CN105670459A - Finish-coat paint for epoxy skid-free road surfaces and application method thereof - Google Patents
Finish-coat paint for epoxy skid-free road surfaces and application method thereof Download PDFInfo
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- CN105670459A CN105670459A CN201610127205.5A CN201610127205A CN105670459A CN 105670459 A CN105670459 A CN 105670459A CN 201610127205 A CN201610127205 A CN 201610127205A CN 105670459 A CN105670459 A CN 105670459A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/35—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them
- E01C7/356—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them with exclusively synthetic resin as a binder; Aggregate, fillers or other additives for application on or in the surface of toppings having exclusively synthetic resin as binder
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a finish-coat paint for epoxy skid-free road surfaces. The finish-coat paint is formed by mixing a component A and a component B. The component A comprises the following ingredients in parts by weight: 50-70 parts of bisphenol A epoxy resin, 5-10 parts of water-resistant agent styrenated phenol, 0.3-0.8 part of ultraviolet absorbent, 15-20 parts of m-xylene and 10-15 parts of n-butanol. The component B comprises the following ingredients in parts by weight: 30-35 parts of modified amine curing agent, 1-3 parts of K54 accelerator for accelerating reaction between the bisphenol A epoxy resin and modified amine curing agent, and 35-50 parts of diluter. The volume ratio of the component A to the component B is 2:1. The finish-coat paint can well protect the skid-free road surface, thereby enhancing the aging resistance and ultraviolet resistance of the skid-free road surface. The application method of the finish-coat paint is simple to operate, has the advantages of low facility request and high work efficiency, and is suitable for actual operation.
Description
Technical field
The present invention relates to the technical field of anti-skidding road, particularly relate to a kind of overlay coating for epoxy anti-skid surface and using method thereof.
Background technology
At present both at home and abroad existing road non-skid coating is mostly with epoxy resin or polyurethane resin for binding agent, with quartz sand, corundum, titanium oxide and common rubber grain for non-skid coating. These products in anti-collision performance, abrasion resistance properties and adhesive force etc., still can not meet the instructions for use of high intensity mostly, there is easy fragmentation, comes off and the defect such as service life is short.
It is " CN200710042454.5 " in Chinese invention patent application number, patent name is in the patent document of " epoxy cement based road antiskid coating and preparation method thereof ", disclose a kind of epoxy cement based road antiskid coating, being made up of epoxy emulsion, firming agent, powder three component, firming agent is mixed by triethylene triamine or triethylene tetramine and low molecule pa resin. Powder is made up of portland cement, quartz sand and water reducer. This epoxy cement base adhesive has given full play to the high bonding force of epoxy resin, aqueous, environmental protective, is prone to the advantage of construction, tells about the adhesivity of the anti-formed material that inorganic coagulation material solves again. But still there is easily aging feature in this protective coating, it is impossible to meet the anti-slip material requirement for durability.
Summary of the invention
For the weak point existed in above-mentioned technology, the present invention provides a kind of low viscosity, can play the overlay coating for epoxy anti-skid surface and the using method thereof of aging resistance effect for epoxy anti-skid surface.
In order to achieve the above object, a kind of overlay coating for epoxy anti-skid surface of the present invention, component A and B component mix, calculate with part by weight number,
Described component A includes following component:
Bisphenol A type epoxy resin 50-70 part,
Water repellent agent styrenated phenol 5-10 part,
UV absorbent 0.3-0.8 part,
Meta-xylene 15-20 part,
And n-butyl alcohol 10-15 part;
Described B component includes following component:
Modified amine curing agent 30-35 part,
Promote K54 accelerator 1-3 part that described bisphenol A type epoxy resin and described modified amine curing agent react,
And diluent 35-50 part;
The mixed volume ratio of described component A and B component is 2:1.
Wherein, the diluent in described B component includes the meta-xylene of 25-35 part and the n-butyl alcohol of 10-15 part.
Wherein, described component A includes following component:
Bisphenol A type epoxy resin 65 parts,
Styrenated phenol 5 parts,
UV absorbent 0.4 part,
Meta-xylene 18 parts,
And n-butyl alcohol 12 parts;
Described B component includes following component:
Modified amine curing agent 33 parts,
K54 accelerator 2 parts,
Meta-xylene 30 parts,
And n-butyl alcohol 10 parts;
The mixed volume ratio of described component A and B component is 2:1.
