CN105671945A - Environment-friendly deepening agent applicable to polyester fiber - Google Patents
Environment-friendly deepening agent applicable to polyester fiber Download PDFInfo
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- CN105671945A CN105671945A CN201610227183.XA CN201610227183A CN105671945A CN 105671945 A CN105671945 A CN 105671945A CN 201610227183 A CN201610227183 A CN 201610227183A CN 105671945 A CN105671945 A CN 105671945A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an environment-friendly deepening agent applicable to polyester fiber.The deepening agent is prepared from water-borne polyacrylic acid, ethylene glycol sodium phosphate, polyethyleneimine and polyvinylmethyl ether, wherein the water-borne polyacrylic acid is obtained through polymerization of methyl acrylate, butyl methacrylate and vinyl acetate.The deepening agent is good in deepening effect, and the refractive index problem of the surface of polyester fiber can be effectively solved; meanwhile, after the deepening agent is used, the fabric will not be stiff, and the hand feeling of the fabric can be kept soft.The raw materials adopted for the deepening agent are low in price and easy to obtain, and the environment-friendly deepening agent is low in production cost and suitable for industrial production.
Description
Technical field:
The present invention relates to field of textiles, particularly a kind of environment-friendly type hyperchromicity agent being applicable to trevira.
Background technology:
Along with present growth in the living standard, people are more and more higher for the requirement of textiles. Trevira is more and more subject to the favor of people due to its intensity height, good springiness, good stability and wear resisting property advantages of higher. Trevira is that development is than class synthon faster at present, and kind is more, and output is bigger. But, polyester fibre surface is smooth so that it is specific refractory power height, and the reflection light quantity on surface is big, and conventional dyeing process is difficult to make it have deeply dense color. Dyeing concentration is low, thus the color making this kind fabric is bright-coloured not.
In the nearly stage, making the technology fast development of trevira dark colorization, wherein comparatively effective two kinds of modes are fiber surface coarseization and use hyperchromicity agent process. Use the principle of operation of hyperchromicity agent process for utilizing hyperchromicity agent to form thin film uniformly at fiber surface. Thus reduce the reflection light quantity of fiber surface, increase the object absorbing light quantity thus reach the color and luster deepening dacron fabric.
Correlative study according to present stage, what hyperchromicity agent use was more is organic fluorine, organosilicon and acrylate resin. Wherein, organic fluorine class hyperchromicity agent, although it increases dark effect better, but this type organic is expensive, and itself has toxicity, HUMAN HEALTH can be damaged. Silicone based resin is with so its better softness, but the dark limited efficiency of the increasing of such hyperchromicity agent, the demand of people cannot be met. The dark effect of the increasing of acrylate resin is good, but is used alone and fabric can be made to become stiff, affects feel. Therefore, research and development are a kind of increases dark effect well, and fabric feeling does not have influential hyperchromicity agent be very valuable.
Summary of the invention:
The present invention relates to a kind of environment-friendly type hyperchromicity agent being applicable to trevira, it is good that this hyperchromicity agent increases dark effect, it is possible to effectively improves the specific refractory power problem of polyester fibre surface. Simultaneously, it may also be useful to after fabric can not be made to become stiff, it is possible to keep the feel of fabric soft. The raw material that this hyperchromicity agent uses is all cheap and easy to get, and production cost is low, is applicable to suitability for industrialized production.
For achieving the above object, the present invention is by the following technical solutions:
A kind of environment-friendly type hyperchromicity agent being applicable to trevira, it is characterised in that, it is prepared from by following method:
(1) by methyl acrylate, butyl methacrylate and vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add a small amount of initiator benzoyl peroxide acetyl, with 60-100 turn/rotating speed of min stirs, adding organic acid for adjusting pH is 5-7, heating and control temperature at 80-95 DEG C, back flow reaction, after sustained reaction 6-8h, add Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtained aqueous polyacrylamide acid;
(2) by the aqueous polyacrylamide acid dissolve that obtains in previous step in ethanolic soln, heating, control temperature is 40-60 DEG C, add ethylene glycol sodium phosphate wherein, polymine and polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
Preferably, methyl acrylate in wherein said step (1), the mol ratio of butyl methacrylate and vinyl acetate between to for plastic is 2-3:1-2:1.
Preferably, in wherein said step (1), the mol ratio of vinyl acetate between to for plastic and benzoyl peroxide acetyl is 1:0.03-0.05.
Preferably, in wherein said step (1), organic acid is the one in formic acid, oxalic acid or acetic acid.
Preferably, in wherein said step (1), the mol ratio of vinyl acetate between to for plastic and Sodium dodecylbenzene sulfonate is 1:0.2-0.5.
Preferably, in wherein said step (2), the mass ratio of aqueous polyacrylamide acid and ethylene glycol sodium phosphate is 1:0.3-0.5.
Preferably, in wherein said step (2), the mass ratio of aqueous polyacrylamide acid and polymine is 1:0.2-0.4.
Preferably, in wherein said step (2), the mass ratio of aqueous polyacrylamide acid and polyethylene methyl ether is 1:0.1-0.3.
