CN105670206A - Environment-friendly high-vicat ABS sheet material for producing cards and preparation method thereof - Google Patents
Environment-friendly high-vicat ABS sheet material for producing cards and preparation method thereof Download PDFInfo
- Publication number
- CN105670206A CN105670206A CN201410677530.XA CN201410677530A CN105670206A CN 105670206 A CN105670206 A CN 105670206A CN 201410677530 A CN201410677530 A CN 201410677530A CN 105670206 A CN105670206 A CN 105670206A
- Authority
- CN
- China
- Prior art keywords
- sheet material
- abs
- environmental protection
- abs sheet
- lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses an environment-friendly high-vicat card ABS sheet material for producing cards and a preparation method thereof. The card substrate material is composed of the following components, by weight, 100 parts of ABS resin, 5-12 parts of a filler, 1.5-2.7 parts of a processing additive, 0.1-0.5 parts of an antioxidant, 0.1-1.0 part of an auxiliary antioxidant, 0.50-0.75 parts of a lubricant, 3.1-6.15 parts of a pigment, 0.2-0.3 parts of an ultraviolet absorbent, and 0.15-1.0 part of an antistatic agent. The sheet material is prepared through a five-roller calendaring method. The card substrate material is 105 DEG C in vicat temperature so that the card substrate material is not liable to deform or cause chip falling off even at a high temperature. The card substrate material is high in strength, has strong toughness and is good in low-temperature-resistance. The ABS sheet material can ensure normal operation of an SIM card at a high temperature better and prolongs the service life of the SIM card. The ABS sheet material belongs to a chlorine-free environment-friendly product.
Description
Technical field
The invention belongs to processing of high molecular material technical field, in particular to a kind of fabrication environmental protection higher-dimension card ABS sheet material and its preparation method.
Background technology
Along with the fast development of society, the raising that developed country of the world requires without cl material for environmental protection, and SIM card is widely used in the industries such as traffic, social security, medical treatment, finance, communication, especially finance card, the universal use of mobile phone card and frequently use for a long time, it is necessary to one is environmental protection both, has again anti-oxidant, weather resistance is good, higher-dimension card, high strength, long-life SIM card.
Produce the existing open formula technique of ABS sheet material about calendering method to have: the Chinese patent being 200910200415.2 such as application number discloses a kind of PVC/ABS blending rolling base material and its preparation method, containing PVC in its major ingredient, can not meet material without chlorine environmental-protecting requirement, and it is on the low side to show card intensity in long-time use procedure, card is heated and is easily out of shape, chip easily comes off, and uses easily cracked at a lower temperature, and serious impact is normal to be used. And for example to be that the German Patent of DE4301678A1 discloses a kind of not containing ABS rolled base material and its preparation method of PVC for the patent No.. Containing softening agent in its major ingredient, belong to soft matter ABS sheet material, it is not fabrication hard ABS sheet material, and environment protection requirement can not be met.
The same with other macromolecular material, ABS material also also exists the many shortcomings in processing and performance, such as heating and melting non-Newtonian fluid viscosity height; ABS is many containing double bond, adds and is more easily oxidized man-hour, and weathering resistance is poor; Process window is narrower. In order to solve these problems that pure ABS exists, it is carried out various chemical modification and physically modified is necessary. In the course of processing of ABS, for product performance feature and method for processing forming, it is also necessary that ABS material carries out some process.
At present, the SIM card by base material of PVC and PVC/ABS, generally uses; The application that pure ABS is used in the aspects such as equipment part, automobile, electric appliance casing is very universal, but taking hard without chlorine ABS as base material, is used in fabrication to yet there are no any type of report; Hard is without chlorine ABS substrate, and the method adopting five roll-ins to prolong method production card base also has no report.
Summary of the invention
It is an object of the invention to provide a kind of fabrication environmental protection higher-dimension card ABS sheet material and its preparation method, ABS sheet material uses at relatively high temperatures and distortion is less likely to occur or chip comes off; The intensity of card base is higher, and toughness is relatively strong, and resistance to low temperature is good.