Wherein, the UV absorbent in described component A is phenyl salicylate, UV absorbent UV-O, UV absorbent UV-9, ultraviolet absorbent UV-531, UV absorbent UVP-327 or UV absorbent RMB.
Wherein, the modified amine curing agent in described B component is preferably used the modified amine curing agent 2771 of US Air gas chemical company.
The invention also discloses the using method of a kind of overlay coating for epoxy anti-skid surface, the preparation method of this overlay coating comprises the following steps:
1) preparation of component A: by the n-butyl alcohol of the bisphenol A type epoxy resin of 50-70 part, the water repellent agent styrenated phenol of 5-10 part, the UV absorbent of 0.3-0.8 part, the meta-xylene of 15-20 part and 10-15 part, put in agitator simultaneously and stir;
2) preparation of B component: by the diluent of the modified amine curing agent of 30-35 part, the K54 accelerator of 1-3 part and 35-50 part, put in agitator simultaneously and stir;
3) carry out being sufficiently stirred for for the ratio of 2:1 by volume by the component A stirred and B component and be mixed to get this overlay coating.
Wherein, the UV absorbent in described component A is phenyl salicylate, UV absorbent UV-O, UV absorbent UV-9, ultraviolet absorbent UV-531, UV absorbent UVP-327 or UV absorbent RMB; Modified amine curing agent in described B component is preferably used the modified amine curing agent 2771 of US Air gas chemical company; Diluent in described B component includes the meta-xylene of 25-35 part and the n-butyl alcohol of 10-15 part.
Wherein, the overlay coating through step 3) adds in flush coater, after epoxy anti-skid surface has been mated formation, with the form even application of spraying to anti-skid surface surface.
Wherein, in step 1), the time being stirred in each composition addition agitator of component A is 20min-30min, does not need heating while stirring, and the rotating speed of agitator is 600-800r/min.
Wherein, in step 2) in, the time being stirred in each composition addition agitator of B component is 20min-30min, does not need heating while stirring, and the rotating speed of agitator is 600-800r/min.
The invention has the beneficial effects as follows:
Compared with prior art, the overlay coating for epoxy anti-skid surface of the present invention, in component A, styrenated phenol is water repellent agent, can effectively prevent the albefaction of epoxy with aging after mixing with bisphenol A type epoxy resin; UV absorbent absorbs ultraviolet and helps heat radiation simultaneously, thus having further functioned as the effect of defying age; Meta-xylene and n-butyl alcohol are as solvent, bisphenol A type epoxy resin is served the effect of dilution, so that mixed solution viscosity is relatively low, it is prone to spray on anti-skid surface, meta-xylene and n-butyl alcohol are volatile substances simultaneously, volatilizing rapidly after being sprayed at anti-skid surface, the coefficient of friction without influence on anti-skid surface leaves behind the cover thin layer playing aging resistance effect. Anti-skid surface can be played good protective action by the overlay coating of the present invention, enhances the aging resistance of anti-skid surface, anti-ultraviolet property. The present invention is simple to operate for the using method of the overlay coating of epoxy anti-skid surface, and equipment requirements is low, and work efficiency is high, is suitable to practical operation.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the present invention overlay coating for epoxy anti-skid surface and using method thereof.
Detailed description of the invention
In order to more clearly state the present invention, below in conjunction with accompanying drawing, the present invention is further described.
