Summary of the invention
In view of this, it is necessary to providing a kind of waterproof and breathable window, it had both had good daylighting effect, also can breathe freely, simultaneously can also the anti-mosquito of waterproof.
A kind of waterproof and breathable window, comprising: window frame main body and transmittance section, and described window frame main body is provided with opening, and described transmittance section is made up of transparent waterproof materials, is located at described opening place;
Described waterproof and breathable window also comprises ventilative framework, described ventilative framework arranges around described opening and is fixedly connected with described window frame main body, and described ventilative framework extends from described window frame main body to the outside of described window frame main body, described ventilative framework bonds with hydrophobic binder by particles of aggregates, formed between adjacent particles of aggregates gas molecule can by and the impervious hole of liquid water molecules.
In an embodiment, described transmittance section is sheet glass or transite plate, is fixed on the outer face of described ventilative framework.
In an embodiment, described ventilative framework is bolted in described window frame main body, or described ventilative framework is bonded in described window frame main body.
In an embodiment, the junction of described ventilative framework and described window frame main body is provided with sealing.
In an embodiment, described transmittance section is bolted in described ventilative framework, or described transmittance section is bonded in described ventilative framework.
In an embodiment, the junction of described transmittance section and described ventilative framework is provided with sealing.
In an embodiment, described transmittance section is embedded at the inner side of described ventilative framework slidably to open or to close the air-flow passage of both sides inside and outside described waterproof and breathable window.
In an embodiment, the inner side of described ventilative framework is provided with guide rail, and the outer rim of described transmittance section is provided with the slip mechanism with described guide rail, thus can relatively described ventilative framework slide in described transmittance section.
In an embodiment, described slip mechanism comprises fixing support, and described fixing support is provided with pulley, and described pulley is located in described guide rail.
In an embodiment, described particles of aggregates is the mixture of one or more in quartz sand, slag, pottery material or glass microballon, and the particle diameter of described particles of aggregates is 0.03-1mm, and the hole aperture formed between adjacent particles of aggregates is 0.001-0.4mm.
According to above-mentioned technical scheme, the transmittance section being positioned at window opening front can ensure good daylighting, waterproof and dustproof effect, and be positioned at the ventilative framework in side and can breathe freely, and ventilative framework also has the characteristic of dust-proof, waterproof, sound insulation, is a kind of ideal window structure.
Embodiment
It is the realization reservation technique means taked of goal of the invention and effect for further setting forth the present invention, below in conjunction with accompanying drawing and better embodiment, to according to the specific embodiment of the present invention, structure, feature and effect thereof, it is described in detail as follows.
The decomposing schematic representation of the waterproof and breathable window that Fig. 1 provides for the embodiment of the present invention 1, and the perspective view of the waterproof and breathable window that Fig. 2 provides for embodiment 1. As shown in Figures 1 and 2, waterproof and breathable window 100 comprises window frame main body 10, transmittance section 11 and ventilative framework 12. Waterproof and breathable window 100 both can be flat windowing, it is also possible to be sliding window.
Wherein window frame main body 10 can be made up of metal, alloy, matrix material, timber etc. Window frame main body 10 is a skeleton construction, is provided with opening 101. The shape of opening 101 is unrestricted, such as, can be rectangle, circle, regular polygon etc.
Transmittance section 11 can be transparent sheet material, the sheet material that such as sheet glass or other transparent materials are made such as transparent plastics.
Ventilative framework 12 is arranged around opening 101, and its one end can be fixedly connected with window frame main body 10, such as, be secured by bolts in a surface of window frame main body 10, or cement in the surface of window frame main body 10 with binding agent; Breathe freely and fit tightly between framework 12 the other end (one end away from window frame main body 10) and transmittance section 11, bolted can be adopted each other or adopt gluing mode to fix. That is, transmittance section 11 is arranged on the outer face of ventilative framework 12. In order to enhanced leaktightness, it is also possible to arrange sealing at the interface of ventilative framework 12 with transmittance section 11.
Ventilative framework 12 bonds with hydrophobic binder by particles of aggregates, formed between adjacent particles of aggregates molecule can by and the impervious hole of liquid water molecules.
Above-mentioned particles of aggregates is the mixture of one or more in quartz sand, slag, pottery material or glass microballon. The particle diameter of particles of aggregates is 0.03-1mm. The hole aperture formed between adjacent particles of aggregates is 0.001-0.4mm, it is preferable that 0.01-0.2mm.
