CN105685034A - Pest preventing and killing mixed composition - Google Patents

Pest preventing and killing mixed composition Download PDF

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Publication number
CN105685034A
CN105685034A CN201410691308.5A CN201410691308A CN105685034A CN 105685034 A CN105685034 A CN 105685034A CN 201410691308 A CN201410691308 A CN 201410691308A CN 105685034 A CN105685034 A CN 105685034A
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methyl
bacterium
azoles
base
ester
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猪俣伸
猪俣伸一
河原敦子
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Mitsui Chemicals Agro Inc
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Sankyo Agro Co Ltd
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Abstract

The present invention provides a pest preventing and killing mixed composition which is capable of effectively preventing and killing pests. The pest preventing and killing mixed composition comprises an acylamide derivative shown as a chemical formula (1) and another compound as an active ingredient, the another compound is selected from at least one of the compound group of free insecticides, miticides, nematicides and bactericides, and the compound group comprises abamectin, acetamiprid, bifenthrin, carbofuran, dichlorvos (DDVP), emamectin benzoate, ethephon, flubendiamide, methidathion (DMTP), omethoate, phoxim, quintiofos, triazophos, trichlorfon (DEP), cypermethrin, azoxystrobin, carbendazim, chlormequat, copper hydroxide, cymoxanil, difenoconazole, fluopicolide, validamycin, mancozeb, metalaxyl, metiram, myclobutanil, paclobutrazol, propiconazole, pyraclostrobin, tebuconazole, thiophanate-methyl and triadimefon.

Description

Pesticidal blend compositions
Technical field
The present invention relates to Pesticidal blend compositions, described Pesticidal blend compositions contains amide derivatives and other compounds that chemical formula (1) represents as effective ingredient。
Background technology
Disclose multiple compounds as the amide derivatives with Pesticidal effect and disclose it as utilization of pesticides method (for example, with reference to patent documentation 1~4,7)。It addition, disclose the Pesticidal blend compositions (for example, with reference to patent documentation 5,6,8) comprising amide derivatives and insecticide, acaricide, nematicide or antibacterial。
And, disclose (for example, with reference to non-patent literatures 1) such as multiple compounds as insecticide, acaricide, nematicide and antibacterial。
Prior art literature
Patent documentation
Patent documentation 1: No. 2005/021488 pamphlet of International Publication
Patent documentation 2: No. 2005/073165 pamphlet of International Publication
Patent documentation 3: No. 2006/137376 pamphlet of International Publication
Patent documentation 4: No. 2006/137395 pamphlet of International Publication
Patent documentation 5: No. 2007/013150 pamphlet of International Publication
Patent documentation 6: No. 2007/013332 pamphlet of International Publication
Patent documentation 7: No. 2010/018714 pamphlet of International Publication
Patent documentation 8: Japanese Unexamined Patent Publication 2011-157294 publication
Non-patent literature
Non-patent literature 1: pesticide handbook (ThePesticideManualThirteenthEdition)
Summary of the invention
But, when using existing noxious organism control agent, exist that can not prevent and kill off or be difficult to the harmful organism prevented and kill off。Therefore, the problem of the present invention is in that to provide the Pesticidal blend compositions of the Pesticidal effect with excellence。
For development of new noxious organism control agent, the present inventor etc. are through concentrating on studies, found that by the amide derivatives that chemical formula (1) is represented and at least one compound combination in insecticide, acaricide, nematicide and antibacterial, can effectively prevent and kill off harmful organism, thus completing the present invention。
That is, the present invention is as described below。
<1>a kind of Pesticidal blend compositions, described Pesticidal blend compositions contains other compounds of amide derivatives that following chemical formula (1) represents and at least one in following the 1st compound group being made up of insecticide, acaricide, nematicide and antibacterial as effective ingredient
1st compound group: fluorine ester chrysanthemum ester, allethrin [(1R)-isomer], Biphenthrin, EXTHIN, EXTHIN S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfloxylate, β-cyfloxylate, lambda-cyhalothrin, gamma-cyhalothrin, λ-lambda-cyhalothrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, cyphenothrin [(1R)-trans-isomer], decis, empenthrin [(EZ)-(1R)-isomer], S-fenvalerate, ethofenprox, Fenpropathrin, fenvalerate, flucythrinate, flumethrin, τ-taufluvalinate, halfenprox, Imiprothrin, methothrin, metofluthrin, Permethrin, phenothrin [(1R)-trans-isomer], prallethrin, resmethrin, RU15525 (Kadethrin), silafluofene, Tefluthrin, tetramethrin, tetramethrin [(1R)-isomer], tralomethrin, transfluthrin, ZXI8901, biopermethrin, PH, third Flumethrin, brofluthrinate, dimefluthrin,
Orthene, methylpyridine phosphorus, azinphos-methyl, azinphos ethyl, vincofos, cadusafos, chlorethoxyfos, chlorfenvinpho, chlormephos, chlopyrifos, chlorpyrifos-methyl, coumafos, cynock (CYAP), demeton-S-methyl, basudin, O-2,4-dichlorophenyl O,O-diethyl phosphorothioate (ECP), dichlorvos (DDVP), Carbicron, Rogor, dimethylvinphos, two sulfur pine (disulfoton), O-ethyl-O-(4-nitrobenzophenone) phenyl phosphorothioate (EPN), Ethodan, ethoprop, Dovip, Nemacur, MEP (fenifrothion), fenthion (MPP), lythidathion, heptenophos, Isofenphos methyl, isocarbophos (O-(Methoxyamino thiophosphoryl) isopropyl salicylate), azoles phosphorus, Malathion, Afos, Bayer 71628, methidathion (DMTP), Menite, Azodrin, 2-dichloroethylk dimethyl phosphate (BRP), omethoate, metilomerkaptofosoksid, parathion, parathion-methyl, phenthoate dimephenthoate cidial (PAP), thimet, zolone, phosmet, phosphamidon, phoxim, methyl pirimiphosmethyl, Profenofos, Propetamphos, BAY-NTN 8629, pyraclofos, Ofunack, quintiofos, sulfotep, butyl pyrimidine phosphorus, Swebate, Terbufos, thiometon, triazophos, metrifonate (DEP), Kilval, compd 22/190 (Bayer22/190), bromobenzene alkene phosphorus, bromofos, Rilariol, special pyrimitate, carbophenothion, chlorophoxim, sulprofos, Nellite, Ravap (CVMP), Kayaphos, fenthion sulfoxide, salithion (salithion), etrimfos, oxydeprofos, An Guo, O,O-diethyl O-[p-(methylsulfinyl)phenyl, isazofos, Imicyafos (AKD3088), Isamidofos, nemaphos, fosthietan,
Second the third phosphorus prestige, alanycarb, butocarboxim, butanone sulfone prestige, thiodicarb, thiofanox, Aldicarb, worm prestige, Benfuracard micro, carbaryl (NAC), carbofuran, carbosulfan, ethiofencarb, Osbac (BPMC), Carzol, furathiocarb, Mobucin (MIPC), mercaptodimethur, methomyl, oxamyl, Aphox, arprocarb (PHC), Landrin, XMC, allyxycarb, Aldicarb sulfone, metalkamate, butacarb, sok, meta-tolyl-N-methylcarbamate (MTMC) (MTMC), Meobal (MPMC), fenothiocarb, acetamiprid, clothianidin, MTI-446, imidacloprid, Nitenpyram, thiacloprid, Diacloden, ring tebufenozide, chlorine tebufenozide, methoxyfenozide, tebufenozide, bistrifluron, UC 62644, TH-6040, flucycloxuron, Cascade, HEXAFLUMURON, fluorine the third oxygen urea, Novaluron, noviflumuron, Teflubenzuron, parasite killing is grand, ABG-6215, hydroprene, kinoprene, alkene worm propyl ester, pyriproxyfen, Niran, 5a,6,9,9a-hexahydro-6,9-methano-2,4, gamma hch (gamma-HCH), everywhere gram, cartap hydrochlorate, thiocyclam, amitraz, ethiprole, Frontline, second phthalein worm is cured, azacyclotin, plictran, fenbutatin oxide (fenbutatin oxide), fenazaquin, fenpyroximate, pyridaben, pyrimidifen, tebufenpyrad, Tolfenpyrad, bromine demodicid mite is special, chlorfenapyr, DNOC, binapacryl, Rynaxypyr, bromine cyanogen insect amide (DPX-HGW86), diazole worm, metaflumizone, Envidor, Spiromesifen, triaguron, flufenzine,
Avilamycin, acequinocyl, Ai Zhading, bensultap, Citrazon, Bifenazate, Buprofezin, CGA50439, chinomethionat, clofentezine, cryolite, cyromazine, dazomet, DCIP, DDT, diafenthiuron, D-D (1,3-dichloropropylene), dicofol, CGA 183893, dinobuton, dinocap, ENT8184, according to killing demodicid mite, flonicamid, fluacrypyrim, fipronil bisamide, GY-81 (peroxycarbonates), Hexythiazox, Hydramethylnon Bait, hydrocyanic acid, iodomethane, karanjin, MB-599 (verbutin), mercuric chloride, metham-sodium, methoxychlor, methyl mustard oil, kill your demodicid mite element, pentachlorophenol, hydrogen phosphide, piperonyl butoxide, compound polynactin, propargite (BPPS), pymetrozine, pyrethrin, pyridalyl, rotenone, S421 (double, two (2,3,3,3-tetra-chloropropyl) ether), jervine, pleocidin, Sulcofuron salt (Sulcofuron-sodium), sulfluramid, tetradiphon, Cupric sulfate, De-Green, drinox, match result, Amidothioate, aminocarb, O,O-diethyl S-(.beta.-diethylamino)ethyl phosphorothiolate, aramite, ethyl methidathion, Alamos, solbar, Bayer22408, Bayer32394, Benclothiaz, 5-(1,3-benzodioxole-5-base)-3-hexyl-2-cyclonene, 1,1-double, two (4-chlorphenyl)-cellosolvos, butyl ester phosphine, dihydropyrone, 2-(2-Butoxyethoxy) ethyl rhodanate acid esters, toxaphene, chlorbenside, kepone, Spanon, Qikron, chlorfenizon, Isoprothiolane, fluorine fluazuron, Lepimectin, Spinetoram, emamectin-benzoate, the methaldehyde, fenisobromolate, fluazinam, bilanafos, benomyl, hydrochloric acid levamisole, pyrifluquinazon (NNII0101), cyflumetofen, sulfanilamide dragonfly vinegar, IKA-2005, nitrile pyrrole demodicid mite ester (NC512), spiral shell worm ethyl ester (BYI08330), sulfoxaflor, Pyrafluprole (V3039), Pyriprole (V3086), bromo pyrrole carbonitrile, Flupyrazofos-containpesticide, luxuriant ether, chlorobenzilate, nicotine neutral sulfate., flufenzine, Citrazon, emamectin-benzoate, potassium oleate, enuatrol, hydroxypropyl starch, crow worm amine, Metaflumizole, tripropyl isocyanuric acid ester, albendazole, oxibendazole, bensultap, Phenbendasol, pyrantel tartrate, metham-sodium sodium, 1,3-dichloropropylene, Imicyafos (AKD-3088), bromo pyrrole carbonitrile, chloropicrin, Bromofume (EDB), vikane, acrylonitrile, double, two (2-chloroethyl) ether, the bromo-2-ethyl chloride of 1-, the chloro-1-propylene of the bromo-1-of 3-, bromocyclne, Carbon bisulfide, carbon tetrachloride, nemadectin, aluminum phosphate, bacillus thuringiensis delta-endotoxin, Borax, calcium polysulfide, cryolite, the basic element of cell division, nicotine, keep away worm alcohol, coal tar, anabasine, pyrantel tartrate, Pyrethrum (pyrethrin), soybean lecithin, starch, fatty glyceride, propylene glycol mono, kieselguhr, bacillus thuringiensis, Cyclaniliprole, Triflumezopyrim, Flometoquin, Flupyradifurone, Pyflubumide, N-(4-methyl-5-isoxazole base)-4-(trifluoromethyl) nicotiamide,
Nitrile Fluoxastrobin, imines bacterium, pyraclostrobin, ZEN 90160, fluoxastrobin, dimoxystrobin, orysastrobin, fork phenalgin amide, trifloxystrobin, Enestroburin, azoles amine bacterium ester, pyraoxystrobin, simeconazoles, Tebuconazole, RH-7592, hexaconazole, amide azoles, triazolone, fluorine ether azoles, prothioconazoles, triticonazole, epoxiconazole, plant bacterium azoles, metconazole, propiconazole, cyproconazole, ether azoles, olefin conversion, Fluquinconazole, bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane, Wu Junzuo, bromuconazole, Triadimenol, Flutriafol, nitrile bacterium azoles, etaconazole, Bitertanol, oxpoconazole fumarate, fluorine bacterium azoles, IMAZALIL, IMAZALIL-S, prochloraz, pefurazoate, triazoxide, Fenamidone,
Pyrrole metsulfovax, flutolanil, the spirit of furan pyrazoles, Boscalid, fenhexamid, cyflufenamid, tecloftalam, mandipropamid, biphenyl pyrrole bacterium amine, carboxin, oxycarboxin, third oxygen mebenil, Silthiopham, thifluzamide, fluorine biphenyl bacterium, Guardian, zoxamide, tiadinil, isotianil, double, two chlorine zarilamids, zarilamid, fluopicolide, fluopyram, fluorine ring propionic acid amide., Tolfenpyrad, fluorine azoles bacterium aniline, fluorine azoles ring bacterium amine, isopyrazam, 3-difluoromethyl-N-[4 '-(3,3-dimethyl butine-1-base) biphenyl-2-base]-1-methyl isophthalic acid H-pyrazole-4-carboxamide, 3-difluoromethyl-N-[4 '-(3-methoxyl group-3-methyl butyne-1-base) biphenyl-2-base]-1-methyl isophthalic acid H-pyrazole-4-carboxamide, metalaxyl, metalaxyl-M, M 9834, M 9834-M, furalaxyl-M, benzene metsulfovax, iprovalicarb, downy mildew goes out, cyazofamid, the U.S. speed of peace, flusulfamide, tolyfluanid, Euparen, hundred dimension spirits, hundred dimension spirit hydrochlorates, diethofencarb, pyrrole bacterium benzene prestige, Mancozeb, maneb, propineb, zineb, Carbatene, ziram, thiuram, polycarbamate, isopropyl is fixed, procymidone, captan, vinclozolin, chlozolinate, folpet, iminoctadine alkane benzene sulfonate, iminoctadine triacetate, Guanoctine, dodine, mepanipyrim, fenarimol, ferimzone, cyprodinil, dimethyl mepanipyrim, nuarimol, dimethirimol, the phonetic bacterium spirit of sulphur, fluorine mepanipyrim, dimethomorph, butadiene morpholine, tridemorph, dodemorfe, flumorph, thiophanate methyl, thiophanate, benomyl, carbendazim, Apl-Luster, furidazol, cough up bacterium ester, fluoromide, fenpiclonil, fosetyl, Hinosan, tolelofos-methyl, iprobenfos, pyrazophos, chlorocholine chloride (Chlormequat), paclobutrazol (paclobutrazol),
Copper hydrate, copper, alkalescence copper chloride, basic cupric sulfate, copper 8-quinolinolate, copper sulfate five water salt, anhydrous cupric sulfate, nonyl benzene cupric sulfocarbolate, DBEDC, kasugarnycin, valida, polyoxin derivant, blasticidin-S S benzylamino benzene sulfonate, streptomycin, natamycin, midolthromycin, oxytetracycline, Bravo, Rabcide, pentachloronitrobenzene, the chloro-7-of 5-(4-methyl piperidine-1-base)-6-(2,4,6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, the chloro-N-of 5-[the fluoro-1-Methylethyl in (1S)-2,2,2-tri-]-6-(2,4,6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, the chloro-N-of 5-[(1R)-1,2-dimethyl propyl]-6-(2,4,6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, 5-(methoxy)-6-octyl group [1,2,4] triazol [1,5-a] pyrimidine-7-amine, azoles mepanipyrim, metrafenone, 3-(2,3,4-trimethoxy-6-methyl benzoyl)-5-chloro-2-methoxyl group-4-picoline, 3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazolidine-3-base] pyridine, 3-[2,3-dimethyl-5-(4-aminomethyl phenyl) isoxazolidine-3-base] pyridine, 3-[2-isopropyl-3-methyl-5-(4-chlorphenyl) isoxazolidine-3-base] pyridine, quinoxyfen, Tebufloquin, 3-(fluoro-3,3,4,4-tetramethyl-3 of 5-, 4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4-bis-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4,5-tri-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, Flutianil, 1-[(2-acrylic sulfo-) carbonyl]-2-(1-Methylethyl)-4-(2-aminomethyl phenyl)-5-amino-1H-pyrazoles-3-ketone, 1-[(ethylenebis dithiocarbamate) carbonyl]-2-(1-Methylethyl)-4-(2-aminomethyl phenyl)-5-amino-1H-pyrazoles-3-ketone, 1-[(ethylenebis dithiocarbamate) carbonyl]-2-(1-Methylethyl)-4-(2,6-Dichlorobenzene base)-5-amino-1H-pyrazoles-3-ketone,