Consult Fig. 1, the using method of a kind of overlay coating for epoxy anti-skid surface of the present invention, the preparation method of this overlay coating comprises the following steps:
S1, component A preparation: by the n-butyl alcohol of the bisphenol A type epoxy resin of 50-70 part, the water repellent agent styrenated phenol of 5-10 part, the UV absorbent of 0.3-0.8 part, the meta-xylene of 15-20 part and 10-15 part, put in agitator simultaneously and stir, the time being stirred in each composition addition agitator of component A is 20min-30min, not needing heating while stirring, the rotating speed of agitator is 600-800r/min;
S2, B component preparation: by the diluent of the modified amine curing agent of 30-35 part, the K54 accelerator of 1-3 part and 35-50 part, put in agitator simultaneously and stir, the time being stirred in each composition addition agitator of B component is 20min-30min, not needing heating while stirring, the rotating speed of agitator is 600-800r/min;
S3, carry out being sufficiently stirred for for the ratio of 2:1 by volume by the component A stirred and B component and be mixed to get this overlay coating;
S4, coating spraying: overlay coating adds in flush coater, after epoxy anti-skid surface has been mated formation, with the form even application of spraying to anti-skid surface surface.
Embodiment 1
Bisphenol A type epoxy resin 65 parts,
Styrenated phenol 5 parts,
UV absorbent 0.4 part,
Meta-xylene 18 parts,
And n-butyl alcohol 12 parts;
Described B component includes following component:
Modified amine curing agent 33 parts,
K54 accelerator 2 parts,
Meta-xylene 30 parts,
And n-butyl alcohol 10 parts;
The mixed volume ratio of described component A and B component is 2:1.
Embodiment 2
Bisphenol A type epoxy resin 50 parts,
Styrenated phenol 5 parts,
UV absorbent 0.3 part,
Meta-xylene 15 parts,
And n-butyl alcohol 10 parts;
Described B component includes following component:
Modified amine curing agent 30 parts,
K54 accelerator 1 part,
Meta-xylene 25 parts,
And n-butyl alcohol 10 parts;
The mixed volume ratio of described component A and B component is 2:1.
Embodiment 3
Bisphenol A type epoxy resin 70 parts,
Styrenated phenol 10 parts,
UV absorbent 0.8 part,
Meta-xylene 20 parts,
And n-butyl alcohol 15 parts;
Described B component includes following component:
Modified amine curing agent 35 parts,
K54 accelerator 3 parts,
Meta-xylene 35 parts,
And n-butyl alcohol 15 parts;
The mixed volume ratio of described component A and B component is 2:1.
(1) ultraviolet accelerated ageing testing
1, experimental condition
This test adopts the QUV aging testing instrument that Q-Lab company of the U.S. produces.
Sunlight is simulated: QUV can realize with fluorescent ultra-violet lamp simulated solar irradiation, painting layer being caused damage. The ultraviolet short-wave band of sunlight is simulated effective by UVA-340 fluorescent tube, and its spectral power distribution is coincide very good with solar spectrum at the cut-off point of sunlight within the scope of about 360nm.
Radiancy controls: QUV ageing machine has daylight eye light intensity control, utilize the feedback loop system of daylight eye, can continuously, automatically controlling and accurately keep irradiance, daylight eye compensates the light intensity change because fluorescent tube is aging and other factors cause automatically by the power adjusting lamp. In only several days or a few week, the infringement even caused for several years at outdoor some months can be simulated.
Moist simulation: the water bottom moist simulation test room is used to heating and produces steam, vapours makes to keep in test cabinet the relative humidity of 100%. In QUV, test sample actually forms the sidewall of test cabinet, and the another side of sample is exposed in indoor ambient air. Indoor relatively cold air makes the temperature low good several years of vapours in the surface ratio test cabinet of test sample, and temperature difference produces condensation cycle phenomenon, and the water at sample surfaces liquid form condenses at leisure. It addition, condensation process carries out under a higher temperature (being generally 50 DEG C), this has greatly accelerated moist erosion. Simulate the moist of open air with the long thermal coagulation cyclic process of QUV and corrode the some other method of ratio, as dabbled, soak or high humility being all more effective.
QUV degradation state modulator is as follows, tests reference standard ASTMG154-06 nonmetallic materials Ultraluminescence exposure test method.
Lamp type: UVA-340;
Irradiance: 0.89W/m2/nm;
Wavelength: 340nm;
Expose the cycle to the open air: 8h irradiation, blackboard temperature 60 DEG C; 4h condenses, blackboard temperature 50 DEG C.
