CN205527890U - Rich hydrogen water glass - Google Patents
Rich hydrogen water glass Download PDFInfo
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- CN205527890U CN205527890U CN201620287656.0U CN201620287656U CN205527890U CN 205527890 U CN205527890 U CN 205527890U CN 201620287656 U CN201620287656 U CN 201620287656U CN 205527890 U CN205527890 U CN 205527890U
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G19/00—Table service
- A47G19/22—Drinking vessels or saucers used for table service
- A47G19/2205—Drinking glasses or vessels
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/008—Mobile apparatus and plants, e.g. mounted on a vehicle
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/46115—Electrolytic cell with membranes or diaphragms
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The utility model relates to a rich hydrogen water glass belongs to life drinking water quality advanced treatment technology field. This water glass includes at least a pair of negative and positive electrodes, electrolysis power and cup for the negative and positive electrodes power supply, be equipped with the water permeability diaphragm between mated negative electrode and the positive electrode, the negative electrode, positive electrode and water permeability diaphragm encapsulate into an integral unit by insulated frame, integral unit establishes the lower part department in the cup and cuts apart into on the water storage cavity and cavity down with the cup, cavity department is located on the adjacent water storage to the negative electrode and adjacent cavity department is down located to the positive electrode, use, deposit the water contact in negative electrode and the cup, the positive electrode only passes through the infiltration water contact of water permeability diaphragm infiltration with the cup. Hydrogen -rich water can high -efficient safety be prepared to this water glass.
Description
Technical field
This utility model relates to a kind of hydrogen-rich watered glass for drinking, belongs to the water quality advanced processing technology field of Drinking Water.
Background technology
Water pollutes the pollutant mainly produced by mankind's activity to be caused, and it includes industrial pollution source, agricultural pollution source and domestic pollution source three parts.Increasingly the water aggravated pollutes, and the living safety of the mankind is constituted significant threat, becomes the major obstacles of human health, economy and social sustainable development.Investigating according to authoritative institution of the world, annual at least cause global 200d 00,000 people dead because drinking unhygienic water, therefore, water pollution is referred to as " world's number one killer ".Currently, water environment is exacerbated, seriously threat to life continuity, especially when burst natural and man-made calamities more so.The most poor and backward area, drink to clean relieved water is the most luxurious for general public.If the common people can be made all can to drink clean relieved water with means simple, cheap, efficient, when for the most immeasurable beneficence！
Domestic and international most of waterworks the most still uses the outmoded process of precipitation, filtration, chlorination, and river or subsoil water are simply processed into drinkable water.But, in the face of trade effluent, rural sewage and sanitary sewage wildness are spread unchecked and poured in life water source, waterworks can't bear the heavy load helpless.Adding tap water and arrive, through water transfer pipe network and high-rise storage tank, the additional pollution that drinking water terminal is brought from water factory, municipal tap water dare not say it is health.Especially, although tap water chlorination can effectively kill except pathogenic bacteria, but also can produce more halogenated hydrocarbon compound, the content of these chlorinated organics is multiplied, and is the significant source causing the mankind to suffer from various disease simultaneously.Even boiling tap water, what above-mentioned residue still drove does not goes, and the carcinogens such as nitrite and chloroform also can be made to increase.That is, even if the safety coefficient of drinking water is also the highest.
Since directly drinking public water supply is difficult to ensure that safety, water purifier are arisen at the historic moment, become common people's hard requirement.But, existing with city for tap water be source water purification of water quality product or drinking water related product, essentially medium absorption or use various bore filter film that water pollutant is intercepted the physical treatment technology filtered.Owing to activated carbon class adsorbing material is easy to saturated inefficacy, and various filter membrane is easy to be contaminated by bacterial or Organic substance blocks or damaged, and therefore practical situation is can not accomplish water pollutant as desired by Design Theory sufficiently cleaned up.In the face of the most serious source, water pollutes, existing with medium absorption or use various bore filter film that water pollutant is intercepted the physics mode water treatment technology filtered the most far to can guarantee that water quality reaching standard.It addition, traditional RO membrane reverse osmosis filter method is very serious to the waste of water resource, often purifies 1 liter of pure water and be accomplished by discharging 3 liters of concentration waste water.But, physics mode water treatment technology also has its points of course: generally do not generate toxic byproduct.
Comparatively speaking, though Water Treatment technique has the plurality of advantages such as the most efficient, and it is unsuitable for civilian terminal Drinking Water field.Trace it to its cause, one is that Water Treatment technique needs enough response time, and in daily life water occasion, and water purifier is from start water inlet to water outlet only several seconds or even shorter, pollutant time of staying in water purifier is the shortest, has had little time related chemistry reaction treatment at all；It two is that Water Treatment technique is generally with certain toxic and side effects.Such as, although chemical oxidation reaction can potent inactivation of bacterial, depth degradation Organic substance, remove the various harmful substances in water, but all kinds of Strong oxdiative factors that chemical oxidization method is generated are substantially non-selectivity, uncontrollable, generating, if dealing with improperly, the novel substance even strong carcinogen not having in the water of source most probably, jeopardizing safe drinking water on the contrary.And reduction reaction controls the improper Similar Problems that also brings along, such as nitrate and may be converted into strong carcinogen nitrite；Just because of this, have no so far in the drinking-water terminal popularization and application of Drinking Water purified treatment field especially family.
