CN105692809A - Alkaline bath water preparing apparatus - Google Patents

Alkaline bath water preparing apparatus Download PDF

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Publication number
CN105692809A
CN105692809A CN201610220429.0A CN201610220429A CN105692809A CN 105692809 A CN105692809 A CN 105692809A CN 201610220429 A CN201610220429 A CN 201610220429A CN 105692809 A CN105692809 A CN 105692809A
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CN
China
Prior art keywords
water
barrier film
penetration barrier
anelectrode
carbon filter
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Pending
Application number
CN201610220429.0A
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Chinese (zh)
Inventor
肖志邦
李烨
滕茂友
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Dalian Shuangdi New Technology Research Institute Co Ltd
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Dalian Shuangdi New Technology Research Institute Co Ltd
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Publication of CN105692809A publication Critical patent/CN105692809A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Supply & Treatment (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Molecular Biology (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Water Treatment By Sorption (AREA)
  • Cosmetics (AREA)

Abstract

The invention relates to an alkaline bath water preparing apparatus which comprises a water container, a pair of positive electrode and negative electrode and an electrolysis power supply. The water container is provided with a water inlet and a bath water outlet; and the electrolysis power supply is used for supplying power for the negative electrode and positive electrode. The water inlet of the water container is connected with public supply tap water; a water-permeable diaphragm is arranged between the negative electrode and the positive electrode and the positive electrode is isolated from the water container through the water-permeable diaphragm; activated carbon filter element coating the positive electrode completely is arranged on the outer side of the positive electrode, and is attached onto the water-permeable diaphragm. During use of the alkaline bath water preparing apparatus, the negative electrode is in contact with water of the water container, and the positive electrode is in contact with the water container via water permeated from the water-permeable diaphragm. Contaminants such as residual chlorine in water can be removed safely, people's requirements for health bath can be met by application of the alkaline bath water preparing apparatus with a little or without shampoo and bath cream.

