CN105688598A - Adsorption method for purifying asphalt fume and practical purifier - Google Patents
Adsorption method for purifying asphalt fume and practical purifier Download PDFInfo
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- CN105688598A CN105688598A CN201511013162.XA CN201511013162A CN105688598A CN 105688598 A CN105688598 A CN 105688598A CN 201511013162 A CN201511013162 A CN 201511013162A CN 105688598 A CN105688598 A CN 105688598A
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- flue gas
- adsorbent
- depurator
- filter bag
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/02—Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/0027—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
- B01D46/0036—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/56—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition
- B01D46/58—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in parallel
- B01D46/60—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in parallel arranged concentrically or coaxially
Abstract
The invention belongs to the technical field of environmental protection, and particularly relates to an adsorption method for purifying asphalt fume and a practical purifier in order to solve an existing restrictive barrier affecting purification of the asphalt fume through an adsorption method. A moving device capable of actively scattering an adsorbent is installed in the purifier provided with a filter bag, and a double adsorption purification mode that the asphalt fume is subjected to absorption purification in an active self-excited three-dimensional adsorbent dust field and then is adsorbed by the filter bag is adopted. The adsorption method for purifying the asphalt fume and the practical purifier have the advantages that the asphalt fume is efficiently purified, and meanwhile the problems that when the adsorption method is used, the occupied area is too large, use of the adsorption capacity of the adsorption material is nonuniform, and when the adsorbent is replaced, conditions are severe, and the labor intensity is too high are solved.
Description
Technical field
The invention belongs to environmental protection technical field, be specifically related to be a kind of adsorption method for asphalt flue gas purifying and entity depurator。
Background technology
The industries such as bitumen flue gas is building materials, build the road, coking, carbon element in operation or production process, the gas producing because using Colophonium and volatilizing。Bitumen flue gas is brown color in appearance, is brown black during burning, has nose of choking and chokes the severe penetrating odor of throat。In exhaust gas components except the multiring aromatic hydrocarbon substances such as contained phenols, anthracene naphthalene class, benzopyrenes to animals and plants except having a degree of hazardness, the mankind are more had carcinogenesis by 3.4 benzopyrene therein。
In order to protect the health of operator and prevent bitumen flue gas pollutant atmosphere, the purification treatment of bitumen flue gas many technical methods are have employed。Wherein, physisorphtion (be called for short: absorption method) is exactly one of method of applying。The depurator working method applying at present this method is: and the horizontal silk screen that arranges in depurator (also referred to as: adsorbent bed) above, if certain thickness active material does adsorbent layer, introduce bitumen flue gas to extend there through as adsorbate, achieve bitumen flue gas adsorption cleaning according to the biphase absorption principle of physical solid and gas in crossing process。Owing to the purification process of this absorption method is directly perceived, and investment and operating cost all relatively small again, and purification efficiency advantages of higher has been affirmed in the industry, but actually used really receives certain restriction。Its reason is, owing to adsorbent is to pave on horizontal silk screen, and the traverse velocity of bitumen flue gas is only small, under the absorption mode of this passivity, and the deficiency of draw three main aspects。First deficiency is owing to the area of adsorbent bed is too big, and then causes that depurator floor space is excessive。Second deficiency is the serious inequality of adsorption capacity use of the upper and lower adsorbent of adsorption layer。3rd is particularly problematic, not only changed adsorbent take that the off-time is long, big and operating condition of changing adsorbent labor intensity but also more severe。
In order to solve these not enough problems, increasing the quantity of adsorption layer although taking some in order to reduce occupation of land, improving the terms of employment and degree of protection of changing adsorbent personnel, depurator is even taked the mode of the using and the reserved to reduce the ways such as off-time。But also cannot fundamentally solve these restrictive barriers。
Summary of the invention