Fortunately, in daily life, drinking water needs often has at times, the feature of interval.Such as, family's three meals water and bathing peak are concentrated mainly on time morning, noon and afternoon；Wash water is then by week/time calculating.Daily life is drunk water storage apparatus, logical refers to the drinking water terminal with storage tank (tank, container), such as: 1) pipeline water cleaning systems end wall on-hook, desk-top or vertical drinking；2) RO water purification machine water outlet pressure store bucket (case), and watered glass for drinking, kettle；3) elevated tank that public supply mains skyscraper top layer is installed, even urban residents' groundwater abstraction are to the water tank on roof.The common problem that at present such system exists is that in water, bacterial micro-organism exceeds standard in storage tank, has a strong impact on water quality even abnormal flavour smelly.The solution that there is no so far.
Meanwhile, according to the applicant understood, the reproducibility of hydrogen is the most important chemical property of hydrogen, and many excellent specific properties such as the selectivity antioxidation of hydrogen and safety have caused the very big concern of international bio medical domain, and quickly form one research boom.A large amount of zooperies and clinical research prove, hydrogen can be treated 68 kinds of mankind's important diseases such as cerebral ischemia, metabolism syndrome, diabetes, arteriosclerosis, alzheimer disease, fatty liver, liver cirrhosis, rheumatoid arthritis, asthma, uremia, noise deaf, acute pancreatitis, tumor chemoradiotherapy side effect and be had clear and definite or potential therapeutic value.And the healthy and the most direct mode of disease treatment drinks hydrogen saturation water, or referred to as hydrogen rich water exactly to utilize hydrogen to promote.
It is modal method by water electrolysis being produced hydrogen rich water.But, there is oxidation reaction and reduction reaction in simultaneously equity inevitable to water electrolysis.Wherein, only cathode reaction be generate hydrogen, produce hydrogen rich water needed for.Anode reaction has no contribution not only for generating hydrogen water, generates unfavorable malicious synetion drunk such as such as ozone on the contrary in water.Especially when in the water of source containing various pollutant (such as chlorine residue), the electrochemical water treatment technology reacted as a kind of advanced oxidation, necessarily also can produce toxic and side effects in various degree.
Therefore, a kind of employing home terminal drinking-water need to be developed, water is carried out purified treatment producing hydrogen rich water simultaneously, prevent originally there is no the water tumbler of toxic byproduct owing to cell reaction generates in the water of source.
Utility model content
First of this utility model solution technical problem is that, not enough for prior art, proposes a kind of hydrogen-rich watered glass for drinking producing hydrogen rich water in safety.
Second of this utility model solution technical problem is that, on the basis of solving above-mentioned first technical problem, not enough for prior art, proposes a kind of at the hydrogen-rich watered glass for drinking carrying out less generation toxic byproduct in degradation water of drinking water the home terminal in water tumbler.
Applicant through repetition test and explores for many years, it is found that electrochemistry is as a kind of advanced oxidation water treatment technology, attached poison seondary effect is little far beyond conventional chemical water treatment technology, and electrochemistry water treatment technology can be carried out intensive treatment intensity by the adjustment of electrical quantity and reduce the response time.So, electrochemical water treatment technology has the certain potentiality overcoming physics water treatment technology weakness, can be used for Drinking Water purified treatment.
Electrochemical water treatment technology is to make polluter Direct Electrochemistry reaction occur on electrode or utilize electrode surface to produce strong oxidizing property active substance generation oxidation reaction and be converted. electrochemical techniques and be aided with the group technology of other high-level oxidation technologies, it is referred to as electrochemical system, including electrode electro-catalysis, electricity-Fenton, electricity-O3, sound-electric, optical-electronic etc..
Electro-chemical water processes and be unable to do without electrode effect, is specifically divided into electrode direct reaction and electrode indirect reaction.Electrode direct reaction refers to that pollutant are directly oxidated or reduced on electrode and remove from water.Direct Electrolysis can be divided into anodic process and cathodic process.Anodic process is exactly that pollutant change into the less material of toxicity or the material of easily biological-degradable in anode surface oxidation, even occurs Organic substance inorganization, thus reaches to cut down, remove the purpose of pollutant.Cathodic process is exactly that pollutant are removed in cathode surface reduction.
