CN105670399A - High-gloss color inkjet printing paper coating and preparation method thereof - Google Patents

High-gloss color inkjet printing paper coating and preparation method thereof Download PDF

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Publication number
CN105670399A
CN105670399A CN201610042713.3A CN201610042713A CN105670399A CN 105670399 A CN105670399 A CN 105670399A CN 201610042713 A CN201610042713 A CN 201610042713A CN 105670399 A CN105670399 A CN 105670399A
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CN
China
Prior art keywords
parts
coating
deionized water
gloss color
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610042713.3A
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Chinese (zh)
Inventor
顾劲松
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Anhui Wenfeng Special Paper Co Ltd
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Anhui Wenfeng Special Paper Co Ltd
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Publication date
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Priority to CN201610042713.3A priority Critical patent/CN105670399A/en
Publication of CN105670399A publication Critical patent/CN105670399A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • D21H19/824Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention discloses a high-gloss color inkjet printing paper coating, comprising a bottom coating and a surface coating; both the bottom coating and the surface coating are added with zirconium carbonate for treatment and are prepared from different materials by different methods.Compared with the prior art, the high-gloss color inkjet printing paper coating has the advantages that both the bottom coating and the surface coating are made from different materials by different processes, the production processes are simple, the bottom coating and the surface coating are synergic after raw paper is treated, the bottom layer gains improved ink absorbing performance owing to uniform micro-cell structure and uniform charge distribution of the bottom layer, the surface layer forms a microporous film outside the bottom layer and functions in fixing color and shortening drying time, and the two layers of special structure are in three-dimensional combination, thus enhancing image layering, improving color reproduction and improving printing effect of the high-gloss color inkjet printing paper.