Description

Alkalescence bath water device for making
Technical field
The present invention relates to a kind of alkalescence bath water device for making, belong to the water quality advanced processing technology field of domestic water。
Background technology
Currently, water environment exacerbated, but domestic and international most of waterworks still adopts the outmoded process of precipitation, filtration, chlorination so far, river or subsoil water is simply processed。But, in the face of trade effluent, rural sewage and sanitary sewage wildness are spread unchecked and poured in life water source, waterworks can't bear the heavy load helpless。
Along with the contaminated situation of tap water is on the rise, the mankind are about the problem also growing interest of own health, and the health problem of shower water increasingly attracts much attention, and develop and exploitation shower water filter has wide market prospect。
In daily life, the micro polluting substance in family's water supply enters human bodies typically via three kinds of channels: drinks, breathe and skin absorption。In shower process, the polluter that we absorb is much more more than in drinking water。During shower, hot water opens the pore on skin, remains chlorine residue and other polluters will be availed oneself of the opportunity to get in water。Polluter is absorbed by skin, then immediately proceeds to blood circulation, just as drinking water enters blood circulation round by digestive system, has same harm。Another noticeable place has sucked substantial amounts of steam when being have a bath, and causes human body to be easy to suck chlorine and other aquatic gases。
It is true that people is by breathing the chemical substance ratio many 6~80 times entered sucked from oral cavity。Radon in water, can evaporate after heating, enters human body by breathing, and long term accumulation can form pulmonary carcinoma。The volatile material contained in water is volatile organic matter (VOCs) mostly, and the important channel that two harm being can not be ignored is healthy is taken in skin absorption and breathing。On the other hand, shampoo, bath gel contain harmful or even carcinogenic chemical all in various degree, should reduce as far as possible or even avoid to use。
Existing market finding showering filter product, it is the pure physical cleaning mode adding special filter (such as calcium sulfite, KDF, solid layer of charcoal, high energy activation stone filter material etc.) with water pollutants such as Adsorption chlorine residue, there is the easily full deficiencies such as needing often replacing that lost efficacy such as limited capacity, filtrate。
Summary of the invention
The invention solves the problems that and technical problem is that: provide and a kind of can remove the pollutant such as chlorine residue and radon in water, the device for making of healthy alkalescence bath water can be produced again。
In order to solve above-mentioned technical problem, the technical scheme that the present invention proposes is: a kind of alkalescence bath water device for making, crosses water container, paired negative electrode and anelectrode, electrolysis power for described negative electrode and anelectrode are powered including what be provided with water inlet and bath water outlet;Being provided with the water penetration barrier film that non-conducting material is made between described negative electrode and anelectrode, anelectrode is separated by described water penetration barrier film with crossing water container;Being provided with the active carbon filter core of this anelectrode completely coated outside described anelectrode, described water penetration barrier film is close to the outer surface of active carbon filter core so that described active carbon filter core separates with crossing water container;During use, described negative electrode contacts with the water of crossing of described water container excessively, and described anelectrode only contacts with the described excessively infiltration water that water container is oozed out by water penetration barrier film。
Preferably, described active carbon filter core is provided with outlet of sewer。
The working mechanism of the present invention and the beneficial effect brought are presented below:
Described water container of crossing is with water penetration barrier film for boundary, and paired negative electrode and anelectrode set up separately in water penetration barrier film both sides, and described negative electrode is crossing in water container, and described anelectrode is to cross water container outer and be coated with active carbon filter core at its outer surface。
Heretofore described anelectrode only contacts (anelectrode does not directly contact) with the water crossing water container with the infiltration water penetrating through water penetration barrier film in water container excessively, the chlorate, the discharge of the hypochlorous acid salt Strong oxdiative factor that generate will be likely to simultaneously, ozone is suppressed to generate, to reduce the risk generating toxic byproduct in container in water。And the present invention transferred to anode direct oxidation reaction and carries out outside water container, in the water of source, chlorine residue and radon shift to anelectrode, are tightly held by activated carbon through water penetration isolating membrane and are likely to be discharged, and will not return again to container internal contamination water quality。
In the present invention, the structure of water penetration barrier film shows as the aquaporin region excessively of countless permeable micropore on microcosmic, owing to water penetration barrier film is that non-conductive material is made, thus produce voltage drop in aquaporin in crossing of permeable micropore, namely after putting on external electrode (anelectrode) and interior electrode (negative electrode) when the decomposition voltage of electrolysis power, form following voltage landing relation: the outer anelectrode of water penetration barrier film (+) the voltage drop U3 of the anti-generation of water resistance between pressure drop U2 → water penetration barrier film and the negative electrode crossed in water container that between → anelectrode and water penetration barrier film, the voltage drop U1 of moisture film → water penetration barrier film direct impedance produces。