Electrode indirect reaction be then the redox materials utilizing electrochemistry to produce as reactant or catalyst, make pollutant change into the material that toxicity is less.Anode indirect reaction, in water, produced redox materials, generally includes following a few class: (1) has the chlorate of strong oxidizing property, hypochlorite etc.；Elecrtonegativity, can be removed by anode；(2) H2O2、O3The Strong oxdiative factors such as (standard electrode EMF 2.07, half-life 30-60min)；(3) electrochemical reaction produces strong oxidizing property and life-span extremely short intermediate, including e (solvated electron), OH, HO2·、·O2Deng free radical, based on OH, can be with degradation of organic substances.
But, electrochemical nature still belongs to chemical treatment technology, even toxic and side effects is the least, still has the risk of the Biological indicators reduction making water.At the unprecedented severe contamination of water environment, in conventional physical water purifier today the most unable to do what one wishes, again the probability that close examination research Water Treatment especially electrochemical water treatment technology is applied in Drinking Water purified treatment, associated with a kind of electrochemical treatments technique that can efficiently remove water pollutant, again non-toxic by-products of innovative development or even electrochemistry water treatment technology are collaborative with physisorptive filter technique, brand-new method for purifying water and device, be of great practical significance.
In order to solve above-mentioned first technical problem, inventor of the present utility model proposes following technical scheme on the basis of above-mentioned cognition: a kind of hydrogen-rich watered glass for drinking, including at least one pair of anodic-cathodic, the electrolysis power powered for described anodic-cathodic and cup, water penetration barrier film it is provided with between paired negative electrode and anelectrode, it is characterized in that: described negative electrode, anelectrode and water penetration barrier film are packaged into an integral unit by insulating frame, described integral unit is located at the bottom in described cup and described cup is divided into water storage upper chamber and lower chambers, described negative electrode is located at adjacent described water storage upper chamber and described anelectrode is located at adjacent lower chambers, in use, described negative electrode contacts with the water in described cup, the infiltration water that described anelectrode is only permeated by described water penetration barrier film with described cup contacts.
Above-mentioned hydrogen-rich watered glass for drinking technical scheme of the present utility model provides the benefit that: the infiltration water that the anelectrode of this utility model device is only permeated by water penetration barrier film with cup contacts, on the basis of the cell reaction ensureing this utility model device is normally carried out, anode direct oxidation reaction is transferred to carry out outside container (cup of water tumbler), reaction product of anode is drained outside container, will not return again to container internal contamination water quality.Meanwhile, the negative pollutant such as chlorine residue etc. in water, by anode voltage effect, it is also possible to through water penetration barrier film water in container, moves to the outer anode region of container.
It needs to be noted: anode direct oxidation reaction not need not, but anode reaction product (such as ozone) may produce toxic and side effects, some toxicity still it is likely to be of by anode direct oxidation reaction product including negative pollutant, anode is arranged external container by this utility model, and above-mentioned toxic byproduct is directly with regard to outer row；And give source water electrolysis product on anelectrode such as oxygen, ozone, chlorine etc. and discharge space greatly, directly can be emitted by outside, the water quality in container internal contamination container will not be returned again to through barrier film, will not remain in container in water, thus significantly reduce the toxic and side effects of above-mentioned Strong oxdiative thing.
Meanwhile, negative electrode is located at the bottom in cup inner bag and adjacent water storage upper chamber, generates hydrogen by negative electrode reaction, produce hydrogen rich water in a large number, producing hydrogen rich water, water can be carried out purified treatment simultaneously, containing various pollutant (such as chlorine residue) in source of degradation water, not produce toxic byproduct.Therefore, the negative pollutant in water, by negative electrode degraded and anelectrode voltage effect, move to the outer anode region of container, and in container, content is few, and comprehensive treatment effect is splendid.
This utility model is for solving above-mentioned second technical problem, and the improvement to technique scheme is: described water penetration barrier film is the water penetration barrier film that non-conductive material is made, and described water penetration barrier film has the permeable micropore of uniform pore size.
It should be noted that, this utility model device process to seem home terminal drinking-water, it is usually city for tap water, as described in the background art, water pollutes the most serious now, home terminal drinking-water has become as a kind of micro-polluted water (or perhaps special contamination water), and its polluter includes environmental pollution (such as pesticide residues etc.), the pollution of chlorination generation and pipeline secondary pollution etc..
Working mechanism and the beneficial effect of hydrogen-rich watered glass for drinking technical scheme disclosed in above-mentioned this utility model are presented below.
This utility model, by being arranged between cathode and anode by the water penetration barrier film of the micropore with uniform pore size, brings beyond conventional electrolysis course of reaction and forms the reaction of water body low pressure cold plasma discharge in water penetration barrier film in micropore, be analyzed as follows:
This utility model apparatus structure feature is to see Fig. 1, with water penetration barrier film for boundary, sets up the anodic-cathodic pair in the upper and lower both sides of water penetration barrier film separately: the adjacent described water storage upper chamber of negative electrode and the adjacent lower chambers of anelectrode.