Description

A kind of high gloss color ink jet printer paper paint and its preparation method
Technical field
The invention belongs to the technical field of coatings of Alhue paper, it is specifically related to a kind of high gloss color ink jet printer paper paint and its preparation method.
Background technology
Spray ink Printing has the advantage being easy to colorize and Digital Control, it is subject to pursuing the favor of the user of personal colors, along with the increase of domestic ink-jet printer recoverable amount, result in the increase to high-quality coated ink jet printer paper demand, color ink jet printer paper in present China market is main mainly with external import, existing domestic production and theoretical investigation are relatively poor, spray ink Printing needs on the recording materials being coated with ink-receiver layer, the pattern resolving power just can done well and color restoration capability. existing color ink jet printer paper, using alumina in Nano level as dominant absorption material, need to add more strong cation dispersion agent and laking agent, coating porosity can be made to reduce, affect rapid absorption ability, and then cause being difficult to realize quick-drying and high image resolution rate, middle institute is known, the quality of color ink jet printer paper depends mainly on the performance of ink-absorbed coated layer, especially high gloss color Alhue paper, to the vividness of print screen on color, sharpness, saturation ratio, finely structured hierarchies and color rendition degree have requirements at the higher level, the coating of high gloss color ink jet printer paper it is specifically designed to it is thus desirable to a kind of, for the print performance of printer paper can not only be increased after body paper, also wanting can fast absorption ink-jet.
Summary of the invention
It is an object of the invention to for existing problem, it provides a kind of high gloss color ink jet printer paper paint and its preparation method.
The present invention is achieved by the following technical solutions: a kind of high gloss color ink jet printer paper paint, comprises priming paint and investment precoat:
Priming paint is made up of the raw material of following weight part:
Deionized water 56.6 parts
Zirconium carbonate 0.8 part
Aerosil 18.6 parts
Polyvinyl alcohol 17998 parts
Butadiene-styrene latex sizing agent 15 parts
Polyacrylamide 0.02 part
Acrylic resin modified 0.08 part
Triethyl citrate 0.4 part
Tripropionin 0.5 part
Investment precoat is made up of the raw material of following weight part:
Deionized water 45.2 parts
Zirconium carbonate 0.5 part
Fatty acid amide Soxylat A 25-7 0.002 part
China clay 0.006 part
Cationic silica emulsion 38.5 parts
Polyvinyl alcohol 17995.8 parts
8.8 parts, Dyhard RU 100 formaldehyde resin laking agent
Polyether antifoam agent 0.001 part
Sumstar 190 0.6 part
Polyacrylamide 0.03 part
0.001 part, aliphatic acid polyethenoxy first ether
Tripropionin 0.56 part
As further improvement of these options, described acrylic resin modified be organosilicon modified crylic acid resin.
The preparation method of a kind of high gloss color ink jet printer paper paint, the preparation method of priming paint is: the deionized water adding 40 parts in a reservoir, add zirconium carbonate and butadiene-styrene latex sizing agent is stirred well to dissolving, then 60 DEG C it are heated to, slowly add aerosil, stir fast in adition process, near normal temperature after fully dissolving to it, adding remaining deionized water and other raw materials at the uniform velocity stirring successively, namely each raw material obtains priming paint after evenly disperseing;
The preparation method of investment precoat is: add 16 parts of deionized waters in a reservoir, it is heated to 80 DEG C, the process stirred fast adds cationic silica emulsion, after fully mixing, adding zirconium carbonate, china clay and Sumstar 190, fully stir, mixture adds deionized water and other raw materials successively after being down to normal temperature, each raw material obtains investment precoat after dissolving completely in mixed solution.
Priming paint is mainly aerosil, with zirconium carbonate synergy, after process body paper, forms a kind of equally distributed micro-screen work structure on body paper surface, and its surface charge is uniformly distributed, make suction ink rapider; Surface coating material adopts cationic silica emulsion, and adds a certain amount of zirconium carbonate and china clay, processes the body paper through primary coat, bottom is formed a kind of equally distributed microporous membrane, the effect of fixation and waterproof can not only be played, moreover it is possible to increase the gloss of fuel, it is to increase form the quality of image.
The present invention has the following advantages compared to existing technology: priming paint and investment precoat adopt different raw materials and technique, manufacturing process is simple, after body paper is processed, acting in conjunction, even micro-screen work structure that bottom is formed by it and electric charge be uniformly distributed raising ink receptivity, surface layer forms microporous membrane outside bottom, play color set and shorten dry effect, the three-dimensional combination of two layers of special construction, add the gradation sense of image, color restoration capability can be improved, it is to increase the printing effect of high gloss color ink jet printer paper.
Embodiment
Embodiment
A kind of high gloss color ink jet printer paper paint, comprises priming paint and investment precoat:
Priming paint is made up of the raw material of following weight part:
Deionized water 56.6 parts
Zirconium carbonate 0.8 part
Aerosil 18.6 parts
Polyvinyl alcohol 17998 parts
Butadiene-styrene latex sizing agent 15 parts
Polyacrylamide 0.02 part
Organosilicon modified crylic acid resin 0.08 part
Triethyl citrate 0.4 part
Tripropionin 0.5 part
Investment precoat is made up of the raw material of following weight part:
Deionized water 45.2 parts
Zirconium carbonate 0.5 part
Fatty acid amide Soxylat A 25-7 0.002 part
China clay 0.006 part
Cationic silica emulsion 38.5 parts
Polyvinyl alcohol 17995.8 parts
8.8 parts, Dyhard RU 100 formaldehyde resin laking agent
Polyether antifoam agent 0.001 part
Sumstar 190 0.6 part
Polyacrylamide 0.03 part
0.001 part, aliphatic acid polyethenoxy first ether
Tripropionin 0.56 part
As further improvement of these options, described acrylic resin modified be organosilicon modified crylic acid resin.
The preparation method of a kind of high gloss color ink jet printer paper paint, the preparation method of priming paint is: the deionized water adding 40 parts in a reservoir, add zirconium carbonate and butadiene-styrene latex sizing agent is stirred well to dissolving, then 60 DEG C it are heated to, slowly add aerosil, stir fast in adition process, near normal temperature after fully dissolving to it, adding remaining deionized water and other raw materials at the uniform velocity stirring successively, namely each raw material obtains priming paint after evenly disperseing;
The preparation method of investment precoat is: add 16 parts of deionized waters in a reservoir, it is heated to 80 DEG C, the process stirred fast adds cationic silica emulsion, after fully mixing, adding zirconium carbonate, china clay and Sumstar 190, fully stir, mixture adds deionized water and other raw materials successively after being down to normal temperature, each raw material obtains investment precoat after dissolving completely in mixed solution.
Priming paint and investment precoat in the present invention is adopted to process the body paper manufactured paper with pulp by 100% wood pulp, glue spread is 10.2g/, gained high gloss color ink jet printer paper absorbency is better, can more completely keep color and the sharpness of original copy, and the contrast detecting its corresponding performance index and body paper is as follows:
Table 1
Wherein by counting, aobvious roughometer measures roughness;
Ink absorption is measured by pitch (1%) dimethylbenzene method, detects the time of its solution dropping liquid gloss completely dissolve;
As known from Table 1, after processing body paper with coating in the present invention, it is possible to greatly improving printer paper to the absorptive character of ink, printing effect gradation sense is better simultaneously, can go back the color of original image preferably.