And anelectrode only contacts with the infiltration water of water penetration barrier film, liberation of hydrogen during such water electrolysis, the gas that oxygen evolution reaction generates easily enters crossing in aquaporin and generating bubble in the water crossed in aquaporin of permeable micropore, in the narrow and small environment crossed in aquaporin of the permeable micropore of water penetration barrier film, bubble is easy to broken thus producing localized hyperthermia's high pressure, and then inspire efficient water body plasma discharge with minimum voltage, in water penetration barrier film and in the water of water penetration barrier film neighboring area, (plasma is and solid-state the plasma of generation hydroxyl free base class transient state oxidation factor, liquid, gaseous state is in material the 4th state of same level, low temperature plasma is rich in electronics, ion, free radical and excited state molecule, electronics and ion have significantly high reactivity, the chemical reaction being difficult under usual conditions or speed is difficult to can be made to become very rapid, plasma group is generated by water body electric discharge, can be greatly improved in water body the degradation efficiency of pollutant), the oxidisability of this hydroxyl radical free radical transient state oxidation factor is extremely strong, there is extraordinary bactericidal effect, can join in water outlet, the existence time in water is shorter again simultaneously, can direct-reduction be water thus not staying any toxic and side effects after sterilization。
Therefore in the present invention, in the water of source, chlorine residue and radon are shifted to and are shifted to anelectrode through water penetration isolating membrane and be tightly held by activated carbon and be likely to be discharged, noxious pollutant (anion) is with current traverse water penetration isolating membrane and active carbon filter core, degraded by the direct oxidation of anelectrode surface, thus obtain being alkalescence, oxidation-reduction potential be bear, the alkaline purified water of the scrubbing that is suitable for deoiling。The alkaline bath water that the present invention produces all eliminates the pollutant such as the chlorine residue in tap water and radon, and do not need the chemical detergents such as shampoo, bath gel and liquid detergent in use, supply water and the micro polluting substance entrance human body in chemical detergent thus avoiding family when wanting bathing。
In order to improve plasma discharge characteristic in film further, it is possible to make described water penetration barrier film all adopt hydrophilic barrier film。Hydrophilic film surface can form hydrogen bond ordered structure with water, it is possible to improves fenestra water-filling wet face state, is conducive to plasma discharge process in film to be performed continuously over。
Preferably, the pore size of the permeable micropore of described water penetration barrier film and shape are essentially identical。
In the present invention, if the aperture of the permeable micropore of water penetration barrier film is excessive (namely microporous space is excessive), it is equivalent to and in a disguised form increases electrode diameter (electrode curvature radius) and cause the initial excitation voltage of discharge in water to increase, and make generation bubble volume become to reduce greatly the catalytic specific surface area of gas-liquid two-phase。And the aperture of the permeable micropore of water penetration barrier film too small (namely crossing aquaporin too small), electrolysis aerogenesis can be made to occur or gas producing efficiency is extremely low, the little permeable aperture that electrolysis aerogenesis can be made to a certain extent to cannot be introduced into micropore, so that plasma discharge cannot be normally carried out。Therefore, through the repetition test of inventor, it is determined that the pore diameter range of the permeable micropore of described water penetration barrier film is 2 millimeters~1 nanometer, and the aperture size of the permeable micropore of described water penetration barrier film differs each other each other less than 20%。
The shape uniformity of membrane micropore and the uniformity of pore size are very big on plasma discharge impact in film。For better more generation hydroxyl radical free radical plasma group, it is preferred that in use, each permeable micropore of described water penetration barrier film is respectively formed plasma discharge。So when using electric discharge, direction of an electric field between anodic-cathodic can pass through the plasma group of each permeable micropore, all mistake in aquaporin that plasma discharge is directed to water penetration barrier film carries out, thus water body plasma discharge can be inspired with minimum voltage, water generates the transient state oxidation factor of a large amount of great sterilizing ability, can be greatly improved in water body the degradation efficiency of pollutant, better carry out sterilizing etc.。
In order to better obtain the micropore of uniform pore diameter, and improve the hydrophilic of barrier film further, thus producing the more plasma group transient state oxidation factor of more great sterilizing ability (the more plasma group mean to generate in water), heretofore described water penetration barrier film preferably employs the barrier film that following method of modifying prepares:
1) by nanometer titanium dioxide titanium solution the ultraviolet case internal irradiation that temperature is 40 DEG C-60 DEG C 10-30 minute;
2) by the raw material component film liquid of following mass ratio:
PVDF:20%-30%
Porogen: 2-5%
Nano titanium oxide after step 1) irradiation: 2%-4%
Surfactant: 3%-5%
Solvent: 70%-80%;
3) the film liquid configured is passed through supersonic oscillations 20-40 minute;
4) spread to liquid film with knifing machine, liquid film is stood in atmosphere the 10-30 second, is then immersed in solidification liquid and is frozen into water penetration barrier film;
5) described barrier film is soak 10-40 minute in 10% alcohol water blend in concentration, is then placed in deionized water and rinses;
6) described barrier film is placed in the pure water tank being applied with 10kv DC pulse high pressure and processes 1 hour。
Further, since water penetration barrier film obtains the clamping protection of paired electrode, it have been experienced that, this water penetration barrier film in use will not be scrapped because of premature failure such as damaged or obstructions, remains reliable and stable duty。
Preferably, described electrolysis power is the direct current pulse power source of high level narrow spaces or the forward voltage level component pulse-changing power more than backward voltage level。
Improving further of technique scheme is: described water container of crossing includes the metal cylinder of tubulose and is arranged on the insulated enclosure end cap at described metal cylinder two ends, described metal cylinder doubles as negative electrode, described water penetration barrier film completely covers and is laid in activated-carbon filter core outer surface, described active carbon filter core is cylindrical and is positioned at described metal cylinder, and described anelectrode, active carbon filter core and metal cylinder are arranged concentrically。So, the more compact structure of apparatus of the present invention can be made, and the area of yin, yang electrode compares other structures of same volume more greatly, such that it is able to improve electrolytic efficiency。Further, described water inlet and bath water outlet were separately positioned on the different insulative end cover at two ends of water container。