The present invention is to solve that impact at present uses absorption method to carry out the restrictive barrier of asphalt flue gas purifying, it is achieved promote the wider application purpose by this method。
The present invention adopts the following technical scheme that realization:
A kind of entity depurator for asphalt flue gas purifying, is provided with the telecontrol equipment that can be actively shed by adsorbent in the depurator being provided with filter bag。
Described telecontrol equipment is train, and train installs one group or array。Preferably, train includes drivewheel, and drivewheel raises plate equipped with shovel。Preferred train includes drivewheel, follower and flexible-belt, and flexible-belt raises plate equipped with shovel。Flexible-belt is rubber strip, conveyer belt, chain or steel wire。
Described depurator has depurator shell, depurator shell has the outlet of bitumen flue gas entrance, adsorbent entrance, pure qi (oxygen), adsorbent outlet and pressure tap, described depurator outer casing bottom is pyramidal structure, telecontrol equipment is installed from bitumen flue gas entrance to adsorbent outlet place in pyramidal structure side, the opposite side of pyramidal structure installs vibrating device, bitumen flue gas entrance top is filter bag, and bitumen flue gas entrance is provided with gas averaging board。
A kind of adsorption method for asphalt flue gas purifying, sheds the three-dimensional adsorbent dirt field of formation by addition actively inspired for adsorbent, when bitumen flue gas is in the process passing through this adsorbent dirt field, carries out the first time adsorption cleaning of gas-particle two-phase;Then, under the effect of pressure reduction, exhaust gas flow direction filter bag, in passing through, filter bag carries out second adsorption purification。Bitumen flue gas is 1.2-1.8m/s in the speed after gas averaging board, adsorbent shed concentration at 50-120g/m3In scope, the rate of filtration of filter bag is within 0.8-1.5m/min。
The passive use pattern of present adsorbent is changed by the present invention, adopt and telecontrol equipment is installed in the depurator being provided with filter bag, shed in addition actively inspired for adsorbent, so as to while forming a three-dimensional adsorbent dirt field, also being hung by the dust of generation is attached on filter bag inner surface, when bitumen flue gas is in the process passing through this absorption dirt field, achieve the first time adsorption cleaning of gas-particle two-phase in space。Then under the effect of pressure reduction, exhaust gas flow direction filter bag, and carried out second time adsorption cleaning to hanging the dust being attached on filter bag surface in passing through, and then achieve the high-efficient purification to bitumen flue gas。
Hinge structure of the present invention has the advantages that this mode method that bitumen flue gas carries out adsorption cleaning in the three-dimensional adsorbent dirt field of active self-excitation。It is carry out in space owing to adsorbent contacts with the two of bitumen flue gas, so in the floor space of depurator, current Planar adsorbent bed pattern will be far smaller than。Again due to adsorbent inspired is shed be random and unordered in carry out, thus again the adsorption capacity utilization rate of adsorbing material having been reached unanimously。Additionally, as long as opening the adsorbent dress of depurator, discharging opening, the adsorbent in depurator just drops down discharge at the flows by action of deadweight, has both achieved the replacing to adsorbent, so changing replacing working environment and condition completely, and then the labor intensity of personnel is also thoroughly alleviated。
Accompanying drawing explanation
Fig. 1 is the structural representation of the entity depurator for asphalt flue gas purifying,
In figure: 1. bitumen flue gas entrance, 2. gas averaging board, 3. depurator shell, 4. train, 5. flexible-belt, 6. plate raised by shovel, 7. adsorbent outlet, 8. vibrating device, 9. adsorbent entrance, 10. filter bag, 11. pressure tap, 12. pure qi (oxygen) outlets。
Detailed description of the invention
Below in conjunction with structural representation, the present invention is described further:
For the entity depurator of asphalt flue gas purifying, the telecontrol equipment that can be actively shed by adsorbent is installed in the depurator being provided with filter bag。Being arranged on the telecontrol equipment in depurator is train, and train installs one group or array。Train include main, take turns and plate composition raised by shovel on flexible-belt and flexible-belt。Flexible-belt can be rubber strip, conveyer belt, chain, steel wire。Or train includes drivewheel, and drivewheel raises plate equipped with shovel。The drivewheel of train by casing outside motor drive, and can according to the size of required adsorbent solid dirt field concentration, the rotating speed corresponding to motor realizes。