Test specimen:
No. 1: be coated with the epoxy anti-skid surface model module of overlay coating in embodiment 1;
No. 2: be coated with the epoxy anti-skid surface model module of overlay coating in embodiment 2;
No. 3: be coated with the epoxy anti-skid surface model module of overlay coating in embodiment 3;
No. 4: the epoxy anti-skid surface model module without overlay coating that company A provides.
Test result analysis is such as shown in following table one:
Table one
| Detection project | No. 1 | No. 2 | No. 3 | No. 4 |
| Gloss loss | 0.2% | 0.3%. | 0.2% | 36.5% |
| Color changes | Unchanged | Unchanged | Unchanged | Fade, turn yellow |
| Adhesive force changes | It is basically unchanged | It is basically unchanged | It is basically unchanged | It is basically unchanged |
Can be obtained by table one data, employ the epoxy anti-skid surface of covering material of the present invention and there is better aging resistance, uvioresistant effect.
(2) bowssening surveys Water Resistance Test
1, experimental condition
1) intensity of light: about 1 meter of distance direct projection product surface of 2 40W fluorescent tubes;
2) visual angle: visual angle 45-90 °;
3) visual range: general about the 30-40cm of visual range;
4) visual demand: vision more than 1.0, weak tendency and achromate should not carry out appearance test.
2, test specimen
No. 1: be coated with the epoxy anti-skid surface model module of overlay coating in embodiment 1;
No. 2: be coated with the epoxy anti-skid surface model module of overlay coating in embodiment 2;
No. 3: be coated with the epoxy anti-skid surface model module of overlay coating in embodiment 3;
No. 4: the epoxy anti-skid surface model module without overlay coating that company A provides.
3, test procedure
1) immersion of sample: add pure water or tap water in glass container, put into wherein by 4 samples, and make the 2/3 of every sample length be soaked in water, at room temperature stand, until the soak time that product standard specifies terminates;
2) inspection of sample: taken out from water by sample, blot with filter paper, carries out visual examination after the Timing specified immediately or by product standard, and the phenomenon such as records sample and whether there is loss of gloss, variable color, albefaction, bubbles, comes off.
Test result analysis is such as shown in following table two:
Table two
| Detection project | No. 1 | No. 2 | No. 3 | No. 4 |
| Gloss loss | 0.05% | 0.05%. | 0.05% | 10.5% |
| Color changes | Unchanged | Unchanged | Unchanged | Albefaction |
| Foaming phenomena | Nothing | Nothing | Nothing | Nothing |
| Obscission | Nothing | Nothing | Nothing | / |
Can being obtained by table two data, the covering material of the present invention can be good at being attached to the surface of epoxy anti-skid surface, difficult drop-off, and this covering material can well prevent albefaction and the catabiosis of epoxy anti-skid surface as overcoat simultaneously.
The several specific embodiments being only the present invention disclosed above, but the present invention is not limited to this, and the changes that any person skilled in the art can think of all should fall into protection scope of the present invention.
Claims (10)
1. the overlay coating for epoxy anti-skid surface, it is characterised in that mixed by component A and B component, calculate with part by weight number,
Described component A includes following component:
Bisphenol A type epoxy resin 50-70 part,
Water repellent agent styrenated phenol 5-10 part,
UV absorbent 0.3-0.8 part,
Meta-xylene 15-20 part,
And n-butyl alcohol 10-15 part;
Described B component includes following component:
Modified amine curing agent 30-35 part,
Promote K54 accelerator 1-3 part that described bisphenol A type epoxy resin and described modified amine curing agent react,
And diluent 35-50 part;
The mixed volume ratio of described component A and B component is 2:1.
2. the overlay coating for epoxy anti-skid surface according to claim 1, it is characterised in that the diluent in described B component includes the meta-xylene of 25-35 part and the n-butyl alcohol of 10-15 part.
3. the overlay coating for epoxy anti-skid surface according to claim 2, it is characterised in that described component A includes following component:
Bisphenol A type epoxy resin 65 parts,
Styrenated phenol 5 parts,
UV absorbent 0.4 part,
Meta-xylene 18 parts,
And n-butyl alcohol 12 parts;
Described B component includes following component:
Modified amine curing agent 33 parts,
K54 accelerator 2 parts,
Meta-xylene 30 parts,
And n-butyl alcohol 10 parts;
The mixed volume ratio of described component A and B component is 2:1.