Hymexazol (first hydroxyl isoxazole), fluazinam, diclomezine, tricyclazole, cymoxanil, famoxadone, Fenamidone, chloropicrin, thiadiazine, third oxygen quinoline, spiroxamine, fenpropidin, Delan, Pencycuron, Isoprothiolane, probenazole, resveratrol, triforine, my acid benzene-S-methyl, pyroquilon, dinocap, organic nickel, kobam, frost spirit, ambam, pyrifenox, oxolinic acide, phosphorous acid, dazomet, methyl mustard oil, methasulfocarb, 1, 3-dichloropropylene, iodomethane, sulfur, lime sulfur, fentin hypochlorite, chinomethionat, chloroneb, anilazine, isopropyl disappears, plant clothing ester, botran, benthiozole, trichlamide, first hydroxyl isoxazole potassium, hydration sulfur agent, zinc sulfate, sodium bicarbonate, potassium bicarbonate, sodium hypochlorite, argent, Oleum Brassicae campestris, machine oil, Harpin albumen and Tolprocarb。
<2>the Pesticidal blend compositions as described in above-mentioned<1>, wherein, other compounds are at least one compound in the following 2nd compound group selecting free insecticide, acaricide, nematicide and antibacterial to constitute,
2nd compound group: chlopyrifos, ethofenprox, MTI-446, Frontline, pleocidin, Rynaxypyr, pymetrozine, Lepimectin, fenifrothion, silafluofene, Buprofezin, ethiprole, pyridaben, acequinocyl, fenbutatin oxide, Envidor, according to killing demodicid mite, Bifenazate, kill your demodicid mite element, N-(4-methyl-5-isoxazole base)-4-(trifluoromethyl) nicotiamide, probenazole, double, two chlorine zarilamids, orysastrobin, tricyclazole, Isoprothiolane, isotianil, pyrrole metsulfovax, simeconazoles, flusulfamide, 3-(fluoro-3,3,4,4-tetramethyl-3 of 5-, 4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4-bis-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4,5-tri-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, hymexazol, clothianidin, imidacloprid, Diacloden, nitrile Fluoxastrobin, carboxin, cough up bacterium ester, plant bacterium azoles, pyraclostrobin, trifloxystrobin, captan, metalaxyl-M, thiuram, Mancozeb, bromine cyanogen insect amide (DPX-HGW86), acetamiprid, Nitenpyram, thiacloprid, orthene, pyriproxyfen, Benfuracard micro, Tolfenpyrad, chlorfenapyr, spiral shell worm ethyl ester (BYI08330), Spiromesifen, methomyl, iminoctadine alkane benzene sulfonate, iminoctadine triacetate, my acid benzene-S-methyl, ferimzone, pyroquilon, tiadinil, Rabcide, kasugarnycin, zarilamid, third oxygen mebenil, diclomezine, Pencycuron, valida, Hinosan, the spirit of furan pyrazoles, thifluzamide, flutolanil, fork phenalgin amide, iprobenfos, oxolinic acide, tecloftalam, ZEN 90160, bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane, Tebuconazole, Triadimenol, Apl-Luster, metalaxyl, streptomycin and Tolprocarb。
<3>the Pesticidal blend compositions as described in above-mentioned<1>, wherein, other compounds are at least one compound in the following 3rd compound group selecting free insecticide, acaricide, nematicide and antibacterial to constitute,
3rd compound group: avilamycin, acetamiprid, Biphenthrin, carbofuran, dichlorvos (DDVP), emamectin-benzoate, vincofos, fipronil bisamide, methidathion (DMTP), omethoate, phoxim, quintiofos, triazophos, metrifonate (DEP), cypermethrin, carbendazim, chlorocholine chloride (Chlormequat), Copper hydrate, cymoxanil, ether azoles, fluopicolide, valida, Mancozeb, metalaxyl, Carbatene, nitrile bacterium azoles, paclobutrazol (paclobutrazol), propiconazole, pyraclostrobin, Tebuconazole, thiophanate methyl, triazolone。
<4>the Pesticidal blend compositions as according to any one of above-mentioned<1>~<3>, wherein, the content ratio of the total amount of other compounds in the amide derivatives that above-mentioned chemical formula (1) represents, the 1st compound group with selecting free insecticide, acaricide, nematicide and antibacterial to constitute, the 2nd compound group or the 3rd compound group, with mass ratio range for 0.005~99%。
In accordance with the invention it is possible to provide the Pesticidal blend compositions of the Pesticidal effect with excellence。
Detailed description of the invention
The Pesticidal blend compositions of the present invention contains other compounds of amide derivatives that following chemical formula (1) represents and at least one in insecticide, acaricide, nematicide and antibacterial as effective ingredient。
The Pesticidal blend compositions of the present invention is except the amide derivatives represented containing following chemical formula (1), possibly together with other compounds of at least one in insecticide, acaricide, nematicide and antibacterial, it is possible to the Pesticidal effect that display is excellent。
Amide derivatives of the present invention represents with following chemical formula (1)。
The amide derivatives that chemical formula of the present invention (1) represents can manufacture according to the method recorded in the description of No. 2010/018714 pamphlet of International Publication etc.。
In the Pesticidal blend compositions of the present invention, the content of the amide derivatives that chemical formula (1) represents, with mass ratio range, it is generally 0.001~99%, is preferably 0.005~95%, is more preferably the scope of 0.01~90%, more preferably 0.1~85%。On the other hand, the content of other compounds, with mass ratio range, it is generally 0.001~99%, is preferably 0.005~95%, is more preferably the scope of 0.1~90%, content ratio as amide derivatives He the total amount of other compounds, with mass ratio range, it is generally 0.005~99%, is preferably the scope of 0.01~90%, more preferably 0.1~85%。
In the Pesticidal blend compositions of the present invention, as can with other compounds of the amide derivatives compound combination of the present invention and insecticide, acaricide or nematicide, it is possible to enumerate the free pyrethroid coumpound of choosing, organophosphorus compound, oxime carbamates (oxime carbamate) compound, carbamate compound, anabasine compound, bishydrazide compounds, benzoyl urea compound, juvenile hormone compounds, cyclic diolefine organochlorine compounds, 2-dimethylaminopropanecompounds-1,3-dithiols compound, amidine compound, benzopyrazoles compounds, organic tin compound, METI compounds, benzilic acid ester (benzilate) compounds, pi-allyl azoles, dinitrophenol compounds, anthryl diamide compound, diazines compounds, semicarbazones compounds, tetronic acid compounds, carbamyl triazole (carbamoyltriazole) compounds, tetrazine kind compound, addicted to cone umbrella compounds, triazole class compounds, glyoxaline compound, carboxamides, anilid compounds, valine amide (valinamide) compounds, sulfamide compound, sulfenamide compounds, dithio amino formate compounds, dicarboximide compounds, guanidine compound, pyrimidines, morpholine kind compound, benzimidazoles compound, azoles, copper compounds, antibiotic, triazolopyrimidines, benzoyl compound, ethylenediamines compound, isoxazolidine compounds, quinolines, compound in the group that thiazolidine compounds and pyrazolone (pyrazolinone) compounds are constituted。
Specifically can enumerate such as following compound:
Fluorine ester chrysanthemum ester (acrinathrin), allethrin (allethrin) [(1R)-isomer], Biphenthrin (bifenthrin), EXTHIN (bioallethrin), EXTHIN S-cyclopentenyl isomer (bioallethrinS-cyclopentenylisomer), bioresmethrin (bioresmethrin), cycloprothrin (cycloprothrin), cyfloxylate (cyfluthrin), β-cyfloxylate (beta-cyfluthrin), lambda-cyhalothrin (cyhalothrin), gamma-cyhalothrin (gamma-cyhalothrin), λ-lambda-cyhalothrin (lambda-cyhalothrin), cypermethrin (cypermethrin), α-cypermethrin (alpha-cypermethrin), β-cypermethrin (beta-cypermethrin), θ-cypermethrin (theta-cypermethrin), ζ-cypermethrin (zeta-cypermethrin), cyphenothrin [(1R)-trans-isomer] (cyphenothrin [(1R)-trans-isomer]), decis (deltamethrin), empenthrin [(EZ)-(1R)-isomer] (empenthrin [(EZ)-(1R)-isomer]), S-fenvalerate (esfenvalerate), ethofenprox (ethofenprox), Fenpropathrin (fenpropathrin), fenvalerate (fenvalerate), flucythrinate (flucythrinate), flumethrin (flumethrin), τ-taufluvalinate (tau-fluvalinate), halfenprox (halfenprox), Imiprothrin (imiprothrin), methothrin (methothrin), metofluthrin (metofluthrin), Permethrin (permethrin), phenothrin [(1R)-trans-isomer] (phenothrin [(1R)-trans-isomer]), prallethrin (prallethrin), resmethrin (resmethrin), RU15525 (Kadethrin (kadethrin)), silafluofene (silafluofen), Tefluthrin (tefluthrin), tetramethrin (tetramethrin), tetramethrin [(1R)-isomer] (tetramethrin [(1R)-isomer]), tralomethrin (tralomethrin), transfluthrin (transfluthrin), ZXI8901, biopermethrin (biopermethrin), PH (furamethrin), third Flumethrin (profluthrin), brofluthrinate (flubrocythrinate), synthetic pyrethroid compounds and their the various isomers such as dimefluthrin (dimefluthrin);
Orthene (acephate), methylpyridine phosphorus (azamethiphos), azinphos-methyl (azinphos-methyl), azinphos ethyl (azinphos-ethyl), vincofos (ethephon), cadusafos (cadusafos), chlorethoxyfos (chlorethoxyfos), chlorfenvinpho (chlorfenvinphos), chlormephos (chlormephos), chlopyrifos (chlorpyrifos), chlorpyrifos-methyl (chlorpyrifos-methyl), coumafos (coumaphos), CYAP (cynock (cyanophos)), demeton-S-methyl (demeton-S-methyl), basudin (diazinon), ECP (O-2,4-dichlorophenyl O,O-diethyl phosphorothioate (dichlofenthion)), DDVP (dichlorvos (dichlorvos)), Carbicron (dicrotophos), Rogor (dimethoate), dimethylvinphos (dimethylvinphos), two sulfur pine (disulfoton) (disulfoton), EPN (O-ethyl-O-(4-nitrobenzophenone) phenyl phosphorothioate (O-ethylO-4-nitrophenylphenylphosphonothioate)), Ethodan (ethion), ethoprop (ethoprophos), Dovip (Famphur), Nemacur (fenamiphos), MEP (fenifrothion (fenitrothion)), MPP (fenthion (fenthion)), lythidathion (fosthiazate), heptenophos (heptenophos), Isofenphos methyl (isofenphos-methyl), isocarbophos (Isocarbophos) (O-(Methoxyamino thiophosphoryl) isopropyl salicylate), azoles phosphorus (isoxathion), Malathion (malathion), Afos (mecarbam), Bayer 71628 (methamidophos), DMTP (methidathion (methidathion)), Menite (mevinphos), Azodrin (monocrotophos), BRP (2-dichloroethylk dimethyl phosphate (naled)), omethoate (omethoate), metilomerkaptofosoksid (oxydemeton-methyl), parathion (parathions), parathion-methyl (parathion-methyl), PAP (phenthoate dimephenthoate cidial (phenthoate)), thimet (phorate), zolone (phosalone), phosmet (phosmet), phosphamidon (phosphamidon), phoxim (phoxim), methyl pirimiphosmethyl (pirimiphos-methyl), Profenofos (profenofos), Propetamphos (propetamphos), BAY-NTN 8629 (prothiofos), pyraclofos (pyraclofos), Ofunack (pyridaphenthion), quintiofos (quinalphos), sulfotep (Sulfotep), butyl pyrimidine phosphorus (tebupirimfos), Swebate (temephos), Terbufos (terbufos), thiometon (thiometon), triazophos (triazophos), DEP (metrifonate (trichlorfon)), Kilval (vamidothion), Bayer22/190 (compd 22/190 (chlorothion)), bromobenzene alkene phosphorus (bromfenvinfos), bromofos (bromophos), Rilariol (bromophos-ethyl), special pyrimitate (butathiofos), carbophenothion (carbophenothion), chlorophoxim (Chlorphoxim), sulprofos (sulprofos), Nellite (diamidafos), CVMP (Ravap (tetrachlorvinphos)), Kayaphos (propaphos), fenthion sulfoxide (mesulfenfos), salithion (salithion) (dioxabenzofos), etrimfos (etrimfos), oxydeprofos (oxydeprofos), peace fruit (formothion), O,O-diethyl O-[p-(methylsulfinyl)phenyl (fensulfothion), isazofos (isazofos), imicyafos (AKD3088), isamidofos, nemaphos (thionazin), the organophosphorus compounds such as fosthietan (fosthietan);
The oxime carbamates compounds such as second the third phosphorus prestige (phosphocarb), alanycarb (alanycarb), butocarboxim (butocarboxim), butanone sulfone prestige (butoxycarboxim), thiodicarb (thiodicarb), thiofanox (Thiofanox);
Aldicarb (aldicarb), worm prestige (bendiocarb), Benfuracard micro (benfuracarb), NAC (carbaryl (carbaryl)), carbofuran (carbofuran), carbosulfan (carbosulfan), ethiofencarb (ethiofencarb), BPMC (Osbac (fenobucarb)), Carzol (Formetanate), furathiocarb (furathiocarb), MIPC (Mobucin (isoprocarb)), mercaptodimethur (methiocarb), methomyl (methomyl), oxamyl (oxamyl), Aphox (pirimicarb), PHC (arprocarb (propoxur)), Landrin (trimethacarb), XMC (3,5-xylyl methylamino acid methyl ester (3,5-xylylmethylcarbamate)), allyxycarb (allyxycarb), Aldicarb sulfone (aldoxycarb), metalkamate (bufencarb), butacarb (butacarb), sok (carbanolate), MTMC (meta-tolyl-N-methylcarbamate (MTMC) (metolcarb)), MPMC (Meobal (xylylcarb)), fenothiocarb (fenothiocarb), Deng carbamate compound;
The anabasine compounds such as acetamiprid (acetamiprid), clothianidin (clothianidin), MTI-446 (dinotefuran), imidacloprid (imidacloprid), Nitenpyram (nitenpyram), thiacloprid (thiacloprid), Diacloden (thiamethoxam);
The bishydrazide compounds such as ring tebufenozide (chromafenozide), chlorine tebufenozide (halofenozide), methoxyfenozide (methoxyfenozide), tebufenozide (tebufenozide);
Bistrifluron (bistrifluron), UC 62644 (chlorfluazuron), TH-6040 (diflubenzuron), flucycloxuron (flucycloxuron), Cascade (flufenoxuron), HEXAFLUMURON (hexaflumuron), fluorine the third oxygen urea (lufenuron), Novaluron (novaluron), noviflumuron (noviflumuron), Teflubenzuron (teflubenzuron), the benzoyl urea compounds such as parasite killing grand (triflumuron);
The juvenile hormone compounds such as ABG-6215 (fenoxycarb), hydroprene (hydroprene), kinoprene (kinoprene), alkene worm propyl ester (methoprene), pyriproxyfen (pyriproxyfen);
The cyclic diolefine organochlorine compounds such as Niran (chlordane), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan), gamma hch (lindane (gamma-HCH)), everywhere gram (dienochlor);
2-dimethylaminopropanecompounds-1 such as cartap hydrochlorate (Cartaphydrochloride), thiocyclam (thiocyclam), 3-dithiols compound;The amidine compounds such as amitraz (amitraz);
The benzopyrazoles compounds such as ethiprole (ethiprole), Frontline (fipronil), second phthalein worm cured (acetoprole);
The organic tin compounds such as azacyclotin (azocyclotin), plictran (cyhexatin), fenbutatin oxide (fenbutatin oxide) (fenbutatinoxide);
The METI compounds such as fenazaquin (fenazaquin), fenpyroximate (fenpyroximate), pyridaben (pyridaben), pyrimidifen (pyrimidifen), tebufenpyrad (tebufenpyrad), Tolfenpyrad (tolfenpyrad);
The benzilic acid ester type compounds such as bromine demodicid mite special (bromopropylate);
The pi-allyl azoles such as chlorfenapyr (chlorfenapyl);
The dinitrophenol compounds such as DNOC, binapacryl (binapacryl);
The anthryl diamide compounds such as DPX-E2Y45 (Rynaxypyr (chlorantraniliprole)), DPX-HGW86 (bromine cyanogen insect amide (cyantraniliprole)), cyclaniliprole;
The diazines compounds such as diazole worm (indoxacarb);The semicarbazones compounds such as metaflumizone (metaflumizone);
The tetronic acid compounds such as Envidor (spirodiclofen), Spiromesifen (spiromesifen);
The carbamyl triazole class compounds such as triaguron (triazamate);
The tetrazine kind compounds such as flufenzine (diflovidazin);
Avilamycin (abamectin), acequinocyl (acequinocyl), Ai Zhading (azadirachtin), bensultap (bensultap), Citrazon (Benzoximate), Bifenazate (bifenazate), Buprofezin (buprofezin), CGA-50439, chinomethionat (chinomethionat), clofentezine (clofentezine), cryolite (cryolite), cyromazine (cyromazine), dazomet (dazomet), DCIP, DDT, diafenthiuron (diafenthiuron), D-D (1,3-dichloropropylene (1,3-Dichloropropene)), dicofol (dicofol), CGA 183893 (dicyclanil), dinobuton (dinobuton), dinocap (dinocap), ENT8184, according to killing demodicid mite (etoxazole), flonicamid (flonicamid), fluacrypyrim (fluacrypyrim), fipronil bisamide (flubendiamide), GY-81 (peroxycarbonates), Hexythiazox (hexythiazox), Hydramethylnon Bait (hydramethylnon), hydrocyanic acid (Hydrogencyanide), iodomethane (methyliodide), karanjin (karanjin), MB-599 (verbutin), mercuric chloride (mercurychloride),