Claims (3)

1. a high gloss color ink jet printer paper paint, it is characterised in that, comprise priming paint and investment precoat:
Priming paint is made up of the raw material of following weight part:
Deionized water 56.6 parts
Zirconium carbonate 0.8 part
Aerosil 18.6 parts
Polyvinyl alcohol 17998 parts
Butadiene-styrene latex sizing agent 15 parts
Polyacrylamide 0.02 part
Acrylic resin modified 0.08 part
Triethyl citrate 0.4 part
Tripropionin 0.5 part;
Investment precoat is made up of the raw material of following weight part:
Deionized water 45.2 parts
Zirconium carbonate 0.5 part
Fatty acid amide Soxylat A 25-7 0.002 part
China clay 0.006 part
Cationic silica emulsion 38.5 parts
Polyvinyl alcohol 17995.8 parts
8.8 parts, Dyhard RU 100 formaldehyde resin laking agent
Polyether antifoam agent 0.001 part
Sumstar 190 0.6 part
Polyacrylamide 0.03 part
0.001 part, aliphatic acid polyethenoxy first ether
Tripropionin 0.56 part.
2. a kind of high gloss color ink jet printer paper paint as claimed in claim 1, it is characterised in that, described acrylic resin modified be organosilicon modified crylic acid resin.
3. the preparation method of a high gloss color ink jet printer paper paint, it is characterized in that, the preparation method of priming paint is: the deionized water adding 40 parts in a reservoir, add zirconium carbonate and butadiene-styrene latex sizing agent is stirred well to dissolving, then it is heated to 60 DEG C, slowly adds aerosil, adition process stirs fast, near normal temperature after fully dissolving to it, adds remaining deionized water and other raw materials successively at the uniform velocity stirring, and namely each raw material obtains priming paint after evenly disperseing;
The preparation method of investment precoat is: add 16 parts of deionized waters in a reservoir, it is heated to 80 DEG C, the process stirred fast adds cationic silica emulsion, after fully mixing, adding zirconium carbonate, china clay and Sumstar 190, fully stir, mixture adds deionized water and other raw materials successively after being down to normal temperature, each raw material obtains investment precoat after dissolving completely in mixed solution.
CN201610042713.3A 2016-01-22 2016-01-22 High-gloss color inkjet printing paper coating and preparation method thereof Pending CN105670399A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610042713.3A CN105670399A (en) 2016-01-22 2016-01-22 High-gloss color inkjet printing paper coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610042713.3A CN105670399A (en) 2016-01-22 2016-01-22 High-gloss color inkjet printing paper coating and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106192560A (en) * 2016-06-29 2016-12-07 安徽文峰特种纸业有限公司 A kind of formula of color ink jet printer paper and preparation method thereof
CN108486953A (en) * 2018-04-25 2018-09-04 内蒙古工业大学 A kind of preparation method and coating process of the coating improving color spray printing paper performance
CN108867170A (en) * 2018-06-14 2018-11-23 清远市天顺办公设备有限公司 A kind of high absorbency art paper and preparation method thereof for high-speed press

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1769588A (en) * 2004-11-05 2006-05-10 南通华润新材料有限公司 Nanometer scale environment-friendly type coating special for color digital printing paper
CN1837463A (en) * 2006-03-28 2006-09-27 孝睿 Bentonite based nano silicon micro-porous membrane, its preparation method and digital photo paper employing the same
CN103669107A (en) * 2013-11-14 2014-03-26 华南理工大学 Preparation method of high-gloss paper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1769588A (en) * 2004-11-05 2006-05-10 南通华润新材料有限公司 Nanometer scale environment-friendly type coating special for color digital printing paper
CN1837463A (en) * 2006-03-28 2006-09-27 孝睿 Bentonite based nano silicon micro-porous membrane, its preparation method and digital photo paper employing the same
CN103669107A (en) * 2013-11-14 2014-03-26 华南理工大学 Preparation method of high-gloss paper

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106192560A (en) * 2016-06-29 2016-12-07 安徽文峰特种纸业有限公司 A kind of formula of color ink jet printer paper and preparation method thereof
CN108486953A (en) * 2018-04-25 2018-09-04 内蒙古工业大学 A kind of preparation method and coating process of the coating improving color spray printing paper performance
CN108867170A (en) * 2018-06-14 2018-11-23 清远市天顺办公设备有限公司 A kind of high absorbency art paper and preparation method thereof for high-speed press
CN108867170B (en) * 2018-06-14 2020-11-24 安徽紫江复合材料科技有限公司 High-ink-absorptivity coated paper for high-speed printing machine and preparation method thereof

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Application publication date: 20160615