Preferably, described outlet of sewer is arranged on the end of active carbon filter core, and this end is positioned on active carbon filter core near one end of bath water exit position。
Preferably, described electrolysis power is the direct current pulse power source of high level narrow spaces or the forward voltage level component pulse-changing power more than backward voltage level。
Preferably, the electrode that described positive electricity extremely titanium material coating platinum group oxide is made。
Preferably, described metal cylinder is rustless steel or the titanium material coating cylinder made of platinum group oxide。
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the invention will be further described。
Fig. 1 is the structural representation of the embodiment of the present invention one。
Fig. 2 is the structural representation of the embodiment of the present invention two。
Detailed description of the invention
Embodiment one
The alkaline bath water device for making of the present embodiment is as shown in Figure 1, including water container 1, be arranged on negative electrode 2 paired in water container 1 and anelectrode 3 and the electrolysis power (not shown) for negative electrode 2 and anelectrode 3 are powered, cross water container 1 and there is the water inlet 1-1 being connected for running water pipe with city and bath water exports 1-2;Being provided with water penetration barrier film 5 that non-conducting material makes between negative electrode 2 and anelectrode 3 so that negative electrode 2 and anelectrode 3 are completely separated, namely water penetration barrier film is divided into cathode chamber and anode chamber by crossing water container;Being provided with the active carbon filter core 4 of this anelectrode 3 completely coated outside anelectrode 3, the outer surface of active carbon filter core 4 is close to by water penetration barrier film 5;Crossing water container 1 to be square, water inlet 1-1 and bath water outlet 1-2 was separately positioned on upper surface and the lower surface of water container 1;Cross and water container 1 has window, the full compress of water penetration barrier film 5 is located on window, and active carbon filter core 4 and the sidewall crossing water container 1 are close to, and water inlet 1-1 and bath water outlet 1-2 was respectively positioned on another sidewall of water container 1, and connect with cathode chamber, active carbon filter core 4 is provided with outlet of sewer 1-3。
Outlet of sewer 1-3 is preferably provided at the end of active carbon filter core 4, and this end is positioned on active carbon filter core 4 near one end of bath water outlet 1-2 position。
Negative electrode paired in the present embodiment and anelectrode can be a pair, it is also possible to be multipair, and the increase of quantity is to improve electrolytic efficiency by electrode。
The barrier film essentially identical in order to improve the ionic discharge reaction in film, the pore size of the preferred permeable micropore of water penetration barrier film 5 and shape。Further, it is preferable that range of aperture size is 2 millimeters~1 nanometer, and the minimum permeable aperture of maximum permeable aperture ratio value differ within 20%, (be namely not more than 20%) barrier film。
The uniform water penetration barrier film 5 in permeable aperture in order to obtain micropore, can adopt known physically or chemically Technology that existing ultrafilter membrane, micro-filtration membrane or NF membrane are modified, the such as shaping of fenestra Regularization, optically catalytic TiO 2, extremely narrow high-voltage pulse to film pretreatment, etc.。In the present embodiment, water penetration barrier film 5 preferably employs the barrier film that following method of modifying prepares:
1) by nanometer titanium dioxide titanium solution the ultraviolet case internal irradiation that temperature is 40 DEG C-60 DEG C 10-30 minute;
2) by the raw material component film liquid of following mass ratio:
PVDF:20%-30%
Porogen: 2-5%
Nano titanium oxide after step 1) irradiation: 2%-4%
Surfactant: 3%-5%
Solvent: 70%-80%;
3) the film liquid configured is passed through supersonic oscillations 20-40 minute;
4) spread to liquid film with knifing machine, liquid film is stood in atmosphere the 10-30 second, is then immersed in solidification liquid and is frozen into barrier film;
5) described barrier film is soak 10-40 minute in 10% alcohol water blend in concentration, is then placed in deionized water and rinses;
6) described barrier film is placed in the pure water tank being applied with 10kv DC pulse high pressure and processes 1 hour。
The present embodiment can also do following improvement: 1) direct current pulse power source of the preferred high level narrow spaces of electrolysis power or forward voltage level are more than the component pulse-changing power of backward voltage level。
2) electrode that positive electricity extremely titanium material coating platinum group oxide is made。
3) water penetration barrier film 5 is hydrophilic water penetration barrier film。
4) in use, each permeable micropore of water penetration barrier film 5 is respectively formed plasma discharge。
Embodiment two
The present embodiment is the improvement on embodiment one basis, it is different in that with embodiment one: as shown in Figure 2, cross water container 1 include the metal cylinder of tubulose and be arranged on the insulated enclosure end cap at metal cylinder two ends, metal cylinder doubles as negative electrode, active carbon filter core 4 is positioned at metal cylinder, water penetration barrier film 5 completely covers and is laid in active carbon filter core 4 outer surface, and active carbon filter core 4 is cylindrical, and anelectrode 3, active carbon filter core 4 and metal cylinder are arranged concentrically;Active carbon filter core 4 is provided with outlet of sewer 1-3。So, the more compact structure of apparatus of the present invention can be made, and the area of yin, yang electrode compares other structures of same volume more greatly, such that it is able to improve electrolytic efficiency。In the present embodiment, water inlet 1-1 and bath water outlet 1-2 was separately positioned on the insulated enclosure end cap at water container top and the insulated enclosure end cap of bottom。
The cylinder that in the present embodiment, the preferred rustless steel of metal cylinder or titanium material coating platinum group oxide are made。
The present invention is not limited to the concrete technical scheme described in above-described embodiment, and in addition to the implementation, the present invention can also have other embodiments, all employings to be equal to the technical scheme replacing formation, is the protection domain of application claims。