Metham-sodium (metam), methoxychlor (methoxychlor), methyl mustard oil (methylisothiocyanate), kill your demodicid mite element (milbemectin), pentachlorophenol (pentachlorophenol), hydrogen phosphide (phosphine), piperonyl butoxide (piperonylbutoxide), compound polynactin (polynactins), BPPS (propargite (propargite)), pymetrozine (pymetrozine), pyrethrin (pyrethrins), pyridalyl (pyridalyl), rotenone (rotenone), S421 (double, two (2,3,3,3-tetra-chloropropyl) ether), jervine (sabadilla), pleocidin (spinosad), Sulcofuron salt (Sulcofuron-sodium (sulcofuron-sodium)), sulfluramid (sulfluramid), tetradiphon (tetradifon), Cupric sulfate (monosultap (dimehypo-mono-sodium (thiosultap-monosodium))), De-Green (Tribufos), drinox (aldrin), match result (amidithion), amidothioate, aminocarb (aminocarb), O,O-diethyl S-(.beta.-diethylamino)ethyl phosphorothiolate (amiton), aramite (aramite), ethyl methidathion (athidathion), Alamos (azothoate), solbar (bariumpolysulphide), Bayer22408, Bayer32394, benclothiaz, 5-(1,3-benzodioxole-5-base)-3-hexyl-2-cyclonene, 1,1-double, two (4-chlorphenyl)-cellosolvos, butyl ester phosphine (butonate), dihydropyrone (butopyronoxyl), 2-(2-Butoxyethoxy) ethyl rhodanate acid esters, toxaphene (camphechlor), chlorbenside (chlorbenside), kepone (chlordecone), Spanon (chlordimeform), Qikron (chlorfenethol), chlorfenizon (chlorfenson), Isoprothiolane (isoprothiolane), fluorine fluazuron (fluazuron), lepimectin, spinetoram, emamectin-benzoate (emamectinbenzoate), the methaldehyde (metaldehyde), fenisobromolate (phenisobromolate), fluazinam (fluazinam), bilanafos (bialaphos), benomyl (benomyl), hydrochloric acid levamisole (levamisol), pyrifluquinazon (NNII0101), cyflumetofen (cyflumetofen), sulfanilamide dragonfly vinegar (amidoflumet), IKA-2005, nitrile pyrrole demodicid mite ester (cyenopyrafen) (NC512), spiral shell worm ethyl ester (spirotetramat) (BYI08330), sulfoxaflor (sulfoxaflor), pyrafluprole (V3039), pyriprole (V3086), bromo pyrrole carbonitrile (tralopyril), Flupyrazofos-containpesticide (flupyrazofos), luxuriant ether (diofenolan), chlorobenzilate (chlorobenzilate), flufenzine (flufenzine), Citrazon (benzomate), crow worm amine (flufenerim), tripropyl isocyanuric acid ester (Tripropylisocyanurate) (TPIC), albendazole (albendazole), oxibendazole (oxibendazole), bensultap (bensultap), Phenbendasol (fenbendazole), metham-sodium sodium (metam-sodium), 1,3-dichloropropylene (1,3-dichloropropene), cyclaniliprole, flometoquin, flupyradifurone, triflumezopyrim, the insecticides such as pyflubumide, acaricide, nematicide;
Chloropicrin (chloropicrin), Bromofume (EDB), vikane (sulfurylfluoride), acrylonitrile (acrylonitrile), double, two (2-chloroethyl) ether, the bromo-2-ethyl chloride of 1-, the chloro-1-propylene of the bromo-1-of 3-, bromocyclne (bromocyclen), Carbon bisulfide (carbondisulfide), carbon tetrachloride (tetrachloromethane), metham-sodium (methamsodium), nemadectin (nemadectin), the fumigant such as aluminum phosphate (aluminumphosphide);
Bacillus thuringiensis delta-endotoxin (Bacillusthuringiensisdelta-endotoxin), Borax (borax), calcium polysulfide (calciumpolysulfide), cryolite (cryolite), the basic element of cell division (cytokinin), nicotine (nicotine), keep away worm alcohol, potassium oleate (potassiumoleate), enuatrol (sodiumoleate), machine oil (machineoil), sulfur (sulfur), coal tar (taroil), anabasine (anabasine), pyrantel tartrate (moranteltartrate), Pyrethrum (pyrethrin (pyrethrum)), nicotine neutral sulfate. (nicotinesulfate), Oleum Brassicae campestris (rapeseedoil), soybean lecithin (soybeanlecithin), starch (starch), hydroxypropyl starch (hydroxypropylstarch), fatty glyceride (decanoyloctanoylglycerol), propylene glycol mono (propyleneglycolfattyacidester), kieselguhr (diatomite), the natural goods compounds such as bacillus thuringiensis (Bacillusthuringiensis);
Additionally, in the Pesticidal blend compositions of the present invention, as can with other compounds of the amide derivatives compound combination of the present invention and antibacterial, such as can enumerate nitrile Fluoxastrobin (azoxystrobin), imines bacterium (kresoxim-methyl), pyraclostrobin (pyraclostrobin), ZEN 90160 (picoxystrobin), fluoxastrobin (fluoxastrobin), dimoxystrobin (dimoxystrobin), orysastrobin (orysastrobin), fork phenalgin amide (metominostrobin), trifloxystrobin (trifloxystrobin), Enestroburin (enestroburin), azoles amine bacterium ester (pyrametostrobin), pyraoxystrobin (pyraoxystrobin) etc. are addicted to cone umbrella compounds;
Simeconazoles (simeconazole), Tebuconazole (tebconazole), RH-7592 (fenbuconazole), hexaconazole (hexaconazole), amide azoles (imibenconazole), triazolone (triadimefon), fluorine ether azoles (tetraconazole), prothioconazoles (prothioconazole), triticonazole (triticonazole), epoxiconazole (epoxiconazole), plant bacterium azoles (ipconazole), metconazole (metconazole), propiconazole (propiconazole), cyproconazole (cyproconazole), ether azoles (difenoconazole), olefin conversion (diniconazole), Fluquinconazole (fluquinconazole), bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane (flusilazole), Wu Junzuo (penconazole), bromuconazole (bromuconazole), Triadimenol (triadimenol), Flutriafol (flutriafol), nitrile bacterium azoles (myclobutanil), etaconazole (etaconazole), the triazole class compounds such as Bitertanol (bitertanol);
The glyoxaline compounds such as oxpoconazole fumarate (oxpoconazole-fumarate), fluorine bacterium azoles (triflumizole), IMAZALIL (imazalil), IMAZALIL-S (imazalil-S), prochloraz (prochloraz), pefurazoate (pefurazoate), triazoxide (triazoxide), Fenamidone (fenamidone);
Pyrrole metsulfovax (penthiopyrad), flutolanil (flutolanil), furan pyrazoles spirit (furametpyr), Boscalid (boscalid), fenhexamid (fenhexamid), cyflufenamid (cyflufenamid), tecloftalam (tecloftalam), mandipropamid (mandipropamide), biphenyl pyrrole bacterium amine (bixafen), carboxin (carboxin), oxycarboxin (oxycarboxin), third oxygen mebenil (mepronil), Silthiopham (silthiofam), thifluzamide (thifluzamide), fluorine biphenyl bacterium (flumetover), Guardian (ethaboxam), zoxamide (zoxamide), tiadinil (tiadinil), isotianil (isotianil), double, two chlorine zarilamids (diclocymet), zarilamid (fenoxanil), fluopicolide (fluopicolide), fluopyram (fluopyram), fluorine ring propionic acid amide. (carpropamid), Tolfenpyrad (tolfenpyrad), fluorine azoles bacterium aniline (penflufen), fluorine azoles ring bacterium amine (sedaxane), isopyrazam (isopyrazam), 3-difluoromethyl-N-[4 '-(3,3-dimethyl butine-1-base) biphenyl-2-base]-1-methyl isophthalic acid H-pyrazole-4-carboxamide, 3-difluoromethyl-N-[4 '-(3-methoxyl group-3-methyl butyne-1-base) biphenyl-2-base]-1-methyl isophthalic acid H-pyrazole-4-carboxamide, the carboxamides such as fluxapyroxad (fluxapyroxad);
The anilid compounds such as metalaxyl (metalaxyl), metalaxyl-M (metalaxyl-M), M 9834 (benalaxyl), M 9834-M (benalaxyl-M), furalaxyl-M (furalaxyl-M);
Benzene metsulfovax (benthiavalicarb-isopropyl), iprovalicarb (iprovalicarb), downy mildew go out valine amide compounds such as (valifenalate);
Cyazofamid (cyazofamid), the peace U.S. speed sulfamide compound such as (amisulbrom), flusulfamide (flusulfamide);
Tolyfluanid (tolylfluanid), Euparen (dichlofluanid) grade sulfamide compound;
The carbamate compounds such as hundred dimensions spirit (propamocarb), hundred dimensions spirit hydrochlorate (propamocarbhydrochloride), diethofencarb (diethofencarb), pyrrole bacterium benzene prestige (pyribencarb);
The dithio amino formate compounds such as Mancozeb (mancozeb), maneb (maneb), propineb (propineb), zineb (zineb), Carbatene (metiram), ziram (ziram), thiuram (thiram), polycarbamate (polycarbamate);
The dicarboximide compounds such as isopropyl fixed (iprodione), procymidone (procymidone), captan (captan), vinclozolin (vinclozolin), chlozolinate (chlozolinate), folpet (folpet);
The guanidine compounds such as iminoctadine alkane benzene sulfonate (iminoctadine-albesilate), iminoctadine triacetate (iminoctadine-triacetate), Guanoctine (guazatine), dodine (dodecylguanidine-acetate);
The phonetic bacterium spirit pyrimidines such as (bupirimate), fluorine mepanipyrim (diflumetorim) of mepanipyrim (mepanipyrim), fenarimol (fenarimol), ferimzone (ferimzone), cyprodinil (cyprodinil), dimethyl mepanipyrim (pyrimethanil), nuarimol (nuarimol), dimethirimol (dimethirimol), sulphur;
The morpholine kind compounds such as dimethomorph (dimethomorph), butadiene morpholine (fenpropimorph), tridemorph (tridemorph), dodemorfe (dodemorph), flumorph (flumorph);
The benzimidazoles compounds such as thiophanate methyl (thiophanate-methyl), thiophanate (thiophanate), benomyl (benomyl), carbendazim (carbendazim), Apl-Luster (thiabendazole), furidazol (fuberidazole);
Cough up the azoles such as bacterium ester (fludioxonil), fluoromide (fluoroimide), fenpiclonil (fenpiclonil);
The organophosphorus compounds such as fosetyl (fosetyl), Hinosan (edifenphos), tolelofos-methyl (tolclofos-methyl), iprobenfos (iprobenfos), pyrazophos (pyrazophos);
The copper compounds such as Copper hydrate (copperhydroxide), copper (copper), alkalescence copper chloride (basiccopperchloride), basic cupric sulfate (basiccoppersulfate), copper 8-quinolinolate (copper-oxinate), copper sulfate five water salt (coppersulfate), anhydrous cupric sulfate (coppersulfateanhydride), nonyl benzene cupric sulfocarbolate (coppernonylphenolsulfonate), DBEDC;
The antibiotic such as kasugarnycin (kasugamycin), valida (validamycin), polyoxin derivant (polyoxins), blasticidin-S S benzylamino benzene sulfonate (blastcidin-Sbenzylaminobenzenesulfonatesalt), streptomycin (streptomycin), natamycin (natamycin), midolthromycin (mildiomycin), oxytetracycline (oxytetracycline);
The organochlorine compounds such as Bravo (chlorothalonil), Rabcide (fthalide), pentachloronitrobenzene (quintozene);
The chloro-7-of 5-(4-methyl piperidine-1-base)-6-(2, 4, 6-trifluorophenyl) [1, 2, 4] triazol [1, 5-a] pyrimidine, 5-chloro-N-[(1S)-2, 2, the fluoro-1-Methylethyl of 2-tri-]-6-(2, 4, 6-trifluorophenyl) [1, 2, 4] triazol [1, 5-a] pyrimidine, 5-chloro-N-[(1R)-1, 2-dimethyl propyl]-6-(2, 4, 6-trifluorophenyl) [1, 2, 4] triazol [1, 5-a] pyrimidine, 5-(methoxy)-6-octyl group [1, 2, 4] triazol [1, 5-a] pyrimidine-7-amine, the triazolopyrimidines such as azoles mepanipyrim (ametoctradin);
The benzoyl compound such as metrafenone (metrafenone), 3-(2,3,4-trimethoxy-6-methyl benzoyl)-5-chloro-2-methoxyl group-4-picoline;
3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazolidine-3-base] isoxazolidine (isoxazolidine) compounds such as pyridine, 3-[2,3-dimethyl-5-(4-aminomethyl phenyl) isoxazolidine-3-base] pyridine, 3-[2-isopropyl-3-methyl-5-(4-chlorphenyl) isoxazolidine-3-base] pyridine;
Quinoxyfen (quinoxyfen), tebufloquin, 3-(5-fluoro-3,3,4,4-tetramethyls-3,4-dihydro-isoquinoline-1-base) quinoline, 3-(4, fluoro-3,3-dimethyl-3 of 4-bis-, 4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4, fluoro-3,3-dimethyl-3 of 5-tri-, 4-dihydro-isoquinoline-1-base) quinolines such as quinoline;
The thiazolidine compounds such as flutianil;
The pyrazolone compounds such as 1-[(2-acrylic sulfo-) carbonyl]-2-(1-Methylethyl)-4-(2-aminomethyl phenyl)-5-amino-1H-pyrazoles-3-ketone, 1-[(ethylenebis dithiocarbamate) carbonyl]-2-(1-Methylethyl)-4-(2-aminomethyl phenyl)-5-amino-1H-pyrazoles-3-ketone, 1-[(ethylenebis dithiocarbamate) carbonyl]-2-(1-Methylethyl)-4-(2,6-Dichlorobenzene base)-5-amino-1H-pyrazoles-3-ketone;
Hymexazol (hydroxyisoxazole), fluazinam (fluazinam), diclomezine (diclomezine), tricyclazole (tricyclazole), cymoxanil (cymoxanil), famoxadone (famoxadone), Fenamidone (fenamidone), chloropicrin (chloropicrin), thiadiazine (thiadiazin), third oxygen quinoline (proquinazid), spiroxamine (spiroxamine), fenpropidin (fenpropidin), Delan (dithianon), Pencycuron (pencycuron), Isoprothiolane (isoprothiolane), probenazole (probenazole), resveratrol (resveratrol), triforine (triforine), my acid benzene-S-methyl (acibenzolar-S-methyl), pyroquilon (pyroquilon), dinocap (dinocap), organic nickel (nickeldimethyldithiocarbamate), kobam (etridiazole), frost spirit (oxadinil), ambam (amobam), pyrifenox (pyrifenox), oxolinic acide (oxolinicacid), phosphorous acid (phosphorousacid), dazomet (dazomet), methyl mustard oil (methylisothiocyanate), methasulfocarb (methasulfocarb),
Iodomethane (methyliodide), sulfur (sulfur), lime sulfur (limesulphurmixture), fentin hypochlorite (fentinhypochlorousacid), chinomethionat (quinomethionate), chloroneb (chloroneb), anilazine (anilazine), isopropyl disappears (nitrothal-isopropyl), plant clothing ester (fenitropan), botran (dicloran), benthiozole (benthiazole), trichlamide (trichlamide), first hydroxyl isoxazole potassium (hydroisoxazole-potassium), hydration sulfur agent (wettablesulfur), zinc sulfate (zincsulfate), sodium bicarbonate (sodiumhydrogencarbonate), potassium bicarbonate (potassiumhydrogencarbonate), sodium hypochlorite (sodiumhypochlorote), argent (silver), Oleum Brassicae campestris (rapeseedoil), machine oil (machineoil), Harpin albumen (harpinprotein), chlorocholine chloride (chlormequat), paclobutrazol (paclobutrazol) and tolprocarb etc.。
There is also, in the above-mentioned compound enumerated, the compound that can obtain tacticity, the present invention also comprises above-mentioned isomer。
The Pesticidal blend compositions of the present invention can effectively prevent and kill off following insect using low concentration: as the various agricultural pests of harm agriculture garden crop and trees etc., the living environment of the people in house etc. is brought dysgenic sanitary insect pest, the grain storage pest of the corn etc. stored in harm warehouse, the insects of the timber food insect etc. of the timber of harm building etc., and produce under similar circumstances, and carry out the demodicid mite class endangered, shell-fish, Mollusca, arbitrary harmful organism in nematode。
The Pesticidal blend compositions that can use the present invention carries out insects, demodicid mite class, shell-fish, Mollusca and the nematode prevented and kill off, specifically such as can enumerate:
Tea Ji's leaf roller (Adoxophyeshonmai), tea olethreutid (Adoxophyesoranafaciata), pears Huang volume moth (Archipsbreviplicanus), manchurian fruit (Grapholitainopinata), random stricture of vagina apple skin worm (Archipsfuscocupreanus), oriental fruit months (Grapholitamolesta), Homona magnanima (Choristoneuramagnanima), eating-core bean worm (Leguminivoraglycinivorella), Mulberry leaf roller (Olethreutesmori), the thin moth of Fructus Mali pumilae (Caloptiliazachrysa), Fructus Persicae Eucosmaspp (Argyresthiaconjugella), the thin moth of pears (Spulerrinaastaurota), bean steinernema (Matsumuraesesphaseoli), the brown leaf roller of Fructus Mali pumilae (Pandemisheparana), pears shuttle fruit moth (Bucculatrixpyrivorella), apple leaf miner (Lyonetiaclerkella), small heart-eating peach worm (Carposinaniponensis), crazing lyonetid (Lyonetiaprunifoliellamalinella), the thin moth of tea (Caloptiliatheivora), the little thin moth (Phyllonorycterringoniella) of diving of Jin Wen, Citrus leaf lyonetid (Phyllocnistiscitrella), Herba Alii fistulosi diamond-back moth (Acrolepiopsissapporensis), Rhizoma Dioscoreae puppet diamond-back moth (Acrolepiopsissuzukiella), diamondback moth (Plutellaxylostella), limb moth (Stathmopodamasinissa) lifted by Fructus Kaki, Rhizoma Dioscoreae esculentae sun gelechiid (Helcystogrammatriannulella), Pectinophora gossypiella (Pectinophoragossypiella), peach fruit moth (Carposinasasakii), striped rice borer (Chilosuppressalis), rice leaf roller (Cnaphalocrocismedinalis), tobacco powder sp (Ephestiaelutella), dichocrocis punctiferalis (Conogethespunctiferalis), Diaphania indica (Diaphaniaindica), soybean pod phycitid (Etiellazinckenella), Mulberry thin,tough silk open country snout moth's larva (Glyphodespyloalis), some snout moth's larvas (Scirpophagaincertulas), Oeobia undalis (Hellulaundalis), Ostrinia furnacalis (Ostriniafurnacalis), bean stalk open country snout moth's larva (Ostriniascapulalis), crambid (Parapediasiateterrella), rice hesperiidae (Parnaraguttata), large white butterfly (Pierisbrassicae), cabbage butterfly (Pierisrapaecrucivora), papilio xuthus Linnaeus (Papilioxuthus), big bridging worm (Ascotisselenaria), Semen sojae atricolor noctuid (Pseudoplusiaincludens), euproctis pseudoconspersa (Euproctispseudoconspersa), gypsymoth (Lymantriadispar), rotation orgyia antiqua (Orgyiathyellina), autumn curtain moth (Hyphantriacunea), peculiar prestige Artiae caja (Lemyraimparilis), withered leaf noctuid (Adristyrannus), white macula is tired of noctuid (Aedialeucomelas), agrotis ipsilo eta (Agrotisipsilon), Radix Brassicae rapae noctuid (Agrotissegetum), stain three-spotted plusia (Autographanigrisigna), three-spotted plusia (Ctenoplusiaagnata), codling moth (Cydlapomonella), bollworm (Helicoverpaarmigera), tobacco budworm (Helicoverpaassulta), paddy reality noctuid (Helicoverpazea), tobacco budworm (Heliothisvirescens), Pyrausta nubilalis (Hubern). (Ostrinianubilalis), lopper worm (Mamestrabrassicae), mythimna separata (Mythimnaseparata), pink rice borer (Sesamiainferens), rice green caterpillar (Narangaaenescens), south spodoptera (Spodopteraeridania), beet armyworm (Spodopteraexigua), noctuid (Spodopterafrugiperda) is coveted on meadow, sea spodoptera (Spodopteralittoralis), Prodenia litura (Spodopteralitura), Spodoptera depravata (Spodopteradepravata), cabbage looper (Trichoplusiani), Fructus Vitis viniferae certain kind of berries fruit moth (Endopizaviteana), Fructus Lycopersici esculenti hawkmoth (Manducaquinquemaculata), the lepidopteran insects such as maduca sexta (Manducasexta);
Fructus Vitis viniferae Ah jassids (Arboridiaapicalis), black breast two Room leafhopper (Balcluthasaltuella), 2 cicadellids (Epiacanthusstramineus), Semen Viciae fabae Empoasca spp (Empoascafabae), Empoascanipponica, pass through greatly smaller green leaf hopper (Empoascaonukii), plate well smaller green leaf hopper (Empoascasakaii), Macrostelesstriifrons, rice green leafhopper (Nephotettixcinctinceps), Psuedatomoscelisseriatus, small brown rice planthopper (Laodelphaxstriatella), brown paddy plant hopper (Nilaparvatalugens), white backed planthopper (Sogatellafurcifera), diaphorina citri (Diaphorinacitri), pear sucker (Psyllapyrisuga), citrus spiny white fly (Aleurocanthusspiniferus), Bemisia argentifolii (Bemisiaargentifolii), Nicotiana tabacum L. aleyrodid (Bemisiatabaci), Citrus aleyrodid (Dialeurodescitri), Trialeurodes vaporariorum Westwood (Trialeurodesvaporariorum), Japanese grape powder louse (Aleurolobustaonabae), grape phylloxera (Viteusvitifolii), radish aphid (Lipaphiserysimi), cotten aphid (Aphisgossypii), spiraea aphid (Aphisspiraecola), black peach aphid (Myzuspersicae), black citrus aphid (Toxopteraaurantii), giant mealy bug (Drosichacorpulenta), icerya purchasi (Iceryapurchasi), Bulbus Lycoridis Radiatae silk floss mealybug (Phenacoccussolani), the green continuous lecanium (Pulvinariaaurantii) of Fructus Citri tangerinae, Fructus Citri tangerinae buttocks stricture of vagina mealybug (Planococcuscitri), mandarin orange circle scale insect (Pseudaonidiaduplex), rattan buttocks stricture of vagina mealybug (Planococcuskuraunhiae), Kang Shi powder scale insect (Pseudococcuscomstocki), pears circle scale insect (Comstockaspisperniciosa), ceroplastes (Ceroplastesceriferus), ceroplastes rubens (Ceroplastesrubens), California red scale (Aonidiellaaurantii), tea place shield scale insect (Fioriniatheae), Paeonia suffruticosa net armored scale (Pseudaonidiapaeoniae), white mulberry scale (Pseudaulacaspispentagona), the white a red-spotted lizard of prunus mume (sieb.) sieb.et zucc. (Pseudaulacaspisprunicola), winged euonymus sloughs off armored scale (Unaspiseuonymi), arrowhead scale (Unaspisyanonensis), bed bug (Cimexlectularius), Dolycoris baccarum (Dolycorisbaccarum), wrinkle cabbage bug (Eurydemarugosum), north two star stinkbugs (Eysarcorisaeneus), Japan two star stinkbugs (Eysarcorislewisi), black abdomen stinkbug (Eysarcorisventralis), blue or green stinkbug (Glauciassubpunctatus), eating attraction (Halyomorphahalys), the green rice stinkbug (Nezaraantennata) of black palpus, Nezara viridula smaragdula Fabricius. (Nezaraviridula), ancient piece of jade, round, flat and with a hole in its centre stinkbug (Piezodorushybneri), amber stinkbug (Plautiacrossota), scotinophora lurida (Scotinophoralurida), rice spiny coreid (Cletuspunctiger), China's Leptocorisa spp (Leptocorisachinensis), rod peak coried (Riptortusclavatus), Radix Dauci Sativae coried (Rhopalusmsculatus), Caulis Sacchari sinensis chinch bug (Caveleriussaccharivorus), calabash chinch bug (Togohemipterus), continuous red stinkbug (Dysdercuscingulatus), Cuculus polioephalus hat lace bug (Stephanitispyrioides), Halticusinsularis, America tarnished plant bug (Lyguslineolaris), the narrow fleahopper in Siberia (Stenodemasibiricum), red bar fibre fleahopper (Stenotusrubrovittatus), the hemipterans such as rice leaf insect (Trigonotyluscaelestialium);
Bronze different beetle (Anomalacuprea), Ji Gold Testudinis (Anomalarufocuprea), little blue and white Gold Testudinis (Gametisjucunda), Colophonium seven cheek Gold Testudinis (Heptophyllapicea), bean Gold Testudinis (Popilliajaponica), colorado potato beetles (Lepinotarsadecemlineata), mexican bean ladybird (Epilachnavarivestis), Radix Ipomoeae comb pawl click beetle (Melanotusfortnumi), multitudinous comb pawl Pleonomus (Melanotustamsuyensis), cigarette beetle (Lasiodermaserricorne), bamboo boring-powder (Lyctusbrunneus), vertical pit cutting pin small moth (Tomicuspiniperda), lesser grain borer (Rhizoperthadominica), Epuraeadomina, mexican bean ladybird (Epilachnavarivestis), potato ladybug (Epilachnavigintioctopunctata), tenebrio molitor (Tenebriomolitor), red flour beetle (Triboliumcastaneum), longicorn beetle (Anoplophoramalasiaca), Monochamus alternatus (Monochamusalternatus), yellow star Anoplophorae seu Aprionae (Psacotheahilaris), grape borer (Xylotrechus pyrrhoderus) (Xylotrechuspyrrhoderus), Callosobruchus chinensis (Callosobruchuschinensis), aulacophora femoralis (Aulacophorafemoralis), rice leaf beetles (Oulemaoryzae), dish flea beetle (Chaetocnemaconcinna), Fructus Cucumidis sativi point chrysomelid (Diabroticaundecimpunctata), corn root leaf A (Diabroticavirgifera), northern com rootworm (Diabroticabarberi), yellow bar leaf flea (Phyllotretastriolata), the narrow breast flea beetle (Psylliodesangusticollis) of eggplant, Fructus Persicae real image (Rhynchitesheros), cylas formicarius (Cylasformicarius), Mexico's cotton boll is as (Anthonomusgrandis), rice is as (Echinocnemussquameus), western India Rhizoma Dioscoreae esculentae is as (Euscepespostfasciatus), alfalfa leaf is as (Hyperapostica), rice water weevil (Lissorhoptrusoryzophilus), vine black ear beak is as (Otiorhynchussulcatus), grain weevil (Sitophilusgranarius), sitophilus zea-mais (Sitophiluszeamais), Sphenophorusvenatusvestitus, the coleopterons such as blue or green wing rove beetle (Paederusfuscipes);
Total homopterous insects such as flower thrips (Frankliniellaintonsa), golden thistle horse (Thripsflavus), western classical architecture (Frankliniellaoccidentalis), greenhouse thrips (Heliothripshaemorrhoidalis), Scirothrips dorsalis (Scirtothripsdorsalis), south golden thistle horse (Thripspalmi), onion thrips (Thripstabaci), Ponticulothripsdiospyrosi;
Asphondyliayushimai, wheat midge (Sitodiplosismosellana), melon fly (Bactroceracucurbitae), citrus fruit fly (Bactroceradorsalis), Mediterranean fruitfly (Ceratitiscapitata), hydrellia griseola (Hydrelliagriseola), Fructus Pruni pseudocerasi fruit bat (Drosophilasuzukii), rice stem maggot (Agromyzaoryzae), Semen Pisi sativi coloured silk is dived fly (Chromatomyiahorticola), Liriomyza brponiae (Liriomyzabryoniae), Biological habit (Liriomyzachinensis), vegetable leafminer (Liriomyzasativae), African Chrysanthemum liriomyza bryoniae (Liriomyzatrifolii), delia platura (Deliaplatura), onion fly (Deliaantique), Xiao Herba chenopodii spring fly (Pegomyacunicularia), Rhagoletis pomonella (Rhagoletispomonella), wheat cecidomyiia (Mayetioladestructor), housefly (Muscadomestica), tatukira (Stomoxyscalcitrans), sheep hippoboscid (Melophagusovinus), bomb fly (Hypodermabovis), heel fly (Hypodermalineatum), Oestrus ovis (Oestrusovis), glossina morsitans (Glossinapalpalis, Glossinamorsitans), Prosimuliumyezoensis, horsefly (Tabanustrigonus), white macula moth buffalo gnat (Telmatoscopusalbipunctatus), the thin midge (Leptoconopsnipponensis) of Japan, culex pipiens pallens (Culexpipienspallens), Aedes Aegypti (Aedesaegypti), Asia tiger mosquito (Aedesalbopicutus), Anopheleshyracanussinesis, the dipteral insects such as ground player whose turn comes next mosquito (Culexpipiensmolestus);
Apethymuskuri, Xinjiang cabbage sawfly (Athaliarosae), Agre papana Panz (Argepagana), pine and cypress Neodiprion spp (Neodiprionsertifer), Chestnut Gall Wasp (Dryocosmuskuriphilus), army antenna (Ecitonburchelli, Ecitonschmitti), this back of a bow ant (Camponotusjaponicus), Vespa magnifiac (Sonan). (Vespamandarina), bull ant (Myrmeciaspp.), red fire ant class (Solenopsisspp.), the hymenopterans such as little red ant (Monomoriumpharaonis);
The orthopterans such as yellow face Cryllus testaceus wallker (Teleogryllusemma), Oriental burmeister (Gryllotalpaorientalis), Locustamigratoria (Linnaeus) (Locustamigratoria), rice grasshopper (Oxyayezoensis), desert locust (Schistocercagregaria);
The Chaetonotoidea insecticides such as the white Onychiurus arcticus of dish (Onychiurusfolsomi), arctic Onychiurus arcticus (Onychiurussibiricus), yellow star sminthurid (Bourletiellahortensis);
The Dictyoptera insecticides such as Peroplaneta fluligginosa (Periplanetafuliginosa), Japan big Lian (Periplanetajaponica), Groton bug (Blattellagermanica), american cockroach (PeriplanetaAmericana);
Workers of Coptotermes formosanus Shiraki (Coptotermesformosanus), the isoptera insects such as north reticulitermes flavipe (Reticulitermessperatus), Odontotermes formosanus Shiraki (Odontotermesformosanus) of dwelling;
The isoptera insects such as cat flea (Ctenocephalidaefelis), dog flea (Ctenocephalidescanis), chicken flea (Echidnophagagallinacea), Pulex irritans (Pulexirritans), Xanthopsyllacheopis (Xenopsyllacheopis);
The Mallophaga insecticides such as corpus luteum poultry louse (Menacanthusstramineus), cattle bird lice (Bovicolabovis);
The Anoplura insecticides such as ox louse (Haematopinuseurysternus), haematopinus suis (Haematopinussuis), Linognathus vituli (Linognathusvituli), solenoptes capillatus (Solenopotescapillatus);
Angstrom demodicid mite classes such as primrose herbivore demodicid mite (Phytonemuspallidus), Polyphagotarsonemus latus Banks (Polyphagotarsonemuslatus), bilobate tarsonemid (Tarsonemusbilobatus);Penthaleuserythrocephalu, wheat leaf pawl demodicid mite (Penthaleusmajor) etc. walk demodicid mite class;The spider mite kinds such as true unguiculus demodicid mite (Oligonychusshinkajii), panonychus citri (Panonychuscitri), Mulberry Panonychus citri (Panonychusmori), panonychus ulmi (Panonychusulmi), kamisawa tetranychus (Tetranychuskanzawai), T.urticae Koch (Tetranychusurticae);Tea point leaf segment Ticks (Acaphyllatheavagrans), Flos Tulipae Gesnerianae wart demodicid mite (Aceriatulipae), Aculops lycopersici (Aculopslycopersici), Fructus Citri tangerinae peronium wart demodicid mite (Aculopspelekassi), Si Shi sting the wart demodicid mite classes such as wart demodicid mite (Aculusschlechtendali), Eriophyeschibaensis, Fructus Citri tangerinae wrinkle leaf Aculus (Phyllocoptrutaoleivora);
The flour mite classes such as anhui fritillary (Rhizoglyphusrobini), corrosion cheese demodicid mite (Tyrophagusputrescentiae), seemingly food cheese demodicid mite (Tyrophagussimilis);
Watt demodicid mite classes such as Varroa jacobsoni (Varroajacobsoni);Boophilus microplus (Boophilusmicroplus), brown dog tick (Rhipicephalussanguineus), haemaphysalis longicornis (Haemaphysalislongicornis), haemaphysalis flava (Haemophysalisflava), haemaphysalis campanulata (Haemophysaliscampanulata), ixodes ovatus (Ixodesovatus), ixodes persulcatus (Ixodespersulcatus), flower Ticks (Amblyommaspp.), the Ticks classes such as leather Ticks (Dermacentorspp.);The cheyletid mite classes such as dog Ji chela demodicid mite (Cheyletiellayasguri), cat Ji chela demodicid mite (Cheyletiellablakei);The vermiform mite classes such as demodicidosis (Demodexcanis), cat vermiform mite (Demodexcati);
The itch mite classes such as sheep itch mite (Psoroptesovis);The acaricide classes such as acaricide (Sarcoptesscabiei), cat back of the body anus demodicid mite (Notoedrescati), knee joint demodicid mite (Knemidocoptesspp.);
The shell-fish such as armadillidum vulgare (Armadillidiumvulgare);The gastropods such as Pomacea canaliculata (Pomaceacanaliculata), Achatina fulica (Ferussae). (Achatinafulica), two-wire Limax (Meghimatiumbilineatum), LimaxValentiana, Limax (Acustadespectasieboldiana), Japan soil Limax (Euhadrapeliomphala);
Coffee pot handle (Prathylenchuscoffeae), Cobb root (Prathylenchuspenetrans), disability Pratylenchidae (Prathylenchusvulnus), globodera rostochiensis (Globoderarostochiensis), soybean cyst nematode Heterodera glycines (Heteroderaglycines), M hapla (Meloidogynehapla), Meloidogyne incognita (Meloidogyneincognita), aphelenchoides besseyi (Aphelenchoidesbesseyi), the nematodies etc. such as Bursaphelenchus xylophilus (Bursaphelenchusxylophilus), but the present invention is not limited to this。
As the plant disease can prevented and kill off by the Pesticidal blend compositions of the present invention, such as can enumerate the rice blast (Pyriculariaoryzae) of Oryza sativa L., banded sclerotial blight (Thanatephoruscucumeris), water rice brown spot (Cochliobolusmiyabeanus), bakanae disease (Gibberellafujikuroi), seedling blight (Pythiumspp., Fusariumspp., Trichodermaspp., Rhizopusspp., Rhizoctoniasolani etc.), false smut (Clavicepsvirens), smut (Tilletiabarelayana);Powdery mildew (the Erysiphegraminisf.sp.hordei of wheat and barley;F.sp.tritici), rust (Pucciniastriiformis;Pucciniagraminis, Pucciniarecondita, Pucciniahordei), stripe disease (Pyrenophoragraminea), net blotch (Pyrenophorateres), head blight (Fusariumgraminearum, Fusariumculmorum, Fusariumavenaceum, Microdochiumnivale), snow mold (Typhulaincarnata, Typhulaishikariensis, Micronectriellanivalis), smut (Ustilagonuda, Ustilagotritici, Ustilagonigra, Ustilagoavenae), bunt (Tilletiacaries, Tilletiapancicii), eye spot (Pseudocercosporellaherpotrichoides), banded sclerotial blight (Rhizoctoniacerealis), moire disease (Rhynchosporiumsecalis), leaf blight (Septoriatritici), glume blight (Leptosphaerianodorum), seedling blight (Fusariumspp., Pythiumspp., Rhizoctoniaspp., Septorianodorum, Pyrenophoraspp.), damping-off (Gaeumannomycesgraminis), anthrax (Colletotrichumgramaminicola), ergot (Clavicepspurpurea), spot disease (Cochliobolussativus);The head blight (Fusariumgraminearum etc.) of Semen Maydis, seedling blight (Fusariumavenaceum, Penicilliumspp, Pythiumspp., Rhizoctoniaspp), rust (Pucciniasorghi), Folium Sesami pinta (Cochliobolusheterostrophus), smut (Ustilagomaydis), anthrax (Colletotrichumgramaminicola), Helminthosporium carbonum (Cochlioboluscarbonum);