The present invention is realized by following technique means:
Fabrication environmental protection higher-dimension card ABS sheet material, is made up of the component of following weight part:
ABS resin 100 parts, filler 5-12 part, processing aid 1.5-2.7 part, oxidation inhibitor 0.1-0.5 part, auxiliary antioxidant 0.1-1.0 part, lubricant 0.50-0.75 part, pigment 3.1-6.15 part, UV light absorber 0.2-0.3 part, static inhibitor 0.15-1.0 part.
ABS resin melting index is: by ASTMD-1238 standard test, melt flow rate (MFR) 220 DEG C/10kg, 6-42 gram/10 minutes.
Filler is active superfine calcium carbonate.
Processing aid is ACR class processing aid, and ACR class processing aid is one or more in polymethylmethacrylate and acrylic ester copolymerization processing aid ACR530, K125P, K175P.
Oxidation inhibitor be Hinered phenols macromole type antioxidant 1076,1010, IRGANOX245,2246-S; Auxiliary antioxidant is one or more in thioesters class, phosphorous acid ester, and thioesters class is DLTP, DSTP, and phosphorous acid ester is IRGAFOS168, IRGAFOS126.
Lubricant is divided into internal lubricant and external lubricant; Internal lubricant 0.15-0.30 part, external lubricant 0.35-0.55 part.
External lubricant is at least one in high density polyethylene waxes, montanic acid ester type waxes, stearates; Internal lubricant is at least one in lipid acid, glyceryl monostearate, ethylene bis stearic acid amide.
Pigment is rutile TiO2, phthalocyanine blue, ultramarine blue, magenta, one or more in purple dye; UV light absorber is UV327; Static inhibitor is one or more in permanent anti-static agent KM400, SD100, AS500 type.
ABS sheet thickness is 0.150-0.810mm.
The flow characteristics of ABS belongs to non-Newtonian fluid, and its melt viscosity and processing temperature and shearing rate have relation, but shearing rate is more responsive. The fabrication of the present invention preparation method of environmental protection higher-dimension card ABS sheet material, it is preferable that machined parameters comprises the steps:
1) ABS resin being crushed to 40-80 order, add homogenizer with filler and stir, rotating speed is 800 revs/min, stirs 2.5min; Then oxidation inhibitor, auxiliary antioxidant, internal lubricant being added, high-speed stirring is to temperature 80 DEG C; External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, and high-speed stirring to material is warmed up to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C;
2) forcing machine plasticizing process is adopted: mixture carries out fusion plastification, and the temperature of one-level screw rod is 170--190 DEG C, and screw speed is 40 revs/min; Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min;
3) five roller rolling out film, five roller rolling temperatures are respectively 138--144 DEG C, 154--162 DEG C, 171--179 DEG C, 183--193 DEG C, 149--155 DEG C; Rotating speed is respectively 11--13.0 m/min, 13.5--15.2 m/min, 14.5--17.3 m/min, 16.0--19.3 m/min, 19.8--24.3 m/min;
4) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C, doff roll speed is 30.0-33.0 m/min;
5) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C;
6) rolling, traction adopts four roller towing mechanisms, and winding tension adopts closed loop magnetic tension control system; Winding process carry out except Electrostatic Treatment;
7) cut, by finished product dimensional requirement, cut base material length and width.
Useful effect:
The fabrication of the present invention with the preparation method of environmental protection higher-dimension card ABS sheet material and base material thereof compared with prior art, there is following advantage: fabrication environmental protection higher-dimension card ABS sheet material provided by the invention, being made up of auxiliary agents such as ABS and corresponding filler, processing aid, oxidation inhibitor, auxiliary antioxidant, lubricant, pigment, UV light absorber, static inhibitor, preparation method is that method is prolonged in five roll-ins. The card base sheet obtained by the present invention, vicat temperature up to 105 DEG C, at relatively high temperatures use be less likely to occur distortion or chip come off; The intensity of card base is higher, and toughness is relatively strong, and resistance to low temperature is good; Compensate for the low vicat temperature of commercial PVC or PVC/ABS blending sheet material and the little deficiency of intensity. The fabrication environmental protection higher-dimension card ABS sheet material of the present invention can ensure the normal use at high temperature of SIM card better, and extends the work-ing life of SIM card; The ABS sheet material of the present invention is without chlorine environmental-protecting product, and the various starting material in composition are commercial prod, and raw material easily obtains, and have significant industrial application value. Method is prolonged in five roll-ins that technical process is ripe, it is easy to realize suitability for industrialized production.