After the decomposition voltage of electrolysis power puts on external electrode (anelectrode) and interior electrode (negative electrode), form following voltage landing relation:
The outer anelectrode of film (+) the pressure drop U3 of the anti-generation of water resistance between negative electrode in → pressure drop U2 → water penetration barrier film that between anelectrode and film, the voltage drop U1 of moisture film → water penetration barrier film direct impedance produces and container (cup of water tumbler).
In this utility model, the effect of water penetration barrier film is not only will to isolate inside and outside container, structure due to self: water penetration barrier film is the water penetration barrier film that non-conductive material is made, show as countless uniform micro on microcosmic crosses aquaporin region (having the micropore of uniform pore size), under decomposition voltage effect, micropore can also form in water penetration barrier film the reaction of water body low pressure cold plasma discharge.Low temperature plasma has the highest reactivity rich in electronics, ion, free radical and excited state molecule, electronics and ion, and the chemical reaction being difficult under usual conditions or speed is difficult to can be made to become the rapidest.
Traditional water body plasma discharge technology, for producing water body plasma discharge, imports gas often through outside in water, and imposes and add high intensity pulses voltage or hot conditions.nullPlasma discharge is then directed to the countless small water storage space of water penetration barrier film by this utility model to be carried out，Rely on anelectrode to water electrolysis liberation of hydrogen、The gas that oxygen evolution reaction generates，It is partially in film induction water body self to gasify (owing to anelectrode contacts with the infiltration water penetrating through water penetration barrier film in container，So，Anelectrode presses close to water penetration barrier film，The oxygen of anode reaction etc. are easily accessible membrane micropore and generate bubble in millipore water，In the narrow and small environment of membrane micropore，Bubble breaking produces localized hyperthermia's high pressure)，And then inspire efficient water body plasma discharge with minimum voltage，Hydroxyl free base class transient state oxidation factor is generated in water，The oxidisability extremely strong (exceeding ozone) of this hydroxyl radical free radical transient state oxidation factor existence time in water simultaneously is the most extremely short，Therefore water can be reduced directly to after rapidly the pollutant such as Organic substance in water (such as antibacterial) being formed extremely strong Degradation self rapid oxidation after generation，Do not stay any toxic and side effects.
Owing to conventional chemical water treatment technology is when purified treatment common people's daily life drinking water, all kinds of Strong oxdiative factors generated are substantially non-selectivity, uncontrollable, jeopardize safe drinking water, the strong carcinogen nitrite etc. that reduction reaction generates, processes occasion suitable for application in common people's daily life drink water purifying.Therefore, current conditions and conventional thinking limit the application in terms of common people's daily life drinking water of the Water Treatment technique.The uncontrollable of all kinds of Strong oxdiative factors that Conventional electrochemical water is generated by this utility model becomes controlled, this utility model utilizes these characteristics of hydroxy radical just, for city for this special micro-polluted water water quality characteristics of tap water, by ingehious design in structure, on the one hand in anode direct oxidation reaction being drawn out to container, the outside of water occurs, and gets rid of oxidation reaction toxic byproduct.On the other hand anode indirect oxidation effect is performed to ultimate attainment, it is achieved to its degree of depth of source water electrode and the purification of safety！
Summarize above-mentioned hydrogen-rich watered glass for drinking technical scheme of the present utility model to provide the benefit that: 1) make full use of electrochemical water treatment technology, to reach existing physics water treatment technology and be unable to reach, to the depth degradation of source water pollutant, the effect efficiently removed, it is drawn out to outside device carry out by anode direct oxidation reaction, suppression ozone generates, to reduce the risk generating toxic byproduct in container in water；2) rely primarily on hydroxy kind strong oxidizing property and the life-span is extremely short and the indirect electrochemical intermediate that has no side effect, realize desired electro-chemical water treatment effect；3) microorganism in water in cup, is inactivated by the electric field action of U3 between the negative electrode in water penetration barrier film and container.
This utility model improving further on the basis of technique scheme is: described water penetration barrier film is hydrophilic water penetration barrier film.
Water penetration barrier film of the present utility model is hydrophilic water penetration barrier film, and hydrophilic film surface can form hydrogen bond ordered structure with water, can improve fenestra water-filling wet face state, and beneficially in film, plasma discharge process is persistently carried out.
This utility model further improvement on the basis of technique scheme is: when using electric discharge, forms plasma discharge in described permeable micropore.
This utility model further improvement on the basis of technique scheme is: when using electric discharge, be respectively formed plasma discharge in each permeable micropore.