The downy mildew (Plasmoporaviticola) of Fructus Vitis viniferae, rust (Phakopsoraampelopsidis), powdery mildew (Uncinulanecator), anthrachose of grape (Elsinoeampelina), late blight (Glomerellacingulata), black rot (Guignardiabidwellii), dead arm (Phomopsisviticola), coal point sick (Zygophialajamaicensis), gray mold (Botrytiscinerea), bud blight (Diaporthemedusaea), purple root rot (Helicobasidium mompa) (Helicobasidiummompa), white root rot (Rosellinianecatrix);The powdery mildew (Podosphaeraleucotricha) of Fructus Mali pumilae, scab (Venturiainaequalis), spot defoliation (Alternariaalternata (Applepathotype)), rust (Gymnosporangiumyamadae), blossom rot (Monilliamali), canker (Valsaceratosperma), ring spot (Botryosphaeriaberengeriana), anthrax (Colletotrichumacutatum), coal point sick (Zygophialajamaicensis), coal spot disease (Gloeodespomigena), diplostomiasis (Mycosphaerellapomi), purple root rot (Helicobasidium mompa) (Helicobasidiummompa), white root rot (Rosellinianecatrix), stem wilt (Phomopsismali, Diaporthetanakae), brown spot (Diplocarponmali);The melasma (Alternariaalternata (Japanesepearpathotype)) of pears, scab (Venturianashicola), rust (Gymnosporangiumharaeanum), ring spot (Physalosporapiricola), stem wilt (Diaporthemedusaea, Diaportheeres), Pyrus communis epidemic disease (Phytophthoracactorum);The scab (Cladosporiumcarpophilum) of Fructus Persicae, Phomopsis sick (Phomopsissp.), epidemic disease (Phytophthorasp.), anthrax (Gloeosporiumlaeticolor);The anthrax (Glomerellacingulata) of Fructus Pruni pseudocerasi, young fruit sclerotiniose (Moniliniakusanoi), grey scab (Moniliniafructicola);The anthrax (Gloeosporiumkaki) of Fructus Kaki, defoliation (Cercosporakaki;Mycosphaerellanawae), powdery mildew (Phyllactiniakakikora);The diplostomiasis (Diaporthecitri) of Citrus, green mould (Penicilliumdigitatum), penicilliosis (Penicilliumitalicum), shot hole (Elsinoefawcettii);
The gray mold (Botrytiscinerea) of Fructus Lycopersici esculenti, Fructus Cucumidis sativi, beans, Fructus Fragariae Ananssae, Rhizoma Solani tuber osi, Brassica oleracea L.var.capitata L., Fructus Solani melongenae, Caulis et Folium Lactucae sativae etc.;The sclerotiniose (Sclerotiniasclerotiorum) of Fructus Lycopersici esculenti, Fructus Cucumidis sativi, beans, Fructus Fragariae Ananssae, Rhizoma Solani tuber osi, Semen Allii Tuberosi, Brassica oleracea L.var.capitata L., Fructus Solani melongenae, Caulis et Folium Lactucae sativae etc.;The seedling blight (Rhizoctoniaspp., Pythiumspp., Fusariumspp., Phythophthoraspp., Sclerotiniasclerotiorum etc.) of the various vegetables such as Fructus Lycopersici esculenti, Fructus Cucumidis sativi, beans, Radix Raphani, Citrullus vulgaris, Fructus Solani melongenae, Semen Allii Tuberosi, Capsicum annuum L., Herba Spinaciae, Radix Betae;Melon downy mildew (Pseudoperonosporacubensis), powdery mildew (Sphaerothecafuliginea), anthrax (Colletotrichumlagenarium), blight dis-ease (Mycosphaerellamelonis), dead arm (Fusariumoxysporum), epidemic disease (Phytophthoraparasitica, Phytophthoramelonis, Phytophthoranicotianae, Phytophthoradrechsleri, Phytophthoracapsici etc.);The ring spot (Alternariasolani) of Fructus Lycopersici esculenti, leaf mold (Cladosporiumfulvam), epidemic disease (Phytophthorainfestans), droop (Fusariumoxysporum), root rot (Pythiummyriotylum, Pythiumdissotocum), anthrax (Colletotrichumphomoides);The powdery mildew (Sphaerothecafuliginea etc.) of Fructus Solani melongenae, sooty mould (Mycovellosiellanattrassii), epidemic disease (Phytophthorainfestans), brown rot (Phytophthoracapsici);The melasma (Alternariabrassicae) of Brassica campestris L, the melasma (Alternariabrassicae etc.) of brassicaceous vegetable, leukoderma (Cercosporellabrassicae), Root-rot disease (Leptospheriamaculans), clubroot (Plasmodiophorabrassicae), downy mildew (Peronosporabrassicae);The banded sclerotial blight (Rhizoctoniasolani) of Brassica oleracea L.var.capitata L., chlorosis (Fusariumoxysporum);The buttocks maize ear rot (Rhizoctoniasolani) of Chinese cabbage, yellows (Verticilliumdahlie);The rust (Pucciniaallii) of Herba Alii fistulosi, melasma (Alternariaporri), southern blight (Sclerotiumrolfsii.Sclerotiumrolfsii), white epidemic disease (Phytophthoraporri);The anaphylactoid purpura (Cercosporakikuchii) of Semen sojae atricolor, anthrachose of grape (Elsinoeglycinnes), diplostomiasis (Diaporthephaseololum), rhizoctonia root rot (Rhizoctoniasolani), cane blight (Phytophthoramegasperma), downy mildew (Peronosporamanshurica), rust (Phakopsorapachyrhizi), anthrax (Colletotrichumtruncatum);The anthrax (Colletotrichumlindemuthianum) of Kidney bean;The black of Semen arachidis hypogaeae relates to disease (Mycosphaerellapersonatum), brown spot (Cercosporaarachidicola);The powdery mildew (Erysiphepisi) of Semen Pisi sativi, downy mildew (Peronosporapisi);The downy mildew (Peronosporaviciae) of Semen Viciae fabae, epidemic disease (Phytophthoranicotianae);The summer epidemic disease (Alternariasolani) of Rhizoma Solani tuber osi, Rhizoctonia Disease (Rhizoctoniasolani), epidemic disease (Phytophthorainfestans), silver maize ear rot (Spondylocladiumatrovirens), dry rot (Fusariumoxysporum, Fusariumsolani), powdery scab (Spongosporasubterranea);The brown spot (Cercosporabeticola) of Radix Betae, downy mildew (Peronosporaschachtii), black root (Aphanomycescochioides), snake eye sick (Phomabatae);The black leaf blight (Alternariadauci) of Radix Dauci Sativae;The powdery mildew (Sphaerothecahumuli) of Fructus Fragariae Ananssae, epidemic disease (Phytophthoranicotianae), anthrax (Gromerellacingulata), breakdown of fruit sick (PythiumultimumTrowvar.ultimum);
The net cake of tea sick (Exobasidiumreticulatum), white star (Elsinoeleucospila), anthrax (Colletotrichumtheaesinensis), ring spot (Pestalotiopsislongiseta);The rust (Alternariaalternata (Tobaccopathotype)) of Nicotiana tabacum L., powdery mildew (Erysiphecichoracearum), anthrax (Colletotrichumtabacum), epidemic disease (Phytophthoraparasitica);Cotton damping-off (Fusariumoxysporum);
The sclerotiniose (Sclerotiniasclerotiorum) of Helianthi;The scab (Diplocarponrosae) of Flos Rosae Multiflorae, powdery mildew (Sphaerothecapannosa), epidemic disease (Phytophthoramegasperma), downy mildew (Peronosporasparsa);The brown spot (Septoriachrysanthemi-indici) of chrysanthemum, white blister (Pucciniahoriana), epidemic disease (Phytophthoracactorum);
The brown spot (Rhizoctoniasolani) of turfgrass, coin pinta (Sclerotiniahomoeocarpa), curved spore leaf blight (Curvulariageniculata), rust (Pucciniazoysiae), Helminthosporium leaf blight (Cochliobolussp.), moire disease (Rhynchosporiumsecalis), damping-off (Gaeumannomycesgraminis), anthrax (Colletotrichumgraminicola), the rotten brown sclerotium oryzicola (Typhulaincarnata) of snow, the rotten black small grain sclerotiniose (Typhulaishikariensis) of snow, snow big grain sclerotinia rot (Sclerotiniaborealis), collarium (Marasmiusoreades etc.), rotten mildew (Pythiumaphanidermatum etc.), rice blast (Pyriculariaoryzae) etc., but it is not limited to this。
The content preventing and kill off compounds effective (amide derivatives that formula (1) represents and other compounds) to harmful organism in the Pesticidal blend compositions of the present invention, under normal circumstances, it is 5~90 weight % when being 0.1~20 weight % and suspending agent when being 5~90 weight %, granule when being 4~50 weight %, wettable powder when being 0.5~20 weight %, Emulsion during powder。
On the other hand, the amount of inert carrier in each dosage form, it is generally the case that be 5~90 weight % when being 70~99 weight %, suspending agent when being 5~90 weight %, granule when being 40~95 weight %, wettable powder when being 60~99 weight %, Emulsion during powder。
It addition, the amount of auxiliary agent, it is generally the case that it is 0.1~20 weight % when being 0.1~20 weight %, suspending agent when being 0.1~20 weight %, granule when being 1~20 weight %, wettable powder when being 0.1~20 weight %, Emulsion during powder。
The Pesticidal blend compositions of the present invention, in order to prevent and kill off various harmful organism, by directly or with in the way of the suitably dilution such as water or making it suspended, the habitat being applied to harmful organism or harmful organism to prevent and kill off harmful organism effectively to measure。It makes consumption change according to the change of various factors (such as purpose, object harmful organism, the upgrowth situation of crop, the generation tendency of harmful organism, weather, environmental condition, dosage form, application process, use place, time of application etc.), generally every 1 are, the amount of application of effective ingredient is in the scope of 0.1g~1000g, suitably select preferably in the scope of 1g~500g。
As the Pesticidal blend compositions of the present invention being directly applied to harmful organism or being applied to the habitat of the harmful organism method to prevent and kill off harmful organism, the such as harmful organism for producing in fruit tree, frumentum, vegetable etc., except being dispersed in leaves and stems, it would however also be possible to employ soil holostrome processes, side slat is used, bed soil is mixed, processs of pipe Seedling, plant hole process, the process of plant root, foliage top dressing (topdressing), Oryza sativa L. nursery box process, used for ponds etc., soil etc. carried out process make it use from root absorption。In addition, it is also possible to used by using in the culture fluid that culture fluid (water planting) is cultivated, fumigation or trunk injection etc.。Further, except such as grain storage pest, house insect, sanitary insect pest, injurious forest-insect etc. can being spread, it is also possible to be coated on house building materials, as fumigation, bait formulation etc.。
By the Pesticidal blend compositions of the present invention being applied to the cutting of agricultural plant, it is possible to prevent and kill off the harmful organism that cutting produces in preservation。Namely, by the Pesticidal composition of the present invention, to prevent and kill off harmful organism and effectively measure, with directly or with in the way of the suitably dilution such as water or making it suspended, the cutting of agricultural plant or the place of retention of agricultural plant cutting sprayed, smear, be coated with, impregnate, after the results such as powder clothing, stifling fumigation or pressurization injection (postharvest) process。
The cutting of so-called agricultural plant, for instance Oryza sativa L. can be enumerated, Fructus Hordei Vulgaris, Semen Tritici aestivi, Semen Maydis, rye (Secale cereale L.), Herba bromi japonici, Semen Pisi sativi, Kidney bean, Semen vignae sinensis, red kidney bean (sultanibean), Semen Phaseoli (sultapyabean), Madagascar bean (butterbean), pegiabean, Semen Phaseoli Vulgaris (whitebean), Phaseolus lunatus L., Semen Viciae fabae, Semen sojae atricolor, Semen Phaseoli, Fructus Pruni, Fructus Armeniacae Mume, Fructus Pruni pseudocerasi, Fructus Pruni salicinae, Prunus persicanucipersica Schneider, Fructus Persicae, Fructus Citri junoris, grapefruit, Xia Cheng, satsuma orange, acid Fructus Citri tangerinae (sudach), Citrus aurantium Linn., Citrus aurantium Linn. from generation to generation, blue or green lemon (lime), Fructus Citri Limoniae, Folium Eriobotryae, , Fructus Mali pumilae, pears, Pyrus communis, American Avocado Tree, Fructus actinidiae chinensis, Fructus psidii guajavae immaturus, date palm, Fructus Ananadis comosi, passionfruit, Fructus Musae, Fructus Chaenomelis, Fructus Mangifera Indicae, Fructus Fragariae Ananssae, mossberry (cranberry), Fructus vaccini vitis-idaeae (huckleberry), blackberry, blue berry, Fructus Kaki, Citrullus vulgaris, Fructus Vitis viniferae, fragrant and sweet melon (orientalmelon), Fructus Melo (melon), Radix Brassicae rapae, Brassica oleracea L. var. botrytis L., Brassica oleracea L.var.capitata L., Radix Raphani, Chinese cabbage, komatsuna, Herba Oenanthes Javanicae, Brassica Oleracea Var.Acephala, Wasabia japonic (Euterma Wasabi), Radix Raphani, Broccoli, Rhizoma Dioscoreae esculentae, Rhizoma amorphophalli, Fructus Colocasiae Esculentae, Rhizoma Solani tuber osi, Fructus Cucurbitae moschatae, Fructus Cucumidis sativi, snake melon, Carlina acaulis, Herba Sonchi Arvensis, Fructus Arctii, tragopogon pratensis l., Herba Cichorii, Caulis et Folium Lactucae sativae, Lentinus Edodes, mushroom, Herba Apii graveolentis (celery), Radix Dauci Sativae, parsnip (parsnip), parsley (parsley), Fructus Lycopersici esculenti, Fructus Solani melongenae, Capsicum annuum L., Germinatus Phragmitis, Bulbus Allii Cepae, Bulbus Allii, Herba Alii fistulosi, shallot, green soyabeans, Flos abelmoschi manihot, Caulis Sacchari sinensis, Rhizoma Zingiberis Recens, Radix Betae, Herba Spinaciae, immaturity Kidney bean, immaturity Semen Pisi sativi, oilseeds (Semen Sesami, Semen Brassicae campestris, Helianthi, Flos Carthami, Semen Gossypii etc.), nuts (Semen Armeniacae Amarum, Semen Ginkgo, Semen Castaneae, Semen Juglandis, pecan etc.), cacao bean, coffee bean, tea, hop etc., but the present invention is not limited to this。
The Pesticidal blend compositions of the present invention is used for plant seed, it is possible to prevent and kill off the harmful organism produced in the preservation (seedstorage) of plant seed。Namely, by the Pesticidal blend compositions of the present invention, to prevent and kill off harmful organism and effectively measure, with directly or with in the way of the suitably dilution such as water or making it suspended, the place of retention of plant seed or plant seed is sprayed, smear, be coated with, impregnate, powder clothing or fumigation is stifling etc. processes。
The Pesticidal blend compositions of the present invention is used for plant seed, it is possible to prevent the infringement caused by the harmful organism produced in plant after planting。Namely, by the Pesticidal blend compositions of the present invention, to prevent and kill off harmful organism and effectively measure, with directly or with in the way of the suitably dilution such as water or making it suspended, plant seed is sprayed, smear, impregnate or powder clothing etc. processes, thus make to prevent and kill off harmful organism compounds effective and contact with plant seed。
