CN105679971B - Aluminum plastic film composite layer and secondary cell - Google Patents

Aluminum plastic film composite layer and secondary cell Download PDF

Info

Publication number
CN105679971B
CN105679971B CN201410658344.1A CN201410658344A CN105679971B CN 105679971 B CN105679971 B CN 105679971B CN 201410658344 A CN201410658344 A CN 201410658344A CN 105679971 B CN105679971 B CN 105679971B
Authority
CN
China
Prior art keywords
layer
plastic film
aluminum plastic
film composite
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201410658344.1A
Other languages
Chinese (zh)
Other versions
CN105679971A (en
Inventor
屈长明
杨帆
杨菲
姜玲燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Amperex Technology Ltd
Original Assignee
Dongguan Amperex Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Amperex Technology Ltd filed Critical Dongguan Amperex Technology Ltd
Priority to CN201410658344.1A priority Critical patent/CN105679971B/en
Publication of CN105679971A publication Critical patent/CN105679971A/en
Application granted granted Critical
Publication of CN105679971B publication Critical patent/CN105679971B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Sealing Battery Cases Or Jackets (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention provides a kind of aluminum plastic film composite layer and secondary cells.The aluminum plastic film composite layer includes the first polymer layer, aluminium foil layer and the second polymer layer, aluminium foil layer is between the first polymer layer and the second polymer layer, and electrolyte can be isolated with aluminium foil layer for the second polymer layer, so that electrolyte cannot contact aluminium foil layer through the second polymer layer.Contain shear thickening liquid in aluminum plastic film composite layer, and shear thickening liquid is located inside of the first polymer layer towards battery core in aluminum plastic film composite layer.The secondary cell includes aforementioned aluminum plastic film composite layer.When secondary cell works normally, the chemical property of secondary cell is unaffected, when secondary cell such as is collided, squeezes, falls at the machinery abuse, aluminum plastic film composite layer in secondary cell can effectively avoid the short circuit occurred inside of secondary cell, to improve the security performance of secondary cell.

