous membrane;
5)The membrane impregnates 10-40 minutes in concentration is 10% alcohol water blend, is then placed in deionized water and floats It washes;
6)The membrane is placed in be applied in the pure water tank of 10kv DC pulse high voltages processing 1 it is small when.
Further, since water penetration membrane obtains the clamping protection of paired electrode, experiment proves that the water penetration membrane is using It will not be scrapped in the process because of premature failures such as damaged or obstructions, remain reliable and stable working condition.
Preferably, the electrolysis power is that the direct current pulse power source of high level narrow spaces or forward voltage level are more than reversely The component pulse-changing power of voltage level.
Being further improved for above-mentioned technical proposal be:The closed vessel includes the metal cylinder of tubulose and is arranged on institute The insulated enclosure end cap at metal cylinder both ends is stated, the metal cylinder doubles as being second electrode, and the active carbon filter core is cylindrical And in the metal cylinder, the first electrode is embedded in active carbon filter core, and the water penetration membrane, which completely covers, to be laid in Active carbon filter core outer surface, the first electrode, active carbon filter core and metal cylinder are arranged concentrically.In this way, dress of the present invention can be made The more compact structure put, and the area of paired yin, yang electrode is electrolysed compared to same volume other structures bigger so as to improve Efficiency.
Preferably, the first electrode coats electrode made of platinum group oxide for titanium.
Preferably, the metal cylinder coats cylinder made of platinum group oxide for stainless steel or titanium.
Description of the drawings
The invention will be further described below in conjunction with the accompanying drawings.
Fig. 1 is the structure diagram of the embodiment of the present invention one.
Fig. 2 is the structure diagram of the embodiment of the present invention two.
Specific embodiment
Embodiment one
The healthy bath water device for making of the present embodiment as shown in Figure 1, including be equipped with water outlet 1-2 closed vessel 1, Paired anodic-cathodic and the electrolysis power for powering to paired anodic-cathodic(It is not shown in figure);Paired negative and positive electricity Pole includes first electrode 3 and second electrode 2, and water penetration made of non-conducting material is equipped between first electrode 3 and second electrode 2 Membrane;The positive-negative polarity of electrolysis power is changeable;3 outside of first electrode is equipped with the active carbon filter core of complete coated first electrode 3 4, water penetration membrane 5 is close to the outer surface of active carbon filter core 4 so that active carbon filter core 4 and closed vessel 1 are completely separated, and Two electrodes 2 are located in closed vessel 1;Closed vessel 1 is connected by the first pipeline with city for tap water, and active carbon filter core 4 passes through Second pipeline is connected with city for tap water, and the first pipeline is equipped with the first valve 6-1, and the second pipeline is equipped with the second valve 6-2.
The present embodiment can produce alkaline bath water and acid bath water, and the alkaline bathing produced respectively as needed Water and acid bath water eliminate the pollutants such as chlorine residue and radon in tap water, therefore shampoo is not required when in use, washes one's hair The chemical detergents such as bath lotion, avoid family when wanting bathing supply water and chemical detergent in micro polluting substance enter human body
The present embodiment can also make following improve:The pore size of the permeable micropore of water penetration membrane 5 and the basic phase of shape Together.Further, preferably range of aperture size is 2 millimeters~1 nanometer, and the value phase in the minimum permeable aperture of maximum permeable aperture ratio Difference is within 20%(It is not more than 20%)Membrane.
The uniform water penetration membrane 5 of the aperture size of permeable micropore in order to obtain, may be employed it is well known physically or chemically Technology is modified existing ultrafiltration membrane, microfiltration membranes or NF membrane, and such as the shaping of fenestra Regularization, titanium-dioxide photo are urged Change, extremely narrow high-voltage pulse is to film pretreatment, etc..Water penetration membrane 5 is preferably made using following method of modifying in the present embodiment Membrane:
1)By nanometer titanium dioxide titanium solution in the ultraviolet case internal irradiation that temperature is 40 DEG C -60 DEG C 10-30 minutes;
2)Film liquid is formed by the raw material of following mass ratio:
PVDF:20%-30%
Pore-foaming agent:2-5%
Step 1)Nano-titanium dioxide after irradiation:2%-4%
Surfactant:3%-5%
Solvent:70%-80%;
3)The film liquid configured is passed through into supersonic oscillations 20-40 minutes;
4)Liquid film is spread to knifing machine, liquid film is stood to 10-30 seconds in air, is then immersed in solidification liquid and is frozen into Aqueous membrane;
5)The membrane impregnates 10-40 minutes in concentration is 10% alcohol water blend, is then placed in deionized water and floats It washes;
6)The membrane is placed in be applied in the pure water tank of 10kv DC pulse high voltages processing 1 it is small when.
Embodiment two
The present embodiment is the improvement on the basis of embodiment one, with embodiment one the difference is that:As shown in Fig. 2, Closed vessel includes the metal cylinder of tubulose and is arranged on the insulated enclosure end cap at metal cylinder both ends, metal in the present embodiment Cylinder doubles as being second electrode 2, and active carbon filter core 4 is cylindrical and in metal cylinder, and first electrode 3 is embedded in active carbon filtration In core 4, water penetration membrane 5, which completely covers, is laid in 4 outer surface of active carbon filter core, first electrode 3, active carbon filter core 4 and metal cylinder It is arranged concentrically.
The preferred stainless steel of metal cylinder or titanium coat cylinder made of platinum group oxide in the present embodiment.Can so it make More compact structure, and the area of paired yin, yang electrode is imitated compared to same volume other structures bigger so as to improve electrolysis Rate, the bath water index of generation is more preferably.
The present embodiment can also make following improve:
1)Active carbon filter core 4 is equipped with blowdown valve.
2)First electrode 3 coats electrode made of platinum group oxide for titanium.
3)Electrolysis power is more than backward voltage electricity using the direct current pulse power source or forward voltage level of high level narrow spaces Flat component pulse-changing power.
4)For more preferably more generation hydroxyl radical free radical plasma groups, water penetration membrane 5 is using each saturating when in use The membrane of plasma discharge is respectively formed in water micropore.
5)Water penetration membrane 5 is hydrophilic water penetration membrane.
The present invention is not limited to the specific technical solution described in above-described embodiment, and in addition to the implementation, the present invention may be used also To there is an other embodiment, all technical solutions formed using equivalent substitution, be the present invention claims protection domain.