The present invention has following useful effect:
The environment-friendly type hyperchromicity agent being applicable to trevira of the present invention, this hyperchromicity agent uses the good aqueous polyacrylamide acid of pliability, while ensureing good deep dyeing energy, it is ensured that fabric keeps good pliability. In addition, it may also be useful to polyethylene methyl ether there is good softness, it is possible to more effectively promote the pliability of fabric. Meanwhile, ethylene glycol sodium phosphate and polymine all can play fine tint retention, also to increase the firmness of color, persistency while deepening trevira color.
Embodiment:
For a better understanding of the present invention, below by embodiment, the present invention is further described, and the present invention, only for explaining the present invention, can not be formed any restriction by embodiment.
Embodiment 1
By 200mmol methyl acrylate, 100mmol butyl methacrylate and 100mmol vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add 3mmol initiator benzoyl peroxide acetyl, stirring with the rotating speed of 60 turns/min, add formic acid, oxalic acid or second acid for adjusting pH are 5, heating and control temperature at 80 DEG C, back flow reaction, after sustained reaction 6h, adds 20mmol Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtain aqueous polyacrylamide acid; The aqueous polyacrylamide obtained in previous step acid 100g is dissolved in ethanolic soln, heating, control temperature is 40 DEG C, add 30g ethylene glycol sodium phosphate wherein, 20g polymine and 30g polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
Embodiment 2
By 250mmol methyl acrylate, 200mmol butyl methacrylate and 100mmol vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add 4mmol initiator benzoyl peroxide acetyl, stirring with the rotating speed of 70 turns/min, add formic acid, oxalic acid or second acid for adjusting pH are 6, heating and control temperature at 85 DEG C, back flow reaction, after sustained reaction 7h, adds 25mmol Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtain aqueous polyacrylamide acid; The aqueous polyacrylamide obtained in previous step acid 100g is dissolved in ethanolic soln, heating, control temperature is 50 DEG C, add 35g ethylene glycol sodium phosphate wherein, 25g polymine and 25g polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
Embodiment 3
By 300mmol methyl acrylate, 100mmol butyl methacrylate and 100mmol vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add 5mmol initiator benzoyl peroxide acetyl, stirring with the rotating speed of 80 turns/min, add formic acid, oxalic acid or second acid for adjusting pH are 7, heating and control temperature at 80 DEG C, back flow reaction, after sustained reaction 8h, adds 30mmol Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtain aqueous polyacrylamide acid; The aqueous polyacrylamide obtained in previous step acid 100g is dissolved in ethanolic soln, heating, control temperature is 60 DEG C, add 40g ethylene glycol sodium phosphate wherein, 30g polymine and 20g polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
Embodiment 4
By 200mmol methyl acrylate, 200mmol butyl methacrylate and 100mmol vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add 3mmol initiator benzoyl peroxide acetyl, stirring with the rotating speed of 90 turns/min, add formic acid, oxalic acid or second acid for adjusting pH are 6, heating and control temperature at 90 DEG C, back flow reaction, after sustained reaction 8h, adds 35mmol Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtain aqueous polyacrylamide acid; The aqueous polyacrylamide obtained in previous step acid 100g is dissolved in ethanolic soln, heating, control temperature is 50 DEG C, add 45g ethylene glycol sodium phosphate wherein, 35g polymine and 15g polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
Embodiment 5
By 250mmol methyl acrylate, 100mmol butyl methacrylate and 100mmol vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add 4mmol initiator benzoyl peroxide acetyl, stirring with the rotating speed of 100 turns/min, add formic acid, oxalic acid or second acid for adjusting pH are 7, heating and control temperature at 95 DEG C, back flow reaction, after sustained reaction 6h, adds 40mmol Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtain aqueous polyacrylamide acid; The aqueous polyacrylamide obtained in previous step acid 100g is dissolved in ethanolic soln, heating, control temperature is 40 DEG C, add 50g ethylene glycol sodium phosphate wherein, 40g polymine and 10g polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
Embodiment 6
By 300mmol methyl acrylate, 200mmol butyl methacrylate and 100mmol vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add 5mmol initiator benzoyl peroxide acetyl, stirring with the rotating speed of 70 turns/min, add formic acid, oxalic acid or second acid for adjusting pH are 5, heating and control temperature at 85 DEG C, back flow reaction, after sustained reaction 7h, adds 50mmol Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtain aqueous polyacrylamide acid; The aqueous polyacrylamide obtained in previous step acid 100g is dissolved in ethanolic soln, heating, control temperature is 60 DEG C, add 40g ethylene glycol sodium phosphate wherein, 25g polymine and 20g polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
Claims (8)
1. one kind is applicable to the environment-friendly type hyperchromicity agent of trevira, it is characterised in that, it is prepared from by following method:
(1) by methyl acrylate, butyl methacrylate and vinyl acetate between to for plastic are dissolved in dehydrated alcohol, add a small amount of initiator benzoyl peroxide acetyl, with 60-100 turn/rotating speed of min stirs, adding organic acid for adjusting pH is 5-7, heating and control temperature at 80-95 DEG C, back flow reaction, after sustained reaction 6-8h, add Sodium dodecylbenzene sulfonate, after vigorous stirring 2h, reduce temperature, steam except ethanol, both obtained aqueous polyacrylamide acid;
(2) by the aqueous polyacrylamide acid dissolve that obtains in previous step in ethanolic soln, heating, control temperature is 40-60 DEG C, add ethylene glycol sodium phosphate wherein, polymine and polyethylene methyl ether, stir evenly, and adjustment pH is 6-8, evaporation concentration, was applicable to the environment-friendly type hyperchromicity agent of trevira described in both having obtained.