Description

Aluminum plastic film composite layer and secondary cell
Technical field
The present invention relates to battery technology field more particularly to a kind of aluminum plastic film composite layers and secondary cell.
Background technology
More frivolous aluminum plastic film is commonly used in the secondary battery as outer packing, but aluminum plastic film is in secondary cell The protective effect in portion is not so good as traditional box hat and aluminum hull, therefore when secondary cell (for example is collided, squeezes, falls by machinery abuse Fall) when, it is easy to cause the short circuit occurred inside of secondary cell, and then cause safety accident.Mainly by right in existing market The external addition protection circuit device of secondary cell, while flame-retardant additive is added in the electrolyte inside secondary cell, and The danger that mechanical abuse in turn results in internal short-circuit is occurred for secondary cell to be preferably minimized.But these measures are to a certain extent The chemical property of secondary cell can be reduced.
Invention content
The problem of in view of background technology, the purpose of the present invention is to provide a kind of aluminum plastic film composite layer and secondary electricity Pond, when secondary cell works normally, the chemical property of secondary cell is unaffected, when secondary cell is collided, When the machinery abuse such as squeezing, fall, the aluminum plastic film composite layer in secondary cell can effectively avoid secondary cell inside occur it is short Road, to improve the security performance of secondary cell.
To achieve the goals above, in one aspect of the invention, the present invention provides a kind of aluminum plastic film composite layers comprising The first polymer layer, aluminium foil layer and the second polymer layer, aluminium foil layer between the first polymer layer and the second polymer layer, And electrolyte can be isolated with aluminium foil layer for the second polymer layer, so that electrolyte cannot contact aluminium through the second polymer layer Layers of foil.Contain shear thickening liquid in aluminum plastic film composite layer, and shear thickening liquid is located at the first polymerization in aluminum plastic film composite layer Inside of the nitride layer towards battery core.
In the second aspect of the present invention, the present invention provides a kind of secondary cells, including battery core, the packaging of packaging electric core Bag and the electrolyte for being contained in packaging bag and impregnating battery core.Wherein, packaging bag use is described according to a first aspect of the present invention Aluminum plastic film composite layer be made, and the second polymer layer is towards battery core.
Compared with the existing technology, beneficial effects of the present invention are as follows:
(1) when secondary cell works normally, the shear thickening liquid in aluminum plastic film composite layer is with readily flowed liquid State exists, therefore the chemical property of secondary cell is unaffected;When secondary cell is collided, squeezes, falls When machinery abuse, the viscosity of the shear thickening liquid in aluminum plastic film composite layer increased dramatically and absorb big energy, or even transformation For class solid matter so that aluminum plastic film composite layer is hardened rapidly, plays the role of protecting battery core, effectively avoids the inside of secondary cell Short circuit occurs, to improve the security performance of secondary cell;After machinery abuse disappears, the shear thickening in aluminum plastic film composite layer Liquid shows readily flowed liquid condition again, therefore does not influence being continuing with for secondary cell.
(2) production cost of secondary cell of the invention is low, simple for process, the side effects such as nonhazardous, and is especially suitable for wide General production.
Description of the drawings
Fig. 1 is the schematic diagram of aluminum plastic film composite layer according to an embodiment of the invention;
Fig. 2 is the schematic diagram of aluminum plastic film composite layer according to another embodiment of the present invention;
Fig. 3 is the schematic diagram of aluminum plastic film composite layer according to yet another embodiment of the invention;
Fig. 4 is the schematic diagram according to the aluminum plastic film composite layer of further embodiment of this invention;
Fig. 5 is the schematic diagram according to the aluminum plastic film composite layer of further embodiment of this invention;
Fig. 6 is the schematic diagram according to the aluminum plastic film composite layer of further embodiment of this invention;
Fig. 7 is the schematic diagram according to the aluminum plastic film composite layer of further embodiment of this invention;
Fig. 8 is the schematic diagram according to the aluminum plastic film composite layer of further embodiment of this invention;
Fig. 9 is the schematic diagram according to the aluminum plastic film composite layer of further embodiment of this invention;
Figure 10 is the schematic diagram of secondary cell according to an embodiment of the invention;
Figure 11 is the rheological curve of the shear thickening liquid of the embodiment of the present invention 1;
Figure 12 is the photo after the secondary cell impact test of the comparative example 1 of the present invention;
Figure 13 is the photo after the secondary cell impact test of the embodiment of the present invention 1.