Accompanying drawing explanation
Fig. 1 is the calendering technology schema of the present invention.
Embodiment
Here is described in further detail the specific embodiment of the present invention, it is necessary to herein means out, and following examples, just for the present invention is described further, can not be interpreted as limiting the scope of the invention; The present invention is made improvement and the adjustment of some non-intrinsically safes by the skilled personnel of this art according to above-mentioned content of the present invention, still belongs to protection scope of the present invention.
The homogenizer used in following examples is that PLASMEC company of Italy produces; Plasticator adopts Germany's bar Field production secondary planet screw extrusion press; Five roll calendars adopt RODOLF0 company of Italy inverted L shape five roll calendar; The raw material of the same model adopted in embodiment is that same company produces.
In embodiment 1-6; The gauge control of sheet material is realized by the gap of calendering roller and the stretching of doff roll, for the ease of comparing, comparison specimen adopts process similarity, identical apparatus processing, the sheet material of PVC and PVC/ABS blending is all controlled at 405 μm as the base material thickness in comparative example, following examples and comparative example.
Embodiment 1
Fabrication environmental protection higher-dimension card ABS sheet material, takes various material by formula constituent shown in following table:
1) ABS resin is crushed to 40-80 order
2) mix: ABS resin and filler first adding homogenizer and stirs, rotating speed is 800 revs/min, stirs 2.5min; Then oxidation inhibitor, auxiliary antioxidant, internal lubricant are added, high-speed stirring to 80 DEG C; External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, high-speed stirring to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C.
3) material melts plasticizing, adopts secondary planet screw extrusion press that material is carried out fusion plastification, and the temperature of one-level screw rod is 183 DEG C, and screw speed is 40 revs/min;Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min.
4) five roller rolling out film, five roller rolling temperatures are respectively 141 DEG C, 155 DEG C, 175 DEG C, 185 DEG C, 151 DEG C; Rotating speed is respectively 11.0 ms/min, 13.7 ms/min, 14.5 ms/min, 16.0 ms/min, 19.8 ms/min.
5) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C. Doff roll speed is 30.0 ms/min.
6) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C.
7) rolling, traction adopts four roller towing mechanisms (roller material is chloroprene rubber, roller diameter 150mm), and winding tension adopts closed loop magnetic tension control system; Winding process carries out except Electrostatic Treatment (static eliminator adopts ES-2025 induction type electrostatic rod to carry out eliminostatic, operating voltage AC220V, and output voltage is 3.5V, length 1800mm).
8) cut, by finished product dimensional requirement, cut base material length and width.
Embodiment 2
Fabrication environmental protection higher-dimension card ABS sheet material, takes various material by formula constituent shown in following table:
1) ABS resin is crushed to 40-80 order;
2) mix: ABS and filler adding homogenizer and stirs, rotating speed is 800 revs/min, stirs 2.5min; Then oxidation inhibitor, auxiliary antioxidant, internal lubricant are added, high-speed stirring to 80 DEG C; External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, high-speed stirring to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C.
3) material melts plasticizing, adopts secondary planet screw extrusion press that material is carried out fusion plastification, and the temperature of one-level screw rod is 180 DEG C, and screw speed is 40 revs/min; Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min.
4) five roller rolling out film, five roller rolling temperatures are respectively 138 DEG C, 154 DEG C, 171 DEG C, 183 DEG C, 149 DEG C; Rotating speed is respectively 11.5 ms/min, 13.5 ms/min, 15.3 ms/min, 17.0 ms/min, 21.2 ms/min.
5) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C. Doff roll speed is 31.0 ms/min.
6) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C.
7) rolling, traction adopts four roller towing mechanisms (roller material is chloroprene rubber, roller diameter 150mm), and winding tension adopts closed loop magnetic tension control system; Winding process carries out except Electrostatic Treatment (static eliminator adopts ES-2025 induction type electrostatic rod to carry out eliminostatic, operating voltage AC220V, and output voltage is 3.5V, length 1800mm).
8) cut, by finished product dimensional requirement, cut base material length and width.
Embodiment 3
Fabrication environmental protection higher-dimension card ABS sheet material, takes various material by formula constituent shown in following table:
1) ABS resin is crushed to 40-80 order
2) mix: ABS and filler first adding homogenizer and stirs, rotating speed is 800 revs/min, stirs 2.5min; Then thermo-stabilizer, oxidation inhibitor, auxiliary antioxidant, internal lubricant are added, high-speed stirring to 80 DEG C;External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, high-speed stirring to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C.
