CN105670295A - 一种应用于室外防腐蚀电缆橡胶配置原料 - Google Patents
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Abstract
本发明公开了一种应用于室外防腐蚀电缆橡胶配置原料。所述一种应用于室外防腐蚀电缆橡胶配置原料，由以下重量份的原料制成：乙丙橡胶：55-71份、丁基橡胶：30-55份、硅橡胶：61-78份、丁腈橡胶：2-4份、硫磺IS6033：2.1-3.2份、乙烯基三甲氧基硅烷：1-7份、苯基三甲氧基硅烷：4-21份、补强体系：89-140份、防老体系：2-9份、硫化促进体系：1.7-2.9份。本发明具有以下有益效果：通过合成橡胶与改进硫化体系、补强体系及防老体系提升橡胶的耐腐蚀性，稳定橡胶结构从而保证橡胶的抗氧化性和老化性特征的发挥，实现提升电缆使用寿命，提高使用安全，降低维护成本的效果。
Description
技术领域
本发明涉及一种橡胶配置原料，具体说是一种应用于室外防腐蚀电缆橡胶配置原料。
背景技术
近代工业革命，从蒸汽机开始，锅炉烧煤，产生蒸汽，推动机器；而后火力电厂星罗棋布，燃煤数量日益猛增。遗憾的是，煤含杂质硫，约百分之一，在燃烧中将排放酸性气体SO2；燃烧产生的高温还能促使助燃的空气发生部分化学变化，氧气与氮气化合，也排放酸性气体NOx。它们在高空中为雨雪冲刷，溶解，雨就成为了酸雨；这些酸性气体成为雨水中杂质硫酸根、硝酸根和铵离子。1872年英国科学家史密斯分析了伦敦市雨水成份，发现它呈酸性，且农村雨水中含碳酸铵，酸性不大；郊区雨水含硫酸铵，略呈酸性；市区雨水含硫酸或酸性的硫酸盐，呈酸性。于是史密斯最先在他的著作《空气和降雨：化学气候学的开端》中提出“酸雨”这一专有名词。
酸雨的成因是一种复杂的大气化学和大气物理的现象。酸雨中含有多种无机酸和有机酸，绝大部分是硫酸和硝酸，还有少量灰尘。
酸雨是工业高度发展而出现的副产物，由于人类大量使用煤、石油、天然气等化石燃料，燃烧后产生的硫氧化物或氮氧化物，在大气中经过复杂的化学反应，形成硫酸或硝酸气溶胶，或为云、雨、雪、雾捕捉吸收，降到地面成为酸雨。如果形成酸性物质时没有云雨，则酸性物质会随着浮沉一起降落到地面，这叫做干沉降，以区别于酸雨、酸雪等湿沉降。干沉降物在地面遇水时复合成酸。酸云和酸雾中的酸性由于没有得到直径大得多的雨滴的稀释，因此它们的酸性要比酸雨强得多。高山区由于经常有云雾缭绕，因此酸雨区高山上森林受害最重，常成片死亡。硫酸和硝酸是酸雨的主要成分，约占总酸量的90%以上，我国酸雨中硫酸和硝酸的比例约为10∶1。
但我国目前在室外使用的外包橡胶多以抗氧化和放老化特性为主，酸雨的影响，导致外包橡胶的结构不稳定，从而降低其抗氧化和抗老化的特性，从而破坏外包橡胶整体的不稳定，导致外包橡胶失去原本的功效，从而导致供电系统发生故障，如短路、漏电，甚至发生火灾或人员触电等危险。
发明内容
本发明所要解决的技术问题是提供一种能经受住目前因为大气污染等因素导致脏雨导致室外电缆外包橡胶腐蚀问的于室外防腐蚀电缆橡胶配置原料。
为解决上述技术问题，本发明的技术方案是：一种应用于室外防腐蚀电缆橡胶配置原料，由以下重量份的原料制成：乙丙橡胶：55-71份、丁基橡胶：30-55份、硅橡胶：61-78份、丁腈橡胶：2-4份、硫磺IS6033：2.1-3.2份、乙烯基三甲氧基硅烷：1-7份、苯基三甲氧基硅烷：4-21份、补强体系：89-140份、防老体系：2-9份、硫化促进体系：1.7-2.9份。
作为优选，所述硫化促进体系为硫化促进剂M：硫化促进剂H：硫化促进剂D：硫化促进剂ZDMC依照1：1：3：1的比例配比而成。
作为优选，所述补强体系为炭黑N219：炭黑N339：炭黑N683：炭黑N765：白炭黑：Gr175依照2：2：1：4：1的比例配比而成。
作为优选，所述老体系为防老剂NBC：防老剂DNP：防老剂AW：石蜡：防老剂DNP：防老剂BLE-W依照1：1：2：1.5：3：1的比例配比而成。