Wherein, the reference numerals are as follows:
1 battery core
2 packaging bags
3 aluminum plastic film composite layers
31 the first polymer layers
32 aluminium foil layers
33 the second polymer layers
331 sublayers
E electrolyte
F shear thickening liquid
Specific implementation mode
The following detailed description of aluminum plastic film composite layer according to the present invention and secondary cell and embodiment, comparative example and test As a result.
Illustrate aluminum plastic film composite layer 3 according to a first aspect of the present invention first.
Referring to figs. 1 to Fig. 9, aluminum plastic film composite layer 3 according to a first aspect of the present invention includes the first polymer layer 31, aluminium foil Layer 32 and the second polymer layer 33, aluminium foil layer 32 is between the first polymer layer 31 and the second polymer layer 33, and second Electrolyte E can be isolated with aluminium foil layer 32 for polymeric layer 33, so that electrolyte E cannot be contacted through the second polymer layer 33 Aluminium foil layer 32.Contain shear thickening liquid F in aluminum plastic film composite layer 3, and shear thickening liquid F is located in aluminum plastic film composite layer 3 Inside of the first polymer layer 31 towards battery core 1.
When aluminum plastic film composite layer 3 according to a first aspect of the present invention is applied to secondary cell (in conjunction with Figure 10), second is poly- Nitride layer 33 is closed towards battery core 1.When secondary cell works normally, the shear thickening liquid F in aluminum plastic film composite layer 3 is to be easy to flow Dynamic liquid condition exists, therefore the chemical property of secondary cell is unaffected;When secondary cell is collided, squeezes When the machinery abuse such as pressing, fall, the viscosity of the shear thickening liquid F in aluminum plastic film composite layer 3 increased dramatically and absorb a large amount of energy Amount, or even it is changed into class solid matter so that aluminum plastic film composite layer 3 is hardened rapidly, plays the role of protecting battery core 1, effectively avoid The short circuit occurred inside of secondary cell, to improve the security performance of secondary cell;After machinery abuse disappears, aluminum plastic film is compound Shear thickening liquid F in layer 3 shows readily flowed liquid condition again, therefore does not influence being continuing with for secondary cell.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the shear thickening liquid F can be at aluminium foil Between layer 32 and the first polymer layer 31 (referring to Fig. 1) and/or in aluminium foil layer 32 and the second polymer layer 33 (referring to Fig. 2) it Between.The set-up mode of shear thickening liquid F may include one or more of injection, sealing, absorption, spraying and dipping.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, as depicted in figs. 1 and 2, the second polymer layer 33 can be one layer and the second polymer layer 33 is non-porous.The polymer of the second polymer layer 33 may include polyester fiber, polyethylene (PE), one or more of polypropylene (PP) and polypropylene, polyethylene (PP/PE) composite material.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, as shown in Fig. 3 to Fig. 9, the second polymer layer 33 include multiple sublayers 331, and at least one of multiple sublayers 331 sublayer 331 is non-porous;Other than non-porous sublayer 331, remaining At least one of sublayer 331 sublayer 331, which has, contains shear thickening liquid F in hole and hole.The set-up mode of shear thickening liquid F It may include one or more of injection, sealing, absorption, spraying and dipping.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the porose sublayer of the second polymer layer 33 331 porosity can be 30%~60%.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the porose sublayer of the second polymer layer 33 331 polymer may include polyester fiber, Fypro, polyethylene (PE), polypropylene (PP) and polypropylene, polyethylene (PP/PE) one or more of composite material.The porosity of the porose sublayer 331 of the second polymer layer 33 can be by poly- Object is closed to be stretched and realized.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the non-porous sublayer of the second polymer layer 33 331 polymer may include that polyester fiber, polyethylene (PE), polypropylene (PP) and polypropylene, polyethylene (PP/PE) are compound One or more of material.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the porose sublayer of the second polymer layer 33 331 thickness can be 5 μm~100 μm.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the viscosity of shear thickening liquid F can be 100PaS/25 DEG C~20000PaS/25 DEG C.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, shear thickening liquid F may include micro-nano Grain and decentralized medium.When secondary cell such as is collided, squeezes, falls at the machinery abuse, near the point of impingement is in suspension The micro-nano granules of state are gathered into particle cluster suddenly, and the viscosity of shear thickening liquid F increased dramatically and absorb big energy, even It is changed into class solid matter, therefore aluminum plastic film composite layer 3 may make to be hardened rapidly, to plays the role of protecting secondary cell.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the quality of the micro-nano granules can be to cut Cut the 10%~70% of the quality of thickening liquid F.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the quality of the decentralized medium can be shearing The 30~90% of the quality of thickening liquid F.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the micro-nano granules may include titanium dioxide One or more of silicon, alundum (Al2O3) and polystyrene.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the median particle diameter of the micro-nano granules can For 10nm~10 μm.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the decentralized medium may include polypropylene glycol, Polyethylene glycol, methoxy group polysiloxanes, hydroxy-terminated polysiloxane and one kind in ethyoxyl terminated polysiloxane or It is several.