3) (3) material melts plasticizing, adopts secondary planet screw extrusion press that material is carried out fusion plastification, and the temperature of one-level screw rod is 185 DEG C, and screw speed is 40 revs/min; Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min.
4) five roller rolling out film, five roller rolling temperatures are respectively 142 DEG C, 158 DEG C, 175 DEG C, 188 DEG C, 152 DEG C; Rotating speed is respectively 12.0 ms/min, 13.9 ms/min, 16.0 ms/min, 17.9 ms/min, 22.4 ms/min.
5) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C. Doff roll speed is 30.5 ms/min.
6) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C.
7) rolling, traction adopts four roller towing mechanisms (roller material is chloroprene rubber, roller diameter 150mm), and winding tension adopts closed loop magnetic tension control system; Winding process carries out except Electrostatic Treatment (static eliminator adopts ES-2025 induction type electrostatic rod to carry out eliminostatic, operating voltage AC220V, and output voltage is 3.5V, length 1800mm).
8) cut, by finished product dimensional requirement, cut base material length and width
Embodiment 4
Fabrication environmental protection higher-dimension card ABS sheet material, takes various material by formula constituent shown in following table:
1) ABS resin is crushed to 40-80 order
2) mix: ABS and filler first adding homogenizer and stirs, rotating speed is 800 revs/min, stirs 2.5min; Then thermo-stabilizer, oxidation inhibitor, auxiliary antioxidant, internal lubricant are added, high-speed stirring to 80 DEG C; External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, high-speed stirring to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C.
3) material melts plasticizing, adopts secondary planet screw extrusion press that material is carried out fusion plastification, and the temperature of one-level screw rod is 185 DEG C, and screw speed is 40 revs/min; Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min.
4) five roller rolling out film, five roller rolling temperatures are respectively 142.5 DEG C, 159 DEG C, 176.5 DEG C, 189 DEG C, 153 DEG C; Rotating speed is respectively 13.0 ms/min, 15.1 ms/min, 17.3 ms/min, 19.3 ms/min, 24.0 ms/min.
5) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C. Doff roll speed is 32.0 ms/min.
6) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C.
7) rolling, traction adopts four roller towing mechanisms (roller material is chloroprene rubber, roller diameter 150mm), and winding tension adopts closed loop magnetic tension control system; Winding process carries out except Electrostatic Treatment (static eliminator adopts ES-2025 induction type electrostatic rod to carry out eliminostatic, operating voltage AC220V, and output voltage is 3.5V, length 1800mm).
8) cut, by finished product dimensional requirement, cut base material length and width
Embodiment 5
Fabrication environmental protection higher-dimension card ABS sheet material, takes various material by formula constituent shown in following table:
1) ABS resin is crushed to 40-80 order
2) mix: ABS and filler first adding homogenizer and stirs, rotating speed is 800 revs/min, stirs 2.5min;Then thermo-stabilizer, oxidation inhibitor, auxiliary antioxidant, internal lubricant are added, high-speed stirring to 80 DEG C; External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, high-speed stirring to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C.
3) material melts plasticizing, adopts secondary planet screw extrusion press that material is carried out fusion plastification, and the temperature of one-level screw rod is 187 DEG C, and screw speed is 40 revs/min; Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min.
4) five roller rolling out film, five roller rolling temperatures are respectively 143 DEG C, 160.5 DEG C, 178 DEG C, 191 DEG C, 154 DEG C; Rotating speed is respectively 12.5 ms/min, 14.6 ms/min, 16.8 ms/min, 18.9 ms/min, 23.8 ms/min.
5) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C. Doff roll speed is 31.5 ms/min.
6) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C.
7) rolling, traction adopts four roller towing mechanisms (roller material is chloroprene rubber, roller diameter 150mm), and winding tension adopts closed loop magnetic tension control system; Winding process carries out except Electrostatic Treatment (static eliminator adopts ES-2025 induction type electrostatic rod to carry out eliminostatic, operating voltage AC220V, and output voltage is 3.5V, length 1800mm).
