CN105685063A - nicotine/matrine aromatic-free emulsifiable concentrate and preparation method thereof - Google Patents

nicotine/matrine aromatic-free emulsifiable concentrate and preparation method thereof Download PDF

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Publication number
CN105685063A
CN105685063A CN201610092411.7A CN201610092411A CN105685063A CN 105685063 A CN105685063 A CN 105685063A CN 201610092411 A CN201610092411 A CN 201610092411A CN 105685063 A CN105685063 A CN 105685063A
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CN
China
Prior art keywords
nicotine
matrine
aromatic hydrocarbons
methyl oleate
emulsifying agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610092411.7A
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Chinese (zh)
Inventor
段文岗
赵宝林
刘永震
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Hebei Gangen Biological Science & Technology Co Ltd
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Hebei Gangen Biological Science & Technology Co Ltd
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Priority to CN201610092411.7A priority Critical patent/CN105685063A/en
Publication of CN105685063A publication Critical patent/CN105685063A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Medicinal Preparation (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses a nicotine/matrine aromatic-free emulsifiable concentrate and a preparation method thereof. The nicotine/matrine aromatic-free emulsifiable concentrate comprises the following materials according to percent by weight: 0.1-0.7% of nicotine, 0.5% of matrine, 5-20% of an emulsifying agent, and the balance of methyl oleate. After being mixed, the methyl oleate and the emulsifying agent in the invention can well dissolve nicotine/matrine crude drug, and the obtained emulsifiable concentrate has good stability and dispersity; methyl oleate is added into the emulsifiable concentrate instead of a benzene solvent, thus reducing usage of the solvents in the emulsifiable concentrate, such as benzene, methylbenzene and xylene and reducing the harm of benzene solvents to environment and human; the methyl oleate is resourceful and low in cost, thus reducing the cost of the emulsifiable concentrate.