Described depurator has depurator shell 3, depurator shell 3 has bitumen flue gas entrance 1, adsorbent entrance 9, pure qi (oxygen) outlet 12, adsorbent outlet 7 and pressure tap 11, it is pyramidal structure bottom described depurator shell 3, telecontrol equipment is installed from bitumen flue gas entrance 1 to adsorbent outlet 7 place in pyramidal structure side, the opposite side of pyramidal structure installs vibrating device 8, bitumen flue gas entrance 1 is arranged above filter bag 10, and bitumen flue gas entrance 1 is provided with gas averaging board 2。
Adsorption method for asphalt flue gas purifying, adopt and telecontrol equipment is installed in the depurator being provided with filter bag, shed in addition actively inspired for adsorbent, so as to while forming a three-dimensional adsorbent dirt field, also being hung by the dust of generation is attached on filter bag surface, when bitumen flue gas is in the process passing through this absorption dirt field, both achieved the first time adsorption cleaning of gas-particle two-phase in space。Then under the effect of pressure reduction, exhaust gas flow direction filter bag, and in passing through by hang be attached on filter bag surface dust carried out second time adsorption cleaning。The size of adsorbent (dust) concentration of the three-dimensional adsorbent dirt field formed, can be realized by the revolution of adjustment drivewheel。Bitumen flue gas is 1.2-1.8m/s in the speed after gas averaging board, adsorbent shed concentration at 50-120g/m3In scope, the rate of filtration of filter bag is within 0.8-1.5m/min。
When using first, adsorbent is encased in depurator from adsorbent entrance 9, and load after highly used by satisfied absorption, starting train 4 drives flexible-belt (such as adhesive tape, conveyer belt, chain, steel wire etc.) 5 motions, several shovels on flexible-belt 4 are raised plate 6 and just adsorbent are constantly shed inspired, thus while forming dirt field, a certain amount of adsorbent (dust) will be had again to hang and to be attached on the inner surface of filter bag 10, when adsorbent (dust) thickness on filter bag 10 reaches after stably, namely bitumen flue gas is entered by bitumen flue gas entrance 1, it is adjusted to uniform speed airflow through gas averaging board 2, in motor process, biphase absorption is carried out with the inspired dirt field of adsorbent, move to filter bag 10 under differential pressure action simultaneously, again purified again during the dust layer on filter bag 10 surface when passing through。After proceeding to a period of time, the conglomeration dust come off from filter bag drops back into again bottom at Gravitative Loads, and the adsorbent fallen with dirt field closes in storehouse undermelting, then inspired by shedding repeatedly again, until adsorption cleaning stops。In order to the aerodynamic drag keeping depurator is stable, the vibrating device 8 being arranged on depurator shell 3 can be started when needed to depurator vibration beating, so as to large stretch of conglomeration dust comes off from filter bag, it is achieved thereby that reduce the purpose of aerodynamic drag。Tail gas after purification is exported 12 discharges by pure qi (oxygen)。And when changing adsorbent, adsorbent is then discharged by adsorbent outlet 7, pressure tap 11 is for measuring the pressure difference value of depurator and air。
Example: Jiaohe City, Jilin Province charcoal ink factory, used in the past double layer planar absorption bed depurator to administer molding and dried in the air the bitumen flue gas of material machine, and the concentration of emission after purification is 50mg/m3Below。But, its floor space (the maintenance area containing necessary) reaches 45M2,, processing flue gas flow 3000M3During/H, STRENGTH ON COKE adsorbent to be changed weekly once, need to stop production 6 hours during replacing, and wants continual the working continuously of four people to complete。And after adopting the present invention, its floor space (the maintenance area containing necessary) is only 18M2, though STRENGTH ON COKE adsorbent is also changed once weekly, but only needs a people to manipulate the dress of adsorbent, discharging opening valve when changing, and can complete in shutting down 15 minutes。
Claims (9)
1. the entity depurator being used for asphalt flue gas purifying, it is characterised in that be provided with telecontrol equipment adsorbent actively can shed in the depurator being provided with filter bag。
2. the entity depurator for asphalt flue gas purifying according to claim 1, it is characterised in that described telecontrol equipment is train, and train installs a group or array。
3. the entity depurator for asphalt flue gas purifying according to claim 1 and 2, it is characterised in that train includes drivewheel, and drivewheel raises plate equipped with shovel。
4. the entity depurator for asphalt flue gas purifying according to claim 1 and 2, it is characterised in that described train includes drivewheel, follower and flexible-belt, and flexible-belt raises plate equipped with shovel。