The shape of membrane micropore and pore size and uniformity are the biggest on plasma discharge impact in film.nullFor plasma group can be efficiently produced under ultralow discharge voltage，As shown in Figure 6，Water penetration barrier film employed in this utility model，When using electric discharge，Direction of an electric field passes through each permeable micropore，Faradaic current each micropore circulation in film between two electrodes，Be equivalent to a broad-area electrode to be divided into the small electrode of numerous tip-like，The electric discharge curvature making electrode reduces，Discharging efficiency is improved，Simultaneously，Plasma discharge is directed to the countless small water storage space of water penetration barrier film by this utility model to be carried out，Rely on water electrolysis liberation of hydrogen、The gas that oxygen evolution reaction generates，It is partially in film induction water body self gasification，And then inspire efficient water body plasma discharge with minimum voltage，Water body plasma discharge can be inspired，The transient state oxidation factor of great sterilizing ability is generated in water，It is greatly improved the degradation efficiency of pollutant in water body.
This utility model improving on the basis of technique scheme one is: have Sewage outlet in described lower chambers.
By having Sewage outlet in lower chambers, waste water and unified blowdown can be collected, maintain the cleaning using environment.
This utility model improving on the basis of technique scheme two is: be provided with physical absorption filtering layer between described water penetration barrier film and anelectrode.
Owing to being provided with physical absorption filtering layer between water penetration barrier film and anelectrode, physical absorption filtering layer can be carried out disinfection and regenerate, extend the use time.
This utility model improving on the basis of technique scheme three is: described electrolysis power is located at bottom of cup and is made as one with cup.
This utility model improving on the basis of technique scheme four is: described electrolysis power is located in an external base, is turned on by the concavo-convex conductive socket socket connection at the bottom of being separately positioned on glass and on base between described electrolysis power and anodic-cathodic.
This utility model improving on the basis of technique scheme five is: the permeable aperture of described water penetration barrier film is respectively less than equal to 2 millimeters and differ the most each other more than or equal to the permeable aperture size of all micropores in 1 nanometer and described water penetration barrier film and is less than 20%.
In this utility model device, if the permeable aperture of water penetration barrier film excessive (i.e. microporous space is excessive) is equivalent in a disguised form to increase electrode diameter (electrode curvature radius) and causes discharge in water to initiate excitation voltage to increase, and make generation bubble volume become to reduce greatly the catalytic specific surface area of gas-liquid two-phase.And the permeable aperture of water penetration barrier film too small (i.e. microporous space is too small), electrolysis aerogenesis can be made to occur or gas producing efficiency is extremely low, little the point discharge of numerous little radius of curvature electrode in each micropore can be caused in barrier film to a certain extent to be normally carried out.Therefore, through the repetition test of inventor, determine that permeable pore diameter range is 2 millimeter of-1 nanometer.
Accompanying drawing explanation
Below in conjunction with the accompanying drawings hydrogen-rich watered glass for drinking of the present utility model is described further.
Fig. 1 is the inside partial structurtes schematic diagram of the hydrogen-rich watered glass for drinking of this utility model embodiment one.
Fig. 2 is the inside partial structurtes schematic diagram of the hydrogen-rich watered glass for drinking of this utility model embodiment four.
Fig. 3 is the inside partial structurtes schematic diagram of the hydrogen-rich watered glass for drinking of this utility model embodiment five.
Fig. 4 is the inside partial structurtes schematic diagram of the hydrogen-rich watered glass for drinking of this utility model embodiment six.
Fig. 5 is the inside partial structurtes schematic diagram of the hydrogen-rich watered glass for drinking of this utility model embodiment seven.
Fig. 6 is the permeable microcellular structure schematic diagram in the water penetration barrier film of Fig. 1.
Detailed description of the invention
Embodiment one
The hydrogen-rich watered glass for drinking of the present embodiment, sees Fig. 1, including at least one pair of negative electrode 22 and anelectrode 23, the electrolysis power 3 powered for anodic-cathodic and cup 1, is provided with water penetration barrier film 21 between paired negative electrode 22 and anelectrode 23.
Negative electrode 22, anelectrode 23 and water penetration barrier film 21 are packaged into an integral unit by insulating frame 25, and integral unit is located at the bottom in cup 1 and cup 1 is divided into water storage upper chamber 13 and lower chambers 14.Negative electrode 22 is located at adjacent water storage upper chamber 13 and anelectrode 23 is located at adjacent lower chambers 14.In use, negative electrode 22 contacts with the water in cup 1, and the infiltration water that anelectrode 23 is only permeated by water penetration barrier film 21 with cup 1 contacts.
The water penetration barrier film 21 of the present embodiment is the water penetration barrier film that non-conductive material is made, and water penetration barrier film 21 has the permeable micropore of uniform pore size.The permeable micropore of uniform pore size is that the shape in pore size and hole is generally uniform, such as, is all the hole of same shape in a film, is the most all the hole of ellipse, the hole of triangle, etc..Pore size in one film is all the hole of same size, etc..