So-called plant seed, refer to store germinate for plant seedlings nutritional labeling, at agriculturally material for breeding。For example, it is possible to enumerate the seed of corn and soybean, Semen Phaseoli, Cotton Gossypii, Oryza sativa L., sugar beet, Semen Tritici aestivi, Fructus Hordei Vulgaris, Helianthi, Fructus Lycopersici esculenti, Fructus Cucumidis sativi, Fructus Solani melongenae, Herba Spinaciae, pea pods (poddedpea), Fructus Cucurbitae moschatae, Caulis Sacchari sinensis, Nicotiana tabacum L., Capsicum annuum L. and canola etc. or Fructus Colocasiae Esculentae, Rhizoma Solani tuber osi, Rhizoma Dioscoreae esculentae, etc. the napiform root planting taro, edible lily, Flos Tulipae Gesnerianae etc. or the kind ball etc. of Chinese onion etc.。Above-mentioned plant seed can also be the seed of inverted plant。So-called convert plant, refer to plant gene etc. being carried out manual operation and produce, for nature non-existent plant originally。The Semen sojae atricolor of herbicide tolerance, Semen Maydis, Cotton Gossypii etc. are imparted for example, it is possible to enumerate;Season oneself to cold the Oryza sativa L. of region, Nicotiana tabacum L. etc.;Impart the Semen Maydis of insect killing substance production capacity, Cotton Gossypii, Rhizoma Solani tuber osi etc.。
The Pesticidal blend compositions of the present invention, generally according to the conventional method on preparation in agriculture gardening medicament, preparation becomes excellent in shape easy to use to use。Namely, they with suitable inert carrier or together can be coordinated with auxiliary agent if desired in the proper ratio, carry out dissolving, separate, suspended, mixing, impregnation, absorption or attachment, preparation becomes suitable dosage form, such as, suspension, Emulsion, liquid preparation, wettable powder, granule, powder, tablet etc., use。
As inert carrier, can be any one of solid or liquid, as the material that can become solid inert carrier, such as can enumerate Semen sojae atricolor powder, grain dust, wood powder, bark powder, saw powder, tobacco stem powder, walnut shell powder, bran, cellulose powder, residue after plant extract extraction, pulverize the synthetic polymers such as synthetic resin, clay class (such as Kaolin, bentonite, Emathlite etc.), talcs (such as Talcum, pyrophyllite etc.), silica-based (such as kieselguhr, silica sand, Muscovitum, white carbon (is also referred to as moisture micropowder silicon, the synthesis high dispersive silicic acid of moisture silicic acid, according to goods, also include containing the calcium silicates material as main constituent。)), activated carbon, sulfur powder, Pumex, burned diatomite, brick ground product, flying dust, sand, calcium carbonate, chemical fertilizer, the compost etc. such as inorganic mineral powder, sulfur ammonium, phosphorus ammonium, ammonium nitrate, carbamide, oronain such as calcium phosphate, above-mentioned material can be used alone or uses with the form of two or more mixture。
As the material that can become liquid inert carrier, have except the material of solvent nature except itself, it is also possible to from solvent-free performance, but can make to prevent and kill off in the scattered material of harmful organism compounds effective by the effect of auxiliary agent and select, such as can enumerate carrier given below as representative examples, following carrier can be used alone or uses with the form of two or more mixture, for instance can enumerate water, alcohols (such as methanol, ethanol, isopropanol, butanol, ethylene glycol etc.), ketone (such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), diisobutyl ketone, Ketohexamethylene etc.), ethers (such as ether, dioxane, cellosolve, Di Iso Propyl Ether, oxolane etc.), aliphatic hydrocarbon (such as kerosene, mineral wet goods), aromatic hydrocarbon based (such as benzene, toluene, dimethylbenzene, solvent naphtha, alkylnaphthalene etc.), halogenated hydrocarbon (such as dichloromethane, chloroform, carbon tetrachloride, chlorobenzene etc.), esters (such as ethyl acetate, butyl acetate, ethyl propionate, diisobutyl phthalate, dibutyl phthalate, dioctyl phthalate etc.), amide-type (such as dimethylformamide, diethylformamide, dimethyl acetylamide etc.), nitrile (such as acetonitrile etc.)。
As auxiliary agent, it is possible to enumerating the following representative auxiliary agent enumerated, above-mentioned auxiliary agent can use according to purpose, it is possible to is used alone, sometimes can merge use by auxiliary agent of more than two kinds, sometimes can also not make used additives completely。
In order to make to prevent and kill off harmful organism compounds effective emulsifying, dispersion, solubilized and/or moistening, surfactant can be used, for instance the surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, polyoxyethylene resin acid ester, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene sorbitan list grease, alkylaryl sulfonates, naphthalene sulfonate, lignosulphonates, higher alcohol sulfate can be enumerated。
Additionally, in order to make to prevent and kill off the effective amide derivatives of harmful organism and other compound decentralized stabilizations, bonding and/or bonding, the following auxiliary agent enumerated can be used, for instance the auxiliary agents such as casein, gelatin, starch, methylcellulose, carboxymethyl cellulose, arabic gum, polyvinyl alcohol, Oleum Terebinthinae, rice oil, bentonite, xanthan gum, lignosulphonates can be used。
In order to improve the mobility of solid articles, it is possible to use the auxiliary agent enumerated below, for instance the auxiliary agents such as wax, stearate, alkylphosphonate can be used。Deflocculant as suspended goods, for instance the auxiliary agent such as naphthalene sulfonic acid condensate, condensed phosphate can also be used。As defoamer, for instance the auxiliary agents such as silicone oil can also be used。
It should be noted that, the Pesticidal blend compositions of the present invention is stable to light, heat, oxidation etc., but appropriate antioxidant or UV absorbent can also be added as required as stabilizer, such as BHT (2,6-di-tert-butyl-4-methy phenol), the phenol derivatives of BHA (butylated hydroxyanisole (BHA)) etc, bisphenol derivative or phenyl-a-naphthylamine, Phenyl beta naphthylamine, phenetidine and acetone arylamine class or the benzophenone compound class such as condensation substance, it is possible to obtain the compositions that effect is more stable。
The Pesticidal blend compositions of the present invention can also mix with plant protection product or the material etc. such as herbicide, fertilizer, soil improvement material, plant growth regulator, makes many purposes compositions that effect is more excellent。
It follows that provide containing the compounds of this invention preparation example as effective ingredient, but the present invention is not limited to this。It should be noted that in preparation example, part represents weight portion。
[preparation example 1]
Mix amide derivatives that 2 parts of chemical formulas (1) represent, 10 parts of probenazoles, 0.5 part of wetting agent (east nation's chemical industry (strain) system, trade name AirrolCT-1), 3 parts of binding agents (Japan's synthesis chemistry (strain) system, Gohsenol), 15 parts of Talcums ((strain) win Guanshan Mountain mining industry is made, trade name VictoryLight), 71.5 parts of clays ((strain) win Guanshan Mountain mining industry is made, trade name SP); after adding water, use extruding granulator molding。After the dry article shaped obtained, carrying out granulate thus making granule, obtaining Pesticidal blend compositions。
[preparation example 2]
Mix amide derivatives that 2 parts of chemical formulas (1) represent, 5 parts of orysastrobins, 0.5 part of wetting agent (east nation's chemical industry (strain) system, trade name AirrolCT-1), 3 parts of binding agents (the first industrial pharmaceutical (strain) system, trade name SEROGEN), 15 parts of Talcums ((strain) win Guanshan Mountain mining industry is made, trade name VictoryLight), 74.5 parts of clays ((strain) win Guanshan Mountain industry is made, trade name SP); after adding water, use extruding granulator molding。After the dry article shaped obtained, carrying out granulate thus making granule, obtaining Pesticidal blend compositions。
[preparation example 3]
Mix the amide derivatives that 0.5 part of chemical formula (1) represents, 0.2 part of kasugarnycin mono-hydrochloric salts, 0.3 part of agglutinant (Mitsui Chemicals AGRO (strain) system, trade name DrilessC), 50 parts of clays ((strain) win Guanshan Mountain industry is made, trade name SP), 49 parts of calcium carbonate (day east efflorescence industry (strain) system, trade name NN#200), pulverizing thus making powder with needle mill (pinmill), obtaining Pesticidal blend compositions。
[preparation example 4]
Mix amide derivatives that 0.5 part of chemical formula (1) represents, 1.0 parts of tricyclazoles, 0.3 part of agglutinant (Mitsui Chemicals AGRO (strain) system, trade name DrilessA), 50 parts of clays ((strain) win Guanshan Mountain industry is made, trade name SP), 48.2 parts of calcium carbonate (day east efflorescence industry (strain) system, trade name NN#200), pulverizing thus making powder with needle mill, obtaining Pesticidal blend compositions。
[preparation example 5]
Mix amide derivatives that 0.5 part of chemical formula (1) represents, 0.3 part of flusulfamide, 0.3 part of agglutinant (Mitsui Chemicals AGRO (strain) system, trade name DrilessA), 50 parts of clays ((strain) win Guanshan Mountain industry is made, trade name SP), 48.9 parts of calcium carbonate (day east efflorescence industry (strain) system, NN#200), pulverizing thus making powder with needle mill, obtaining Pesticidal blend compositions。
[preparation example 6]
After mixing amide derivatives, 10 parts of imidacloprids, 1.5 parts of wetting dispersing agents (east nation's chemical industry (strain) system, trade name Sorpol3074), 2.5 parts of dispersants (flower king (strain) system, trade name DemolN), 0.08 part of thickening agent (Rhodia solar corona (strain) system, trade name RHODPOL) and the 80.92 parts of water that 5 parts of chemical formulas (1) represent, pulverize with wet crushing mill, filtering thus making suspending agent, obtaining Pesticidal blend compositions。
[preparation example 7]
After mixing amide derivatives, 15 parts of pyridabens, 2.5 parts of moistening powders (east nation's chemical industry (strain) system, trade name Sorpol3074), 3.0 parts of dispersants (flower king (strain) system, trade name DemolN), 0.08 part of thickening agent (Rhodia solar corona (strain) system, trade name RHODPOL) and the 69.42 parts of water that 10 parts of chemical formulas (1) represent, pulverize with wet crushing mill, filtering thus making suspending agent, obtaining Pesticidal blend compositions。
[preparation example 8]
After mixing amide derivatives, 5 parts of chlorfenapyr, 1.5 parts of wetting dispersing agents (east nation's chemical industry (strain) system, trade name Sorpol3074), 2.5 parts of dispersants (flower king (strain) system, trade name DemolN), 0.08 part of thickening agent (Rhodia solar corona (strain) system, trade name RHODPOL) and the 80.92 parts of water that 10 parts of chemical formulas (1) represent, pulverize with wet crushing mill, filtering thus making suspending agent, obtaining Pesticidal blend compositions。
[preparation example 9]
After mixing amide derivatives, 20 parts of Buprofezins, 1.5 parts of wetting agent (east nation's chemical industry (strain) system, trade name Sorpol5050), 2.5 parts of dispersants (flower king (strain) system, trade name Emal), 2.0 parts of dispersants (flower king (strain) system, trade name DemolN) and the 64 parts of kieselguhr that 10 parts of chemical formulas (1) represent, pulverize with jet pulverizer, make wettable powder, obtain Pesticidal blend compositions。
[preparation example 10]
After mixing amide derivatives, 5 parts of Frontlines, 2.0 parts of wetting agent (east nation's chemical industry (strain) system, trade name Sorpol5050), 2.0 parts of dispersants (flower king (strain) system, trade name Emal), 2.0 parts of dispersants (flower king (strain) system, trade name DemolN) and the 79 parts of kieselguhr that 10 parts of chemical formulas (1) represent, pulverize with jet pulverizer, make wettable powder, obtain Pesticidal blend compositions。
[preparation example 11]
After mixing amide derivatives, 20 parts of pymetrozines, 1.5 parts of wetting agent (east nation's chemical industry (strain) system, trade name Sorpol5050), 2.5 parts of dispersants (flower king (strain) system, trade name Emal), 2.0 parts of dispersants (flower king (strain) system, trade name DemolN) and the 64 parts of kieselguhr that 10 parts of chemical formulas (1) represent, pulverize with jet pulverizer, make wettable powder, obtain Pesticidal blend compositions。
[preparation example 12]
After mixing amide derivatives, 5 parts of MTI-446,2.0 parts of wetting agent (east nation's chemical industry (strain) system, Sorpol5050), 2.0 parts of dispersants (flower king (strain) system, trade name Emal) and the 86 parts of kieselguhr that 5 parts of chemical formulas (1) represent, pulverize with jet pulverizer, make wettable powder, obtain Pesticidal blend compositions。
[preparation example 13]
Dissolve amide derivatives, 10 parts of MTI-446,30 parts of dimethyl sulfoxide, 40 parts of dimethylbenzene and 20 parts of Sorpol (east nation's chemistry (strain) system, Sorpol5050) that 10 parts of chemical formulas (1) of mixing represent equably, make Emulsion, obtain Pesticidal blend compositions。
[preparation example 14]
After the amide derivatives that 5 parts of chemical formulas (1) of mixing represent equably, 5 parts of MTI-446,3 parts of CMC sodium, 5 parts of alkyl sulfates, 72 parts of clays, carry out adding water mixing, pelletize, dry, granulate, make water dispersion granule, obtain Pesticidal blend compositions。
It follows that mix the serviceability of agent for preventing and eliminating as harmful organism for the present composition, specifically illustrate in tests below example, but the present invention is not limited to this。
Blend compositions is prevented and kill off according to the harmful of use in the preparation test of above-mentioned preparation example。The compound that chemical formula (1) represents and the match ratio of other compounds being selected from insecticide, acaricide, nematicide and antibacterial are with when illustrating different, and adjustment match ratio makes compound that chemical formula (1) represents and the aggregate values of other compounds be the value identical with illustration。
It should be noted that, " reagent agent " in following table refers to the compound constituting Pesticidal blend compositions, the compound that chemical formula (1) represents is expressed as " compound (1) ", the compound in insecticide, acaricide, nematicide and antibacterial is expressed as " other compounds "。
[test example 1] insecticidal test to Prodenia litura (Spodopteralitura)
The Emulsion prepared according to the method recorded in preparation example 13 dilution is configured to the concentration of regulation, is dispersed on the Brassica oleracea L.var.capitata L. (kind: the four seasons are obtained) being planted in basin。After air-dry, cut leaf, put in the polyethylene cup of the 9cm being equipped with filter paper, put into Prodenia litura 4 instar larvae, close the lid。It is statically placed in 25 DEG C of thermostatic chambers, 6 days " Invest, Then Investigate " life and death borer populations, calculate dead worm rate。Carry out in the way of 52,1st district even makes。Result is shown in the 1st table。
[table 1]
1st table
[test example 2] insecticidal test to diamondback moth (Plutellaxylostella)