In the aluminum plastic film composite layer 3 described according to a first aspect of the present invention, the polymer in the first polymer layer 31 can Including one kind in polyethylene (PE), polypropylene (PP) and polypropylene, polyethylene (PP/PE) composite material.
Secondly the secondary cell of explanation according to a second aspect of the present invention.
Referring to Fig.1 0, secondary cell according to a second aspect of the present invention, including battery core 1, packaging electric core 1 packaging bag 2, with And it is contained in packaging bag 2 and impregnates the electrolyte E of battery core 1.Wherein, 2 use of packaging bag is described according to a first aspect of the present invention Aluminum plastic film composite layer 3 be made, and the second polymer layer 33 is towards battery core 1.
The embodiment and comparative example of aluminum plastic film composite layer and secondary cell according to the present invention will be illustrated next.
Embodiment 1
(1) aluminum plastic film composite layer is prepared
At 25 DEG C, by silica dioxide granule and the polypropylene glycol liquid in mass ratio 50 that median particle diameter is 120nm:50 Mechanical agitation mixes 30min in planet stirring equipment, and the shear thickening liquid that viscosity is 2000 ± 500PaS is made;
As shown in figure 3, being 10 μm by thickness, the two sides for the polyester material cut that porosity is 42% is immersed in In shear thickening liquid through preparing, dip time 2h will impregnate the polyester material (i.e. second of shear thickening liquid later Polymeric layer has hole sublayer), thickness be 20 μm non-porous PP materials (i.e. the nonporous sublayers of the second polymer layer), thickness 40 μm aluminium foil (i.e. aluminium foil layer) and thickness be 25 μm non-porous PE materials (i.e. the first polymer layer) obtain aluminium after hot pressing successively Plastic film composite layer.
(2) secondary cell is prepared
By positive active material cobalt acid lithium, bonding agent Kynoar (PVDF), conductive agent conductive black in mass ratio 94: 3:3 are uniformly mixed with solvent N-methyl pyrilidone, and finely dispersed anode sizing agent is obtained through high-speed stirred, then starch anode Material is uniformly coated on plus plate current-collecting body aluminium foil, then carries out forced air drying, after through cold pressing obtain positive plate;
Negative electrode active material graphite, bonding agent butadiene-styrene rubber (SBR) and sodium carboxymethylcellulose (CMC), conductive agent are led Electric carbon black in mass ratio 95:2:1:2 are uniformly mixed with solvent deionized water, and obtaining finely dispersed cathode through high-speed stirred starches Material, then negative electrode slurry is uniformly coated on negative current collector copper foil, then carry out forced air drying, after through cold pressing obtain cathode Piece;
LiPF6 and ethylene carbonate (EC) and diethyl carbonate (DEC) are configured to the LiPF of 1.0mol/L6Solution (wherein, EC and DEC mass ratioes are 3:7) nonaqueous electrolytic solution, is obtained;
By the positive plate of preparation, negative plate and isolation film PE film rolls around being assembled into naked battery core, then by aluminum plastic film composite layer Punching hole is carried out according to the size of naked battery core, naked battery core is placed in again later in the interior hole of aluminum plastic film composite layer and completes assembling, finally Electrolyte is injected, and is packaged, is melted into, obtaining secondary cell after the processes such as capacity.
Embodiment 2
(1) aluminum plastic film composite layer is prepared
At 25 DEG C, the alundum (Al2O3) particle that median particle diameter is 600nm is pressed with methoxy group polyorganosiloxane fluid Mass ratio 40:60 mix 60min under ultrasonic wave, and the shear thickening liquid that viscosity is 1500 ± 300PaS is made;
As shown in figure 3, shear thickening liquid obtained is sprayed on, thickness is 12 μm, porosity is 50% to cut On the two sides of PP materials, spray 5 times repeatedly, by the PP materials for spraying shear thickening liquid, (i.e. the second polymer layer has later Hole sublayer), the non-porous PP materials (i.e. the nonporous sublayers of the second polymer layer) that another thickness is 20 μm, the aluminium foil that thickness is 40 μm It is compound that the non-porous PE materials (i.e. the first polymer layer) that (i.e. aluminium foil layer) and thickness are 25 μm obtain aluminum plastic film after hot pressing successively Layer.
(2) secondary cell is prepared
Secondary cell is prepared according to (2) the step of embodiment 1, removes following difference:
The aluminum plastic film composite layer prepared using (1) the step of embodiment 2.
Embodiment 3
(1) aluminum plastic film composite layer is prepared