The infiltration water of this utility model device is successively to produce.Water membrane only it is clamped with between anelectrode 23 and the water penetration barrier film 21 of this utility model device, so, the anelectrode of this utility model device does not has water on remaining side, can reduce the reaction on anelectrode of the source water electrolysis the most especially outside cell reaction is normally carried out.Simultaneously, anelectrode presses close to water penetration barrier film, the oxygen of anode reaction etc. are easily accessible membrane micropore and generate bubble in millipore water, in the narrow and small environment of membrane micropore, bubble breaking produces localized hyperthermia's high pressure, it is partially in film induction water body self gasification, and then inspires efficient water body plasma discharge with minimum voltage, water generates hydroxyl free base class transient state oxidation factor.
The water penetration barrier film 21 of the present embodiment is the non-conductive material filter membranes such as monolayer microfiltration-nanofiltration.When using electric discharge, permeable micropore forms plasma discharge.Generate hydroxyl radical free radical plasma group in order to the most more, when using electric discharge, each permeable micropore is respectively formed plasma discharge.
In order to water penetration barrier film 21 obtains the micropore of uniform pore size, so that plasma preferably discharges in film, can be by being modified producing acquisition to water penetration barrier film 21, modified water penetration barrier film improves ultrafilter membrane hydrophilic, enhance the stain resistance of film, extend film service life, cold plasma discharge is mutually promoted with water simultaneously, can be effectively improved Organic substance in water degradation rate, also effectively prevent the deterioration being easily caused biological index because electric current density is excessive.It is the barrier film by making according to following steps that water penetration barrier film 21 has the micropore of uniform pore size:
1) by nanometer titanium dioxide titanium solution the ultraviolet case internal irradiation that temperature is 40 DEG C-60 DEG C 10-30 minute；
2) by the raw material component film liquid of following mass ratio:
PVDF:20%-30%
Porogen: 2-5%
Nano titanium oxide after step 1) irradiation: 2%-4%
Surfactant: 3%-5%
Solvent: 70%-80%；
3) the film liquid configured is passed through supersonic oscillations 20-40 minute；
4) spread to liquid film with knifing machine, liquid film is stood in atmosphere the 10-30 second, is then immersed in solidification liquid being frozen into barrier film；
5) barrier film soaks 10-40 minute in concentration is 10% alcohol water blend, is then placed in deionized water rinsing；
6) it is placed in barrier film to be applied with in the pure water tank of 10kv DC pulse high pressure and processes 1 hour.
Water penetration barrier film uses titania modified technology, by using irradiation technique to increase nano titanium oxide hydrophilic monomer at ultrafiltration membrane surface, improves ultrafilter membrane hydrophilic, the stain resistance of reinforcing membrane, prolonging service lifetime of film.Cold plasma discharge is mutually promoted with water simultaneously, can be effectively improved Organic substance in water degradation rate.
Sewage outlet 15 is had in the lower chambers 14 of the present embodiment.Hydrophilic water penetration barrier film selected by the water penetration barrier film 21 of the present embodiment.The permeable aperture of the water penetration barrier film 21 of the present embodiment differs less than 20% the most each other less than or equal to 2 millimeters and more than or equal to the permeable aperture size of all micropores in 1 nanometer and water penetration barrier film 21.Preferably ultrafilter membrane.
One, experiment 1
Tap water is manually filled in cup 1, as a example by the city in DaLian, China area supplies tap water, the DC source of the high level narrow spaces that electrolysis power 3 uses average voltage to be 40V, constant current 800mA is provided, water penetration barrier film 21 uses ultrafilter membrane, negative electrode 22 adjacent water storage upper chamber 13 and the adjacent lower chambers of anelectrode 23 14.
Source water remains chlorine residue and various harmful anion migrate to anode, pass water body discharge between barrier film entrance anode and film and fall.Total plate count ＜ 2CFU/ml in testing inspection, water；Phenol compounds ＜ 0.001 mg/L；Anion synthetic detergent ＜ 0.001mg/L；Carbon tetrachloride ＜ 0.001 mg/L；Chloroform ＜ 0.013mg/L, relative city, for tap water, well improves water quality.
In order to prevent anions and canons precipitate in electrode and the deposition fouling on water penetration barrier film 21 surface, electrolytic process is suitably switched the electrolysis power polarity being applied to paired electrode.
Embodiment two
The hydrogen-rich watered glass for drinking of the present embodiment is the improvement on the basis of embodiment one, is with the difference of embodiment one:
The present embodiment manually fills tap water in cup 1, as a example by still the city by DaLian, China area supplies tap water, electrolysis power 3 uses the forward voltage level component pulse-changing power more than backward voltage level, average voltage is 15V, water penetration barrier film 21 uses micro-filtration membrane, spacing δ between micro-filtration membrane and the anelectrode outside film 23 to be 15 millimeters.
Embodiment three
The hydrogen-rich watered glass for drinking of the present embodiment is the improvement on the basis of embodiment one, is with the difference of embodiment one: being positioned in the present embodiment on the anelectrode 23 outside water penetration barrier film 21 and have some through holes, water penetration barrier film 21 uses NF membrane.