The Emulsion prepared according to the method recorded in preparation example 13 dilution is configured to normal concentration, is dispersed on the Brassica oleracea L.var.capitata L. (kind: the four seasons are obtained) being planted in basin。After air-dry, cut leaf, put in the polyethylene cup of the 9cm being equipped with filter paper, put into diamondback moth 3 instar larvae, close the lid。It is statically placed in 25 DEG C of thermostatic chambers, 6 days " Invest, Then Investigate " life and death borer populations, calculate dead worm rate。Carry out in the way of 52,1st district even makes。Result is shown in the 2nd table。
[table 2]
2nd table
The insecticidal test of [test example 3] Whitebacked Planthopper (Sogatellafurcifera)
The Emulsion prepared according to the method recorded in preparation example 13 dilution is configured to normal concentration, is dispersed on rice seedling (kind: KOSIHIKARI)。After air-dry, put into together with 10 white backed planthopper 3 instar larvaes added with the diameter 3cm of water, high 10cm teat glass in, close the lid。Survival number after investigating 6 days, calculates dead worm rate。Carry out in the way of 10 2,1st district even makes。Result is shown in the 3rd table。
[table 3]
3rd table
[test example 4] insecticidal test to kamisawa tetranychus (Tetranychuskanzawai)
Topped up with water in the plastic cup of diameter 9cm, covers the lid in the hole of diameter 1cm, places absorbent cotton on the top of lid so that it is hang on water from lid, utilizes capillarity to make absorbent cotton keep hygrometric state。Make the leaf dish (leafdisk) of diameter 2cm of Kidney bean acrospire (kind: Greentop), be placed on above-mentioned absorbent cotton, wherein 4 kamisawa tetranychus female adult worm of inoculation。Second day, after removing female adult worm, investigation laying, the Emulsion prepared according to the method recorded in preparation example 13 dilution is configured to normal concentration, uses tower sprayer (towersprayer) to spread。It is statically placed in the thermostatic chamber of 25 DEG C after distribution, spreads the larvae number of survival on 9 days " Invest, Then Investigate " leaf dishes, calculate the incubation rate of the larvaes (1 medicament 1 concentration 2 is system even)。Result is shown in the 4th table。
[table 4]
4th table
[test example 5] by using the insecticidal test carrying out rice water weevil (Lissorhoptrusoryzophilus) and the test preventing and kill off rice blast to seedling cultivation of rice case
With regulation dose according to the granule prepared of method recorded in preparation example 1,2 to after in nursery box, the Oryza sativa L. (kind: KOSIHIKARI) of cultivation processes, transplant 4 to 1/5000a basin, co-transplantation 4 basin。For 2 basins, put into 5 rice water weevil adults after processing 14 days, cover Seedling with cylinder mould, 4 days dead worm rates of " Invest, Then Investigate " (2 even make)。It addition, for other 2 basins, put into artificial meteorological office (imposing a condition: light and shade circulation in 25 DEG C, 12 hours), spray inoculation rice blast spore suspension after processing 30 days。Keep high humidity in meteorological office, 7 days " Invest, Then Investigate " rice blast scab numbers, following calculating formula calculate the valency of preventing and kill off (2 even make)。Result is shown in the 5th table。
Prevent and kill off valency=(the scab number in the scab number of 1-treatment region/untreated district) × 100
[table 5]
5th table
Prodenia litura (Spodopteralitura) insecticidal test of [test example 6] Fructus Solani melongenae and powdery mildew preventing iron test
The Emulsion prepared according to the method recorded in preparation example 13 dilution is configured to normal concentration, spreads q.s on the Fructus Solani melongenae (kind: 1,002 No. two) of temperature indoor cultivation。Spread 1 leaf under 7 days rear cutout, put in plastic cup (diameter 10cm, high 10cm) together with 5 Prodenia litura 4 instar larvaes, 4 days dead worm rates of " Invest, Then Investigate "。It addition, after spreading 1 day, brush lightly the Powdery Mildew on the morbidity leaf of the Fructus Solani melongenae fallen ill in advance with paintbrush equably, inoculate, survey on implementation after 10 days。According to following index, investigation scab accounts for the area of every 1 leaf of Fructus Solani melongenae, is calculated the valency of preventing and kill off (2 even make) according to the average onset degree in each district by following calculating formula。Result is shown in the 6th table。
Disease severity 0: without scab
1: lesion area is less than 5%
2: lesion area is 6~25%
3: lesion area is 26~50%
4: lesion area is more than 51%
Prevent and kill off valency=(the average onset degree in the average onset degree of 1-treatment region/untreated district) × 100
[table 6]
6th table
[test example 7] prevents and kill off the test of clubroot by Brassica oleracea L.var.capitata L. is carried out soil treatment
Test is used in every 1ml soil and is vaccinated with 106The soil of individual resting spore。For untreated district, soil is directly seated in the biscuiting basin of diameter 15cm, for chemicals treatment district, is seated in biscuiting basin after mixed with soil for the powder prepared according to the method recorded in preparation example 3,4,5 of regulation dose。Then, the Brassica oleracea L.var.capitata L. (kind: the four seasons are obtained) of plantation test tube Seedling cultivation。Extract plant after processing 50 days, in sub-degree investigation knee raw situation, calculated, by following calculating formula, the valency of preventing and kill off according to the average onset degree in each district。Result is shown in the 7th table。
Disease severity 0: have no knee and raw
1: root system overall more than 1%~less than on the root of 25% take root swollen
2: root system overall more than 25%~less than on the root of 50% take root swollen
3: root system overall more than 50%~less than on the root of 75% take root swollen
4: root system overall more than 75% root on take root swollen
Prevent and kill off valency=(the average onset degree in the average onset degree of 1-treatment region/untreated district) × 100
[table 7]
7th table
[test example 8] graw mold of tomato preventing iron test
The Emulsion prepared according to the method recorded in preparation example 13 dilution is configured to normal concentration, spreads q.s on the Fructus Lycopersici esculenti (kind: the world one) of 2 basins (diameter 5cm) temperature indoor cultivation。After medicinal liquid is dry, the conidium suspension that spray inoculation is prepared by the ash arrhizus bacteria cultivated in NY culture medium in advance。After inoculation, basin is put into the moist chamber of artificial vaccination room (20~22 DEG C), through taking out two days later, survey on implementation。According to following occurring degree index, lesion area is accounted for the ratio survey on implementation of the every whole lobule of Fructus Lycopersici esculenti。It addition, utilize following calculating formula to be calculated, by the average onset degree of each treatment region, the valency of preventing and kill off。Result is shown in the 8th table。
Occurring degree 0: without scab
1: lesion area is less than the 1/3 of whole lobule
2: lesion area is more than the 1/3 of whole lobule, less than 2/3
3: lesion area is more than the 2/3 of whole lobule
Using the meansigma methods in each treatment region and untreated district as occurring degree。Valency of preventing and kill off calculates as follows。
Prevent and kill off valency=(the average onset degree in the average onset degree of 1-treatment region/untreated district) × 100
[table 8]
8th table
[test example 9] thinning beet damping-off preventing iron test
The preparation of contaminated soil is carried out as follows: after the rhizoctonia culture and pythium spp culture of having cultivated 20 days in each comfortable wheat bran medium at 25 DEG C being pulverized respectively, being filled in plastic tub, the amount making the rhizoctonia culture of the mass ratio range with sterile soil is 1%, the amount of pythium spp culture is 1%。The effective ingredient treating capacity being separately added in table in beet seed (kind: A-bent) to record according to preparation example 3,4,5 in the powder prepared of method recorded, be sufficiently mixed。Beet seed by the beet seed crossed through chemicals treatment, without chemicals treatment is sowed in amounting to 20 basins with the amount of 5, every basin respectively, makes it grow in greenhouse。Investigate, by naked eyes, the number that do not sprout after sowing 7 days, it addition, sowing investigated Seedling by naked eyes after 14 days founds withered number, utilize following calculating formula to calculate Seedling and found withered rate。It addition, investigate with or without poisoning also by naked eyes。Result is shown in the 9th table。
The withered rate of Miao Li=((non-germinative number+Seedling founds withered number)/sowing number) × 100
[table 9]
9th table
[test example 10] potato scab preventing iron test
Test soil is carried out as follows making: loaded by the soil that the farm polluted from potato scab gathers in concrete basin (long 50cm × wide 50cm × deep 30cm)。The wettable powder prepared according to the method recorded in preparation example 9,10,11,14 is diluted to normal concentration and makes medicinal liquid, potato seed taro (kind: baron) is carried out impregnation process by this medicinal liquid, after making kind of taro air-dry, burying kind of a taro (2, every basin) underground, the Yi Gequ mode of 5 times repeatedly makes it grow。For untreated, it is bury the kind taro without chemicals treatment underground。After burying kind of taro underground 110 days, excavate the taro being newly formed, investigated with or without morbidity by naked eyes, utilize following calculating formula to calculate morbidity taro rate。It addition, occur with or without poisoning also by naked eyes investigation。Result is shown in the 10th table。
Morbidity taro rate=(morbidity taro number/total investigation taro number) × 100
[table 10]
10th table
Radix Brassicae rapae noctuid (Agrotissegetum) preventing iron test of [test example 11] Semen Maydis
According to the wettable powder prepared of method recorded in preparation example 9,10,11,14,5g corn seed (kind: sweet corn) is carried out powder clothing process with regulation dose。1/10000a basin is sowed 3 seeds crossed through chemicals treatment, after sowing 9 days, puts into 5 Radix Brassicae rapae noctuid 3 instar larvaes, cover net (2 even make)。Put 5 days " Invest, Then Investigate " life and death of worm, calculate dead worm rate。Result is shown in the 11st table。
[table 11]
11st table
[test example 12] prevents and kill off the test of the Zea mays root timber rot caused by rhizoctonia
According to the suspending agent prepared of method recorded in preparation example 6,7,8, corn seed (kind: first state Semen Maydis) is smeared process with regulation dose, square flat chassis (vat) is spread out, till in time sowing, makes it air-dry。It addition, after the rhizoctonia culture cultivated at 25 DEG C in wheat bran medium 20 days is pulverized, according to the amount being 1% with mass ratio range and the mixing with soil through steam sterilization, be filled in plastic tub。Corn seed by the corn seed crossed through chemicals treatment, without chemicals treatment is sowed in amounting to 20 basins with the amount of 2, every basin respectively so that it is at temperature indoor growing。Investigate, by naked eyes, the number that do not sprout after sowing 10 days, it addition, sowing investigated Seedling by naked eyes after 3~4 weeks founds withered number, utilize following calculating formula to calculate Seedling and found withered rate。It addition, investigate with or without poisoning also by naked eyes。Result is shown in the 12nd table。
The withered rate of Miao Li=((non-germinative number+Seedling founds withered number)/sowing number) × 100
[table 12]
12nd table
[test example 13] prevents and kill off by the test of the rotten mould maize seedling damping-off caused
According to the suspending agent prepared of method recorded in preparation example 6,7,8, corn seed (kind: first state Semen Maydis) is smeared process with regulation dose, side's flat chassis is spread out, till when sowing, makes it air-dry。It addition, after the pythium spp culture cultivated at 25 DEG C in potato dextrose agar 7 days is pulverized, according to the amount being 1% with mass ratio range and the mixing with soil through steam sterilization, be filled in plastic tub。Corn seed by the corn seed crossed through chemicals treatment, without chemicals treatment is sowed in amounting to 20 basins with the amount of 2, every basin respectively so that it is at temperature indoor growing。Investigate, by naked eyes, the number that do not sprout after sowing 10 days, it addition, sowing investigated Seedling by naked eyes after 3~4 weeks founds withered number, utilize following calculating formula to calculate Seedling and found withered rate。It addition, investigate with or without poisoning also by naked eyes。Result is shown in the 13rd table。
The withered rate of Miao Li=((non-germinative number+Seedling founds withered number)/sowing number) × 100
[table 13]
13rd table
[test example 14] prevents and kill off by the test of the microbial maize seedling damping-off of reaping hook
According to the suspending agent prepared of method recorded in preparation example 6,7,8, corn seed (kind: first state Semen Maydis) is smeared process with regulation dose, side's flat chassis is spread out, till when sowing, makes it air-dry。It addition, after the Fusarium spp. culture cultivated at 25 DEG C in potato dextrose agar 7 days is pulverized, according to the amount being 1% with mass ratio range and the mixing with soil through steam sterilization, be filled in plastic tub。Corn seed by the corn seed crossed through chemicals treatment, without chemicals treatment is sowed in amounting to 20 basins with the amount of 2, every basin respectively so that it is at temperature indoor growing。Investigate, by naked eyes, the number that do not sprout after sowing 10 days, it addition, sowing investigated Seedling by naked eyes after 3~4 weeks founds withered number, utilize following calculating formula to calculate Seedling and found withered rate。It addition, investigate with or without poisoning also by naked eyes。Result is shown in the 14th table。
The withered rate of Miao Li=((non-germinative number+Seedling founds withered number)/sowing number) × 100
[table 14]
14th table
[test example 15] insecticidal test to Prodenia litura (Spodopteralitura)
Brassica oleracea L.var.capitata L. (kind: the four seasons are obtained) blade is impregnated in medicinal liquid Emulsion prepared by the method recorded according to preparation example 13 being diluted to normal concentration and make, after air-dry, put in the polyethylene cup of the 9cm being equipped with filter paper, put into Prodenia litura 2 instar larvae, close the lid。It is statically placed in 25 DEG C of thermostatic chambers, 5 days " Invest, Then Investigate " life and death borer populations, calculate dead worm rate。Carry out in the way of 52,1st district even makes。Result is shown in the 15th table。