At 25 DEG C, granules of polystyrene and ethyoxyl terminated polysiloxane liquid that median particle diameter is 5 μm are pressed into quality Than 60:40 on planet mixing plant mechanical agitation 3.5h, be made viscosity be 4000 ± 500PaS shear thickening liquid;
As shown in figure 3, being 15 μm by thickness, the two sides for the PP/PE composite materials cut that porosity is 58% dipping In the shear thickening liquid made, dip time 5h will impregnate the PP/PE composite materials of shear thickening liquid later (i.e. the second polymer layer has hole sublayer), thickness be 20 μm non-porous PP materials (i.e. the nonporous sublayers of the second polymer layer), Non-porous PE materials (i.e. the first polymer layer) hot pressing successively that the aluminium foil (i.e. aluminium foil layer) and thickness that thickness is 40 μm are 25 μm After obtain aluminum plastic film composite layer.
(2) secondary cell is prepared
Secondary cell is prepared according to (2) the step of embodiment 1, removes following difference:
The aluminum plastic film composite layer prepared using (1) the step of embodiment 3.
Embodiment 4
(1) aluminum plastic film composite layer is prepared
It is 50 in mass ratio by granules of polystyrene and polypropylene glycol liquid that median particle diameter is 1 μm at 25 DEG C:50 In planet stirring equipment after mechanical agitation 4h, ultrasonic vibration dispersion 1h is reused, it is cutting for 3500 ± 300PaS that viscosity, which is made, Cut thickening liquid;
As shown in Fig. 2, by thickness be 35 μm non-porous PP materials (i.e. the second polymer layer, and it is single layer), thickness be Non-porous PE materials (i.e. the first polymer layer) hot pressing successively that 40 μm of aluminium foil (i.e. aluminium foil layer) and thickness is 25 μm later will Shear thickening liquid is injected between PP materials and aluminium foil, aluminum plastic film composite layer is obtained after sealing, wherein in aluminum plastic film composite layer Shear thickening liquid distribution content be 1.5mL/cm3
(2) secondary cell is prepared
Secondary cell is prepared according to (2) the step of embodiment 1, removes following difference:
The aluminum plastic film composite layer prepared using (1) the step of embodiment 4.
Comparative example 1
Secondary cell is prepared according to the method for embodiment 1, only in step (1), is not provided with shear thickening liquid, i.e., directly Connect by non-porous polyester material (i.e. the second polymer layer is single layer) that thickness is 35 μm, aluminium foil (aluminium foil layer) that thickness is 40 μm with And the non-porous PE materials (i.e. the first polymer layer) that thickness is 25 μm obtain aluminum plastic film composite layer after hot pressing successively.
Finally provide the performance test process and the performance test results of embodiment 1-4 and the secondary cell of comparative example 1.
(1) volume test of secondary cell
Under conditions of 25 ± 3 DEG C, with 0.5C constant-current charge 2h, constant-voltage charge to electric current is then carried out again and is reduced to 0.05C, Then 5min is stood, then with 1C constant-current discharges, tests the discharge capacity of secondary cell.Take all secondary cells that test obtains The average value of 1C discharge capacities weigh the discharge capacity of secondary cell.
(2) extruding (crush) test of secondary cell
Under conditions of 25 ± 3 DEG C, secondary cell is charged to by 100%SOC with the continuous current of 0.1C, is set later (pressure is 0.5 ton) carries out extruding test in extrusion equipment.
(3) shock (impact) test of secondary cell
Under conditions of 25 ± 3 DEG C, the metal bar of a diameter of 15.8mm is placed on to the centre of secondary cell, uses 9.1kg Weight from specified altitude assignment (61 ± 2.5cm) fall, hit metal bar, to secondary cell carry out impact test.
The criterion of the safety test of secondary cell is:It does not explode, is not on fire, not burning as passing through.
Table 1 provides the performance test results of embodiment 1-4 and the secondary cell of comparative example 1.
Figure 11 is that the rheological curve of the shear thickening liquid of embodiment 1 is cut it can be seen from the figure that shear rate is bigger The viscosity for cutting thickening liquid is bigger.
From table 1 it follows that the chemical property of the secondary cell of the embodiment of the present invention 1-4 does not obviously deteriorate. This is because when secondary cell works normally, the shear thickening liquid in aluminum plastic film composite layer is with readily flowed liquid condition In the presence of, therefore the chemical property of secondary cell is unaffected.
Figure 12 is the photo after the secondary cell impact test of comparative example 1, and Figure 13 is that the secondary cell of embodiment 1 hits survey Photo after examination.It can also be seen that the secondary electricity of the present invention from the performance test results in the comparison of Figure 12 and Figure 13 and table 1 Pond has higher security performance.This is because when secondary cell such as is collided, squeezes, falls at the machinery abuse, aluminum plastic film The viscosity of shear thickening liquid in composite layer increased dramatically and absorb big energy, or even be changed into class solid matter so that Aluminum plastic film composite layer is hardened rapidly, plays the role of protecting battery core, effectively avoids the short circuit occurred inside of battery, secondary to improve The security performance of battery.