4. the overlay coating for epoxy anti-skid surface according to claim 3, it is characterized in that, the UV absorbent in described component A is phenyl salicylate, UV absorbent UV-O, UV absorbent UV-9, ultraviolet absorbent UV-531, UV absorbent UVP-327 or UV absorbent RMB.
5. the overlay coating for epoxy anti-skid surface according to claim 1, it is characterised in that the modified amine curing agent in described B component is preferably used the modified amine curing agent 2771 of US Air gas chemical company.
6. the using method for the overlay coating of epoxy anti-skid surface, it is characterised in that the preparation method of this overlay coating comprises the following steps:
1) preparation of component A: by the n-butyl alcohol of the bisphenol A type epoxy resin of 50-70 part, the water repellent agent styrenated phenol of 5-10 part, the UV absorbent of 0.3-0.8 part, the meta-xylene of 15-20 part and 10-15 part, put in agitator simultaneously and stir;
2) preparation of B component: by the diluent of the modified amine curing agent of 30-35 part, the K54 accelerator of 1-3 part and 35-50 part, put in agitator simultaneously and stir;
3) carry out being sufficiently stirred for for the ratio of 2:1 by volume by the component A stirred and B component and be mixed to get this overlay coating.
7. the using method of the overlay coating for epoxy anti-skid surface according to claim 6, it is characterized in that, the UV absorbent in described component A is phenyl salicylate, UV absorbent UV-O, UV absorbent UV-9, ultraviolet absorbent UV-531, UV absorbent UVP-327 or UV absorbent RMB; Modified amine curing agent in described B component is preferably used the modified amine curing agent 2771 of US Air gas chemical company; Diluent in described B component includes the meta-xylene of 25-35 part and the n-butyl alcohol of 10-15 part.
8. the using method of the overlay coating for epoxy anti-skid surface according to claim 6, it is characterized in that, overlay coating through step 3) adds in flush coater, after epoxy anti-skid surface has been mated formation, with the form even application of spraying to anti-skid surface surface.
9. the using method of the overlay coating for epoxy anti-skid surface according to claim 6, it is characterized in that, in step 1), the time being stirred in each composition addition agitator of component A is 20min-30min, not needing heating while stirring, the rotating speed of agitator is 600-800r/min.
10. the preparation method of the adhesive for porous pavement top layer according to claim 6, it is characterized in that, in step 2) in, the time being stirred in each composition addition agitator of B component is 20min-30min, not needing heating while stirring, the rotating speed of agitator is 600-800r/min.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610127205.5A CN105670459A (en) | 2016-03-07 | 2016-03-07 | Finish-coat paint for epoxy skid-free road surfaces and application method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610127205.5A CN105670459A (en) | 2016-03-07 | 2016-03-07 | Finish-coat paint for epoxy skid-free road surfaces and application method thereof |
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| CN105670459A true CN105670459A (en) | 2016-06-15 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266998A (en) * | 2016-12-23 | 2017-10-20 | 惠州兴鑫涂料化工有限公司 | A kind of environment-friendly type pavement antiskid paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481576A (en) * | 2008-12-19 | 2009-07-15 | 洛阳七维防腐工程材料有限公司 | Ultra-thick film solvent-free thermal spraying quick-drying heavy-duty anti-corrosive paint and preparation thereof |
| CN104710910A (en) * | 2015-03-27 | 2015-06-17 | 上海灿达建材科技有限公司 | Solvent-free medium coating and manufacturing method thereof |
-
2016
- 2016-03-07 CN CN201610127205.5A patent/CN105670459A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481576A (en) * | 2008-12-19 | 2009-07-15 | 洛阳七维防腐工程材料有限公司 | Ultra-thick film solvent-free thermal spraying quick-drying heavy-duty anti-corrosive paint and preparation thereof |
| CN104710910A (en) * | 2015-03-27 | 2015-06-17 | 上海灿达建材科技有限公司 | Solvent-free medium coating and manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266998A (en) * | 2016-12-23 | 2017-10-20 | 惠州兴鑫涂料化工有限公司 | A kind of environment-friendly type pavement antiskid paint |
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