The present embodiment is still as a example by the city in DaLian, China area supplies tap water, and spacing δ between water penetration barrier film 21 and the anelectrode outside barrier film 23 is 0 millimeter, 10 millimeters respectively and tests.
Embodiment four
The hydrogen-rich watered glass for drinking of the present embodiment is the improvement on the basis of above-described embodiment, and the difference of above-described embodiment is: as in figure 2 it is shown, be provided with physical absorption filtering layer 24 between the water penetration barrier film 21 of the present embodiment and anelectrode 23.Physical absorption filtering layer 24 is seed activity layer of charcoal, sintering activity layer of charcoal, activated carbon fiber layers, the microfiltration material layer being made up of PP cotton or the microfiltration material layer being made up of porous ceramics.
Embodiment five
The hydrogen-rich watered glass for drinking of the present embodiment is the improvement on the basis of above-described embodiment, is with the difference of above-described embodiment: as it is shown on figure 3, the cup 1 of the present embodiment is made up of metal material, and negative electrode 22 is located at outside integral unit 25 and is made as one with cup 1.
Embodiment six
The hydrogen-rich watered glass for drinking of the present embodiment is the improvement on the basis of above-described embodiment, is with the difference of above-described embodiment: as shown in Figure 4, and the electrolysis power 3 of the present embodiment is located at bottom of cup and is made as one with cup 1.
Embodiment seven
The hydrogen-rich watered glass for drinking of the present embodiment is the improvement on the basis of above-described embodiment, it is with the difference of above-described embodiment: as shown in Figure 5, the electrolysis power 3 of the present embodiment is located in an external base, is turned on by the concavo-convex conductive socket socket connection at the bottom of being separately positioned on glass and on base between electrolysis power 3 and anodic-cathodic.
Hydrogen-rich watered glass for drinking of the present utility model is not limited to the concrete technical scheme described in above-described embodiment, such as: 1) electrolysis power 3 is the direct current pulse power source of high level narrow spaces or the forward voltage level component pulse-changing power more than backward voltage level；2) anelectrode 23 is to be composited with titanium material coating platinum group oxide by activated carbon or activated carbon；3) technical scheme of each embodiment above-mentioned of the present utility model can form new technical scheme with combined crosswise each other, etc..The technical scheme that all employing equivalents are formed is the protection domain that this utility model requires.
Claims (10)
1. a hydrogen-rich watered glass for drinking, including at least one pair of anodic-cathodic, the electrolysis power powered for described anodic-cathodic and cup, water penetration barrier film it is provided with between paired negative electrode and anelectrode, it is characterized in that: described negative electrode, anelectrode and water penetration barrier film are packaged into an integral unit by insulating frame, described integral unit is located at the bottom in described cup and described cup is divided into water storage upper chamber and lower chambers, described negative electrode is located at adjacent described water storage upper chamber and described anelectrode is located at adjacent lower chambers, in use, described negative electrode contacts with the water in described cup, the infiltration water that described anelectrode is only permeated by described water penetration barrier film with described cup contacts.
Hydrogen-rich watered glass for drinking the most according to claim 1, it is characterised in that: described water penetration barrier film is the water penetration barrier film that non-conductive material is made, and described water penetration barrier film has the permeable micropore of uniform pore size.
Hydrogen-rich watered glass for drinking the most according to claim 2, it is characterised in that: described water penetration barrier film is hydrophilic water penetration barrier film.
Hydrogen-rich watered glass for drinking the most according to claim 3, it is characterised in that: when using electric discharge, described permeable micropore forms plasma discharge.
Hydrogen-rich watered glass for drinking the most according to claim 4, it is characterised in that: when using electric discharge, each permeable micropore is respectively formed plasma discharge.
6. according to the arbitrary described hydrogen-rich watered glass for drinking of claim 1 to 5, it is characterised in that: have Sewage outlet in described lower chambers.
7. according to the arbitrary described hydrogen-rich watered glass for drinking of claim 1 to 5, it is characterised in that: it is provided with physical absorption filtering layer between described water penetration barrier film and anelectrode.
8. according to the arbitrary described hydrogen-rich watered glass for drinking of claim 1 to 5, it is characterised in that: described electrolysis power is located at bottom of cup and is made as one with cup.
9. according to the arbitrary described hydrogen-rich watered glass for drinking of claim 1 to 5, it is characterised in that: described electrolysis power is located in an external base, is turned on by the concavo-convex conductive socket socket connection at the bottom of being separately positioned on glass and on base between described electrolysis power and anodic-cathodic.