5. the entity depurator for asphalt flue gas purifying according to claim 4, it is characterised in that flexible-belt is rubber strip, conveyer belt, chain or steel wire。
6. the entity depurator for asphalt flue gas purifying according to claim 3, it is characterized in that described depurator has depurator shell (3), depurator shell (3) has bitumen flue gas entrance (1), adsorbent entrance (9), pure qi (oxygen) outlet (12), adsorbent outlet (7) and pressure tap (11), described depurator shell (3) bottom is pyramidal structure, telecontrol equipment is installed from bitumen flue gas entrance (1) to adsorbent outlet (7) place in pyramidal structure side, the opposite side of pyramidal structure installs vibrating device (8), bitumen flue gas entrance (1) is arranged above filter bag (10), bitumen flue gas entrance (1) is provided with gas averaging board (2)。
7. the entity depurator for asphalt flue gas purifying according to claim 5, it is characterized in that described depurator has depurator shell (3), depurator shell (3) has bitumen flue gas entrance (1), adsorbent entrance (9), pure qi (oxygen) outlet (12), adsorbent outlet (7) and pressure tap (11), described depurator shell (3) bottom is pyramidal structure, telecontrol equipment is installed from bitumen flue gas entrance (1) to adsorbent outlet (7) place in pyramidal structure side, the opposite side of pyramidal structure installs vibrating device (8), bitumen flue gas entrance (1) is arranged above filter bag (10), bitumen flue gas entrance (1) is provided with gas averaging board (2)。
8. the adsorption method being used for asphalt flue gas purifying, it is characterised in that shed the three-dimensional adsorbent dirt field of formation by addition actively inspired for adsorbent, when bitumen flue gas is in the process passing through this adsorbent dirt field, carry out the first time adsorption cleaning of gas-particle two-phase;Then, under the effect of pressure reduction, exhaust gas flow direction filter bag, in passing through, filter bag carries out second adsorption purification。
9. the adsorption method for asphalt flue gas purifying according to claim 8, it is characterised in that bitumen flue gas is 1.2-1.8m/s in the speed after gas averaging board, adsorbent shed concentration at 50-120g/m3In scope, the rate of filtration of filter bag is within 0.8-1.5m/min。
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CN201511013162.XA CN105688598B (en) | 2015-12-31 | 2015-12-31 | For the adsorption method and entity clarifier of asphalt flue gas purifying |
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CN201511013162.XA CN105688598B (en) | 2015-12-31 | 2015-12-31 | For the adsorption method and entity clarifier of asphalt flue gas purifying |
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CN105688598B CN105688598B (en) | 2019-03-08 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109772096A (en) * | 2019-03-21 | 2019-05-21 | 武汉科技大学 | A kind of bitumen fume purifying device |
Citations (5)
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CN1077395A (en) * | 1992-04-14 | 1993-10-20 | 抚顺石油学院 | A kind of method of asphalt flue gas purifying |
US5538541A (en) * | 1995-04-03 | 1996-07-23 | On-Demand Environmental Systems Inc. | Apparatus and method for removing volatile organic compounds from an air stream |
CN102716622A (en) * | 2012-07-06 | 2012-10-10 | 哈尔滨工业大学(威海) | Integrated bag-type dust removal and fluidized adsorption device |
CN102728181A (en) * | 2012-07-23 | 2012-10-17 | 东南大学 | Fluidized bed jetting adsorbent smoke demercuration device and method thereof |
CN205517131U (en) * | 2016-02-24 | 2016-08-31 | 吉林工业职业技术学院 | Pitch gas cleaning ware |
-
2015
- 2015-12-31 CN CN201511013162.XA patent/CN105688598B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1077395A (en) * | 1992-04-14 | 1993-10-20 | 抚顺石油学院 | A kind of method of asphalt flue gas purifying |
US5538541A (en) * | 1995-04-03 | 1996-07-23 | On-Demand Environmental Systems Inc. | Apparatus and method for removing volatile organic compounds from an air stream |
CN102716622A (en) * | 2012-07-06 | 2012-10-10 | 哈尔滨工业大学(威海) | Integrated bag-type dust removal and fluidized adsorption device |
CN102728181A (en) * | 2012-07-23 | 2012-10-17 | 东南大学 | Fluidized bed jetting adsorbent smoke demercuration device and method thereof |
CN205517131U (en) * | 2016-02-24 | 2016-08-31 | 吉林工业职业技术学院 | Pitch gas cleaning ware |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109772096A (en) * | 2019-03-21 | 2019-05-21 | 武汉科技大学 | A kind of bitumen fume purifying device |
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Effective date of registration: 20200106 Address after: Room 201-213, management committee, Tiangang Stone Industrial Park, Jiaohe City, Jilin Province Patentee after: Jiaohe Tianxiang Carbon Industry Co., Ltd Address before: 132013 No. 15, West Mt. Hengshan Road, Fengman District, Jilin, Jilin Patentee before: Jilin Vocational College of Industry and Technology |
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