Description

A kind of nicotine matrine is without aromatic hydrocarbons cream and preparation method thereof
Technical field
The present invention relates to emulsifiable concentrates for agricultural chemicals field, particularly relate to a kind of oil smoke alkali matrine without aromatic hydrocarbons cream and preparation method thereof。
Background technology
Current farm chemical emulsion preparation is the formulations of pesticide that China is traditional, accounts for 40% in various dosage forms, and in annual production more than in 19 kinds of pesticidal preparations products of 5 kilotons, having 11 kinds of Pesticidal products is cream dosage form, accounts for the 60% of sum。The primary solvent used in emulsifiable concentrates for agricultural chemicals is benzene,toluene,xylene, but a large amount of use of benzene, toluene and dimethylbenzene creates many problems, such as benzene, toluene and dimethylbenzene are irritant to skin, mucosa, central nervous system is had anesthetic action, sucks higher concentration in the short time and may occur in which the obvious stimulation symptom of eyes and upper respiratory tract；And often in contact with the synthesis of human deoxyribonucleic acid can be suppressed, cause chromosome mutation, destroy hemopoietic system, leukemogenesis；Benzene, toluene and dimethylbenzene dissolubility in water is little, therefore floating or be distributed in the water surface in oily, causes Fish and other aquatile dead。Additionally, toluene and dimethylbenzene also have stronger volatility and inflammability, in transport and use procedure thereof, there is bigger potential safety hazard。
But at present make the cream preparation of solvent with toluene, dimethylbenzene to be still widely used, this is mainly such cream preparation and is better than other preparation in drug effect, such as wettable powder etc., therefore some special insects are being prevented and treated, such as the aspect such as coccid, aleyrodid is better than other dosage form, and it is becoming present aspect also superior to dosage forms such as water dispersible granules, therefore cream or the formulations of pesticide that China commonly uses at present。Therefore, research and development substitute the hypotoxicity of benzene in cream, toluene and dimethylbenzene, the solvent that environmental hazard is little is very urgent。
Methyl oleate, has another name called octadecenic acid methyl ester, for pale yellow transparent oily liquids, can be miscible in water with dehydrated alcohol, ethanol, and these product are the intermediate of detergent, emulsifying agent, wetting agent and stabilizer。Methyl oleate is a kind of material that nature is very general, content is higher, it is common to be present in the oil substances in plant seed such as Semen Sesami, Semen Brassicae campestris, Semen arachidis hypogaeae, Semen Maydis, camellia oleosa seed, Semen Glycines etc., is also one of the main component of some Animal fat class materials。Methyl oleate can also have methanol and oleic acid to obtain through esterification, its method is: by oleic acid and methanol mixed, add catalyst concentrated sulphuric acid or p-methyl benzenesulfonic acid, it is heated to reflux 10h, cooling, being neutralized to pH value with Feldalat NM is 8 ~ 9, washes with water to neutrality, carry out decompression distillation after drying through anhydrous calcium chloride, obtain methyl oleate。Owing to methyl oleate source is wide, nontoxic and environmental hazard is little, it is substitute the ideal solvent of benzene, toluene and dimethylbenzene in cream。
But when adopting methyl oleate to replace the benzene in cream, toluene and dimethylbenzene, the emulsifying agent of different former pharmacopoeia apoplexy due to endogenous wind cream preparations is not suitable for methyl oleate, it is necessary to research and development are applicable to the emulsifying agent of methyl oleate。
Summary of the invention
It is an object of the invention to provide a kind of originate wide, nontoxic and to the little nicotine matrine of environmental hazard without aromatic hydrocarbons cream。
Further object is that the preparation method providing nicotine matrine without aromatic hydrocarbons cream。
The above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of nicotine matrine, without aromatic hydrocarbons cream, is got the raw materials ready by following percentage by weight:
Nicotine 0.1% ~ 0.7%,
Matrine 0.5%,
Emulsifying agent 5% ~ 20%,
Methyl oleate polishing。
Preferably, described emulsifying agent percentage by weight is 10%。
Preferably, described methyl oleate percentage by weight is 88.2%。
In order to better dissolve former medicine, described emulsifying agent is one or more in farm chemical emulgent, emulsification agent and diesel oil emulsifier。
Preferably, described farm chemical emulgent include 100#, 500#, 1601,1602, OP-7, OP-10,600,600-1,600-2,600-3, BY-110, BY-112, BY-120, BY-130, BY-140,400,403。
Preferably, described emulsifying agent be farm chemical emulgent monomer 100#, 500#, 1601, OP-7, OP-10, emulsification agent mixture。
Preferably, described emulsification agent is formed by multiple the moon/nonionic surfactant and additive compound。
Described nicotine matrine, without aromatic hydrocarbons cream, is prepared according to the following steps:
(1) emulsifying agent is added in appropriate methyl oleate, mix homogeneously；
(2) former for nicotine matrine medicine is added in the solution of step (1) gained, mix homogeneously；
(3) remaining methyl oleate is added in the solution of step (2) gained, mix homogeneously, obtain nicotine matrine without aromatic hydrocarbons cream。
Beneficial effects of the present invention: after the methyl oleate in the present invention mixes with emulsifying agent, it is possible to dissolve the former medicine of nicotine matrine well, and the cream obtained has good stability and dispersibility；The present invention adopts methyl oleate to be substituted into the benzene-series solvent in oil, thus decreasing the consumption that makes of benzene in cream, toluene and dimethylbenzene equal solvent, and decreases the harm that environment and human health are caused by benzene-series solvent；And methyl oleate wide material sources, cost are low, thus reducing the cost of cream。
Detailed description of the invention
For describing the technology contents of the present invention in detail, realizing target effect, it is explained in detail below in conjunction with embodiment。
Embodiment 1
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.1%,
Matrine 0.5%,
Emulsifying agent 5%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment, without aromatic hydrocarbons cream, is prepared according to the following steps:
(1) emulsifying agent is added in appropriate methyl oleate, mix homogeneously；
(2) former for nicotine matrine medicine is added in the solution of step (1) gained, mix homogeneously；
(3) remaining methyl oleate is added in the solution of step (2) gained, mix homogeneously, obtain nicotine matrine without aromatic hydrocarbons cream。
Embodiment 2
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.5%,
Matrine 0.5%,
Emulsifying agent 5%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 3
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.7%,
Matrine 0.5%,
Emulsifying agent 5%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 4
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.1%,
Matrine 0.5%,
Emulsifying agent 10%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 5
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.5%,
Matrine 0.5%,
Emulsifying agent 10%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 6
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.7%,
Matrine 0.5%,
Emulsifying agent 10%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 7
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.1%,
Matrine 0.5%,
Emulsifying agent 15%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 8
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.5%,
Matrine 0.5%,
Emulsifying agent 15%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 9
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.7%,
Matrine 0.5%,
Emulsifying agent 15%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 10
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.1%,
Matrine 0.5%,
Emulsifying agent 20%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 11
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.5%,
Matrine 0.5%,
Emulsifying agent 20%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
Embodiment 12
The present embodiment provides a kind of nicotine matrine without aromatic hydrocarbons cream, gets the raw materials ready by following percentage by weight:
Nicotine 0.7%,
Matrine 0.5%,
Emulsifying agent 20%,
Methyl oleate polishing。
The nicotine matrine of the present embodiment without aromatic hydrocarbons cream preparation method with embodiment 1。
In embodiment 1 to embodiment 20, described emulsifying agent is one or more in farm chemical emulgent, emulsification agent and diesel oil emulsifier, described farm chemical emulgent include 100#, 500#, 1601,1602, OP-7, OP-10,600,600-1,600-2,600-3, BY-110, BY-112, BY-120, BY-130, BY-140,400,403。
Preferably, described emulsifying agent be farm chemical emulgent monomer 100#, 500#, 1601, OP-7, OP-10, emulsification agent mixture, this emulsifying agent mixture accounts for better effects if when the percentage by weight of described emulsifiable concentrate formulation is 10%。
Emulsification agent of the present invention is formed by multiple the moon/nonionic surfactant and additive compound, for weak yellow liquid, soluble in water, in acid, alkali, oxidant all very stable, there is the functions such as emulsifying, dispersion, removing oil, decontamination, animals and plants and mineral greasy dirt cleansing power are very strong, it is widely used in all kinds of cleaning industry, such as ink cleaning, engine washing, die casting cleaning etc.。
Methyl oleate of the present invention accounts for the percentage by weight of emulsifiable concentrate formulation preferably 88.2%。
After methyl oleate in the present invention mixes with mentioned emulsifier, the former medicine of nicotine matrine can be dissolved well, and the cream obtained has good stability and dispersibility, thus decreasing the consumption that makes of benzene in cream, toluene and dimethylbenzene equal solvent, and decrease the harm that environment and human health are caused by benzene-series solvent。
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent transformation utilizing description of the present invention to make, or directly or indirectly it is used in other relevant technical fields, all in like manner include in the scope of patent protection of the present invention。