Hydrophobic binder is fluorine-containing epoxy resin binding agent, containing a kind of or wherein several mixture in epoxy silicone binding agent, silicone sealants, polychlorostyrene fat, alkyd resin and resol, the saturated alkyd resin of vibrin bisphenol A-type or resol rosin modified phenolic resin.
Waterproof and breathable window according to the present embodiment, owing to ventilative framework 12 can allow gas molecule to pass through, therefore, when being placed on wall by the waterproof and breathable window 100 of the present embodiment, the air of indoor and outdoor can carry out gaseous interchange through ventilative framework 12.
In a concrete enforcement mode, particles of aggregates is mixed with weight ratio 5: 1 by quartz sand and slag, the particle diameter of described quartz sand is 0.075-0.3mm, and the particle diameter of slag is 0.1 to 0.3mm, and forms the hole of 0.01-0.2mm between adjacent particles of aggregates.The hydrophobic binder used is for fluorine-containing epoxy resin binding agent 2,2-bis-phenol base HFC-236fa diglycidylether, hydrophobic binder and particles of aggregates are by weight 1: 99 use; And ventilative framework 12 adopts following method to obtain:
Step 1, pours stirrer into and stirs evenly after being mixed with hydrophobic binder by particles of aggregates;
Step 2, pours the particles of aggregates of coated by hydrophobic binding agent into forming mould;
Step 3, normal temperature is placed and within 2 hours, is made adhesive cures rear demoulding can obtain described ventilative framework.
In a concrete enforcement mode, particles of aggregates is mixed with weight ratio 2: 1 by haydite and glass microballon, the particle diameter of described haydite is 0.075-0.6mm, and the particle diameter of described glass microballon is 0.04-0.15mm, and is formed with the hole of 0.02-0.3mm between adjacent particles of aggregates. The hydrophobic binder used is for using by weight 1: 49 containing epoxy silicone binding agent diphenyl silane modified bisphenol A epoxy resin, hydrophobic binder and particles of aggregates.
Further, the surface of particles of aggregates can also being coated with hydrophobic resin film, the quality of hydrophobic resin film accounts for the 1-8% of aggregate quality. wherein, hydrophobic resin film is by one or more films formed in hydrophobicity epoxy resin, hydrophobicity resol, hydrophobicity urethane resin and silicone resin. hydrophobicity epoxy resin can be glycidyl ether type epoxy resin, glycidyl ester epoxy resin, glycidyl amine epoxy resin, linear aliphatic based epoxy resin, Zhi Huan same clan epoxy resin, polysulfide-rubber-modified epoxy, polyamide resin modified epoxy, the tertiary butyraldehyde modified epoxy of polyvinyl alcohol, butyronitrile school glue modified epoxy, phenolic resin modified epoxy resin, vibrin modified epoxy, urine aldehyde melamine resin modified epoxy, furfuryl resin modified epoxy, ethenoid resin modified epoxy, one or more in isocyanate modified epoxy resin or silicone resin modified epoxy, hydrophobicity resol be preferably in dimethylbenzene modified phenolic resins, epoxy resin modification resol or organic silicon modified phenolic resin one or more.
Above hydrophobic resin can be obtained by following method modification, and concrete method of modifying is:
By epoxy resin, such as adjacent benzene two or four acid anhydrides or maleic anhydride, with oil-soluble monomer copolymerization, oil-soluble monomer is: alkyl acrylate, any one in alkyl methacrylate, ethylacrylic acid, vinyl acetate, ethene acid propyl ester, sodium vinyl sulfonate, methylvinylether, methallyl ether, dimethylaminoethyl methacrylate, vinylformic acid two first chlorine base second ester, vinylformic acid dimethylamino propyl ester, vinylformic acid diethylin propyl ester, vinylformic acid two first ammonia fourth ester, dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate.
Or, it is also possible to by epoxy resin graft modification, form institute's graftomer; By the new water-based group of epoxy resin, such as hydroxyl, react with hydrophobic function monomer, connect; Hydrophobic function monomer is: phenyl aldehyde, alkylbenzaldehyde (a big class), utilize the reaction of hydroxyl and aldehyde radical.
Or, it is also possible to epoxy resin is carried out substitution reaction, under the catalyzed reaction of illumination, participates in substitution reaction with chlorine, halogen is received above epoxy resin, to improve hydrophobic performance.