Claims (8)

1. a kind of health bath water device for making, closed vessel, at least a pair including being equipped with water outlet are paired as negative and positive First electrode and second electrode and the electrolysis power for powering to the paired anodic-cathodic;It is characterized in that:Institute It states and water penetration membrane made of non-conductive material is equipped between first electrode and second electrode;The positive and negative anodes of the electrolysis power Property is changeable;The active carbon filter core of the complete coated first electrode, the water penetration membrane are equipped on the outside of the first electrode The outer surface of active carbon filter core is close to so that the active carbon filter core is separated with closed vessel, the second electrode is located at envelope It closes in container;The closed vessel is connected by the first pipeline with city for tap water, and the active carbon filter core passes through the second pipeline It is connected with city for tap water;When first pipeline connection, the disconnection of the second pipeline and the electrolysis power Switching power polarity make When second electrode is negative electrode, first electrode is positive electrode, alkaline bath water is produced;When the second pipeline connection, the first pipeline break It opens and when the electrolysis power Switching power polarity makes second electrode be positive electrode, first electrode is negative electrode, produces acidity and wash Bath water.
2. health bath water device for making according to claim 1, it is characterised in that:The closed vessel includes tubulose Metal cylinder and be arranged on the insulated enclosure end cap at the metal cylinder both ends, the metal cylinder is doubled as the second electricity Pole, the water penetration membrane, which completely covers, is laid in active carbon filter core outer surface, and the active carbon filter core is cylindrical and positioned at the gold Belong in cylinder, the first electrode, active carbon filter core and metal cylinder are arranged concentrically.
3. health bath water device for making according to claim 1, it is characterised in that:The water penetration membrane it is permeable The pore size and shape of micropore are essentially identical.
4. health bath water device for making according to claim 1, it is characterised in that:When in use, the water penetration Plasma discharge is respectively formed in each permeable micropore of membrane.
5. health bath water device for making according to claim 1, it is characterised in that:The water penetration membrane is hydrophilic The water penetration membrane of property.
6. according to any healthy bath water device for making of claim 1-4, it is characterised in that:The activity carbon filtration Core is equipped with blowdown valve.
7. according to any healthy bath water device for making of claim 1-4, it is characterised in that:The first electrode Electrode made of platinum group oxide is coated for titanium.
8. health bath water device for making according to claim 2, it is characterised in that:The metal cylinder is stainless steel Or cylinder made of titanium coating platinum group oxide.
CN201610220533.XA 2015-09-20 2016-04-08 Healthy bath water device for making Active CN105692810B (en)

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CN201510600783 2015-09-20
CN2015106007831 2015-09-20

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CN105692810B true CN105692810B (en) 2018-05-29

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Publication number Priority date Publication date Assignee Title
CN105692810B (en) * 2015-09-20 2018-05-29 大连双迪创新科技研究院有限公司 Healthy bath water device for making
CN111115765A (en) * 2020-01-15 2020-05-08 福建工程学院 Bathing water generator

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US8470143B2 (en) * 2010-01-26 2013-06-25 Daniel Moroni Tucker Advanced chlorine generating system
CN101921032B (en) * 2010-09-10 2012-11-14 北京大学 Electrolytic deposition-membrane separation combined treatment device for electrolytic zinc rinse wastewater
KR101351223B1 (en) * 2011-09-28 2014-01-14 한국전력공사 Recovery process of metal ions from the seawater
US20140217022A1 (en) * 2013-02-01 2014-08-07 Masdar Institute Of Science And Technology Novel in-situ membrane cleaning using periodic electrolysis
CN203807281U (en) * 2014-05-09 2014-09-03 张志雄 Spline flange connector type seawater desalting equipment
CN104787938B (en) * 2015-03-31 2017-10-24 宁波方太厨具有限公司 It is a kind of effectively to remove the electrolyzed water machines of removing heavy metals
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