8) cut, by finished product dimensional requirement, cut base material length and width
Embodiment 6
Fabrication environmental protection higher-dimension card ABS sheet material, takes various material by formula constituent shown in following table:
1) ABS resin is crushed to 40-80 order
2) mix: ABS and filler first adding homogenizer and stirs, rotating speed is 800 revs/min, stirs 2.5min; Then thermo-stabilizer, oxidation inhibitor, auxiliary antioxidant, internal lubricant are added, high-speed stirring to 80 DEG C; External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, high-speed stirring to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C.
3) material melts plasticizing, adopts secondary planet screw extrusion press that material is carried out fusion plastification, and the temperature of one-level screw rod is 190 DEG C, and screw speed is 40 revs/min; Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min.
4) five roller rolling out film, five roller rolling temperatures are respectively 144 DEG C, 162 DEG C, 179 DEG C, 193 DEG C, 155 DEG C; Rotating speed is respectively 12.5 ms/min, 14.7 ms/min, 17.0 ms/min, 19.2 ms/min, 24.3 ms/min.
5) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C. Doff roll speed is 33.0 ms/min.
6) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C.
7) rolling, traction adopts four roller towing mechanisms (roller material is chloroprene rubber, roller diameter 150mm), and winding tension adopts closed loop magnetic tension control system; Winding process carries out except Electrostatic Treatment (static eliminator adopts ES-2025 induction type electrostatic rod to carry out eliminostatic, operating voltage AC220V, and output voltage is 3.5V, length 1800mm).
8) cut, by finished product dimensional requirement, cut base material length and width
The environmental protection higher-dimension card ABS card matrix material that above-mentioned 6 embodiments are obtained, with the commercial PVC card sill (comparative example 1) adopting similar technique and same equipment to prepare, and commercialization PVC/ABS card matrix material (comparative example 2) carries out performance test.
Testing method: tensile strength measures according to GB/T1040.3, elongation at break GB/T1040.3 measures, and tensile yield strength measures according to GB/T13525, and vicat softening temperature is tested according to GB/T1633B50 method, and surface tension is tested according to GB/T14216. Test result sees the following form.
Fabrication environmental protection higher-dimension card ABS sheet properties
By upper table data, SIM card base sheet prepared by the composition and engineering method provided by this patent, it can be seen that:
(1) in embodiment, material vicat temperature is higher than comparative example 1 16-28 DEG C, higher than comparative example 2 5-17 DEG C.
(2) by embodiment 4, obtained card matrix material, exceeds 10.5 DEG C than the vicat temperature of commercial PVC/ABS sheet material, and tensile strength exceeds 10MPa than comparative example 2, therefore has better over-all properties.
(3) by embodiment 4,6, obtained sheet material is all higher than commercial PVC sheet and PVC/ABS sheet strength
(4) embodiment 1-6 is obtained sheet surface tension force and comparative example are close, therefore do not have problems in printing.
(5) pure ABS sheet material can select dimension stuck point as required in wider scope, and wherein embodiment 6 ties up card up to 105 DEG C.
(6) example 4 tension fracture elongation rate is big, it is possible to normally use at-40 DEG C.
Above-described embodiment is just for setting forth the content of the present invention, instead of restriction, and the therefore any change in the implication suitable with the claim book of the present invention and scope, all it is believed that be included in the scope of claim book.
Claims (10)
1. fabrication environmental protection higher-dimension card ABS sheet material, it is characterised in that, it is made up of group part of following weight part:
ABS resin 100 parts, filler 5-12 part, processing aid 1.5-2.7 part, oxidation inhibitor 0.1-0.5 part, auxiliary antioxidant 0.1-1.0 part, lubricant 0.50-0.75 part, pigment 3.1-6.15 part, UV light absorber 0.2-0.3 part, static inhibitor 0.15-1.0 part.
2. fabrication environmental protection higher-dimension card ABS sheet material according to claim 1, it is characterised in that, ABS resin melting index is: by ASTMD-1238 standard test, melt flow rate (MFR) 220 DEG C/10kg, 6-42 gram/10 minutes.
3. fabrication environmental protection higher-dimension card ABS sheet material according to claim 1, it is characterised in that, filler is active superfine calcium carbonate.
4. fabrication environmental protection higher-dimension card ABS sheet material according to claim 1, it is characterised in that, processing aid is one or more of ACR class processing aid.