In addition, hydrophobic resin film can be added with solidifying agent, and, different solidifying agent is added for different resins, wherein, the selection of solidifying agent is specific as follows:
For glycidyl ether type epoxy resin, glycidyl ester epoxy resin, glycidyl amine epoxy resin, linear aliphatic based epoxy resin, Zhi Huan same clan epoxy resin, polysulfide-rubber-modified epoxy, polyamide resin modified epoxy, the tertiary butyraldehyde modified epoxy of polyvinyl alcohol, acrylonitrile butadiene rubber modified epoxy resin, phenolic resin modified epoxy resin, vibrin modified epoxy, urine aldehyde melamine resin modified epoxy, furfuryl resin modified epoxy, ethenoid resin modified epoxy, isocyanate modified epoxy resin or silicone resin modified epoxy, the described solidifying agent added is aliphatic amide, fat cyclammonium, aromatic amine, polymeric amide, acid anhydrides, any one or several in tertiary amine,
For dimethylbenzene modified phenolic resins, epoxy resin modification resol or organic silicon modified phenolic resin, the solidifying agent added is hexamethylenetetramine;
Solidifying agent for silicone resin is dibutyl tin dilaurate or N, N, N ', any one or several in N ' tetramethyl guanidine salt;
Solidifying agent for hydrophobicity urethane resin is the affixture of TDI and TMP, the tripolymer of the prepolymer of TDI and hydroxyl group part and single-component moisture solidification agent, TDI.
For poly-unsaturated acid (polymkeric substance of terephthalic acid and ethylene glycol), the solidifying agent added during normal temperature is ketone peroxide and cobalt naphthenate; The solidifying agent added during heating is one or more in the two ester of peroxidized t-butyl perbenzoate, peroxy dicarbonate, dialkyl peroxide, the tertiary own ester of peroxidation acid and peroxy dicarbonate.
In present embodiment, hydrophobicity epoxy resin obtains by Tetra hydro Phthalic anhydride and methylvinylether copolymerization. The method being coated on particles of aggregates by hydrophobicity epoxy resin is:
1) epoxy resin is heated to molten state;
2) when particles of aggregates is heated to 200 degrees Celsius, add epoxy resin, 20 seconds stirring and evenly mixings, make epoxy resin be dispersed in particles of aggregates surface;
3) paraformaldehyde solidifying agent (accounting for the 0.05wt% of particles of aggregates) is added in the above-mentioned mixture prepared, stirring and evenly mixing, solidify 20 seconds;
4) adding in the mixture being cured by polyethylene wax lubricant (accounting for the 0.0025wt% of particles of aggregates), stir evenly, cooling, sieves, can obtain the hydrophobic granule being coated with hydrophobic resin film.
After obtaining hydrophobic particle, it is possible to according to the obtained ventilative framework 12 of following method:
A. pouring stirrer with hydrophobic binder after being mixed by the particles of aggregates being coated with hydrophobicity epoxy resin into stirs evenly;
B. the particles of aggregates being bonded with hydrophobic binder is poured into forming mould;
C. after rotating 48 hours curing moldings at 5 degrees Celsius, the demoulding can obtain ventilative framework 12.
In a concrete enforcement mode, particles of aggregates is mixed with weight ratio 1: 4 by haydite and quartz sand, the particle diameter of described haydite is 0.05-0.3mm, and the particle diameter of described quartz sand is 0.06-0.112mm, and is formed with the hole of 0.001-0.2mm between adjacent particles of aggregates. Hydrophobic binder is that silicone sealants methyl phenyl silicone resin, hydrophobic binder and particles of aggregates use by weight 3: 97.
Being coated with hydrophobic PTFE on particles of aggregates, hydrophobic PTFE is the 3wt% of particles of aggregates. The method that poly-four tetrafluoroethylene of hydrophobicity are coated on particles of aggregates is:
1) hydrophobic PTFE is heated to molten state;
2) when particles of aggregates is heated to 200 degrees Celsius, add the hydrophobic PTFE of melting, 30 seconds stirring and evenly mixings, make hydrophobic PTFE be dispersed in particles of aggregates surface;
3) hexamethylenetetramine solidifying agent (accounting for the 0.015wt% of particles of aggregates) is added in the above-mentioned mixture prepared, stirring and evenly mixing, solidify 60 seconds;
4) adding in the mixture being cured by oxidic polyethylene wax lubricant (accounting for the 0.009wt% of particles of aggregates), stir evenly, cooling, sieves, can obtain the hydrophobic granule being coated with hydrophobic PTFE.