由于采用了上述技术方案，一种应用于室外防腐蚀电缆橡胶配置原料，由以下重量份原料制成：乙丙橡胶：55-71份、丁基橡胶：30-55份、硅橡胶：61-78份、丁腈橡胶：2-4份、硫磺IS6033：2.1-3.2份、乙烯基三甲氧基硅烷：1-7份、苯基三甲氧基硅烷：4-21份、补强体系：89-140份、防老体系：2-9份、硫化促进体系：1.7-2.9份；本发明具有以下有益效果：
通过合成橡胶与改进硫化体系、补强体系及防老体系提升橡胶的耐腐蚀性，稳定橡胶结构从而保证橡胶的抗氧化性和老化性特征的发挥，实现提升电缆使用寿命，提高使用安全，降低维护成本的效果。
具体实施方式
下面结合具体实施例对本发明做进一步地说明。
实施例1
一种应用于室外防腐蚀电缆橡胶配置原料，由以下重量份原料制成：
乙丙橡胶：55份、丁基橡胶：30份、硅橡胶：61份、丁腈橡胶：2份、硫磺IS6033：2.1份、乙烯基三甲氧基硅烷：1份、苯基三甲氧基硅烷：4份、补强体系：89份、防老体系：2份、硫化促进体系：1.7份。
使用上海林频仪器股份有限公司的LRHS-108-RY耐腐蚀测试机，台湾高铁科技股份有限公司的GT-7011-D屈挠试验机，上海迈沪试验设备有限公司臭氧试验箱QL-500，对橡胶性能进行试验验证，依照上述配比制的橡胶先放经耐腐蚀测试机进行24h、96h、120h的酸碱盐雾耐腐蚀实验，完成实验后清洗好表面，再经屈挠试验机和臭氧试验箱进行时实验得出一下数据。
| 耐腐蚀实验 | 抗屈挠实验 | 结果 | 老化实验 | 结果 |
| 24h | ≥120万次 | 180万次 | 无龟裂 | 无龟裂 |
| 96h | ≥100万次 | 150万次 | 无龟裂 | 无龟裂 |
| 120h | ≥80万次 | 100万次 | 无龟裂 | 无龟裂 |
实施例2
一种应用于室外防腐蚀电缆橡胶配置原料，由以下重量份原料制成：
乙丙橡胶：71份、丁基橡胶：55份、硅橡胶：78份、丁腈橡胶：4份、硫磺IS6033：3.2份、乙烯基三甲氧基硅烷：7份、苯基三甲氧基硅烷：21份、补强体系：140份、防老体系：9份、硫化促进体系：2.9份。
使用上海林频仪器股份有限公司的LRHS-108-RY耐腐蚀测试机，台湾高铁科技股份有限公司的GT-7011-D屈挠试验机，上海迈沪试验设备有限公司臭氧试验箱QL-500，对橡胶性能进行试验验证，依照上述配比制的橡胶先放经耐腐蚀测试机进行24h、96h、120h的酸碱盐雾耐腐蚀实验，完成实验后清洗好表面，再经屈挠试验机和臭氧试验箱进行时实验得出一下数据。
| 耐腐蚀实验 | 抗屈挠实验 | 结果 | 老化实验 | 结果 |
| 24h | ≥120万次 | 180万次 | 无龟裂 | 无龟裂 |
| 96h | ≥100万次 | 150万次 | 无龟裂 | 无龟裂 |
| 120h | ≥80万次 | 100万次 | 无龟裂 | 无龟裂 |
实施例3
一种应用于室外防腐蚀电缆橡胶配置原料，由以下重量份原料制成：
乙丙橡胶：63份、丁基橡胶：42.5份、硅橡胶：13.5份、丁腈橡胶：3份、硫磺IS6033：2.7份、乙烯基三甲氧基硅烷：4份、苯基三甲氧基硅烷：12.5份、补强体系：114.5份、防老体系：5.5份、硫化促进体系：2.3份。
使用上海林频仪器股份有限公司的LRHS-108-RY耐腐蚀测试机，台湾高铁科技股份有限公司的GT-7011-D屈挠试验机，上海迈沪试验设备有限公司臭氧试验箱QL-500，对橡胶性能进行试验验证，依照上述配比制的橡胶先放经耐腐蚀测试机进行24h、96h、120h的酸碱盐雾耐腐蚀实验，完成实验后清洗好表面，再经屈挠试验机和臭氧试验箱进行时实验得出一下数据。
| 耐腐蚀实验 | 抗屈挠实验 | 结果 | 老化实验 | 结果 |
| 24h | ≥120万次 | 180万次 | 无龟裂 | 无龟裂 |
| 96h | ≥100万次 | 150万次 | 无龟裂 | 无龟裂 |
| 120h | ≥80万次 | 100万次 | 无龟裂 | 无龟裂 |