[table 15]
15th table
By result above it can be seen that the multiple harmful organism being difficult to the harmful organism prevented and kill off and display Drug resistance etc. is also had significant preventive effect by the Pesticidal blend compositions of the present invention in the past。Therefore, the Pesticidal blend compositions of the present invention brings tremendous contribution can to the Labor-saving of agricultural。

Claims (4)

1. a Pesticidal blend compositions, described Pesticidal blend compositions contains other compounds of amide derivatives that following chemical formula (1) represents and at least one in following the 1st compound group being made up of insecticide, acaricide, nematicide and antibacterial as effective ingredient
1st compound group: fluorine ester chrysanthemum ester, allethrin [(1R)-isomer], Biphenthrin, EXTHIN, EXTHIN S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfloxylate, β-cyfloxylate, lambda-cyhalothrin, gamma-cyhalothrin, λ-lambda-cyhalothrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, cyphenothrin [(1R)-trans-isomer], decis, empenthrin [(EZ)-(1R)-isomer], S-fenvalerate, ethofenprox, Fenpropathrin, fenvalerate, flucythrinate, flumethrin, taufluvalinate, halfenprox, Imiprothrin, methothrin, metofluthrin, Permethrin, phenothrin [(1R)-trans-isomer], prallethrin, resmethrin, RU15525 (Kadethrin), silafluofene, Tefluthrin, tetramethrin, tetramethrin [(1R)-isomer], tralomethrin, transfluthrin, ZXI8901, biopermethrin, PH, third Flumethrin, brofluthrinate, dimefluthrin,
Orthene, methylpyridine phosphorus, azinphos-methyl, azinphos ethyl, vincofos, cadusafos, chlorethoxyfos, chlorfenvinpho, chlormephos, chlopyrifos, chlorpyrifos-methyl, coumafos, cynock (CYAP), demeton-S-methyl, basudin, O-2,4-dichlorophenyl O,O-diethyl phosphorothioate (ECP), dichlorvos (DDVP), Carbicron, Rogor, dimethylvinphos, two sulfur pine (disulfoton), O-ethyl-O-(4-nitrobenzophenone) phenyl phosphorothioate (EPN), Ethodan, ethoprop, Dovip, Nemacur, MEP (fenifrothion), fenthion (MPP), lythidathion, heptenophos, Isofenphos methyl, isocarbophos (O-(Methoxyamino thiophosphoryl) isopropyl salicylate), azoles phosphorus, Malathion, Afos, Bayer 71628, methidathion (DMTP), Menite, Azodrin, 2-dichloroethylk dimethyl phosphate (BRP), omethoate, metilomerkaptofosoksid, parathion, parathion-methyl, phenthoate dimephenthoate cidial (PAP), thimet, zolone, phosmet, phosphamidon, phoxim, methyl pirimiphosmethyl, Profenofos, Propetamphos, BAY-NTN 8629, pyraclofos, Ofunack, quintiofos, sulfotep, butyl pyrimidine phosphorus, Swebate, Terbufos, thiometon, triazophos, metrifonate (DEP), Kilval, compd 22/190 (Bayer22/190), bromobenzene alkene phosphorus, bromofos, Rilariol, special pyrimitate, carbophenothion, chlorophoxim, sulprofos, Nellite, Ravap (CVMP), Kayaphos, fenthion sulfoxide, salithion (salithion), etrimfos, oxydeprofos, An Guo, O,O-diethyl O-[p-(methylsulfinyl)phenyl, isazofos, Imicyafos (AKD3088), Isamidofos, nemaphos, fosthietan,
Second the third phosphorus prestige, alanycarb, butocarboxim, butanone sulfone prestige, thiodicarb, thiofanox, Aldicarb, worm prestige, Benfuracard micro, carbaryl (NAC), carbofuran, carbosulfan, ethiofencarb, Osbac (BPMC), Carzol, furathiocarb, Mobucin (MIPC), mercaptodimethur, methomyl, oxamyl, Aphox, arprocarb (PHC), Landrin, XMC, allyxycarb, Aldicarb sulfone, metalkamate, butacarb, sok, meta-tolyl-N-methylcarbamate (MTMC) (MTMC), Meobal (MPMC), fenothiocarb, acetamiprid, clothianidin, MTI-446, imidacloprid, Nitenpyram, thiacloprid, Diacloden, ring tebufenozide, chlorine tebufenozide, methoxyfenozide, tebufenozide, bistrifluron, UC 62644, TH-6040, flucycloxuron, Cascade, HEXAFLUMURON, fluorine the third oxygen urea, Novaluron, noviflumuron, Teflubenzuron, parasite killing is grand, ABG-6215, hydroprene, kinoprene, alkene worm propyl ester, pyriproxyfen, Niran, 5a,6,9,9a-hexahydro-6,9-methano-2,4, gamma hch (gamma-HCH), everywhere gram, cartap hydrochlorate, thiocyclam, amitraz, ethiprole, Frontline, second phthalein worm is cured, azacyclotin, plictran, fenbutatin oxide (fenbutatin oxide), fenazaquin, fenpyroximate, pyridaben, pyrimidifen, tebufenpyrad, Tolfenpyrad, bromine demodicid mite is special, chlorfenapyr, DNOC, binapacryl, Rynaxypyr, bromine cyanogen insect amide (DPX-HGW86), diazole worm, metaflumizone, Envidor, Spiromesifen, triaguron, flufenzine,
Avilamycin, acequinocyl, Ai Zhading, bensultap, Citrazon, Bifenazate, Buprofezin, CGA50439, chinomethionat, clofentezine, cryolite, cyromazine, dazomet, DCIP, DDT, diafenthiuron, D-D (1,3-dichloropropylene), dicofol, CGA 183893, dinobuton, dinocap, ENT8184, according to killing demodicid mite, flonicamid, fluacrypyrim, fipronil bisamide, GY-81 (peroxycarbonates), Hexythiazox, Hydramethylnon Bait, hydrocyanic acid, iodomethane, karanjin, MB-599 (verbutin), mercuric chloride, metham-sodium, methoxychlor, methyl mustard oil, kill your demodicid mite element, pentachlorophenol, hydrogen phosphide, piperonyl butoxide, compound polynactin, propargite (BPPS), pymetrozine, pyrethrin, pyridalyl, rotenone, S421 (double, two (2,3,3,3-tetra-chloropropyl) ether), jervine, pleocidin, Sulcofuron salt (Sulcofuron-sodium), sulfluramid, tetradiphon, Cupric sulfate, De-Green, drinox, match result, Amidothioate, aminocarb, O,O-diethyl S-(.beta.-diethylamino)ethyl phosphorothiolate, aramite, ethyl methidathion, Alamos, solbar, Bayer22408, Bayer32394, Benclothiaz, 5-(1,3-benzodioxole-5-base)-3-hexyl-2-cyclonene, 1,1-double, two (4-chlorphenyl)-cellosolvos, butyl ester phosphine, dihydropyrone, 2-(2-Butoxyethoxy) ethyl rhodanate acid esters, toxaphene, chlorbenside, kepone, Spanon, Qikron, chlorfenizon, Isoprothiolane, fluorine fluazuron, Lepimectin, Spinetoram, emamectin-benzoate, the methaldehyde, fenisobromolate, fluazinam, bilanafos, benomyl, hydrochloric acid levamisole, Pyrifluquinazon (NNII0101), cyflumetofen, sulfanilamide dragonfly vinegar, IKA-2005, nitrile pyrrole demodicid mite ester (NC512), spiral shell worm ethyl ester (BYI08330), sulfoxaflor, Pyrafluprole (V3039), Pyriprole (V3086), bromo pyrrole carbonitrile, Flupyrazofos-containpesticide, luxuriant ether, chlorobenzilate, nicotine neutral sulfate., flufenzine, Citrazon, emamectin-benzoate, potassium oleate, enuatrol, hydroxypropyl starch, crow worm amine, Metaflumizole, tripropyl isocyanuric acid ester, albendazole, oxibendazole, bensultap, Phenbendasol, pyrantel tartrate, metham-sodium sodium, 1,3-dichloropropylene, Imicyafos (AKD-3088), bromo pyrrole carbonitrile, chloropicrin, Bromofume (EDB), vikane, acrylonitrile, double, two (2-chloroethyl) ether, the bromo-2-ethyl chloride of 1-, the chloro-1-propylene of the bromo-1-of 3-, bromocyclne, Carbon bisulfide, carbon tetrachloride, nemadectin, aluminum phosphate, bacillus thuringiensis delta-endotoxin, Borax, calcium polysulfide, cryolite, the basic element of cell division, nicotine, keep away worm alcohol, coal tar, anabasine, pyrantel tartrate, Pyrethrum (pyrethrin), soybean lecithin, starch, fatty glyceride, propylene glycol mono, kieselguhr, bacillus thuringiensis, Cyclaniliprole, Triflumezopyrim, Flometoquin, Flupyradifurone, Pyflubumide, N-(4-methyl-5-isoxazole base)-4-(trifluoromethyl) nicotiamide,
Nitrile Fluoxastrobin, imines bacterium, pyraclostrobin, ZEN 90160, fluoxastrobin, dimoxystrobin, orysastrobin, fork phenalgin amide, trifloxystrobin, Enestroburin, azoles amine bacterium ester, pyraoxystrobin, simeconazoles, Tebuconazole, RH-7592, hexaconazole, amide azoles, triazolone, fluorine ether azoles, prothioconazoles, triticonazole, epoxiconazole, plant bacterium azoles, metconazole, propiconazole, cyproconazole, ether azoles, olefin conversion, Fluquinconazole, bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane, Wu Junzuo, bromuconazole, Triadimenol, Flutriafol, nitrile bacterium azoles, etaconazole, Bitertanol, oxpoconazole fumarate, fluorine bacterium azoles, IMAZALIL, IMAZALIL-S, prochloraz, pefurazoate, triazoxide, Fenamidone,
Pyrrole metsulfovax, flutolanil, the spirit of furan pyrazoles, Boscalid, fenhexamid, cyflufenamid, tecloftalam, mandipropamid, biphenyl pyrrole bacterium amine, carboxin, oxycarboxin, third oxygen mebenil, Silthiopham, thifluzamide, fluorine biphenyl bacterium, Guardian, zoxamide, tiadinil, isotianil, double, two chlorine zarilamids, zarilamid, fluopicolide, fluopyram, fluorine ring propionic acid amide., Tolfenpyrad, fluorine azoles bacterium aniline, fluorine azoles ring bacterium amine, isopyrazam, 3-difluoromethyl-N-[4 '-(3,3-dimethyl butine-1-base) biphenyl-2-base]-1-methyl isophthalic acid H-pyrazole-4-carboxamide, 3-difluoromethyl-N-[4 '-(3-methoxyl group-3-methyl butyne-1-base) biphenyl-2-base]-1-methyl isophthalic acid H-pyrazole-4-carboxamide, metalaxyl, metalaxyl-M, M 9834, M 9834-M, furalaxyl-M, benzene metsulfovax, iprovalicarb, downy mildew goes out, cyazofamid, the U.S. speed of peace, flusulfamide, tolyfluanid, Euparen, hundred dimension spirits, hundred dimension spirit hydrochlorates, diethofencarb, pyrrole bacterium benzene prestige, Mancozeb, maneb, propineb, zineb, Carbatene, ziram, thiuram, polycarbamate, isopropyl is fixed, procymidone, captan, vinclozolin, chlozolinate, folpet, iminoctadine alkane benzene sulfonate, iminoctadine triacetate, Guanoctine, dodine, mepanipyrim, fenarimol, ferimzone, cyprodinil, dimethyl mepanipyrim, nuarimol, dimethirimol, the phonetic bacterium spirit of sulphur, fluorine mepanipyrim, dimethomorph, butadiene morpholine, tridemorph, dodemorfe, flumorph, thiophanate methyl, thiophanate, benomyl, carbendazim, Apl-Luster, furidazol, cough up bacterium ester, fluoromide, fenpiclonil, fosetyl, Hinosan, tolelofos-methyl, iprobenfos, pyrazophos, chlorocholine chloride (Chlormequat), paclobutrazol (paclobutrazol),
Copper hydrate, copper, alkalescence copper chloride, basic cupric sulfate, copper 8-quinolinolate, copper sulfate five water salt, anhydrous cupric sulfate, nonyl benzene cupric sulfocarbolate, DBEDC, kasugarnycin, valida, polyoxin derivant, blasticidin-S S benzylamino benzene sulfonate, streptomycin, natamycin, midolthromycin, oxytetracycline, Bravo, Rabcide, pentachloronitrobenzene, the chloro-7-of 5-(4-methyl piperidine-1-base)-6-(2,4,6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, the chloro-N-of 5-[the fluoro-1-Methylethyl in (1S)-2,2,2-tri-]-6-(2,4,6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, the chloro-N-of 5-[(1R)-1,2-dimethyl propyl]-6-(2,4,6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, 5-(methoxy)-6-octyl group [1,2,4] triazol [1,5-a] pyrimidine-7-amine, azoles mepanipyrim, metrafenone, 3-(2,3,4-trimethoxy-6-methyl benzoyl)-5-chloro-2-methoxyl group-4-picoline, 3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazolidine-3-base] pyridine, 3-[2,3-dimethyl-5-(4-aminomethyl phenyl) isoxazolidine-3-base] pyridine, 3-[2-isopropyl-3-methyl-5-(4-chlorphenyl) isoxazolidine-3-base] pyridine, quinoxyfen, Tebufloquin, 3-(fluoro-3,3,4,4-tetramethyl-3 of 5-, 4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4-bis-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4,5-tri-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, Flutianil, 1-[(2-acrylic sulfo-) carbonyl]-2-(1-Methylethyl)-4-(2-aminomethyl phenyl)-5-amino-1H-pyrazoles-3-ketone, 1-[(ethylenebis dithiocarbamate) carbonyl]-2-(1-Methylethyl)-4-(2-aminomethyl phenyl)-5-amino-1H-pyrazoles-3-ketone, 1-[(ethylenebis dithiocarbamate) carbonyl]-2-(1-Methylethyl)-4-(2,6-Dichlorobenzene base)-5-amino-1H-pyrazoles-3-ketone,
Hymexazol (first hydroxyl isoxazole), fluazinam, diclomezine, tricyclazole, cymoxanil, famoxadone, Fenamidone, chloropicrin, thiadiazine, third oxygen quinoline, spiroxamine, fenpropidin, Delan, Pencycuron, Isoprothiolane, probenazole, resveratrol, triforine, my acid benzene-S-methyl, pyroquilon, dinocap, organic nickel, kobam, frost spirit, ambam, pyrifenox, oxolinic acide, phosphorous acid, dazomet, methyl mustard oil, methasulfocarb, 1, 3-dichloropropylene, iodomethane, sulfur, lime sulfur, fentin hypochlorite, chinomethionat, chloroneb, anilazine, isopropyl disappears, plant clothing ester, botran, benthiozole, trichlamide, first hydroxyl isoxazole potassium, hydration sulfur agent, zinc sulfate, sodium bicarbonate, potassium bicarbonate, sodium hypochlorite, argent, Oleum Brassicae campestris, machine oil, Harpin albumen and Tolprocarb。
2. Pesticidal blend compositions as claimed in claim 1, wherein, other compounds are at least one compound in the following 2nd compound group selecting free insecticide, acaricide, nematicide and antibacterial to constitute,
2nd compound group: chlopyrifos, ethofenprox, MTI-446, Frontline, pleocidin, Rynaxypyr, pymetrozine, Lepimectin, fenifrothion, silafluofene, Buprofezin, ethiprole, pyridaben, acequinocyl, fenbutatin oxide, Envidor, according to killing demodicid mite, Bifenazate, kill your demodicid mite element, N-(4-methyl-5-isoxazole base)-4-(trifluoromethyl) nicotiamide, probenazole, double, two chlorine zarilamids, orysastrobin, tricyclazole, Isoprothiolane, isotianil, pyrrole metsulfovax, simeconazoles, flusulfamide, 3-(fluoro-3,3,4,4-tetramethyl-3 of 5-, 4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4-bis-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, 3-(4,4,5-tri-fluoro-3,3-dimethyl-3,4-dihydro-isoquinoline-1-base) quinoline, hymexazol, clothianidin, imidacloprid, Diacloden, nitrile Fluoxastrobin, carboxin, cough up bacterium ester, plant bacterium azoles, pyraclostrobin, trifloxystrobin, captan, metalaxyl-M, thiuram, Mancozeb, bromine cyanogen insect amide (DPX-HGW86), acetamiprid, Nitenpyram, thiacloprid, orthene, pyriproxyfen, Benfuracard micro, Tolfenpyrad, chlorfenapyr, spiral shell worm ethyl ester (BYI08330), Spiromesifen, methomyl, iminoctadine alkane benzene sulfonate, iminoctadine triacetate, my acid benzene-S-methyl, ferimzone, pyroquilon, tiadinil, Rabcide, kasugarnycin, zarilamid, third oxygen mebenil, diclomezine, Pencycuron, valida, Hinosan, the spirit of furan pyrazoles, thifluzamide, flutolanil, fork phenalgin amide, iprobenfos, oxolinic acide, tecloftalam, ZEN 90160, bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane, Tebuconazole, Triadimenol, Apl-Luster, metalaxyl, streptomycin and Tolprocarb。
3. Pesticidal blend compositions as claimed in claim 1, wherein, other compounds are at least one compound in the following 3rd compound group selecting free insecticide, acaricide, nematicide and antibacterial to constitute,
3rd compound group: avilamycin, acetamiprid, Biphenthrin, carbofuran, dichlorvos (DDVP), emamectin-benzoate, vincofos, fipronil bisamide, methidathion (DMTP), omethoate, phoxim, quintiofos, triazophos, metrifonate (DEP), cypermethrin, carbendazim, chlorocholine chloride (Chlormequat), Copper hydrate, cymoxanil, ether azoles, fluopicolide, valida, Mancozeb, metalaxyl, Carbatene, nitrile bacterium azoles, paclobutrazol (paclobutrazol), propiconazole, pyraclostrobin, Tebuconazole, thiophanate methyl, triazolone。
4. the Pesticidal blend compositions as according to any one of claims 1 to 3, wherein, the content ratio of the total amount of other compounds in the amide derivatives that described chemical formula (1) represents, the 1st compound group with selecting free insecticide, acaricide, nematicide and antibacterial to constitute, the 2nd compound group or the 3rd compound group, with mass ratio range for 0.005~99%。
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