2. the environment-friendly type hyperchromicity agent being applicable to trevira according to claim 1, it is characterised in that, methyl acrylate in wherein said step (1), the mol ratio of butyl methacrylate and vinyl acetate between to for plastic is 2-3:1-2:1.
3. the environment-friendly type hyperchromicity agent being applicable to trevira according to claim 1, it is characterised in that, in wherein said step (1), the mol ratio of vinyl acetate between to for plastic and benzoyl peroxide acetyl is 1:0.03-0.05.
4. the environment-friendly type hyperchromicity agent being applicable to trevira according to claim 1, it is characterised in that, in wherein said step (1), organic acid is the one in formic acid, oxalic acid or acetic acid.
5. the environment-friendly type hyperchromicity agent being applicable to trevira according to claim 1, it is characterised in that, in wherein said step (1), the mol ratio of vinyl acetate between to for plastic and Sodium dodecylbenzene sulfonate is 1:0.2-0.5.
6. the environment-friendly type hyperchromicity agent being applicable to trevira according to claim 1, it is characterised in that, in wherein said step (2), aqueous polyacrylamide acid is 1:0.3-0.5 with the mass ratio of ethylene glycol sodium phosphate.
7. the environment-friendly type hyperchromicity agent being applicable to trevira according to claim 1, it is characterised in that, in wherein said step (2), aqueous polyacrylamide acid is 1:0.2-0.4 with the mass ratio of polymine.
8. the environment-friendly type hyperchromicity agent being applicable to trevira according to claim 1, it is characterised in that, in wherein said step (2), aqueous polyacrylamide acid is 1:0.1-0.3 with the mass ratio of polyethylene methyl ether.
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CN201610227183.XA CN105671945A (en) | 2016-04-12 | 2016-04-12 | Environment-friendly deepening agent applicable to polyester fiber |
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CN201610227183.XA CN105671945A (en) | 2016-04-12 | 2016-04-12 | Environment-friendly deepening agent applicable to polyester fiber |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106758378A (en) * | 2017-01-12 | 2017-05-31 | 苏州经贸职业技术学院 | A kind of textile dyeing increases deep functional agent and preparation method thereof, application |
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CN103243591A (en) * | 2013-05-09 | 2013-08-14 | 湖州吉昌丝绸有限公司 | Improved dye fixing agent |
CN103694416A (en) * | 2013-12-11 | 2014-04-02 | 宁波润禾化学工业有限公司 | Preparation method of environment-friendly type fabric deepening agent |
CN104074053A (en) * | 2014-06-27 | 2014-10-01 | 广东德美精细化工股份有限公司 | Efficient deep dyeing promoter, and preparation and after treatment application methods thereof |
CN105113247A (en) * | 2015-08-26 | 2015-12-02 | 浙江理工大学 | Coating liquid with latex particle reflection deducting capability as well as preparation method and application of coating liquid |
CN105113246A (en) * | 2015-08-26 | 2015-12-02 | 浙江理工大学 | Reflection-deducting coating liquid with blended soft and hard particles as well as preparation method and application of reflection-deducing coating liquid |
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2016
- 2016-04-12 CN CN201610227183.XA patent/CN105671945A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103243591A (en) * | 2013-05-09 | 2013-08-14 | 湖州吉昌丝绸有限公司 | Improved dye fixing agent |
CN103694416A (en) * | 2013-12-11 | 2014-04-02 | 宁波润禾化学工业有限公司 | Preparation method of environment-friendly type fabric deepening agent |
CN104074053A (en) * | 2014-06-27 | 2014-10-01 | 广东德美精细化工股份有限公司 | Efficient deep dyeing promoter, and preparation and after treatment application methods thereof |
CN105113247A (en) * | 2015-08-26 | 2015-12-02 | 浙江理工大学 | Coating liquid with latex particle reflection deducting capability as well as preparation method and application of coating liquid |
CN105113246A (en) * | 2015-08-26 | 2015-12-02 | 浙江理工大学 | Reflection-deducting coating liquid with blended soft and hard particles as well as preparation method and application of reflection-deducing coating liquid |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106758378A (en) * | 2017-01-12 | 2017-05-31 | 苏州经贸职业技术学院 | A kind of textile dyeing increases deep functional agent and preparation method thereof, application |
CN106758378B (en) * | 2017-01-12 | 2018-10-30 | 苏州经贸职业技术学院 | A kind of textile dyeing increases deep functional agent and preparation method thereof, application |
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Application publication date: 20160615 |