5. fabrication environmental protection higher-dimension card ABS sheet material according to claim 1, it is characterised in that, oxidation inhibitor is Hinered phenols macromole type oxidation inhibitor; Auxiliary antioxidant is at least one in thioesters class, phosphorous acid ester.
6. fabrication environmental protection higher-dimension card ABS sheet material according to claim 1, it is characterised in that, lubricant is divided into internal lubricant and external lubricant; Internal lubricant 0.15-0.30 part, external lubricant 0.35-0.55 part.
7. fabrication environmental protection higher-dimension card ABS sheet material according to claim 6, it is characterised in that, external lubricant is at least one in high density polyethylene waxes, montanic acid ester type waxes, stearate series lubricant agent; Internal lubricant is at least one in lipid acid, glyceryl monostearate, ethylene bis stearic acid amide.
8. fabrication environmental protection higher-dimension card ABS sheet material according to claim 1, it is characterised in that, pigment is rutile TiO2, phthalocyanine blue, ultramarine blue, magenta, at least one in purple dye; UV light absorber is UV327; Static inhibitor is at least one in permanent anti-static agent KM400, SD100, AS500 type.
9. fabrication environmental protection higher-dimension card ABS sheet material according to claim 1, it is characterised in that, ABS sheet thickness is 0.150-0.810mm.
10. the fabrication preparation method of environmental protection higher-dimension card ABS sheet material described in any one in claim 1 ~ 9, it is characterised in that comprise the steps:
1) ABS resin being crushed to 40-80 order, add homogenizer with filler and stir, rotating speed is 800 revs/min, stirs 2.5min; Then oxidation inhibitor, auxiliary antioxidant, internal lubricant being added, high-speed stirring is to temperature 80 DEG C; External lubricant, processing aid, UV light absorber, pigment, static inhibitor are together added homogenizer, and high-speed stirring to material is warmed up to 110 DEG C; Put into cold mixer, mixture is cooled to 50 DEG C;
2) two grades of forcing machine plasticizings are adopted: mixture carries out fusion plastification, and the temperature of one-level screw rod is 170--190 DEG C, and screw speed is 40 revs/min; Two grades of extruder temperatures are 150 DEG C, and screw speed is 15 revs/min;
3) five roller rolling out film, five roller rolling temperatures are respectively 138--144 DEG C, 154--162 DEG C, 171--179 DEG C, 183--193 DEG C, 149--155 DEG C; Rotating speed is respectively 11--13.0 m/min, 13.5--15.2 m/min, 14.5--17.3 m/min, 16.0--19.3 m/min, 19.8--24.3 m/min;
4) draw from stretching adopt five groups draw from draw roll, near calendering roller be first group, one to five group temperature is respectively 120 DEG C, 110 DEG C, 100 DEG C, 90 DEG C, 75 DEG C, doff roll speed is 30.0-33.0 m/min;
5) cooling, adopt three groups of roller coolings, heat-eliminating medium is circulation soft water, is first group near doff roll, and one to three group temperature of cooling water is respectively 50 DEG C, 40 DEG C, 30 DEG C;
6) rolling, traction adopts four roller towing mechanisms, and winding tension adopts closed loop magnetic tension control system; Winding process carry out except Electrostatic Treatment;
7) cut, by finished product dimensional requirement, cut base material length and width.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410677530.XA CN105670206A (en) | 2014-11-21 | 2014-11-21 | Environment-friendly high-vicat ABS sheet material for producing cards and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410677530.XA CN105670206A (en) | 2014-11-21 | 2014-11-21 | Environment-friendly high-vicat ABS sheet material for producing cards and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105670206A true CN105670206A (en) | 2016-06-15 |
Family
ID=56957667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410677530.XA Pending CN105670206A (en) | 2014-11-21 | 2014-11-21 | Environment-friendly high-vicat ABS sheet material for producing cards and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105670206A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752846A (en) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | A kind of ABS composite material and preparation method thereof of vehicle-mounted clarifier ducting outlet |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798446A (en) * | 2009-02-11 | 2010-08-11 | 江苏华信塑业发展有限公司 | PETG (Polyethylene Terephthalate Glycol) printing sheet for RFID (radio frequency identification device) label and manufacture process thereof |