Claims (8)

1. a nicotine matrine is without aromatic hydrocarbons cream, it is characterised in that get the raw materials ready by following percentage by weight:
Nicotine 0.1% ~ 0.7%,
Matrine 0.5%,
Emulsifying agent 5% ~ 20%,
Methyl oleate polishing。
2. nicotine matrine according to claim 1 is without aromatic hydrocarbons cream, it is characterised in that described emulsifying agent percentage by weight is 10%。
3. nicotine matrine according to claim 1 is without aromatic hydrocarbons cream, it is characterised in that described methyl oleate percentage by weight is 88.2%。
4. nicotine matrine according to claim 1 is without aromatic hydrocarbons cream, it is characterised in that described emulsifying agent is one or more in farm chemical emulgent, emulsification agent and diesel oil emulsifier。
5. nicotine matrine according to claim 4 is without aromatic hydrocarbons cream, it is characterized in that, described farm chemical emulgent include 100#, 500#, 1601,1602, OP-7, OP-10,600,600-1,600-2,600-3, BY-110, BY-112, BY-120, BY-130, BY-140,400,403。
6. nicotine matrine according to claim 4 is without aromatic hydrocarbons cream, it is characterised in that described emulsifying agent be farm chemical emulgent monomer 100#, 500#, 1601, OP-7, OP-10, emulsification agent mixture。
7. nicotine matrine according to claim 4 is without aromatic hydrocarbons cream, it is characterised in that described emulsification agent is formed by multiple the moon/nonionic surfactant and additive compound。
8. the nicotine matrine according to claim 1 to 7 any one is without the preparation method of aromatic hydrocarbons cream, it is characterised in that be prepared according to the following steps:
Emulsifying agent is added in appropriate methyl oleate, mix homogeneously；
Former for nicotine matrine medicine is added in the solution of step (1) gained, mix homogeneously；
Remaining methyl oleate is added in the solution of step (2) gained, mix homogeneously, obtain nicotine matrine without aromatic hydrocarbons cream。
CN201610092411.7A 2016-02-19 2016-02-19 nicotine/matrine aromatic-free emulsifiable concentrate and preparation method thereof Pending CN105685063A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610092411.7A CN105685063A (en) 2016-02-19 2016-02-19 nicotine/matrine aromatic-free emulsifiable concentrate and preparation method thereof

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CN105685063A true CN105685063A (en) 2016-06-22

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106719846A (en) * 2016-11-22 2017-05-31 恒大园林集团有限公司 A kind of complex ecological agricultural chemicals and preparation method thereof
CN108294021A (en) * 2018-02-01 2018-07-20 黑龙江省平山林业制药厂 A kind of nicotine-matrine fumicants and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101961012A (en) * 2009-07-22 2011-02-02 张治业 2.5 percent tobacco.picrin soluble liquid and preparation method thereof
CN104823969A (en) * 2015-05-28 2015-08-12 苏州丰倍生物科技有限公司 Development and application of fatty acid methyl ester serving as environment-friendly solvent in pesticide preparations

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101961012A (en) * 2009-07-22 2011-02-02 张治业 2.5 percent tobacco.picrin soluble liquid and preparation method thereof
CN104823969A (en) * 2015-05-28 2015-08-12 苏州丰倍生物科技有限公司 Development and application of fatty acid methyl ester serving as environment-friendly solvent in pesticide preparations

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
第9期: "1.2%烟碱和苦参碱防治草地虫害药效试验", 《养殖与饲料》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106719846A (en) * 2016-11-22 2017-05-31 恒大园林集团有限公司 A kind of complex ecological agricultural chemicals and preparation method thereof
CN108294021A (en) * 2018-02-01 2018-07-20 黑龙江省平山林业制药厂 A kind of nicotine-matrine fumicants and preparation method thereof
CN108294021B (en) * 2018-02-01 2020-11-03 黑龙江省平山林业制药厂 Nicotine-matrine smoking agent and preparation method thereof

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