以上所述仅为本发明示意性的具体实施方式，并非用以限定本发明的范围。任何本领域的技术人员，在不脱离本发明的构思和原则的前提下所作出的等同变化与修改，均应属于本发明保护的范围。
Claims (4)
1.一种应用于室外防腐蚀电缆橡胶配置原料，其特征在于，由以下重量份的原料制成：乙丙橡胶：55-71份、丁基橡胶：30-55份、硅橡胶：61-78份、丁腈橡胶：2-4份、硫磺IS6033：2.1-3.2份、乙烯基三甲氧基硅烷：1-7份、苯基三甲氧基硅烷：4-21份、补强体系：89-140份、防老体系：2-9份、硫化促进体系：1.7-2.9份。
2.如权利要求1所述的一种应用于室外防腐蚀电缆橡胶配置原料，其特征在于：所述硫化促进体系为硫化促进剂M：硫化促进剂H：硫化促进剂D：硫化促进剂ZDMC依照1：1：3：1的比例配比而成。
3.如权利要求1所述的一种应用于室外防腐蚀电缆橡胶配置原料，其特征在于：所述补强体系为炭黑N219：炭黑N339：炭黑N683：炭黑N765：白炭黑：Gr175依照2：2：1：4：1的比例配比而成。
4.如权利要求1所述的一种应用于室外防腐蚀电缆橡胶配置原料，其特征在于：所述防老体系为防老剂NBC：防老剂DNP：防老剂AW：石蜡：防老剂DNP：防老剂BLE-W依照1：1：2：1.5：3：1的比例配比而成。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057356A (zh) * | 2017-04-06 | 2017-08-18 | 安徽三鑫电缆材料有限公司 | 一种硅橡胶控制电缆料 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977609A (zh) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | 一种船用耐油耐低温低烟无卤阻燃电缆料及其制备方法 |
| CN103524806A (zh) * | 2013-10-25 | 2014-01-22 | 安徽文峰电子科技集团有限公司 | 一种高强度耐热老化改性丁腈橡胶电缆料 |
| CN104046030A (zh) * | 2014-06-25 | 2014-09-17 | 安徽嘉木橡塑工业有限公司 | 一种耐高温耐油橡胶 |
| CN104403318A (zh) * | 2014-11-20 | 2015-03-11 | 安徽渡江电缆集团有限公司 | 一种高阻燃高耐磨改性硅橡胶电缆材料 |
-
2016
- 2016-03-04 CN CN201610125055.4A patent/CN105670295A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977609A (zh) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | 一种船用耐油耐低温低烟无卤阻燃电缆料及其制备方法 |
| CN103524806A (zh) * | 2013-10-25 | 2014-01-22 | 安徽文峰电子科技集团有限公司 | 一种高强度耐热老化改性丁腈橡胶电缆料 |
| CN104046030A (zh) * | 2014-06-25 | 2014-09-17 | 安徽嘉木橡塑工业有限公司 | 一种耐高温耐油橡胶 |
| CN104403318A (zh) * | 2014-11-20 | 2015-03-11 | 安徽渡江电缆集团有限公司 | 一种高阻燃高耐磨改性硅橡胶电缆材料 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057356A (zh) * | 2017-04-06 | 2017-08-18 | 安徽三鑫电缆材料有限公司 | 一种硅橡胶控制电缆料 |
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