After obtaining hydrophobic particle, it is possible to according to the obtained ventilative framework 12 of following method:
A. pouring stirrer with hydrophobic binder after being mixed by the particles of aggregates being coated with hydrophobicity epoxy resin into stirs evenly;
B. the particles of aggregates being bonded with hydrophobic binder is poured into forming mould;
C. normal temperature is placed and within 3 hours, is made the shaping rear demoulding of adhesive cures can obtain ventilative framework 12.
In a concrete enforcement mode, particles of aggregates is that haydite and quartz sand mix with weight ratio 4: 6, the particle diameter of described haydite is 0.09-0.3mm, and the particle diameter of described quartz sand is 0.05-0.1mm, and is formed with the hole of 0.03-0.1mm between adjacent particles of aggregates. Hydrophobic binder is that Polyurethane aromatic isocyanate system Polyurethane, hydrophobic binder and particles of aggregates use by weight 1.5: 98.5.
Being coated with resol in particles of aggregates, resol is the 1wt% of particles of aggregates. Hydrophobicity resol obtains by maleic anhydride and sodium vinyl sulfonate copolymerization.
The method that resol is coated on particles of aggregates is:
1) resol is heated to molten state;
2) when particles of aggregates is heated to 220 degrees Celsius, add the resol of melting, 60 seconds stirring and evenly mixings, make resol be dispersed in particles of aggregates surface;
3) fatty amine solidifying agent (accounting for the 10wt% of particles of aggregates) is added in the above-mentioned mixture prepared, stirring and evenly mixing, solidify 120 seconds;
4) adding in the mixture being cured by stearic acid amide lubricant (accounting for the 1.25wt% of particles of aggregates), stir evenly, cooling, sieves, can obtain the hydrophobic granule being coated with hydrophobic resin film.
After obtaining hydrophobic particle, it is possible to according to the obtained ventilative framework 12 of following method:
A. pouring stirrer with hydrophobic binder after being mixed by the particles of aggregates being coated with resol into stirs evenly;
B. the particles of aggregates being bonded with hydrophobic binder is poured into forming mould;
C. the shaping rear demoulding of adhesive cures within 1 hour, is made can to obtain ventilative framework 12 120 degrees Celsius of rotations.
The structural representation of the waterproof and breathable window that Fig. 3 provides for second embodiment of the invention. In the present embodiment, waterproof and breathable window 200 is similar to waterproof and breathable window 100 structure shown in Fig. 1, its difference is, transmittance section 11 is embedded at the inner side of described ventilative framework 12 slidably to open or to close the air-flow passage of both sides inside and outside described waterproof and breathable window 200.
Specifically, the outer contoured shape of transmittance section 11 is mated mutually with the inner shape of ventilative framework 12, but the external diameter of transmittance section 11 is slightly less than the internal diameter of ventilative framework 12, such as little 2 to 5 millimeters. So, transmittance section 11 can be embedded at the inner side of ventilative framework 12. Being provided with slide rail 120 on the inner surface of ventilative framework 12, correspondingly, the position that the outer rim in transmittance section 11 is corresponding with slide rail 110 is provided with fixing support 110, fixing support 110 is provided with pulley, and pulley is contained in slide rail. So, just can slide along slide rail 120 in transmittance section 11. It should be appreciated that transmittance section 11 is not limited to above-described enforcement mode with the slip mechanism before ventilative framework 12, arbitrary slip set-up mode all can be used in the present embodiment.
When transmittance section 11 slides into inner side, when namely contacting with window frame main body, waterproof and breathable window 200 becomes the structure similar with ordinary glazed window, all closes, can daylighting, dust-proof, waterproof, but cannot breathe freely. When sliding laterally in transmittance section 11, some meeting of ventilative framework 12 communicate with the inner side of waterproof and breathable window 200, it is provided that air permeable effect. Transmittance section 11 is the closer to outside, and air permeable effect is more good. Owing to the pore dimension of ventilative framework 12 material used only can allow gas molecule to pass through, therefore there is the function of water proof and dust proof equally.
The above, it it is only the better embodiment of the present invention, not the present invention is done any restriction in form, although the present invention discloses as above with better embodiment, but and be not used to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, make a little change when the technology contents of above-mentioned announcement can be utilized or it is modified to the equivalent embodiment of equivalent variations, in every case it is do not depart from technical solution of the present invention content, the any brief introduction amendment above embodiment done according to the technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.