10. according to the arbitrary described hydrogen-rich watered glass for drinking of claim 1 to 5, it is characterised in that: the permeable aperture of described water penetration barrier film is respectively less than equal to 2 millimeters and differs the most each other less than 20% more than or equal to the permeable aperture size of all micropores in 1 nanometer and described water penetration barrier film.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2015105976344 | 2015-09-20 | ||
| CN201510597634 | 2015-09-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205527890U true CN205527890U (en) | 2016-08-31 |
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ID=56219379
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610215331.6A Active CN105692806B (en) | 2015-09-20 | 2016-04-08 | Hydrogen-rich water glass |
| CN201620287656.0U Withdrawn - After Issue CN205527890U (en) | 2015-09-20 | 2016-04-08 | Rich hydrogen water glass |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610215331.6A Active CN105692806B (en) | 2015-09-20 | 2016-04-08 | Hydrogen-rich water glass |
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| Country | Link |
|---|---|
| CN (2) | CN105692806B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105692806A (en) * | 2015-09-20 | 2016-06-22 | 大连双迪创新科技研究院有限公司 | Hydrogen-rich drinking cup |
| CN106473542A (en) * | 2016-11-09 | 2017-03-08 | 李宁 | A kind of safe hydrogen-rich water tumbler |
| CN106978608A (en) * | 2017-04-18 | 2017-07-25 | 深圳氢爱天下健康科技控股有限公司 | A kind of hydrogen-rich hydrogenesis machine |
| CN107981666A (en) * | 2017-12-27 | 2018-05-04 | 浙江致善新能源科技有限公司 | A kind of new hydrogen-rich cup |
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| CN106063664B (en) * | 2016-07-29 | 2018-05-04 | 南京中脉科技发展有限公司 | One kind sterilization hydrogen-rich cup |
| CN106063665B (en) * | 2016-07-29 | 2018-05-04 | 南京中脉科技发展有限公司 | A kind of hydrogen-rich cup |
| CN106119889A (en) * | 2016-07-30 | 2016-11-16 | 广州市宜康电子科技有限公司 | A kind of hydrogen rich water generating means |
| CN106263952A (en) * | 2016-08-22 | 2017-01-04 | 李向华 | A kind of separate type electrolysis cup |
| CN106380025A (en) * | 2016-08-31 | 2017-02-08 | 福建金源泉科技发展有限公司 | Nitrite-resistant water purifier filter core |
| CN106430762A (en) * | 2016-11-09 | 2017-02-22 | 上海辨洁环保科技有限公司 | Safe hydrogen-rich water glass |
| CN108113390A (en) * | 2016-12-26 | 2018-06-05 | 郑州诚合信息技术有限公司 | A kind of self-priming cup |
| CN107512761A (en) * | 2017-10-11 | 2017-12-26 | 立宝（清远）实业有限公司 | A kind of hydrogen-rich electrolysis unit |
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| CN107555550A (en) * | 2017-10-11 | 2018-01-09 | 立宝（清远）实业有限公司 | A kind of fluid flow channel structure of the electrode accommodating chamber of hydrogen-rich electrolysis unit |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130024109A (en) * | 2011-08-30 | 2013-03-08 | (주)이피엔씨테크 | Electrolytically ionized water generator |
| CN103936111B (en) * | 2014-04-12 | 2016-08-17 | 大连双迪创新科技研究院有限公司 | Water purifier auxiliary purification device |
| CN103936109B (en) * | 2014-04-12 | 2016-08-17 | 大连双迪创新科技研究院有限公司 | Drinking-water Electrowinning device |
| CN203938504U (en) * | 2014-04-12 | 2014-11-12 | 大连双迪创新科技研究院有限公司 | Drinking-water Electrowinning device and apply the equipment of this device |
| CN105692806B (en) * | 2015-09-20 | 2019-03-08 | 大连双迪创新科技研究院有限公司 | Hydrogen-rich water glass |
-
2016
- 2016-04-08 CN CN201610215331.6A patent/CN105692806B/en active Active
- 2016-04-08 CN CN201620287656.0U patent/CN205527890U/en not_active Withdrawn - After Issue
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105692806A (en) * | 2015-09-20 | 2016-06-22 | 大连双迪创新科技研究院有限公司 | Hydrogen-rich drinking cup |
| CN105692806B (en) * | 2015-09-20 | 2019-03-08 | 大连双迪创新科技研究院有限公司 | Hydrogen-rich water glass |
| CN106473542A (en) * | 2016-11-09 | 2017-03-08 | 李宁 | A kind of safe hydrogen-rich water tumbler |
| CN106978608A (en) * | 2017-04-18 | 2017-07-25 | 深圳氢爱天下健康科技控股有限公司 | A kind of hydrogen-rich hydrogenesis machine |
| CN107981666A (en) * | 2017-12-27 | 2018-05-04 | 浙江致善新能源科技有限公司 | A kind of new hydrogen-rich cup |
| CN107981666B (en) * | 2017-12-27 | 2024-01-30 | 藤田(上海)生物科技有限公司 | Novel hydrogen-rich water cup |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105692806B (en) | 2019-03-08 |
| CN105692806A (en) | 2016-06-22 |
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