| CN101921439A (en) * | 2010-06-29 | 2010-12-22 | 上海达凯塑胶有限公司 | ABS (Acrylonitrile Butadiene Styrene) calendered substrate and preparation method thereof |
| CN102399412A (en) * | 2011-11-09 | 2012-04-04 | 金发科技股份有限公司 | Halogen free flame resistant ABS composition with low cost and high performance, and preparation method and application thereof |
-
2014
- 2014-11-21 CN CN201410677530.XA patent/CN105670206A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798446A (en) * | 2009-02-11 | 2010-08-11 | 江苏华信塑业发展有限公司 | PETG (Polyethylene Terephthalate Glycol) printing sheet for RFID (radio frequency identification device) label and manufacture process thereof |
| CN101921439A (en) * | 2010-06-29 | 2010-12-22 | 上海达凯塑胶有限公司 | ABS (Acrylonitrile Butadiene Styrene) calendered substrate and preparation method thereof |
| CN102399412A (en) * | 2011-11-09 | 2012-04-04 | 金发科技股份有限公司 | Halogen free flame resistant ABS composition with low cost and high performance, and preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| MANFRED H. BREED: "《增值印刷》", 29 February 2012, 印刷工业出版社 * |
| 周祥兴等编著: "《实用塑料技术丛书-塑料助剂应用速查手册》", 31 October 2010, 印刷工业出版社 * |
| 张光磊主编: "《新型建筑材料》", 30 April 2008, 中国电力出版 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752846A (en) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | A kind of ABS composite material and preparation method thereof of vehicle-mounted clarifier ducting outlet |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103756179B (en) | A kind of expanded plastic for making motorway column and its preparation method | |
| CN104497461A (en) | Heat-resistant scratch-resistant high-transmittance PMMA alloy resin composition and preparation method thereof | |
| JP2020521834A5 (en) | ||
| CN103314040A (en) | High loading carbon black masterbatch for pressure pipe applications | |
| CN110128808A (en) | A kind of polycarbonate functionality master batch and its preparation method and application | |
| CN103450609A (en) | CPVC/PVC (Chlorinated Polyvinyl Chloride/Polyvinyl Chloride) sheet for card making and preparation method thereof | |
| CN103360695A (en) | Durable polyvinyl chloride salt membrane composition and preparation method thereof | |
| CN112759846A (en) | Graphene modified polymer composite material for bearing seat and preparation method thereof | |
| CN105670206A (en) | Environment-friendly high-vicat ABS sheet material for producing cards and preparation method thereof | |
| CN108928078A (en) | A kind of tablecloth and its production technology | |
| CN109553842A (en) | It is used to prepare the composition and preparation method thereof of linear low density polyethylene film | |
| CN102702655B (en) | Polyvinyl alcohol/high amylose biodegradable material and melting preparation method thereof | |
| CN110092987A (en) | Train floor cloth advanced composite material (ACM) and preparation method thereof | |
| CN102101927A (en) | PVC (polyvinyl chloride)/ABS (acrylonitrile-butadiene-styrene) blend calendered substrate and preparation method thereof | |
| CN111635600A (en) | High-speed extruded PVC (polyvinyl chloride) coated yarn color master batch formula and preparation method thereof | |
| CN115284703B (en) | Wide low-temperature impact-resistant bending-resistant PVC (polyvinyl chloride) foaming co-extrusion plate and preparation method thereof | |
| CN105331024A (en) | Flame-retardant calendered film and production process thereof | |
| CN109503967B (en) | Cold-resistant-65 ℃ chlorinated polyethylene waterproof coiled material and production method thereof | |
| CN105482387A (en) | Toughening modified transparent PET (polyethylene terephthalate) sheet composite and preparation method thereof | |
| CN1302066C (en) | Method for fabricating hard products of PVC not containing any plasticizer | |
| CN110293726A (en) | A kind of thermoplastic polyolefin water-proof coiled material and preparation method thereof | |
| CN106147063A (en) | PVC heat shrink films | |
| CN101921439B (en) | ABS (Acrylonitrile Butadiene Styrene) calendered substrate and preparation method thereof | |
| CN1408768A (en) | Formulation of full environment protection thermoplastic polyurethane (TPU) film and its calendering production method | |
| CN109867917B (en) | Tough PET (polyethylene terephthalate) antibacterial composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160615 |