Claims (10)

1. an alkaline bath water device for making, crosses water container, paired negative electrode and anelectrode, electrolysis power for described negative electrode and anelectrode are powered including what be provided with water inlet and bath water outlet;It is characterized in that: between described negative electrode and anelectrode, be provided with the water penetration barrier film that non-conducting material is made, being provided with the active carbon filter core of this anelectrode completely coated outside described anelectrode, described water penetration barrier film is close to the outer surface of active carbon filter core so that described active carbon filter core separates with crossing water container;During use, described negative electrode contacts with the water of crossing of described water container excessively, and described anelectrode only contacts with the described excessively infiltration water that water container is oozed out by water penetration barrier film。
2. alkalescence bath water device for making according to claim 1, it is characterized in that: described water container of crossing includes the metal cylinder of tubulose and is arranged on the insulated enclosure end cap at described metal cylinder two ends, described metal cylinder doubles as negative electrode, described water penetration barrier film completely covers and is laid in activated-carbon filter core outer surface, described active carbon filter core is cylindrical and is positioned at described metal cylinder, and described anelectrode, active carbon filter core and metal cylinder are arranged concentrically。
3. alkalescence bath water device for making according to claim 1, it is characterised in that: pore size and the shape of the permeable micropore of described water penetration barrier film are all essentially identical。
4. alkalescence bath water device for making according to claim 1, it is characterised in that: described water penetration barrier film is hydrophilic water penetration barrier film。
5. the arbitrary described alkaline bath water device for making according to claim 1-4, it is characterised in that: the range of aperture size of the permeable micropore of described water penetration barrier film is 2 millimeters~1 nanometer, and aperture size differs each other each other less than 20%。
6. the arbitrary described alkaline bath water device for making according to claim 1-4, it is characterised in that: described electrolysis power is the direct current pulse power source of high level narrow spaces or the forward voltage level component pulse-changing power more than backward voltage level。
7. the arbitrary described alkaline bath water device for making according to claim 1-4, it is characterised in that: the electrode that described positive electricity extremely titanium material coating platinum group oxide is made。
8. alkalescence bath water device for making according to claim 2, it is characterised in that: described metal cylinder is rustless steel or the titanium material coating cylinder made of platinum group oxide。
9. the arbitrary described alkaline bath water device for making according to claim 1-4, it is characterised in that: described active carbon filter core is provided with outlet of sewer。
10. the arbitrary described alkaline bath water device for making according to claim 1-4, it is characterised in that: in use, each permeable micropore of described water penetration barrier film is respectively formed plasma discharge。
CN201610220429.0A 2015-09-20 2016-04-08 Alkaline bath water preparing apparatus Pending CN105692809A (en)