Claims (10)

1. a kind of aluminum plastic film composite layer, including the first polymer layer, aluminium foil layer and the second polymer layer, aluminium foil layer is located at first Between polymeric layer and the second polymer layer, and electrolyte can be isolated with aluminium foil layer for the second polymer layer, so that electrolyte Aluminium foil layer cannot be contacted through the second polymer layer,
It is characterized in that,
Contain shear thickening liquid in aluminum plastic film composite layer, and shear thickening liquid is located at first polymer in aluminum plastic film composite layer Level is to the inside of battery core.
2. aluminum plastic film composite layer according to claim 1, which is characterized in that shear thickening liquid is in aluminium foil layer and first Between polymeric layer and/or in aluminium foil layer between first polymer layer and the second polymer layer.
3. aluminum plastic film composite layer according to claim 2, which is characterized in that the second polymer layer is one layer and the second polymerization Nitride layer is non-porous.
4. aluminum plastic film composite layer according to claim 3, which is characterized in that
The polymer of the second polymer layer includes polyester fiber, polyethylene, polypropylene and polypropylene, polyethylene composite material One or more of.
5. aluminum plastic film composite layer according to claim 1 or 2, which is characterized in that
The second polymer layer includes multiple sublayers, and at least one of multiple sublayers sublayer is non-porous;
Other than non-porous sublayer, at least one of remaining sublayer sublayer, which has in hole and hole, contains shear thickening liquid.
6. aluminum plastic film composite layer according to claim 5, which is characterized in that the hole of the porose sublayer of the second polymer layer Gap rate is 30%~60%.
7. aluminum plastic film composite layer according to claim 5, which is characterized in that
The polymer of the porose sublayer of the second polymer layer include polyester fiber, Fypro, polyethylene, polypropylene, with And one or more of polypropylene, polyethylene composite material;
The polymer of the non-porous sublayer of the second polymer layer includes polyester fiber, polyethylene, polypropylene and polypropylene/poly- One or more of ethylene composite material.
8. aluminum plastic film composite layer according to claim 1, which is characterized in that
Shear thickening liquid includes micro-nano granules and decentralized medium;
The micro-nano granules include one or more of silica, alundum (Al2O3) and polystyrene;
The decentralized medium include polypropylene glycol, polyethylene glycol, methoxy group polysiloxanes, hydroxy-terminated polysiloxane, with And one or more of ethyoxyl terminated polysiloxane.
9. aluminum plastic film composite layer according to claim 1, which is characterized in that the polymer in the first polymer layer includes poly- One kind in ethylene, polypropylene and polypropylene, polyethylene composite material.
10. a kind of secondary cell, including battery core, packaging electric core packaging bag and be contained in packaging bag and impregnate battery core Electrolyte, which is characterized in that packaging bag is made of the aluminum plastic film composite layer according to any one of claim 1-9, and The second polymer layer is towards battery core.
CN201410658344.1A 2014-11-18 2014-11-18 Aluminum plastic film composite layer and secondary cell Active CN105679971B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410658344.1A CN105679971B (en) 2014-11-18 2014-11-18 Aluminum plastic film composite layer and secondary cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410658344.1A CN105679971B (en) 2014-11-18 2014-11-18 Aluminum plastic film composite layer and secondary cell