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Application Number Priority Date Filing Date Title
CN201510599509 2015-09-20
CN2015105995097 2015-09-20

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CN201620301020.7U Active CN205527898U (en) 2015-09-20 2016-04-08 Device is got to basicity bathing water preparing

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105692809A (en) * 2015-09-20 2016-06-22 大连双迪创新科技研究院有限公司 Alkaline bath water preparing apparatus

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Publication number Priority date Publication date Assignee Title
CN101805046A (en) * 2010-03-10 2010-08-18 肖志邦 Alkali reductive water diaphragm-free electrolysis device
CN201842680U (en) * 2010-10-29 2011-05-25 肖志邦 Electrolytic water quality regulator
CN103936114A (en) * 2014-04-12 2014-07-23 大连双迪创新科技研究院有限公司 Auxiliary cleaning device of water purifier
CN103932358A (en) * 2014-04-12 2014-07-23 大连双迪创新科技研究院有限公司 Fruit and vegetable cleaning machine
CN203833744U (en) * 2014-04-12 2014-09-17 大连双迪科技股份有限公司 Commercial water dispenser
CN203833687U (en) * 2014-04-12 2014-09-17 大连双迪科技股份有限公司 Healthy water dispenser
CN205527898U (en) * 2015-09-20 2016-08-31 大连双迪创新科技研究院有限公司 Device is got to basicity bathing water preparing

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805046A (en) * 2010-03-10 2010-08-18 肖志邦 Alkali reductive water diaphragm-free electrolysis device
CN201842680U (en) * 2010-10-29 2011-05-25 肖志邦 Electrolytic water quality regulator
CN103936114A (en) * 2014-04-12 2014-07-23 大连双迪创新科技研究院有限公司 Auxiliary cleaning device of water purifier
CN103932358A (en) * 2014-04-12 2014-07-23 大连双迪创新科技研究院有限公司 Fruit and vegetable cleaning machine
CN203833744U (en) * 2014-04-12 2014-09-17 大连双迪科技股份有限公司 Commercial water dispenser
CN203833687U (en) * 2014-04-12 2014-09-17 大连双迪科技股份有限公司 Healthy water dispenser
CN205527898U (en) * 2015-09-20 2016-08-31 大连双迪创新科技研究院有限公司 Device is got to basicity bathing water preparing

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Application publication date: 20160622