Publications (2)

Publication Number Publication Date
CN105679971A CN105679971A (en) 2016-06-15
CN105679971B true CN105679971B (en) 2018-07-13

Family

ID=56944598

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410658344.1A Active CN105679971B (en) 2014-11-18 2014-11-18 Aluminum plastic film composite layer and secondary cell

Country Status (1)

Country Link
CN (1) CN105679971B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110931660A (en) * 2019-11-12 2020-03-27 浙江锋锂新能源科技有限公司 A protection architecture and soft packet of battery for soft packet of battery
CN113381067A (en) * 2020-03-10 2021-09-10 荣盛盟固利新能源科技有限公司 High-safety electrolyte of high-energy-density soft package battery and high-energy-density soft package battery
CN111725565A (en) * 2020-06-24 2020-09-29 珠海冠宇电池股份有限公司 Battery cell structure, preparation method and lithium ion battery
WO2022133726A1 (en) * 2020-12-22 2022-06-30 宁德新能源科技有限公司 Electrochemical device and electronic device
CN113148436B (en) * 2021-03-24 2022-07-29 丝艾(合肥)包装材料有限公司 Manual easy-to-open lining film for tobacco package and processing method thereof
KR20240053088A (en) * 2022-10-14 2024-04-24 광성기업 주식회사 Plastic complex containing shear thickening fluid and manufacturing method therefor

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102330355A (en) * 2011-06-29 2012-01-25 深圳航天科技创新研究院 Fiber fabric composite energy absorbing material and preparation method thereof
CN103786385B (en) * 2014-02-19 2018-02-27 东莞新能源科技有限公司 The preparation method of lithium ion battery and its wrapping film and wrapping film

Also Published As

Publication number Publication date
CN105679971A (en) 2016-06-15

Similar Documents

Publication Publication Date Title
CN105679971B (en) Aluminum plastic film composite layer and secondary cell
CN104795249B (en) A kind of novel battery capacitance based on compound positive and negative electrode material
CN104466186B (en) Microcapsule and positive electrode material for battery as well as preparation methods and application of microcapsule and positive electrode material
TWI649121B (en) Conductive carbon material dispersant and conductive carbon material dispersion
CN106486639B (en) A kind of lithium battery pole slice and preparation method thereof
CN1953247B (en) Lithium secondary battery
CN105304850A (en) Mixed paint for composite membrane of lithium ion battery, composite membrane and preparation method thereof, and lithium ion battery
CN102751530B (en) High capacity lithium ion battery containing metal conductive substances
CN105161661A (en) Composite diaphragm for lithium ion battery, preparation method of composite diaphragm, and lithium ion battery
CN104466231B (en) A kind of lithium rechargeable battery and preparation method thereof
WO2021023135A1 (en) Positive electrode sheet, electrochemical energy storage device related thereto, and apparatus
CN105140450A (en) Lithium ion battery composite separator, preparation method thereof, and lithium ion battery
CN103165840B (en) Electrode assembly of lithium secondary battery
CN104979581B (en) Capsule and lithium ion battery
CN106450261B (en) A kind of the homogenate coating method and its preparation method of lithium ion battery of cathode lithium titanate
CN108011067A (en) A kind of membrane configuration
CN103531814A (en) Composite conductive agent, dispersion method thereof, positive plate and lithium ion battery
WO2021023136A1 (en) Electrochemical energy storage apparatus and device
CN102487151A (en) Lithium ion secondary battery
CN102769149A (en) Preparation method of polymer lithium ion battery and polymer lithium ion battery
CN112736247A (en) Water-based composite binder, negative electrode slurry and preparation method thereof, negative electrode sheet, lithium ion battery cell, lithium ion battery pack and application thereof
CN101826640B (en) Pole core for lithium ion battery and lithium ion battery using pole core
EP3113255B1 (en) Lithium ion secondary battery
CN101557016B (en) A kind of process and products obtained therefrom preparing polymer Li-ion battery
CN106450433A (en) High-rate high-safety soft package lithium-ion battery and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant